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By J. Güntner

Most copper/cobalt ores from the Central African Copperbelt contain sulphidic compounds, which are not extractable in direct leaching. Roasting provides the possibility to transfer the valuable components into leachable compounds. In an operation window defined by temperature and off-gas composition it is possible to selectively oxidize iron sulphides to haematite and copper/cobalt sulphides to sulphates. Selective sulphating of the valuable minerals is an important condition for the subsequent leaching stage. The dissolved copper and cobalt are recovered by solvent extraction and electrowinning. This technology has been part of an established process for many decades. The concentrates from recent projects on the Copperbelt have lower sulphur contents, and frequently higher copper contents, than those from older projects. The paper shows the consequences of this trend for plant operation and explains useful counter actions by means of case studies. Autothermal combustion is ensured even at very low sulphur contents. Off-gas treatment has so far been based on SO2 removal through sulphuric acid production. The generated acid is used to make up acid losses in the hydrometallurgical plant section. This well-proven process combination is still the preferred route if the feed sulphur content is high enough; however, some cases may require different off-gas cleaning concepts without compromising on clean air quality. Roasting in a fluid-bed furnace remains the core of the technology. Fluid-bed roasters are easy to operate and provide an excellent control of the calcine quality. Different feeding and heat-recovery systems are used to provide a tailor-made solution for each project. Outotec built it first sulphatizing roaster in Zambia about 30 years ago. At that time, the roasting of metal sulphides was already one of the main technologies in the company. Outotec has developed roasting solutions for copper, gold, zinc, lead, molybdenum, and pyrite ores. The continuously expanded and upgraded research facilities provide an excellent basis for developing sustainable, energy-efficient, and economic solutions for copper and cobalt production in Africa.

Jan 1, 2012

By J. Güntner

Most copper/cobalt ores from the Central African Copperbelt contain sulphidic compounds, which are not extractable in direct leaching. Roasting provides the possibility to transfer the valuable components into leachable compounds. In an operation window defined by temperature and off-gas composition it is possible to selectively oxidize iron sulphides to haematite and copper/cobalt sulphides to sulphates. Selective sulphating of the valuable minerals is an important condition for the subsequent leaching stage. The dissolved copper and cobalt are recovered by solvent extraction and electrowinning. This technology has been part of an established process for many decades. The concentrates from recent projects on the Copperbelt have lower sulphur contents, and frequently higher copper contents, than those from older projects. The paper shows the consequences of this trend for plant operation and explains useful counter actions by means of case studies. Autothermal combustion is ensured even at very low sulphur contents. Off-gas treatment has so far been based on SO2 removal through sulphuric acid production. The generated acid is used to make up acid losses in the hydrometallurgical plant section. This well-proven process combination is still the preferred route if the feed sulphur content is high enough; however, some cases may require different off-gas cleaning concepts without compromising on clean air quality. Roasting in a fluid-bed furnace remains the core of the technology. Fluid-bed roasters are easy to operate and provide an excellent control of the calcine quality. Different feeding and heat-recovery systems are used to provide a tailor-made solution for each project. Outotec built it first sulphatizing roaster in Zambia about 30 years ago. At that time, the roasting of metal sulphides was already one of the main technologies in the company. Outotec has developed roasting solutions for copper, gold, zinc, lead, molybdenum, and pyrite ores. The continuously expanded and upgraded research facilities provide an excellent basis for developing sustainable, energy-efficient, and economic solutions for copper and cobalt production in Africa.

