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By P. L. Woolf

Three trials with oxygen-enriched unheated blast air are described. The trials were conducted in the Bureau of Mines experimental blast furnace located in Bruceton, PA. The first trial utilized moisture addition to the oxygenated blast. The second and third trial were conducted with natural gas injection. The test was basically a feasibility study and in that regard the practice was demonstrated to be feasible and also have possible advantages over hot blast operation. The testwork was conducted in 1964 and 1965 as part of a continuing study of iron making technology in cooperation with several North American Steel Companies.

Jan 1, 1985

By T. I. Moore, L. A. Painter

THE electrolytic zinc plant of the American Zinc Co. of Illinois was described by Davidson' in 1944. Since then, improvements as well as expansion of the plant facilities have been made. In order to increase the production of high grade zinc which was needed for war purposes, an expansion program designed to double the slab zinc capacity was started in 1942 and completed in March 1943. This expansion was propagated by a contract between the American Zinc Co. of Ill. and the Defense Plant Corp. The contract included the facilities of the Fairmont City, Ill., property of the American Zinc Co., where a suspension-type roaster with contact acid plant, cadmium distillation furnace, Waelz oxide and densifying plant, and horizontal retort furnaces were installed. The expanded Monsanto, Ill., plant and the additional facilities of' the Fairmont plant were designed to integrate the metallurgical treatment of zinc concentrates for the production of special high grade zinc at Monsanto with the production of acid, cadmium, high grade zinc from furnace skimmings and the Waelz treatment of leach residue at Fairmont. In general, the original flowsheet was not changed, except for the addition of the filtering, drying and reclaiming of leach residue, and the treatment of purification cake for the recovery of copper, cadmium sponge, and zinc. Fig. 1 is a flow diagram of present operations. The original plant facilities, desi-gned for 50 tons daily production of slab zinc, had some units which were more than adequate. Therefore, in expanding the facilities to 100 tons per day, it was not necessary to double all operating components. Table I gives the comparison of the changes made in the unit operating components for the original facilities, 1941, the 1943 expansion, and the 1951 facilities. During the past 11 years a number of improvenients have been made resulting in: 1—an increase in slab production, 2—higher recoveries on the calcine treated, 3—better quality of slab zinc produced, 4—higher current efficiencies, and 5—less man hours Table I. Changes in Operating Facilities Operating Unit 1941 1943 1951 Calcine unloading (pneumatic), 10 tons per hr 12 calcine unloading track hpr. and elev., 60 tons per hr 1 Calcine storage, tons 1,000 2,000 2,000 Leach tanks, 35 vol. tons. No. 3 5 6 slurry mixing 6x6 ft stainless tank, No. 1 Ball mill. 4.5 rt x 16 in. conical. No. 1 CLassifier duplex, No. 1 1 Thickeners. 50 it diam. No. 2 9 2 Filter thickeners, sq ft '-- Moore filters, sq ft 5.760 11,520 Drum filters, 10 ft diam x 16 ft, No. 3 3 Rotary arlers, No. 1 2 1st stage Cu-As purificatlon tank. 90 vol. tons, No. 3 Solution heaters, No. 3 Filter press, 30x30 bronze, No. 4 Zinc dust purification tanks, 45 vol tons. No. 3 5 4 Filter press, 36x36 bronze, No. 3 5 3 Cadmium recovery plant: Process tank. No. 5 2 Cake roaster, 20 ft diam x 4 hearth. No. 1 Filter press, 24x24, No. 4 1 Sponge wash box, 4x6 ft, No. 1 Evaporative cooling unit (vacuum), No. 1 Purified storage tank, vol. tons 400 400 400 Cell acid storage, vol. tons 400 400 400 Electrolytic cells, No. 180 372 372 Cell room ventilation, cu ft per min 35,000 125,000 125,000 Cell cooling water. gal per min 1,500 2,300 2,300 Deep well 16 in. x 95 ft, 1500 gal per min, No. 2 3 3 Melting and casting furnace, 130 ton. No. I Furnace fume scrubber unit, No. 1 Dross drums, No. 2 Dross roaster, 8 ft diam x 8 hearth, No. 1 Electrolysis power conversion, kw 6,250 23,750 23,750 Power transformers, 13,800/440, kva 1,000 1,500 2,000 Steam boilers fire tube, 15 psi, lb per hr 12,000 18,000 18,000 Steam boilers water tube. 125 psi, Ib per hr 30,000 Air compressor, 2 stage. 300 cu ft per min. 100 psi, No. 1 2 Air compressor, 1 stage, 300 cu ft per min, 20 psi, No. 1 Vacuum pumps, 18x7, 720 cu ft per day, No. - - . Vacuum pumps, 24x11, 1.633 cu ft per day, No. 3 3 Building area, sq ft 60,854 113,568 115,000 per ton of metal produced. In the summer of 1944, the "reverse" leaching process was placed in operation and since it has been described,' no further description will be given. Other facilities and changes which have contributed to the process improvements were the scrubbing of fume from the melting and

