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By S. A. Hovanessian

The method of characteristics which reduces the Buckley-Leverett mnlineur, partial differential equation to two first-order, linear differential equations is applied to the solution of a waterffood recovery problem for multiple lines of producing wells and one line of injection wells. The application of the method is described by a numerical example, and a brief theoretical background is given. From the results of this study, it is concluded that the cumulative water injected and oil produced are the same for single and multiple sets of producing wells. INTRODUCTION In this paper, the method of characteristics is applied to the solution of a waterflood recovery problem with multiple lines of producing wells and one line of injection wells. The application of the method to this type of recovery problem considerably simplifies the procedure of obtaining a numerical solution. It differs from the method described by Kern1 because it eliminates the need for integration in obtaining saturation fronts. In addition, the saturation history at any location within the field is obtained from a single diagram (time vs distance with saturation as a parameter)'. The paper includes a brief theory of the method of characteristics and its application to the solution of oil recovery problems. A numerical example is worked out, and the cumulative oil recovery-vs-time curve for a system with multiple sets of producing wells is obtained. This curve is then compared with the recovery curve of a system with only one set of producing wells. From this study, it is concluded that the cumulative water injected and oil produced are the same for single and multiple lines of producing wells. However, the recovery time is considerably longer for multiple sets of producing wells.

By O. N. Cole, R. E. Davis, T. D. Brotherton

Pvfoperties of rubidium and cesium are compared with those of other alkali metals. Methods for the preparation of rubidium and cesium metal are reviewed briefly, ad hazards and safety precautions required in handling rubidium and cesium metal are described. SimPle methods for handling laboratory quantities of elemental rubidium ad cesium under oil and under argon are illustrated. CESIUM and rubidium were both discovered by Bunsen and Kirchoff in the years 1860 and 1861. Cesium was discovered while Bunsen and Kirchoff were making a spectrographic study of spring water from Durkheim, Germany. It was the first element discovered by this technique. The element was given the Latin name "caesius" for sky blue because of the color it imparted to flames. Elemental cesium was first prepared by Setterberg in 1881 through electrolysis of a molten mixture of cesium and barium cyanides.' In 1861, Bunsen and Mirchoff discovered rubidium while making a spectrographic study of the alkali content of lepidolite ore from Saxony. Two prominent dark red lines appeared in the spectrum and so the element was named "rubidius" or dark red. In 1861 Bunsen and Kirchoff first prepared elemental rubidium through the electrolysis of molten rubidium chl~ride.~ The alkali metals are very similar in their chemical and physical properties. They are the most active metals, and all exhibit a single oxidation state of one. They are so reactive that they are never found in nature in the elemental state. The reactivity of he metals increases with atomic number. Rubidiurn and cesium ignite spontaneously in air and react explosively with water. This extreme reactivity makes necessary special equipment and techniques for the safe preparation and use of the metals. The cation: of Group IA can be separated from the metallic cations of other groups with relative ease, but the separation of the individual alkali cations is much more difficult because of their close chemical similarity. This close chemical and physical similarity of alkali metals can be inferred from the atomic radii, oxidation numbers, and ioni-zation potentials shown in Table I. A difficult but the most practical physical method of separating the elemental alkali metals from one another is by distillation. Only lithium has a boiling point sufficiently far-removed from the boiling points of the other alkali metals to make this method of separation feasible without elaborate and expensive equipment. This method is not used, however, for lithium because it possesses sufficient chemical dissimilarity from the other alkalies for it to be separated relatively easily as lithium hydroxide monohydrate or as lithium carbonate. Francium, the last member of the group, has no known stable isotopes. The naturally occurring

