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By F. E. Rizzo, L. R. Bidwell, D. F. Frank

THE use of galvanic cells for the determination of oxygen activities has spread rapidly since the suitability of calcia-stabilized zirconia as a solid electrolyte material was first demonstrated by Kiukkola and Wagner.' In many of these investigations:-7 including several at ARL, the free-energy changes for various oxidation-reduction reactions involving the oxides FexO, NiO, and Cu2O have been measured as a means of assuring that a cell apparatus is functioning properly. As a result, a large quantity of data pertinent to the calculation of the high-temperature standard free energy of formation (?GO) of these oxides has been accumulated. AGFexo has been carefully measured in many independent investigations, using a variety of techniques, and consequently is accurately known. chipmans has used this informa-

Jan 1, 1968

By Kenneth Blower

This paper gives a detailed coverage of the ore flow through the primary crusher, cobbing plant and concentrator, including equipment sizes, recoveries, reagent consumptions and product descriptions. Special features, such as rubber chutes, rubber-lined mills, pebble-mill grinding, steam-hooded filters and process control instrumentation, are also discussed.

Jan 1, 1968

By L. Rosato

In the past decade, as a result of increasing iron loads, Canadian Electrolytic Zinc (CEZinc) has become a pioneer in understanding the critical factors that affect the roasting of concentrates with high pyrite contents as well as those factors governing the effects of high iron loads on the leaching circuit. De-bottlenecking efforts in the roaster and acid plant section of CEZinc have given rise to a better appreciation of the impact of iron on roaster productivity. High standards for impure solution quality, zinc recoveries and residue disposal have all led to an increased comprehension of the limits of the leaching circuit and the optimization potentials with respect to iron and ferrites. In this paper, the impact of iron on the roasting and leaching circuits of CEZinc will be reviewed and special emphasis will be given to some of the more recent process optimization and improvement activities.

Jan 1, 2006

By Jorgen Elbrond

The capacity calculation of complex transportation systems involving variable activity times such as encountered in the mining industry are often worked out by means of simulation, which reconstructs waiting times and cycle times. The queuing theory, which mathematically calculates waiting times, has been used mainly to describe the, phenomena. This is due partly to the difficulties encountered in modelling complex systems and partly to the difficulty of reconciling the required time distribution laws with the real phenomena by means of the queuing theory. It is, however, obvious that formulas for capacity calculations would be preferable to simulation procedures because of their higher calculation speed, shorter and more flexible programs and shorter programming work. The calculation procedure presented in this paper is composed of some rather simple models, which are based on the queuing theory, and on some probabilistic and some deterministic considerations. The models are supported by observations, and to some extent by simulations. It has been attempted to find all the components of the cycle time and to include them in a comprehensive model. It is the intention to demonstrate that even quite complex mine transportation systems can be treated by means of the queuing theory with the advantages mentionned above and, without sacrificing the precision of the estimates. The speed of calculation of a wide range of parameter combinations is such that the procedure can be used extensively by a project engineer in the search for optimal modifications of the entire transportation system.

Jan 1, 1979

This study was conducted to establish the effects of a diesel particulate filter (DPF) system with sintered metal substrate on the concentrations and size distributions of nano and ultrafine aerosols and concentrations of nitric oxides in underground mine air. The study focused on the formation and transformation of nucleation mode particles in mine air under prevailing test conditions. Experimental work was conducted in the NIOSH Diesel Laboratory at the Lake Lynn Laboratory experimental mine, a facility developed to allow evaluation of control technologies directly in underground conditions. The DPF system was examined for four repeatable steady-state engine modes using a naturally aspirated mechanically controlled Isuzu C240 diesel engine fueled with ultralow sulfur fuel. The engine coupled to an eddy-current dynamometer was operated in the underground drift with tightly controlled ventilation. Measurements upwind and downwind of the exhaust system discharge were used to quantify the effects of the DPF system on the mine air. A baseline was established using a standard muffler. The study showed that sintered metal DPF systems reduced the total mass of aerosols in the mine air by more than ten-fold when compared to a muffler. The nucleation mode aerosols (50dem<40 nm) in mine air were found to be strongly influenced by engine operating mode. The concentration of nucleation mode aerosols was found to be significantly higher for high-load modes than for low-load modes. The muffler and DPF system resulted in comparable total nitrogen oxides (NOx) concentrations. However, the nitrogen dioxide (NO2) fraction of the total NOx was found to be substantially higher for both systems for low-load modes than for high-load modes.