Jan 1, 1953

By Karl A. Higgins, Michael D. Venezia

The South Capitol Street Corridor Project is one of the District Department of Transportation’s (DDOT) largest projects, and is currently under construction. This case study will focus on the design of the foundation piles for the main spans of the iconic Frederick Douglass Memorial (FDM) Bridge, and will include a discussion of the foundation design evolution from an originally designed alternative foundation system (i.e. coffer dams and drilled shafts), to the current use of driven Large Diameter Open End Pipe (LDOEP) Piles. The paper will provide a discussion of the design methodology used during preliminary engineering and final design, and will highlight insight gained from the extensive load testing program completed to date. The load testing program consists of a combination of high strain dynamic testing (PDA), as well as Statnamic Load Testing on select sacrificial, pre-production test piles. Specifically, data gathered during the nearly-completed load testing program suggests the development of significant internal shaft frictional resistance within the tested LDOEP Piles. This paper will also discuss limitations of currently accepted industry design methods for predicting the capacity of LDOEP piles, a subject that is also currently being researched by FHWA. The data from this test pile program will help design assumptions for future projects. INTRODUCTION The Frederick Douglass Memorial (FDM) Bridge carries South Capitol Street across the Anacostia River in Southeast/Southwest, Washington, DC, and is owned and maintained by the District Department of Transportation (DDOT). The existing FDM Bridge is nearly 70 years old, serves as a major artery into the city, and has been classified as functionally obsolete. As a result of the condition, age and limitations of the existing bridge structure, DDOT deemed it necessary for complete replacement of the bridge. The replacement project consists of the construction of a new bridge traversing the Anacostia River, as well as the reconfiguration of the Suitland Parkway and I-295 interchanges located at the eastern terminus of the FDM Bridge. Final design and construction services for the replacement project were procured by DDOT through a Design-Build contract. This paper will focus on the driven Large Diameter Open End Pipe (LDOEP) Piles used for support of the main span of the new FDM Bridge which is currently under construction. Discussion regarding the LDOEP Pile design methodology has been included, along with commentary regarding currently available industry guidance related to design and construction of LDOEP Piles. Much insight has been gained during the mostly-completed and extensive load testing program which consists of a combination of high strain dynamic testing (PDA), as well as Statnamic Load Testing on select sacrificial, pre- production test piles. Specifically, data gathered during the mostly-completed load testing program suggests the development of significant internal shaft frictional resistance within the tested LDOEP Piles.

Jan 1, 2019

By O C. Aitken

Mining project developers are committed to taking on all the challenges and obligations of financial risk management. It is interesting that our current models of project finance have not changed markedly in principle for some 700 years, yet the rules which prepare the way for effective project assessment and subsequent loan management still do not seem to be well understood by project or corporate developers. Probability and gravity fill the opposing trays of the golden balance of financial risk. Understanding the relationship between these opposing, but intimately related elements is critically important for successful risk management. It is important to move beyond the qualitative approach and use quantitative methodologies to measure the financial impact of the occurrence of each major risk. We live in a world where the only constant is change and thus it is not surprising that a bankerÆs life is still governed by assessing, measuring and pricing risk. Banks are attracted to funding well managed companies with strong cash flow projects. But we are more risk averse compared with the credit appetites of late last century. This attitudinal shift has resulted in tougher term sheets for the early 21st century, encompassing more conditions, warranties, undertakings and stronger cash sweep provisions. Banks require well balanced portfolios to achieve an acceptable spread of risk, thus there is a more restricted market for small company lending than that available to large multi-project corporate entities with less concentrated risk profiles. Because of this focus, junior company debt finance remains comparatively expensive and especially so for more challenging geographical and political environments.