Jan 1, 2012

By C. Dorfling, S. Bradshaw, J. Eksteen, M. Khesa, C. A. Snyders

Titaniferous ores serve as a major feedstock for the production of a white titanium dioxide pigment, a titanium metal and several other titanium-based products. Such ores exist mainly as heavy mineral sands. Ilmenite is upgraded to intermediate products namely synthetic rutile and titania slag through the synthetic rutile route and the reductive smelting route respectively. Tronox KwaZulu Natal Sands (Pty) Ltd recovers high titania slag via the reductive smelting process while slag is used as a feedstock to the pigment industry and furnace dust from the gas cleaning plant is disposed as waste. Previous investigations have shown that such furnace dust can contain significant amount of titanium-bearing minerals. This study looks at the characteristics of the furnace dust obtained from Tronox KwaZulu Natal Sands and investigates a possible high temperature recovery route in detail. The furnace dust was examined by using x-ray fluorescence, x-ray diffraction, microscopy and laser-diffraction size analyses. The characterization work showed that the furnace dust was rich in titanium and iron, containing 49.4 wt% ??????2 and 29.5 wt% ????2??3. These oxides were associated with Si, Mn, K, and Al oxides as impurities. A Carbolite® vertical tube furnace was used to investigate the extent of formation of titania slag and metallic iron on a laboratory scale at 1500°C, 1600°C and 1650°C. The laboratory reduction tests revealed that the slag samples with an equivalent titanium dioxide content ranging from 70.9 -76.9 wt% at 1600°C and 1650°C could be obtained. The Fe content of the metallic iron samples produced ranged between 93.0 and 97.1 wt%. The experimental results were found to be in relatively good agreement with the FactSage simulations, both of which demonstrated the potential of producing a titania slag and a metallic iron from the furnace dust.

Jan 1, 2018

The Australian metallurgical processing industry has shown great innovation and progressiveness over the past ten years. During the same period, exploration activity, particularly by Australian companies, has increased substantially in Indonesia. Following feasibility studies, the decision was made to establish a metallurgical laboratory and design facility in Indonesia. An Indonesian partner was selected, and legal and corporate matters were determined. The laboratory was established but proved far more difficult than a similar undertaking in Australia. Australian and Indonesian staff were recruited and training programs, including training of Indonesian staff in Australia, were implemented. Difficulties of operating in Indonesia included: ò language difficulties ò _ local pace of life ò culture ò communications. Rewards of the decision to establish the means to present the technology to Indonesia have included: ò a contribution to Australia's export of technology. ò an opportunity to expand Normet's client base. ò the opportunity to learn aspects of a foreign culture. ò the means to establish a sound long term investment. This export of technology from the Australian mining industry to Indonesia is an example of the initiatives and capabilities shown by the Australian mining service industry.

Jan 1, 1989

By Marie Kinzel

LOS ALAMOS, New Mexico, the birthplace f the atomic bomb, is one of the most famous-and mysterious-places in the world. It leaped into fame on Aug. 6, 1945, when the first atomic bomb burst over Hiroshima. Unheard of until that day, its present life is as hidden from most people as was its very existence in pre-Hiroshima days. Then, those who did know of it dared not breathe their knowledge. "What do you tell your wife when you go to Shangri La?" was the favorite quip of the few consultants who made regular trips from east or west to Los Alamos during the tense months when the bomb was in the making. Security regulations made it impossible even to hint at the rigid secrecy surrounding the project. The puzzled wives in question knew only that their husbands had top priority on airplane flights to Albuquerque. When they had verified the safe arrival of the flight, they undoubtedly breathed a sigh of relief. If they could have visualized the rest of the trip, the sigh of relief would have been replaced by a state of tizzy, until a telegram came saying "Arriving home on Flight X" (on a nice safe airplane).

Jan 1, 1946

By K. Morin

"Silver and gold leaching by cyanidation is a well-known process used around the world. This reaction is often accompanied by the leaching of other species throughtout the cyanidation circuit that causes the diversion of cyanide towards non valuable by-products (SCN-, Cu(CN)x, Fe(CN)x, etc.). One of the detrimental impacts of the formation of these by-products is the precipitation of silver-cyanide complexes that occurs when cyanide concentration is too low. Without any extra-addition of free cyanide, the precipitated silver is lost and cannot be recovered causing an important economic loss. To overcome silver precipitation, cyanidation circuits are often operated at higher cyanide concentrations. Recently, COREM’s research team has been working on a technology to measure and control silver precipitation during the cyanidation process. Moreover, a methodology has been elaborated in order to evaluate threshold cyanide level which corresponds to the cyanide concentration at which silver starts to precipitate. This technology has been tested on site on a real cyanidation circuit at Agnico Eagle’s LaRonde mine."