Jan 1, 2009

By Sunil Katharia

In February 2016, the upgraded Blast Furnace 1 of JSW Steel Limited (JSW) at its Vijayanagar Steel Plant was blown in after a 6 months shutdown in which the whole furnace was rebuilt on the existing foundation and within the existing tower structure. Despite several plant constraints it was possible to increase the furnace inner volume by 85% - reaching 2307 m3 from existing 1250m3. The upgradation project covered the stockhouse and its dedusting system, top charging system, furnace profile, furnace cooling system, casthouse and its dedusting system, slag granulation plant, pulverized coal injection plant, hot blast system and gas cleaning plant – with major interventions in order to cope up with the changed operating conditions. The total scope of the project was split by JSW into several packages, all based on design data provided by Paul Wurth. JSW was responsible for coordinating the local subcontractors along with Paul Wurth which has been appointed as main technology supplier in charge of complete basic and selected detail engineering in the key areas and of the supply of core equipment such as the Bell-less Top®, copper staves, GCP key items and TMT casthouse machines. The main design concept and the key points of the project such as optimization of project ROI, advanced erection concepts as well as a summary of the operating results are presented confirming JSW “BF1” upgradation as one latest examples of the current state of the art in the revamping projects.

Aug 17, 2017

By D. Odendaal, S. Bharat, R. D. Cromarty

The aim of this investigation was to determine the effect of high-temperature heat treatment on the electrical resistivity of charcoal. Samples of two different wood types (eucalyptus and black wattle) were pyrolised in a retort at a temperature of 700°C and the resulting charcoals heat-treated in an induction furnace at temperatures from 800°C to 1800°C and residence times from 60 to 120 minutes. After cooling, the resistivities of the samples were measured at room temperature using the four-point probe technique. It was found that as the heat treatment temperature increased the electrical resistivity of the charcoal decreased, approaching an asymptotic value at higher temperatures. Longer residence times decreased the resistivity, but this effect was not pronounced.

Oct 3, 2023

Drilling underground can be a hazardous undertaking in many circumstances. Raiseboring and boxhole boring underground could form an integral part of the block caving production methodology and getting the right mix of technical capability, ergonomics and economical viability has been the goal of many machine manufacturers. With the introduction of the Terratec Universal Boring Machine concept, flexibility of raiseboring, downreaming and boxholing has been enhanced by the introduction of a single machine that will perform all three processes. In addition to its technical flexibility, additional safety features have been introduced that will eliminate many sources of injury by mechanising most of the operational procedures. Together with the one-man remote operation, this machine design addresses and solves many of the safety issues. This paper outlines the machine concept, details its safety features and shows the techno-economic advantages for use in the block caving environment. Block caving is a distinct caving method applied mostly to large massive orebodies because of the inherent low costs and high production capabilities. Areas of sufficient size are mined by undercutting so that the mass above will cave naturally. Extraction of the caved ore at the bottom of the ore column causes the caving action to continue upward until all of the ore above the undercut level is broken into sizes suitable for handling (Figure 1).

Jan 1, 2000

By A. Melkumyan, M. Balamurali, J. Zigman

Understanding the contribution of geophysical variables is vital for identifying ore indicator regions. Both magnetometry and gamma-rays are used to identify the geophysical signatures of the rocks. Density is another key variable for tonnage estimation in mining, and needs to be re-estimated in areas of change when a boundary update has been conducted. Modelling these geophysical variables in 3D will enable investigation of the properties of the rocks and improve our understanding of the ore. The Gaussian Process (GP) was previously used to generate 3D spatial models for grade estimation using geochemical assays. This study investigates the influence of the following two factors on the GP-based autonomously generated 3D geophysical models: the resolution of the input data, and the number of nearest samples used in the training process. A case study conducted on a typical Hammersley Ranges iron ore deposit using geophysical logs, including density, collected from the exploration holes, is examined in this paper.