Jan 1, 2004

By Noel Jarrett

Energy consumption and distribution in aluminum production, conservation accomplishments, and future goals are presented. Electrolysis and electrode manufacture show the greatest promise for major improvements. Means are proposed for reducing waste heat generation in smelting and for conserving energy in anode manufacture by furnace design and substitution of other materials for petroleum coke. Hall-Heroult Process modifications, alternative designs, and the Alcoa Smelting Process are discussed as energy savers. Scrap recycling, more use of aluminum in transportation, and the installation of offshore smelters in less developed countries are shown to be additional means of coping with possible energy dislocations.

Jan 1, 1981

By F. E. Brantley, D. M. Yergensen, D. A. Martin

Fluidized - bed roasting was investigated as a means of decomposing gypsum and gypsum mixtures to produce a gas rich in sulfur dioxide and a lime or portland cement residue . Ninety- eight percent desulfurization of gypsum in a 10 - inch fluidized- bed reactor took 1.5 hours at an operating temperature between 1,200 ° and 1,225 ° C. A cement- type residue was obtained but had to be refired at 1,450 ° C before mortar prepared from it met the physical specifications for cement .

Jan 1, 1963

By Katherine A. Klein

Refuge chambers may potentially save the lives of miners during a mine emergency. For this reason, it is crucial that miners know how to operate them. Unfortunately, because refuge chambers provide so many services, they can be very complicated and difficult to operate. Therefore, NIOSH has created this document with suggestions for developing manuals and educational materials. A multidisciplinary team comprised of NIOSH engineers, sociologists, psychologists, health communication professionals, and geologists developed the recommendations contained in this document. These recommendations are based on an evaluation of manufacturers? instruction manuals from both the U.S. and globally, interviews with over 20 mining and safety experts, and an extensive literature review. This research, focused on the best practices for refuge chambers, led to the formulation of this document. It is intended to offer suggestions to manufacturers and mine operators on how to create effective and easy-to-understand training manuals for miners as well as tips to create the most comfortable and usable refuge chambers. It should be noted that these recommendations are not meant to substitute for manufacturer-supplied materials but rather to be used in conjunction with manufacturer?s materials. Manufacturers should always be consulted for up-to-date information about their chamber. Although different states and different mines refer to underground refuges by different names, this guide will simply refer to underground refuges nearest to the face as refuge chambers, whether inflatable from a skid or constructed from steel. Other popular terms for refuge chambers are rescue chambers, rescue shelters, and refuge shelters. Refuges that are nearer to the shaft, whether a prefabricated refuge chamber or one built into a crosscut, will be referred to as outby refuges because of their location in the mine. Outby refuges can be permanent, semipermanent, or portable and are usually located at every other SCSR cache. Outby refuges are sometimes called hardened rooms, outby shelters, and in-place shelters. When discussing outby refuges and refuge chambers collectively, this guide will refer to them as underground refuges. Other terms for underground refuges include refuge alternatives, locations of safety, and safe havens. This document is designed to be read either cover to cover or by specific section. It is recommended that on first read, this guide be read cover to cover. In subsequent readings, manufacturers and mine operators may find it easier to use the table of contents page to locate specific information on parts of the refuge chamber.

Jan 1, 2009

By M. Szumny, P. Mertuszka, K. Fuławka

Mining-induced seismicity is one of the adverse side effects of mining with the use of explosives at great depths. Disturbance of the primary stress state by the development of the network of excavations combined with the continuous generation of dynamic loads by the detonation of explosives in mining faces has a negative impact on the level of safety of crew and machines. To ensure the stability of excavations it is necessary to identify in detail the nature of the seismic hazard by means of continuous seismic measurements. Unfortunately, the technologies used so far are characterized by high costs of installation and further maintenance, which clearly limits the possibility of using a large number of stations in a small area. A breakthrough in this matter may be the technology of microelectromechanical systems, which is several times cheaper than standard solutions used in mining seismology. This technology, with the appropriate configuration of devices, can be successfully used to monitor dynamic phenomena generated by mining activities. As part of this study, the assumptions and configurations of a prototype 42-channel accelerometer network using MEMS technology have been presented. The network was installed in the Lubin underground copper mine in Poland in a seismically active area, where multi-face destress blasting are conducted regularly. As a result, 14 tri-axial accelerometers were installed in the immediate vicinity of the active mining front at a distance of about 1,000–4,000 ft (300–1,200 meters) from the closest faces. Highfrequency recordings are collected based on algorithms that trigger the system when the Peak Particle Acceleration set value is exceeded or on the basis of a manual external triggering device connected to the blasting machine. During the measurement period, several high-energy seismic tremors and several dozen of waveforms generated by blasting were recorded. The obtained results are the basis for assessing the effectiveness of the destressing measures and for the analysis of geomechanical risk based on periodic analysis of the velocity of seismic wave propagation