Jan 1, 1962

By Louis G. Bailey

This paper .reviews some of the key developments which have been made in the synthesis of the III-V compound semiconductors and the associated progress in obtaining high-quality material for device development. The history of the investigation of the semi-conducting properties of these materials has indicated the need for synthesis techniques capable of producing rnaterial of high chemical purity and physical perfection. The progress in the area is described, and the present status of quality of several compounds is discussed. In addition, recent studies of localized epitaxial deposition of GaAs into semi-insulating GaAs substvates for the development of arrays of devices ave reviewed. In conclusion, some important areas for future research and developrnent are discussed. INTEREST in III-V compounds as semiconductors dates back to the period 1950 to 1952, when Goryunova, Ioffe, and, in particular, Welker determined that 111-V compounds were structural analogs of the group IV elements carbon, silicon, germanium, and tin and that they were also semiconductors.'-3 Since that time interest in the properties of these materials has ex- panded rapidly. During 1953 and 1954, the first reports of rectification, photoconductivity, and optical absorption in these materials came from several investigators. In 1955, recombination radiation from samples of GaAs, InP, and GaSb was reported by ~raunstein .' This radiation was produced by injected minority carriers from point and large-area contacts. From 1955 to 1960, efforts increased on preparing large, pure specimens of these materials for the study of basic physical phenomena and device exploration. By 1960, materials preparation and the understanding of the physics of some of the materials had advanced to where some very interesting and potentially useful phenomena came under study. The first observation of electric-field-induced changes in the optical absorption edge (Franz -Keldysh effect) of 111-V compounds was reported for GaAs by Moss in 1961.' In 1962 the study of recombination radiation advanced rapidly. Keyes and Quist6 and Pankove and Berkey-heiser7 reported high radiative efficientices obtained from recombination, and then the first injection electroluminescent lasers in GaAs were announced by Hall ef al.,' by Nathan et al.,O and by Quist ef al.,'O and in Ga(As, P) alloys by Holonyak and Bevacqua." Hil-sum has reviewed the early work leading to the first observations of laser action in GaAS." Recombination processes in GaAs, Gap, and the other 111-V com-

Jan 1, 1968

By H-S Yang, H Park, S-J Kim, Y-H Ko, H-S Kim, S-H Cho, J-K Kim

An investigation was undertaken to devise a new method for reducing dust spread during blasting demolition utilising water tube and detonating cord. Modelling of smooth particle hydrodynamics (SPH) with AUTODYN software was initially completed to determine the expected diffusing behaviour of the water tube. The actual behaviour was then captured with high speed videos during each experiment, and each result analysed in detail. Water mist diffusion was generated and analysed by changing three key variables. In sequence, these included changing the location of detonating cord in the tube, the charge quantity and the tube diameter.As a result of experiments and simulation, optimum design for ideal diffusion behaviour was suggested and each behaviour of water mist was classified by diffusing shape of water tube as the design criteria.CITATION:Ko, Y-H, Kim, J-K, Kim, S-J, Park, H, Kim, H-S, Cho, S-H and Yang, H-S, 2015. Mist diffusion experiment and evaluation of water tube for blasting demolition dust control, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 809–814 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By H. Y. Sohn

A novel solvent extraction process in which the emulsion is generated by bottom gas injection rather than mechanical stirring has been developed. This process has a number of advantages over the mixer-settler unit or the spray column in terms of simple equipment configuration and the ease of cleaning and process control while providing a large interfacial area for mass transfer. The equipment consists of a horizontal cylindrical vessel in which the two immiscible liquids flow countercurrently. High-strength gas jets are injected from the bottom at certain intervals along the length of the vessel. The gas jet creates a plume zone consisting of an emulsion of the two liquids which contains a large interfacial area for rapid mass transfer. The two liquids then disengage and flow in the opposite directions before entering another plume zone. Thus, the process combines the simplicity of a cylindrical vessel, having no moving parts, with the contacting efficiency of a mixer-settler. The gas can be recycled in a closed loop, thus eliminating mist and other emission problems. These advantages would be especially significant for treating large-volume/low-value liquid streams which contain hazardous substances and/or suspended solid particulates.