Sep 1, 2021

By Frederick C. Hull

THE grain size of a metal or alloy is one of the most important factors determining its properties. In steels, for example, grain size affects hardenability, toughness and machinability; in brasses, grain size is related to hardness and deep-drawing quality. In the field of heat-resistant alloys, grain size has a marked effect on ductility, creep and endurance strength. In order to determine these effects, as well as to control the properties of materials, many accurate and rapid measurements of grain size must be made. This paper presents a new and improved method for the estimation of grain size. USUAL METHODS of EVALUATING GRAIN SIZE A frequently used method of estimating grain size is that of comparing the image of a polished and etched specimen on the ground-glass screen of a metallographic microscope with standard grain-size charts. Several types of standards are available for use with different classes of microstructures. Geometric Grids.-The Metals Handbook1 has a series of hexagonal grids ranging in size from ASTM No. I to 8. Idealized Grain Networks.-Idealized grain-boundary networks for ASTM grain sizes I to 8 are included in the American Society for Testing Materials Tentative Standard E19-39T. Standard Micrographs.- The Metals Handbook and ASTM Tentative Standard EI9-39T contain micrographs of hypoeutectoid and hypereutectoid steels ranging in grain size from No. I to 8. The grain size of annealed brass (diam¬eter of the average grain in millimeters) is obtained by comparison with 10 micrographs of varying grain size in ASTM Tentative Standard Es-39T. A handicap to accurate evaluation of grain size by this method is the fact that it is difficult to compare photographs in a dimly lighted room with the image on the ground-glass screen, or, if the general illumination is increased so that the printed standards may be clearly seen, the contrast of the image of the unknown is decreased. It is easier to estimate grain size by comparing a micrograph of the unknown with the grain-size standards. However, photographing every specimen on which the grain size is desired is too costly in time and materials to be practicable. For hardened steels, the Shepherd or Jernkontoret fracture grain-size standards are very accurate and useful, but this method obviously cannot be applied to ductile alloys such as brass, stainless steels and austenitic heat-resistant alloys. Jeffries&apos; method for grain-size measurements consists of counting the number

Jan 1, 1947

By AIME AIME

ON Sept. 24, 1875, a remarkable deposit of silver ore was discovered by James Ryan and Samuel Hawkes at the east base of Grampian Hill in central Beaver County, Utah.. A shaft was begun and had been sunk about 30 ft. in ore when the claim was sold on Feb. 17, 1876, to A. G. Campbell, Matthew Cullen, Dennis Ryan, and A. Byram for $25,000. To them is due the credit of having developed the mine and started the district on the road to its present state of prosperity. Their development resulted in proving the vein to a depth of over 280 ft. and about 2500 tons of ore was extracted and turned into bullion. In February, 1879, the mine came into the possession of the Horn Silver Mining Co., and since then over $65,000,000 worth of ore has been taken from the mine. Two smelters were built in 1878, near the mine; 400 men were employed underground, and 1000 on the surface, burning charcoal, hauling wood from the surrounding hills, and freighting and hauling hay for the hundreds of horses used in the work. Ore was hauled thirty miles to the

Jan 1, 1936

By Nikhil Dhawan, Shrey Agrawal, Ashwini Kumar

The current study investigates sericite clay as an alternative source of potash and alumina. The alumina and potash content in the sericite is approximately 35 and 10%, respectively, compared with 50–55% in bauxite ore. Muscovite and illite phases are stable, and direct leaching is found to be ineffective. Here, planetary ball milling was performed, which provided dissociation of stable phases to relatively reactive phases. The milling led to a five-fold increase in the surface area, resulting in enhanced leaching kinetics even at low acid concentration. The statistical design obtained optimal conditions of 8 h of milling followed by leaching in 1.73 M HCl at 75 °C, yielding 82% alumina extraction in precipitate with 85% purity in γ-alumina form and 63% potassium dissolution in sylvinite phase. The yield of the precipitate was ~65–68%, and the acid leach residue contained primarily silica.

By S. E. Phillipson

The Late Miocene San Cristobal Ag-Zn-Pb deposit represents syngenetic and epigenetic mineralization with low- and high-sulfidation characteristics. Geology is characterized by barren dacitic ring fracture domes, mineralized resurgent rhyodacite domes, strongly altered and mineralized tuffaceous lacustrine sedimentary rocks, and an extensive crystal-lithic tuff debris apron. The ore body is hosted by intra-cauldron sedimentary rocks and breccias. Fluid inclusions suggest that silver, lead, and zinc were transported as chloride complexes and precipitated by cooling in veins from <5 wt. % NaCl eq. fluids at 170°-215° C. Silver associated with resurgent rhyodacite was transported as a chloride complex and precipitated by increased H2S activity or increased fluid pH.