Jan 1, 2024

By Robert J. Anderson

"Introductory Statement:In melting the nonferrous metals and alloys for foundry and rolling-mill work, even with the best practice, there is always a loss, due principally to oxidation. Melting losses are a serious source of financial loss in brass and bronze practice, but they are especially serious in the case of aluminum and its light alloys because of the relatively high price of aluminum. The indications are that the melting losses in many aluminum foundries of the United States are at times high, and in some plants (especially where certain furnaces are used) they are entirely too high when compared with the average practice. The fact that the oxidation losses in melting aluminum and its light alloys are high is well known, but it is doubtful whether the factors governing the most suitable methods of melting for a minimum of dross are equally well known. The metal losses involved in melting are worthy of especial attention now because of the rapidly growing importance of the aluminum industry.Factors in the operation of furnaces which affect metal and fuel losses:The essential requirements in the commercial melting of any metal or alloy are that the melting losses should be low, the melting should be rapid, and the melting cost should be low. Certainly it may not be possible to obtain these requirements in any furnace selected at random, and it follows that the design and the operation of furnaces for melting different metals are subjects that warrant the most extensive study and tests. As a general rule, in the industrial operation of furnaces, run on aluminum and aluminum alloys, an effort is made to keep the dross and oxidation losses as low as possible. In attempting to hold dross losses low, numerous factors involved in metal melting may be overlooked, or at least disregarded, and the net practical result may be that the furnace is exceedingly wasteful of fuel. In the case of aluminum and its light alloys, the effect of increasing the temperature of melting, at least in an atmosphere containing free oxygen and nitrogen, is to increase the net melting loss."

Apr 1, 1921

Knowledge of the crystal chemistry of carbonate apatites is very important for the development of the concept of biomineralisation and the creation of a scientific base for new biocompatible materials for medical purposes. The present work is devoted to research results on various synthetic and biological carbonate apatites obtained at Saint Petersburg University over many years. All-important problems will be considered such as the location of CO32- ions in the apatite structure, the ionic substitutions in various biological apatites and the development of synthesis methods for their analogues. Syntheses of apatites were realised by precipitation methods and under hydrothermal conditions (from solid compounds and by calcite treatment). Biological samples used in this study were physiogenic and pathogenic apatites formed in the human organism, eg in teeth and in renal and salivary stones and dental calculi as well as apatites from fossils of different taxonomic families (brachiopods, conodonts, fishes, reptiles, mammal) with different geological ages and burial conditions. The study of the crystal chemistry of carbonate apatites has been carried out by powder (including high-temperature measurements) and single-crystal X-ray diffraction methods, IR-spectroscopy, thermal analysis and various chemical analytical techniques.