Jan 1, 1996

By D. R. Mitchell

FOR the second consecutive year, attendance at the Coal Division sessions far exceeded exoectations. Those in charge were continually faced with problems of finding seats and space for attending members. 115 seats were set - II~ for the annual luncheon meeting of the Division and approximately 175 members showed un. Since the hotel management would not serve more than the 115 it meant that 60 members were forced to eat elsewhere. This created hard feelings with some members. How- ever, officials of the Division were not able to obtain in advance any indication of this overflow crowd, but are suggesting to the New York Office that some means other than ticket sales be adopted to obtain an estimate of Division luncheon and dinner attendance. Members could be circularized prior to he meeting or they could be checked when registering as to the events they expect to attend. Under the inspiring leadership of Cadwallader Evans, Jr., Chairman, the Coal Division had a phenomenal growth during the year. Reporting at the luncheon meeting, Newel1 Alford stated that approximately 190 new members had been obtained. A few more years of continuing increase at this rate will make the Coal Division one of the largest Divisions in the Institute.

Jan 1, 1944

By Peter Grandone

Steel and iron pipe lined with cement to protect it against corrosion has been used in the municipal water systems of the New England States since about 1870. In most recent years, the petroleum industry adopted cement-lined pipe to forestall corrosion, particularly in those areas where large quantities of corrosive brines and hydrogen sulfide are associated with the oil produced. Many of the oil companies had on hand large quantities of corroded pipe, normally disposed of as scrap, which could be cleaned, lined with cement, and returned to service. It was soon learned that after the so-called scrap pipe was lined with cement much of it could serve fully as well as new cement-lined pipe. The demand for lining used pipe with cement resulted in the establishment of several processing, plants in the Mid-Continent oil-producing area. Today six cement-lining plants serve the areas three in Oklahoma and one each in Kansas, Texas, and Illinois. All of these plants have lined large quantities of used pipe for the brine-disposal systems of western Kansas, Illinois, and east Texas and also for the operators of water-flooding projects in northeastern Oklahoma and southeastern Kansas, where large quantities of brine and fresh water are being injected into the oil-bearing formations as a secondary oil-recovery method. Since war demands during the past 2 years have created an acute shortage of steel, the need of reclaiming used pipe for the expansion of oil-producing operations has become more evident than ever before. Thus the new industry (about 6 years old) - lining used pipe with cement - is saving large quantities of steel at a critical time by reclaiming used pipe and preventing further- corrosion.

Jan 1, 1945

By R. Rushforth

The surge of activity in the solar energy market, spurred by government incentives, has created new and more efficient solar technologies, but issues surrounding land- and water-use have backlogged the full-scale development of solar farms. This paper explores siting solar power plants on degraded or polluted lands, such as mine tailings impoundments. Historically, mining and has been integral to Arizona?s economy, but has dwindled in relevance due to urban pressures and environmental regulations. Currently, it is legal to site solar power plants on degraded or polluted lands, but the question remains whether the economics of this degraded lands solar development is more favorable than developing pristine land. Therefore, we explore economics of developing mine tailings impoundments at both the institutional and financial level. Methods of research for this paper were interviews with government regulators, environmental advocacy organizations, farmers, and mining company executives. Financial models using extant tax incentives show a positive net present value for the installation of solar power plants, even when accounting for the costs of land remediation.

Jan 1, 2011

By George W. Toth

In a recently completed research project for the U.S. Bureau of Mines - Twin Cities Research Center, a computerized costing procedure for uranium in situ leach mining was developed by the NUS Corporation. This costing procedure, termed a cost model, employs a process engineering approach for estimating total project costs as well as equipment and manpower requirements for uranium in situ leaching operations in either Texas or Wyoming. 80th capital and operating costs are generated by the model along with the overall production cost/pound U3O8 subject to a known rate of return. Conversely, rate of return on equity can be solved for, subject to a given price of yellowcake. During the course of the research effort, this cost model was applied 50 typical site conditions in Texas and Wyoming. Sensitivity rests were conducted for numerous key parameters to determine the cost influence attributable to incremental changes In parameter values. The results of these sensitivity tests along with a description of the in situ leaching cost model have been documented as Bureau of Mines, Mineral Research Contract Report No. J019912, "Cost and Sensitivities Analysis for Uranium In Situ Leach Mining," dated March 1981.