Jan 1, 2001

By R. Bhaskar

The control of quartz levels in the respirable dust requires an approach different from that used to control respirable coal dust. The unique physical properties of quartz have to be utilized when developing quartz dust control systems. Also, techniques that modify the surface properties of quartz dust so that conventional dust control measures are effective should be explored. For instance, the wetting characteristics of quartz can be modified so that the capture efficiency of the quartz dust can be improved. Foam sprays assist in modifying surface wetting characteristics. This paper summarizes the results of a study that was conducted in an operating mine to evaluate the effectiveness of a compressed air foam spray system installed under the boom of a continuous miner and directed so as to cover the pan and the gathering arm. The objectives of the study were to evaluate the effect of the foam underboom sprays on (1) the respirable dust concentration in the ambient air, (2) the quartz concentration in the respirable dust. The engineering design of the foam generation and delivery system is described in the paper, followed by a description of the mine and the dust sampling strategy. The data were analyzed to study the effect of foam on respirable dust and quartz concentrations at the miner cab, face return and the intake. The results of the data analyses and costs are presented in the paper.

Jan 1, 1991

By B. F. Naylor, C. H. Shomate, F. S. Boericke

"Ilmenite is the most important titanium-bearing constituent of titaniferous iron ores. Such ores, of which the United States has abundant reserves, are of interest because they constitute an important potential source of both iron and titanium that may be tapped in times of stress, and which eventually may be utilized in the normal course of events.As the iron and titanium constituents of titaniferous iron ores are not completely separable from each other by ore-dressing methods, any process for metal recovery will, of necessity, involve reduction of the iron in ilmenite. Consequently, knowledge of the thermodynamic properties of ilmenite should supplement information already available concerning those ores. With this in view, the Pacific Experiment Station of the Bureau of Mines undertook to evaluate thermodynamic properties; the data obtained are the subject of this report.Three types of experimental work were involved. First, low-temperature specific heats of ilmenite were measured in the temperature range 500 to 29S° K. These data serve to evaluate the entropy, a quantity necessary for a reliable evaluation and correlation of other thermodynamic properties. Second, high-temperature heat-content measurements were made in the temperature range 298° to 1,743° K. The data serve to bridge the gap between room temperature and elevated reduction-process temperatures. Finally, hydrogen-reduction equilibria were measured in the temperature range 1,220° to1,375° K. These data-give a direct measure of the free energy of reduction of ilmonite at these temperatures and, in conjunction with results of the other two types of measurements, serve to obtain the heat of formation of ilmenite, a quantity not readily determinable by direct calorimetric means.The data are correlated to form a composite, self-consistent portrayal of the thermodynamic properties of ilmenite, which may be used in evaluating the efficacy of any reducing agent of known thermodynamic properties. Selective-reduction of iron in ilmenite by hydrogen, carbon monoxide, and carbon are considered in this report."

May 1, 1946

By C. O. Hawk

As an exploratory effort to produce useful products from coal by a new path, the Bureau has made a few experiments on the fast heating of finely ground coal particles by irradiation with a flash of high intensity light. The flash was produced by an electrical discharge at high voltage through a xenon-filled tube. The flashes lasted from 2 to 3 milliseconds. The reaction took place in small sample tubes, ½ inch-dimeter by 4 inches long, and with small amounts of coal (total amount charged 0.1 gram, probable effective amount not more than 20 milligrams). Average particle size of the coal, estimated on a numerical basis, was 20 microns. Temperatures reached were evidently quite high, because all products obtained in quantity were characteristic of high temperature pyrolysis. Apparently, conversion of the coal was extensive where isolated particles received the full benefit of a flash. It seems particularly significant that acetylene was present in appreciable amounts--comprising almost 3 percent of the total gaseous product in one case. This is good evidence of a short heating period to very high temperature (well above 1,000° C) followed by rapid quenching. Although the results are interesting, they do not suggest any immediate practical application.