Jan 1, 2008

By C. H. Veloso

"Starch is the most widely used depressant in the reverse cationic flotation of iron ores. There is however, an indication from recent studies, that other polysaccharides may successfully replace them. When starches are used in the flotation of iron ores in the presence of quartz as gangue mineral, their strong adsorption on the surface of iron oxides can be explained by the molecular conformation between the available sites on the mineral surface and two hydroxyls of starches. However, when the gangue minerals are iron-bearing silicates, the strong interaction with starch can occur on these minerals since they have the same surface behaviour as iron oxide. In this work bench scale tests were conducted in order to generate scientific knowledge about other alternatives depressants for the flotation of iron ores. A magnetic pre-concentrate from a skarn iron ore processing plant was used as feed material for flotation tests. The reverse flotation approach was used to upgrade the iron content by removing complex ironbearing silicates. The depressants used in this study were: corn starch, dextrin, carboxymethyl cellulose (CMC) and humic acid. The tests were performed under different pH conditions in order to try to relate the efficiency of depression to the pH used during flotation. The results show the important role of pH as each depressant reached its best performance at different pH values. At alkaline pH the corn starch showed best depression performance while the humic acid is more efficient at pH close to neutrality.INTRODUCTIONIron corresponds to approximately 6% of earth’s crust composition (McDonough and Sun, 1995). It is the most used metal in our lives, some of its properties as resistance and facility to be shaped makes is replacement very difficult. The primary sources of iron on our planet are minerals. The iron-bearing minerals most commonly found in nature and economically exploited are magnetite [Fe3O4], hematite [Fe2O3], goethite [FeO(OH)] and siderite [FeCO3] (L O Filippov et al., 2014). These minerals are commonly associated with other minerals (most of the time not economically exploited) forming the so-called iron ore. Iron ore is the source of primary iron for the world’s iron and steel industries."

Jan 1, 2018

By MALCOLM FRASER

I was delighted to be invited to be patron of this Joint Conference, but the challenging task you have set yourselves, and your speakers' depth of expertise, deny anyone, even the patron, the opportunity to be patronizing. Australia's history has been inextricably linked with the fortunes of our great mining industry. That link will remain. Just as the gold rushes of the last century, and the discoveries at Kalgoorlie and Broken Hill changed the lives of generations, so the more recent development activity in iron ore, bauxite, nickel, coal, and uranium are having a significant impact on the lives of Australians today. The minerals industry has contributed to Australia's jobs and prosperity. Mining is not free of problems, but so long as safeguards are strong and appropriate the net benefits the mining industry brings Australia will continue to be enormous. We rely on our mining industry to find, prove, develop and sell our minerals profitably, and my Government is committed to maintaining a healthy mining industry. In the past year there have been positive signs of a resurgence in exploration and development. The North-West Shelf ventures are spending $50 million on a feasibility study to work out the extent of future investment in that project; exploration expenditure for minerals other than petroleum increased by 34 per cent in 1976-77 to $134 million; petroleum exploration increased dramatically last year almost doubling to $94 million-this year it is projected to reach $125 million.

Jan 1, 1978

By Frederick Bloetscher

An improved parachute-type stopping for changing the course of mine ventilation air during mine emergencies has been developed by Goodyear Aerospace Corporation for The Bureau of Mines. The stopping can be quickly deployed by one man from a single attachment point and provides excellent stopping performance with the flow in the design direction. Adding pin and foam attachments between its skirt and the passage-way surfaces improves its performance with flow in the design direction and maintains the stopping with zero or reverse air flows. Stopping performance results for a range of airway sizes including 7.5 X 10 ft simulated airway with pressure differentials of up to 3.0 inches of water are presented. Predicted performance values for this stopping design for larger passageways are also presented.

Jan 1, 1977

By P B. Hills

Increasingly over the past couple of decades, the importance of understanding the in situ stress regime in underground hard rock mines has become accepted by all. Providers have responded to this requirement and various techniques for undertaking the measurements have been honed while others have slipped from use. It is a simple, though not inexpensive task to engage a provider to undertake the require measurements, and a comprehensive report will ensue. So, what has actually been obtained? What should the geotechnical engineer do next? What tools are necessary to do so? Regardless of the method of measurement, the report will describe the location of the measurement site and describe the basis of the methodology used in undertaking the measurements and a log of the measurement program. Finally, it will include the results, which should incorporate the normal and shear stress components of the full stress tensor. Ground control management plans (GCMP’s) and stress summary reports and spreadsheets prepared by site geotechnical engineers always include the magnitude, trend and plunge of the principal stresses. Remarkably few site-based summaries include the full stress tensor. This is a significant gap as the full stress tensor is vital for any further data manipulation. However, without the algebraic tools to undertake those manipulations, their value is diminished. This paper seeks to provide a checklist of ideas to be considered. It provides commentary on the options available to dissect the stress measurement report and ensure that the maximum possible value is derived from it. The manipulation and presentation of component stress data is also discussed. The various methods of stress measurement are not the focus of the paper but some of the strengths and weaknesses of them over which the site geotechnical engineer has some control, are highlighted.