Jan 1, 2014

By Suresh Menon

The explosive industry in India has passed through various stages - from a period of total dependency to a period of self sufficiency and now, is saddled with large spare capacity. The last decade and a half saw the emergence of small scale manufacturers, which until then was thriving on International technology.

Jan 1, 1998

The history of the industry which recovers rutile and zircon from the heavy mineral beach sand deposits of Eastern Australia began with the initial discovery of zircon in 1895. Whereas a large number of small companies operated during the rutile boom of 1955-57, the industry is now controlled by a few large groups.Mining is mainly by suction dredging. Metallurgical practice is a two-stage process in which a bulk concentrate of heavy minerals, recovered by gravity methods, is separated into its constituent minerals by processes based mainly on surface, electrical, and magnetic properties.Various separating devices using these principles have been developed in the industry and combined in various ways in the operating plants.There is scope for future metallurgical developments.INTRODUCTIONThe existence of deposits of heavy minerals ("black sands") on the northern coast of New South Wales has been known for at least 90 years. The earliest metallurgical operations aimed at the recovery of gold, platinum, tin and monazite. Mainly because of the low grade of these deposits with respect to these minerals, but also due to metallurgical difficulties, such operations were abandoned by about 1895 (Whitworth, 1959). The presence of zircon was recorded quite early (Carne, 1895) but Raggatt (1925) appears to have been the first to report the presence of rutile.The economic exploitation of the deposits was initiated in 1928 when D. H. Newland, State Geologist of New York, made an examination on behalf of The Titanium Alloy Manufacturing Company of America. Developments were then delayed by the world-wide depression, and the first commercial separation of the heavy minerals was made at Byron Bay in 1934 by Zircon Rutile Ltd. using a froth...

Jan 1, 1963

By Greenwood J. N

This work was commenced at a time when information on the manufacture of cemented tungsten carbide was urgently needed in Australia. Much information of a general type has been published, but many of the details of the processes used are still undisclosed. The aim of this research was to determine a satisfactory way in which cemented tungsten carbide could, be made, and to investigate the problems which are associated with the process. As the work proceeded, its ramifications grew continually, and it was necessary to limit the possible lines of investigation. After much experimental work, a 9% cobalt-tungsten carbide alloy was developed which had satisfactory properties when used as a cutting tip. The effect of certain variables on the properties of this particular alloy was investigated.The tungsten carbide was prepared in stages from King Island scheelite concentrates under strict laboratory control, whilst the cobalt (1) used was made from cobalt oxide prepared from crude cobalt oxide obtained from Eisdon.In order to clarify the detailed experimental work, a brief summary of the method used for the preparation of cemented tungsten carbide follows.Tungsten carbide and cobalt are prepared in a very finely powdered state, and are then thor,oughly mixed by a ball milling operation. The resultant mixture is pressed in a suitably shaped die into small compacts which are subsequently '''presintered,'' i.e., heated' in hydrogen between 800°C. and 1000°C. The final sintering is carried out in hydrogen between 1,400°C.and 1,600°C. for about half an hour. These "alloys" may contain from 3 to 13% cobalt, depending on the particular properties required of them.PREPARATION OF MATERIALSThe tungsten oxide prepared as described by Smithells (2) was extremely finely divided, and after a few hours' grinding in a ball mill, the powder consisted of material below 10 microns iJ;l size. The oxide was reduced to tungsten metal with hydrogen in a tube furnace. The reduction was carried out at 800-900° C., a rapid flow of hydrogen being maintained in order to remove the water vapour' formed as a result of the reactions:

Jan 1, 1942

By Allan Herse

"The years following World War II were nation building years in Australia. Soldiers returned from the European and Asian theatres of war sparking a major infrastructure construction boom. Dams and highways were built to keep up with the growth of towns and cities, which were bursting at the seams, not just from the returning soldiers settling down with their families but also from the many waves of refugees from war torn areas around the globe.The demand for electricity generation and distribution required for the growing population sparked the expansion of the national power grid with new high-voltage transmission towers appearing across the landscape. However, with an original design life of 50 years, those transmission lines constructed in the 1950s are nearing, or are at the end of, their anticipated service life.In recent years, the Australian power distribution network has changed from a period of high construction activity in greenfield high-voltage lines to a period that is now focused on reducing cost and maintaining existing assets. Replacing aboveground structural members and electrical components is relatively simple even under live conditions. However, the replacement or repair of tower foundations, many of which are in remote locations, has been a problem that has caused difficulties for power utilities trying to operate on a budget while also avoiding costly and unpopular power outages.With thousands of miles of aging transmission lines needing life extension work, Piling & Civil Australia (PCA) has developed a patented system of upgrading the foundations with micropiles while under live-line conditions without requiring costly outages. The system is seen as revolutionary by power utilities, allowing the utilities to extend the life of their existing assets until demand increases to warrant the construction of a new line. PCA has been working on a potential solution with Powerlink Queensland for the past 5 years to develop a quick and cost-effective foundation replacement system that can extend the life of its existing asset base anywhere from an additional 5 years to 50 years.With design support from Quanta Subsurface, USA, PCA recently completed the foundation replacement of 26 lattice tower foundations in the Townsville region of North Queensland. Using a steel bracket (patent pending) to connect hollow bar micropiles to the lattice towers, the installation techniques that were developed enabled the micropiles to be installed within a tolerance of less than about 3/8 in (10 mm) through the existing steel grillage foundation while maintaining live line conditions. The project was an Australian first and a trial by Powerlink for wider use within its network, and it was delivered on time and within budget at one tenth of the cost of traditional methods."

Jan 1, 2017

By Allan Herse

"The years following World War II were nation building years in Australia. Soldiers returned from the European and Asian theatres of war sparking a major infrastructure construction boom. Dams and highways were built to keep up with the growth of towns and cities, which were bursting at the seams, not just from the returning soldiers settling down with their families but also from the many waves of refugees from war torn areas around the globe.The demand for electricity generation and distribution required for the growing population sparked the expansion of the national power grid with new high-voltage transmission towers appearing across the landscape. However, with an original design life of 50 years, those transmission lines constructed in the 1950s are nearing, or are at the end of, their anticipated service life.In recent years, the Australian power distribution network has changed from a period of high construction activity in greenfield high-voltage lines to a period that is now focused on reducing cost and maintaining existing assets. Replacing aboveground structural members and electrical components is relatively simple even under live conditions. However, the replacement or repair of tower foundations, many of which are in remote locations, has been a problem that has caused difficulties for power utilities trying to operate on a budget while also avoiding costly and unpopular power outages. With thousands of miles of aging transmission lines needing life extension work, Piling & Civil Australia (PCA) has developed a patented system of upgrading the foundations with micropiles while under live-line conditions without requiring costly outages. The system is seen as revolutionary by power utilities, allowing the utilities to extend the life of their existing assets until demand increases to warrant the construction of a new line. PCA has been working on a potential solution with Powerlink Queensland for the past 5 years to develop a quick and cost-effective foundation replacement system that can extend the life of its existing asset base anywhere from an additional 5 years to 50 years.With design support from Quanta Subsurface, USA, PCA recently completed the foundation replacement of 26 lattice tower foundations in the Townsville region of North Queensland. Using a steel bracket (patent pending) to connect hollow bar micropiles to the lattice towers, the installation techniques that were developed enabled the micropiles to be installed within a tolerance of less than about 3/8 in (10 mm) through the existing steel grillage foundation while maintaining live line conditions. The project was an Australian first and a trial by Powerlink for wider use within its network, and it was delivered on time and within budget at one tenth of the cost of traditional methods."