Jan 1, 1981

By M. Muravyov, T. Kondrat’eva, A. Bulaev

Metallurgical treatments of sulfide ores containing copper and zinc are characterized by significant losses of base metals, particularly formation of the flotation tailings and slags during the dressing and pyrometallurgical treatment respectively. In addition, SO2 gas obtained during roasting and converting may be as raw material for sulfuric acid production. A treatment of the industrial metallurgical wastes has been investigated. Two samples of old pyrite tailings from two concentrators that contained 0.36% and 0.26% of copper and 0.23% and 0.22% of zinc were leached with 10% sulfuric acid in the column. Recovery of copper reached 47% and 38% while recovery of zinc was 47% and 41% from the first and second samples, respectively. The pregnant leach solutions contained 15.9 g/l and 10.5 g/l of ferric iron. Ferric iron is the strong oxidant and ferric containing pregnant leach solutions can be used for ferric leaching of different types of raw materials containing sulfide minerals. Therefore, ferric leaching of copper converter slag flotation tailings contained 0.53% of copper and 2.77% of zinc with the first pregnant leach solution was conducted. The effect of various experimental parameters on the leaching dynamics of copper, zinc, and iron under batch conditions was investigated. Under the best conditions (temperature 70oC, pulp density 30%) the recovery of copper and zinc reached 80% and 42%, respectively. Thus, it has been shown that acid leaching of base metals from old pyrite flotation tailings with using of the pregnant leach solution for the ferric leaching of copper converter slag flotation tailings is a prospective technique for the complex treatment of mining and metallurgical wastes. Investigated processes could be introduced into the technological flow-sheet of typical pyrometallurgical plants.

Jan 1, 2014

By David S. Yang, Osamu Taki

The innovative Soil-Cement Mixing Wall Technique, developed independently in Japan, consists of mixing in-place soils with cement grout using multi-axis augers and mixing paddles to construct overlapping soil-cement columns. The applications of overlapped soil-cement columns include cutoff walls for groundwater control and structural diaphragm walls for excavation support. The special features of this technique include water tightness, versatile strength design, and efficient installation in subsurface materials varying from clayey soils to cobbles or soft rocks. Through the introduction of two recent subway projects in Japan, this paper presents the design parameters, construction procedure, quality control and performance of soil-cement wall for excavation support and groundwater control.

Jan 1, 1989

By Tsuyoshi Adachi

Photovoltaic (PV) system is especially taken notice as one of important renewable energy resources, because PV has potential to provide a certain amount of energy supply as well as without greenhouse gases emission. Considering recent rapid increasing demand for PV system, more expansion of PV system is expected in the future. However, some precious metals and minor metals such as silver, indium and others are used as component materials of solar cell in PV system. Even if energy supply would become renewable, strict limitation of these metals still remain because amount of natural resources and recycling of metals has restrictions intrinsically. The aim of this study is to reveal the possibility of materials supply restrictions for Photovoltaic system quantitatively and to propose several measurements to assess supply risks for materials. Especially, silver supply potential which is used as wire line in PV system as well as PV demand forecast to estimate material use in the future are focused on. We divide underlying supply risk into 5 measurements and analyze them by time series, i.e. price volatility, resource potential, recycling ratio, production type and supply concentration are investigated. Comparing these factors of silver with other metals, the potential of silver supply for PV is presented. In addition to it, we propose another method to quantify country risk applied an insurance pricing model in finance pricing theory and combine it with the supply concentration measurement. As a result, supply risk of silver will increase gradually in the near future because of its resource constraints and supply-demand balances although silver market is sufficiency competitive one. From the country risk analysis, Peru is not only a significant supply country but also has the highest country risk. Some higher risk countries will increase the level of supply risk even if the concentration ratio of supply indicates moderate level.