Nov 29, 2022

By Sean Gallagher, William S. Marras, Alan S. Litsky, Velimir Matkovic, Deborah Burr, John Landoll

Study Design. Survival analysis techniques were used to compare the fatigue failure responses of elderly motion segments to a middle-aged sample. Objectives. To compare fatigue life of a middle-aged sample of lumbosacral motion segments to a previously tested elderly cohort. An additional objective was to evaluate the influence of bone mineral content on cycles to failure. Summary of Background Data. A previous investiga¬tion evaluated fatigue failure responses of 36 elderly lumbosacral motion segments (average age, 81 ± 8 years) subjected to spinal loads estimated when lifting a 9-kg load in 3 torso flexion angles (0°, 22.5°, and 45°). Results demonstrated rapid fatigue failure with increased torso flexion; however, a key limitation of this study was the old age of the specimens. Methods. Each lumbosacral spine was dissected into 3 motion segments (L1-L2, L3-L4, and L5-S1). Motion segments within each spine were randomly assigned to a spinal loading condition corresponding to lifting 9 kg in 3 torso flexion angles (0°, 22.5°, or 45°). Motion segments were statically loaded and allowed to creep for 15 minutes, then cyclically loaded at 0.33 Hz. Fatigue life was taken as the number of cycles to failure (10 mm displacement after creep loading). Results. Compared with the older sample of spines, the middle-aged sample exhibited increased fatigue life (cycles to failure) in all the torso flexion conditions. Increased fatigue life of the middle-aged specimens was associated with the increased bone mineral content (BMC) in younger motion segments (mean ± SD, 30.7 11.1 g per motion segment vs. 27.8 ± 9.4 g). Increasing bone mineral content had a protective influence with each additional gram increasing survival times by approximately 12%. Conclusion. Younger motion segments survive considerably longer when exposed to similar spine loading conditions that simulate repetitive lifting in neutral and flexed torso postures, primarily associated with the increased bone mineral content possessed by younger motion segments. Cycles to failure of young specimens at 22.5° flexion were similar to that of older specimens at 0° flexion, and survivorship of young specimens at 45° flexion was similar to the older cohort at 22.5°. Key words: biomechanics, low back disorders, fatigue failure, age, motion segments, vertebral endplate fractures, torso flexion, lifting, bone mass. Low back disorders (LBDs) are a major cause of both short- and long-term occupational disability in the United States, and it is clear that workers in certain occupations are more susceptible to LBD.2-5 Specifically, epidemiologic studies have shown that jobs involving heavy physical demands such as construction,2,3 mining,2,4 and farming,5 engender increased risk of back pain. These occupations are thought to experience high LBD rates as a result of their extreme postural and manual lifting demands. Studies have shown that jobs involving significant lifting 6-9 and jobs that involve frequent bending10-12 are associated with increased LBD risk. Workers in the mining industry, in particular, often have to lift heavy materials in restricted workspaces that compel torso flexion. An understanding of the impact of repeated loading of the spine in flexion on fatigue failure of spinal tissues is thus a critical issue for our research agency, which is concerned with reducing the pain and disability associated with LBD in the mining industry. It is well accepted that loads experienced by the spine during manual lifting tasks are sufficient to cause fractures in the endplates of lumbar vertebrae, particularly on repeated loading. 13-15 Endplate fractures may not be painful in and of themselves 16; however, evidence suggests that the process of internal disc disruption and disc degeneration may be initiated via endplate fractures. 16,17 It has been shown that endplate damage will alter the distribution of stress in the disc, resulting in buckling of the lamellas of the internal anulus.17 Once this process has been initiated, repeated spine loading will cause additional disruption of the anular fibers, resulting in formation of significant fissures or tears. 11-21 If these tears occur near or extend close to the outer portions of the anulus, a wound healing process is initiated, which involves infiltration of mast cells, macrophages, and re¬lease of cytokines and growth factors. 21 The presence of these infiltrates has been strongly linked to discogenic low back pain. 21,22 Indeed, for patients experiencing chronic low back pain, the prevalence of internal disc disruption is at least 39%,19 which represents the most