Jan 1, 2017

By Pengfei Pan, Lianjun Guo, Houguang Sun, Donglin Xu, Chi Yang, Lihua Luan, Daning Zhang

"Based on the introduction of production technology of Anqian mining company, the stope ore mass distribution was analyzed in detail. The processability indexes of different grade ores were obtained with magnetic tube whereas the grinding time, concentrate grade and concentrate yield were measured. On the basis of digital ore deposit model which integrates ore natural attributes and processing attributes, two stages of ore blending optimization models were established. The first stage model sought the minimum of stope ore transportation cost under the restraints of output ore grade and stope production. The second stage was a system optional model that aimed at the furthest use of resources meeting not only the production constraints of mining field and process field but also ore beneficiability and the system output requirements of the concentrate grade. Lastly, the solving method of big M simplex algorithm was discussed and used in production. 1. Foreword China is the biggest iron ore consumption market. But most of iron ore deposits in china possess such features as low grade, complex compositions, weak magneticity and refractoriness. Under the current economic and technical conditions, rational utilization of low-grade and refractory iron ore is strongly needed to improve the utilization ratio of mineral resources and keep mine development sustainable (Lei 2011). In recent years, the domestic research institutions and mines made a lot of achievements of rational development and utilization of low grade iron ore resources in the beneficiation technology and equipment, high and low grade balance, cost and tax analysis (Wang and Zhao 2013, Zhang 2014, Zhu and Li 2014), laying the foundation for reasonable utilization of low grade iron ore. In this paper, Anqian mining company is taken as an example in which the production conditions, raw ore quality control, different grade of ore processability, and ore blending optimization mode in mining pit and processing plant were discussed to achieve the maximum utilization of low-grade refractory ores under the economical and reasonable conditions. This will ensure the stable operation of mining joint ventures and maximize the enterprise's production life and therefore, maximize the economic and social benefits in the enterprise life cycle."

Jan 1, 2017

By Ramie H. Thompson

1.1 BACKGROUND In many underground coal mining operations the use of electromagnetic field equipment, particularly communication systems, not only increases the overall efficiency of the mining operation but can be directly linked with mine safety considerations. The use of electromagnetic field producing equipment in underground coal mining operations can only be expected to grow. Several new communication systems have already been proposed. In addition, high-frequency producing equipments for many diverse uses in mining operations are under study. The use of these equipment in underground mining operations is hampered by the possibility of their electromagnetic fields interacting with the electric blasting cap operations commonly carried out in the mines. Such interactions can have at least two results bearing directly on mine safety: o premature initiation of the cap, either in its normal shot location or during hookup or transportation; o dudding of the cap so that normal firing operations do not cause irritation; thereby leaving unexploded high explosives after normal firing. Since the consequences of a premature initiation could, particularly in coal mines operations, result in catastrophe involving human life, the overall approach to prediction of possible hazard must be, as far as possible, of a "worst case" nature. The general problem of predicting possible RF hazards for any electroexplosive device (EED) is best treated by reference to Appendix A of

Jan 9, 1983

By Adnan A. Malik, Tadashi Maejima, Jiro Kuwano, Shinya Tachibana

"The helical piling system provides solution to many geotechnical related problems due to its quick installation, higher compressive and pullout resistance, no wastage of material, workable in limited areas and reusability. However, its use as a foundation for bridges and high-rise buildings is still limited as compared to other piling methods. In the present study, the performance and load settlement behavior of screw and straight pile is investigated under cyclic compressive load in dense ground conditions. To achieve the set objectives, pile load tests were conducted in a cylindrical steel container. The model ground was compacted with dry sand at relative density of 80%. It is observed from the test results that screw and straight pile resistance reduced when the cyclic load is applied at allowable pile resistance state. The reduction in the ultimate pile capacity is more in straight pile than in screw pile. However, straight pile showed higher ultimate pile capacity than screw pile under similar pile tip diameter. The effect of helix bending deflection on load settlement behavior and ultimate pile capacity increases under cyclic loading.INTRODUCTIONScrew pile is one of the new developments in deep foundation, which is growing tremendously fast because of its quick installation technique, less noisy operation, no wastage of material and involvement of minimum manpower. Screw piles have an edge on straight pipe piles due to its high bearing capacity and uplift resistance. The installation mechanism of screw pile is different from straight pile. Torque and pressure is required to install the screw pile whereas hammering, pressure and vibration is required to install straight pile. As the installation mechanism is different between screw and straight pile, therefore, the ground disturbance that is produced during their installation is also different. The ground disturbance produced during the installation also depends upon the pile tip condition i.e. open or closed ended. Sakr, (2009) stated that the compressive capacity of screw pile in 3 to 5 times higher than driven piles having the same shaft diameter and length. The reason for this increase in pile capacity is due to helix, which is generally 2 to 2.5 times the pile shaft diameter. Larger helices can give higher end bearing capacity but it requires very powerful machinery to install in dense grounds. For instance, if large helix screw pile is installed in a dense ground then helix-bending deflection will start affecting the end bearing capacity (Yttrup and Abramsson, 2003; Malik et al. 2013 and 2015). According to Malik (2015), the equations of thin plate (Young and Budynas, 2002) with uniformly distributed load on the plate can give reasonable estimation of helix deflection due to dense ground conditions."