Aug 1, 2013

By Renato G. Bautista

"The development of processing methods for the preparation .of three electronic materials with rare-earth components is discussed. The resulting processing innovations are the results of a search for an economically competitive pilot scale or industrial production flowsheet without compromising the required properties of the final products. The three cases highlighted in this presentation are: 1) The preparation of high energy (Pr-Nd-Ce)FeB magnets for MRI application from a mixed-rare-earth oxide with a narrow range of composition directly prepared from the solvent extraction circuit of bastnaesite ore. 2) The kg production of the giant magnetocaloric effect Gds(SixGe1-x)4 magnetic refrigerant materials from commercial grade gadolinium metal (95 to 98 at. % pure) instead of high purity gadolinium metal (99.8 at. %); and 3). An industrial chemical synthesis flowsheet for the production of the superconductor precursor of YBa2Cu3O7.INTRODUCTIONIn the laboratory discovery stage, the synthesis of a new material is carried out using very high purity components, usually the highest purity available. As the new material is studied and characterized, the effectiveness of its desirable properties becomes better defined and understood. The evaluation of the effectiveness of the .property over the range of a given parameter and other interactions are further studied. Once it's potential application becomes clear, a practical and economical processing method need to be developed. The successful material processing flow sheet does not necessarily have to be a scale up of the laboratory procedure. At this stage, substitution of starting components and with lower purity materials is considered as the economics of the processing becomes a major issue. In addition, other approach to it's synthesis"

Jan 1, 2000

By Apostolos Vrakas, Georgios Anagnostou

"INTRODUCTION The small strain assumption routinely made in tunnel analyses remains sufficient from an engineering point of view as long as convergences do not exceed 10%. More specifically, small strain theory assumes that deformations are so small (in relation to the size of the underground opening) that any geometric change in the continuum can be disregarded (Fig. 1a). In fact, however, the geometry is updated during loading (or unloading) according to large strain theory and thus equilibrium and stiffness are evaluated on the deformed configuration of the continuum (Fig. 1b).In problems involving large deformations, where the undeformed and the deformed tunnel geometry differ significantly, small strain theory leads to erroneous and sometimes even nonsensical results (i.e. it can predict wall displacements even greater than the excavated radius under conditions of very low stiffness and strength, high in situ stress and low support pressure). This can easily be verified from the widely applied relationships for the ground response curve. For example, in the ideal case of linearly elastic behaviour, the convergence of an unsupported opening equals (1+?) s0 / E (where E, ? and s0 denote the Young’s modulus, Poisson’s ratio and initial isotropic stress, respectively) and is greater than 100% for E < (1+?) s0. Although convergences are less than 10% in the great majority of tunnelling projects, very large deformations may take place when tunnelling through weak rocks under a high overburden (Fig. 2). This paper will first present a very simple and practicable way to account for large strains, based entirely on the results of routine small strain analyses, and will subsequently show the importance of addressing large strains in tunnel analysis and design with reference to three typical case studies of tunnelling in squeezing ground."

Jan 1, 2016

By H. C. George

With a growth of 718 per cent in the petroleum industry from 1901 to 1931, there was a corresponding increase in the demand for technically trained men in the industry. This was first met by increasing numbers of college graduates from the old established courses in chemistry, geology and engineering. However, a need began to be felt for scientists and engineers specially trained for the petroleum industry. In 1912 the University of Pittsburgh established the first department in any university in the world that offered major work in petroleum engineering and petroleum geology. In Europe, the first major work in petroleum engineering was offered in England in 1913 at the University of Birmingham. The University of California and Stanford University offered major work in petroleum engineering in 1915. Since that time at least 10 other American universities and colleges have offered major work and at least 12 others are now offering some courses dealing with petroleum and the petroleum industry.

Jan 1, 1934

By David Martin Menne, Chris Campbell-Hicks

Optimisation of many oxide gold processing facilities, in most cases, either does not really take place or if it does take place it happens too late or takes too long. This is unf01tunate as extra profits and early cash flows are lost, in new projects, and/or may not be realised at all in others. The situation is easily avoid­ed by ensuring that the plant optimisation happens immediately following commissioning or for an established operation simply 'biting the bullet' and making it happen immediately as a 'better late than never' decision. This type of optimisation requires intense undiluted focus on each and every problem or restriction that contributes to reduced plant performance or bottlenecks, without letting go, until the predetermined outcome is produced. Thus a dedicated person with specific quantative goals is required for these tasks. Methodology and strategies for optimi­sation are discussed and numerous examples presented. The secret of successful heap leaching is discussed.