By FREDERICK H. WILLCOX

In the past the blast-furnace industry was under the stigma of being one of the most prolific sources of killed or seriously inj ured and permanently disabled workmen of any of the industries of the country. In the popular mind, labor at blast furnaces was little less hazardous than mining, powder making, or railroad work. This impression wasbased not so much on definite knowledge of the number actnally injured and the causes of injury as on the spectacular nature of the accidents that from time to time were described in the press. As with a mine disaster or a railroad wreck so with many furnace accidents, the number fatally injured in such accidents constitutes only a minor proportion of the workmen who suffer more or less serious injuries. However, the reader of the daily paper receives a distinct impression-of frightful and sudden disaster which is apt to be associated henceforth in his mind with work at blast furnaces. It is true that in the past this impression has not been without warrant, for from the time of the advent of Mesabi ores, taller furnaces, and faster smelting, which begain in the early nineties, the newspapers have chronicled a large number of blastfurnace disasters. Blast-furnace men have never assumed to tolerate failures in construction or defective control of furnaces. But the admitted hazards of the work are many, and the slow development of improvements in the construction and control of the furnace and its auxiliaries have occasionally given rise to a tendency to accept as a part of the day's work not only the unforeseen and difficultly controlled accidents but accidents whose recurrence might be stopped by the adoption of suitable preventive measures. In the smelting of iron, even more than in many other industries, safety is inseparably related to efficiency in production, and. the accidents strictly incident to work about the furnace are proportional in some degree to the success with which obstacles to smooth working are overcome. This relation does not hold, however, in regard .to such accidents as are incident to hand labor, falls, falling and flying objects, machinery, and the use of hand tools.

Jan 1, 1917

By Batric Pesic

The interactions of mineral-pyrite with T. ferrooxidans were studied by using a cyclic voltametry technique. The interactions with bacteria were carefully examined during the entire growth stage of bacteria (fermentation). Several very important discoveries were made. For example, the pyrite surface invariably drastically changed its properties at the second day of fermentation. Beyond two days of fermentation, the cyclic voltamograms were insensitive to convective diffusion produced by stirring. The SEM study revealed that bacteria populated the pyrite surface at an extremely high density levels. The high density of bacteria, and the solid reaction products formed on the pyrite surface created conditions for pore diffusion which explained why the CVs became insensitive to convective diffusion in solution (stirring).

Jan 1, 1990

By K. Hanumantha Rao, A. Javadi Nooshabadi

"Formation of hydrogen peroxide (H2O2), an oxidizing agent stronger than oxygen, by chalcopyrite (CuFeS2), which is a copper iron sulfide mineral, during grinding, was investigated. It was observed that chalcopyrite generated H2O2 in pulp liquid during wet grinding and also in the solids when placed in water immediately after dry grinding. The generation of H2O2 during either wet or dry grinding was thought to be due to a reaction between chalcopyrite and water where the mineral surface is catalytically active in producing •OH free radicals by breaking down the water molecule. The effect of pH in the grinding medium or in the water in which solids are added immediately after dry grinding showed that the lower the pH value, the higher the H2O2 generation. When chalcopyrite and pyrite are mixed in different proportions, the formation of H2O2 was seen to increase with increasing pyrite fraction in the mixed composition. The results of H2O2 formation in pulp liquid of chalcopyrite and together with pyrite at different experimental conditions have been explained by Eh-pH diagrams of these minerals. This study highlights the necessity of revisiting the electrochemical and/or galvanic interaction mechanisms between the chalcopyrite and pyrite in terms of their flotation behavior.IntroductionHydrogen peroxide causes nonselective oxidation of sulfide minerals if present in pulp liquid. Oxidation of sulfide minerals takes place when they are exposed to atmosphere and during the grinding process when the particle size is reduced for flotation. The oxidation of chalcopyrite leads to iron dissolution from the particle surface and from a metal-deficient, sulfur-rich surface (Fairthorne et al., 1997). Other studies report the formation of iron hydroxide on the surface with the metal ion dislodged on the surface (Buckley and Woods, 1984; Chander, 1991). The chemical reactions for the oxidation of chalcopyrite in alkaline and in acidic solutions with the addition of oxidants, such as oxygen or hydrogen peroxide, are shown in Eqs. (1) and (2), respectively (Shi and Fornasiero, 2010)."