Jan 1, 2016

By Nick Barton

A recent analysis of 145 TBM tunnels of more than 1000km total length has helped to quantify the time dependence of utilization (U). In fact U = Tm, where T is time in hours and m is a negative gradient of deceleration. In poor quality ground, gradient m has a strong dependence on rock mass quality Q, for example m ˜ -0.5when Q = 0.1. Good investigation is critical for ensuring faster TBM tunneling then drill-and-blasting, which tends not to slow down (in m/hr) as the tunnel length increases. Anew design model called QTBM allows more reliable prognoses be made, and occasionally will disqualify the TBM solution.

Jan 1, 2001

By T. Holmes, D. C. Russell, G. Jolly

"The AMEC Oakville office is involved in the design and construction of an iron ore concentrator located in Liberia. Currently, the site ships Direct Shipped Ore (DSO) to overseas customers. The DSO mine-site and port can experience heavy annual rainfalls. The IMSBC Code requires that cargoes are only accepted for loading when the moisture content of the cargo is less than its Transportable Moisture Limit (TML). The moisture content of the DSO has, on occasions, risen to near or above its TML. AMEC was asked to advise whether the concentrate produced from the new concentrator would or would not have the same problems with moisture content and ship loading as the DSO.INTRODUCTION Liberia was, at one time, the world’s sixth largest exporter of iron ore and used some of the most modern mining operations of their time. However, the country has not produced iron ore over the past seventeen years because of civil unrest. The return of stability to the country has allowed the redevelopment of the iron ore industry. ArcelorMittal Liberia (AML) obtained a concession for mining in the Nimba County area of Liberia (Figure 1) in December, 2004 and has studied the known iron ore deposits and former mining operations in this area. It began phase 1 operations in June 2011 with the direct shipping of high grade ore at a rate of up to 4Mtpa. The processing of the lower grade ore in phase 2 of the project requires additional processing capability to produce at the design rate of 15Mtpa. DSO and Concentrate The DSO in the first phase is selectively mined at an average grade of 60% Fe, and then crushed and screened to -10 mm with no washing or concentration. Testing of samples has indicated a size distribution that is finer than typical sinter feed material, although critical material below 0.10 mm is low in most cases, and overall the ore is coarser than typical concentrates or ultrafine products (Feasibility study report, 2011). The phase 1 DSO facility will cease operation after the phase 2 concentrator comes into operation."

Jan 1, 2014

The Youga gold mine in Burkina Faso, West Africa, is scheduled to produce first gold in the third quarter of calendar 2007. The project is expected to produce 540 000 oz of gold over 6.5 years, from a conventional open pit carbon in leach mine. The direct capital cost of the project is US$47 M. Etruscan Resources Inc, a Canadian based gold exploration and development company, holds 90 per cent of the project company Burkina Mining Company SA (BMC). The state of Burkina Faso is free-carried for the remaining ten per cent of BMC. RMB Resources Limited, of Melbourne Australia, has arranged a US$35 M project finance facility for BMC (the Borrower) as the majority of funding for the Youga project development. The loan facility was provided by RMB Australia Holdings and Macquarie Bank Ltd (the Lenders) each as to 50 per cent in the lending syndicate. The Lenders also provided a gold hedging facility to guarantee a minimum price for the projectÆs gold production. Burkina Faso is a francophone country, part of the Economic and Monetary Union of West Africa (UEMOA). The project financing is the first such facility to be arranged for a mining project in Burkina Faso, with little or no precedent available in other UEMOA countries. Therefore, while the Youga gold project is forecast to be a robust project applying conventional mining and processing methods, a number of legal, technical, commercial and social issues required identification, evaluation and resolution before the loan could be established. This paper describes that evaluation process and the resolution of these issues. In-house experience and expertise in both the LendersÆ and BorrowerÆs teams has facilitated a greater understanding and æownershipÆ of the issues and hence provided comfort with risks which might not normally be taken in conventional project developments and project financings. As a result, blanket external reviews were not required by the Lenders. A long-standing relationship between Etruscan and RMB Resources also facilitated solutions to a number of issues. Nevertheless, a degree of flexibility by the Lenders, the Borrower and Etruscan was required to successfully close the financing.