Jan 1, 1998

By Chi-Yuen Wang, Chaw-Long Chu

The time-dependent volumetric constitutive relation for a San Andreas fault gouge and a consolidated kaolinite are experimentally determined at confining pressures to 200 Mpa, under creep condition and at ultrasonic frequency. At any given pressure, the bulk modulus determined at 1 Mhz frequency is identical to the "elastic" modulus determined at a stepwise change of pressure. After the pressure change, there occur a time-dependent change of volume and thus the effective bulk modulus. The constitutive relations may be modeled by a standard linear viscoelastic medium with pressure-dependent moduli and viscosity. For the San Andreas fault gouge, viscosity increases from 2x10 13 poise, at 17 Mpa, and 10 14 poise, at 100 Mpa. For kaolinite sample, the corresponding values are 3x10 12 poise and 10 13 poise. These results imply that both stress and pore pressure in fault zones may show time-dependent variations in response to a change of state of stress, such as that occurring after an earthquake.

Jan 1, 1982

By Z. T. Bieniawski, D. A. Newman

The Geomechanics Classijication (RMR System) (Bieniawski, 1979) was modified for entry and roof support design in underground coal mines. Adjustment multipliers were introduced to incorporate the influence of high horizontal stresses and the roof support reinforcement into the existing classification system. Sixty- two case histories of standing and fallen mine roof were collected from two mines in the northern Appalachian coalfield. Twenty-seven engineering and geologic parameters were recorded for each case. A partial correlation analysis was carried out on the cases to establish which parameters have a significant im- pact on the stand-up time of supported coal mine roof. Survival analysis, a statistical technique used in medical research to assess the effect of a drug or treatment on a patient&apos;s life expectancy, was conducted together with stepwise multiple regression to derive values for the adjustment multipliers. A practical example is included to illustrate the application of the modified Geomechanics Classification to underground coal mine design.

Jan 1, 1987

In late November 2010, a Laotian landmark was achieved for the country?s first tunnel boring machine - (TBM) driven tunnel. Italian contractor CMC di Ravenna celebrated the breakthrough of a 7.6-m- (25.1-ft-) diameter Robbins single shield TBM for a hydroelectric tunnel on the Nam Theun River. The Theun Hinboun expansion project and 5.5 km (3.4 miles) headrace tunnel will bring much needed power in-creases to Laos and Thailand. . ?Since this is the country?s first machine, it has awakened people?s curiosity and interest. We had experienced Italian and Chinese crew members, but we also trained many Lao workers during the course of the project, as this was something they had not seen before,? said Luca Barbàra, Far East Manager for CMC di Ravenna. The machine broke through on Nov. 21 into an exit shaft close to the intake structure on the river. The machine is now being disassembled and removed - CMC hopes to use it on upcoming projects in the region. Due to the current rainy season and relative low level of the tunnel, the last 100 m (330 ft) up to the intake structure will be completed using drill-and-blast after the waters recede below the tunnel invert.

Jan 1, 2011

Determine the minimum waterflow rate needed for effective control of dust produced by cutting machines used to mine water-soluble ores. Approach Conventional wet-bar cutting techniques were studied to evaluate their dust control performance, and the optimum water flow needed for dust suppression was determined. Wet-bar type cutting techniques are used to help control mine dust by keeping the cutting chain wet. As the chain cuts the kerf, it dampens the dust produced by the cutting action at the point of generation. The Bureau, under contract, evaluated three basic wet-bar techniques, as shown in the diagram: water-trickle system A uses a gravity-feed or low-pressure (less than 50 psi) pump to send water through the bar and to discharge it at the bar tip. Water-spray system B uses a low-pressure spray nozzle located at the front of the cutter head. For protection the nozzle can be located within the cutter

Jan 1, 1982