Jan 1, 2015

By Xiqing Wu, Tao Yue

"Magnetic seeding co-agglomeration, i.e. adding magnetic seeds, organic depressant (such as the starch), and pre-magnetization for co-agglomeration, was applied in the reverse flotation for hematite ore slimes. Samples of the hematite ore slimes and the pure hematite fines were investigated by the co-agglomeration, respectively. Flotation tests suggest that the depressing effect of starch in the flotation was further enhanced with the addition of magnetic seeds and the pre-magnetization. Following the laser size analysis and flotation tests, TOC adsorption analysis, VSM, surface charge measurement, AFM, FTIR study, and SEM imaging have been utilized to understand the depressing mechanism. Based on the results it was demonstrated that with the addition of magnetic seeds and the low field pre-magnetization, the adsorption of starch onto hematite minerals was strengthened through the magnetic seeding co-agglomeration. The co-agglomeration improved the flotation performance by introducing the magnetic interactions and acting the bridging adsorption of starch between fine hematite and magnetic seeds in a suspension, and then resulting in an intensified coverage of the starch onto hematite particles and positive action in the coagglomeration under the pre-magnetization.INTRODUCTIONFlotation is undoubtedly the most important and versatile mineral processing technique, and both its use and application are continually being expanded to treat greater tonnages and to cover new area. However, its influence was limited to a relatively narrow particle size range of 5–300 µm (Wills and Napier-Munn, 2006). The main reason behind this limitation lies in that fine particles have high specific surface area, so need relatively high dosage of reagents (collectors or depressants), and exhibit poor flotation performance while intermediate or properly-sized particles produce high flotation kinetics and need low consumption of reagents. In order to increase the recovery of fine particles, quite a few of flotation techniques have been investigated. Most of them are based on particle aggregation, namely, by enlarging the apparent particle size, such as carrier flotation (Valderrama and Rubio, 1998; Zhu et al., 2009), shear flocculation (Duzyola and Ozkan, 2010; Yin et al., 2011), selective polymer flocculation (Rubio et al., 2007; Song et al., 2012; Ng et al., 2015), oil agglomeration (Laskowski and Lopez- Vladivieso, 2004; Forbes, 2011), temperature responsive polymer flocculation flotation (Forbes et al, 2011), and etc. However, these techniques above-mentioned are mainly studied for the direct flotation of fine minerals, and most of these techniques have not found applications for iron ore slimes especially recovered by the reverse cationic or anionic flotation."

Jan 1, 2018

By Y. Huang, P. B. Prangnell

"An Al-0.1Mg alloy was firstly deformed at room temperature by ECAE to a true strain of 10, where a steady state deformation was established and further processing had little effect on grain refinement. The ECAE samples, with an average grain size of ~0.55µm, were then compressed in a channel die at 77K- 473K to various reductions. Microstructures were characterized by electron backscatter imaging and EBSD in a FEGSEM. Grain refinement to the ECAE submicron structure occurred during deformation at cryogenic temperatures of 77 – 213K, whereas coarsening took place during deformation at elevated temperatures. A steady state deformation was observed at all temperatures where a constant grain structure was developed and maintained upon further straining due to dynamic recovery. The mechanisms of dynamic recovery during steady state deformation at cryogenic temperatures are discussed.IntroductionSevere deformation processing (SDP) has been successfully used to produce submicron grain structures, and in some cases nano-scale crystallite sizes, in a wide range of alloys. However, the rate of grain refinement becomes increasingly inefficient at high strains as a steady state grain structure is approached [1-3]. Steady-state grain sizes have also been reported in other ultra-high strain deformation processes, like cryogenic ball-milling [4]. There is thus a minimum grain size achievable in a material by a given SPD process under constant deformation conditions.It is well documented that a steady state subgrain size is observed in warm deformation of metals due to dynamic recovery (e.g. [5]). In severely deformed alloys a constant grain size at ultra-high strains has similarly been attributed to dynamic recovery [1-3]. Mechanisms have been proposed, for rapid deformation induced grain growth including stress driven boundary migration and breakaway from solute pinning [2]. However, as pointed out by Humphreys et al. [2] the restoration processes are currently poorly understood, particularly at low temperatures, where the boundary migration rates required to maintain a constant grain size are orders of magnitude higher than can be satisfactory explained from diffusion controlled migration. Similar to the subgrain size, the steady state grain size obtained during SDP is generally related to the temperature compensated strain rate [2, 6]. Thermally activated restoration processes are thus expected to be suppressed by lowering the deformation temperature and a smaller steady state grain size can be achieved."

Jan 1, 2012