Jan 1, 2007

By J. R. Kunkel, V. Lishnevsky

At mine sites, the operational and required storage volumes of solution and water storage ponds and reservoirs are usually calculated based upon a water-balance approach. Many climatological variables including precipitation, air temperature, solar radiation, pan evaporation and relative humidity along with operating parameters, are used in the water-balance model. The water-balance model often seeks to find a “critical period” of wet or dry climatological sequences which result in a “maximum” pond storage volume or water demand. The problem with this approach is that the designer usually does not know when the project will come on line in relation to the historical record. To avoid this pitfall, we use a more robust approach. In the more robust method, the water-balance calculations begin in each year of the historic climatological record. This method results in the same number of water-balance runs (or realizations) as the number of years of climatological record. Results of this type of analysis guarantee that the critical period or maximum required pond volume will be found if it is assumed that the historical climatological record repeats itself or if a synthetic time series is used. In addition, this method permits calculation of the likelihood (probability) that a given pond volume will be equaled or exceeded in any given month of the operational life of the facility. In this paper, the results of the sizing of a heap leach pad solution pond are presented along with the probabilities of a given solution pond size being equaled or exceeded based on the robust water-balance approach.

Jan 1, 2002

By Daniel Adolfsson, Ryan Robinson, Fenwei Su, Jelena Blagojevic

"Cold bonded briquetting of steel plant by-products has proven to be a viable recycling alternative concerning technology, economy and environment in both the traditional blast furnace route and the direct reduction process. A critical parameter in cold bonded briquettes is the type and amount of binder used during production. The binder material must meet certain quality requirements concerning low and high temperature strength, chemistry and economy. Currently, SSAB Tunnplåt uses ordinary Portland cement (OPC) as binder in their cold bonded briquettes. In order to improve binder quality and possibly decrease OPC dependency, a binder feasibility study has been conducted concerning an internal by-product, ladle slag, as a supplement and/or partial substitute for OPC. Several characterization techniques have been used to study the behaviour of ladle slag, these include: XRD, XRF, SEM, glass content analysis, calorimetric analysis, particle size distribution and thermochemical stability considerations concerning the CaO-Al2O3-SiO2 system.IntroductionRecently, a project was initiated at SSAB Tunnplåt AB, in Sweden, which aimed at reducing the amount of ordinary Portland cement (OPC) as hydraulic binder in cold bonded briquettes by partly replacing it with ladle slag. OPC is traditionally used within civil engineering, and widely accepted as a hydraulic binder in a number of different applications. OPC consists of four major crystalline phases, i.e. C3S, C2S, C3A and C4AF. Tricalcium aluminate as well as the ferrite phase in OPC reacts very quickly with water, for this reason gypsum is added to the clinker in order to retard these reactions. The fact that gypsum is present in the system limits the recycling of briquettes to the BOF, since the presence of gypsum during steelmaking results in a significant amount of sulphur emissions. The latter along with the expense that follows, makes it worthwhile to consider alternatives for OPC as binder in cold bonded briquettes."

Jan 1, 2008

By Seth C. Schaefer

The Bureau of Mines investigated the thermodynamic properties of Bi203 (bismuth sesquioxide) and Sn02 (stannic oxide). Standard Gibbs energies of formation (AGfO) of these compounds were determined with high-temperature electromotive force (emf) cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained from the cell

Jan 1, 1984