Jan 1, 1963

By R. M. Hardgrove

PULVERIZED coal was first used for firing cement kilns about 45 years ago, with such success that it has continued in general use. Based on cost, pulverized coal is usually the most economical fuel. In some localities natural gas or oil is cheaper, but 85.5 per cent of all cement kilns at present are fired with pulverized coal. The pulverized-coal flame is well suited to kiln conditions. Its soft, luminous nature gives it a high radiating property and the length of the flame can be readily varied to suit conditions in a kiln of any length. Ash and slag cause most of the difficulties incident to the burning of coal. In a cement kiln, however, the ash, being similar in composition to the raw mix and being deposited uniformly in the mix and clinker, occasions no difficulty as long as it remains constant in quality and quantity. Until 6 years ago almost all cement kilns using pulverized coal employed the bin system. The coal was dried and pulverized in a separate plant and delivered into a bin at the kiln. Thus the bin system requires driers, storage-type pulverizers, conveying systems, individual kiln bins, pulverized-coal feeders and primary air fans. The direct-fired system requires only a pulverizer and a blower. Fig. I shows typical plants. The first installations of direct-fired pulverizers were of the impact type but fineness of pulverization was both inadequate and variable. About 1927 a few direct-fired installations employing tube-type pulverizers were made, which were much more satisfactory. As more efficient pulverizers were developed from 1934 on, equipment for direct firing was installed at a large number of plants, until now 196 of about 900 kilns in use in the United States are direct-fired. Most of these replaced antiquated bin systems. PROCESS OF BURNING CEMENT CLINKERS The process of burning cement clinkers is fundamentally one of heat transfer. In boilers and other heat-exchange apparatus the area of the surface receiving heat from the gases is the best unit for comparing output. This seems to be equally true for kilns. The inside kiln surface is the heat-receiving surface and its area is used as the unit of kiln size in the following comparisons. Heat input is based on British thermal units in the fuel. E. G. Bailey,1 in his work on boiler-furnace heat absorption, has used the unit "B.t.u. available." This is the practical calorific power of the fuel, plus the heat in the air used for combustion. In other words, it is the heat available for useful work in the furnace or kiln. The unit of kiln output is barrels per hour. The composition of the raw mix, the percentage of water in the slurry of wet plants and hardness of burning all affect the output. These conditions, however, are hard to evaluate and probably have less effect on the output than irregularities of raw feed and clinker discharge and inexpert control of combustion. WET VS. DRY PLANTS The study presented here covers 88 plants, of which 41 are wet and 47 dry. Of

Jan 1, 1941

By W. N. Cathey

Many materials including carbides, silicides, phosphides, borides, nitrides, oxides, and metals were studied by the Bureau of Mines as potential fuel cell catalysts for electroreduction of oxygen in a 1[N]H2S04 electrolyte. The objective of this study was to assess the potential of abundant, low-cost materials as substitutes for platinum or to increase the catalytic efficiency of platinum. Several compounds were rejected because of their reaction in the corrosive environment of the oxygen electrode. However, some of the remaining were the most active catalysts. Activity of carbides such as tungsten carbide could be improved by doping with platinum-group metals, by varying stoichiometry, or by sputtering on a layer of platinum. While no catalysts were found with activity as high as platinum, some compounds were shown to be deserving of further investigation.

Jan 1, 1979

By R. Burkhard

Recovery of metals from complex mixed wastes is a challenging task of modem material and waste management strategies. Thermal methods are an important tool in this respect. Plasma turned out to be particularly useful for treatment of complex or toxic wastes and residuals. In order to study plasma processes at reasonable costs, a pilot plasma plant has been used and wastes like ~pent Raney-Nickel catalysts, copper and ah.:lminum drosses, and. other metal containing wastes were investigated. The paper summarizes the most significant findings

Jan 1, 1995

By C. Gordon Saunders

"The ungraded-fibre mill is located at the mine site and has a rated capacity of 6,600 tons of ore input and 1,200 tons of ung1•aded fib1 •e product per day. Power for operation is obtained from a diesel generating plant located on the site, which has a capacity of 5,300 kW. The preliminary milling process consists of prima1•y and secondary crushing, drying and temporary storage of plus-1 1h -in. material. The final milling processes are two stages of crushing and three stages of screening, with air-lift separation of the fibre from the host rock. The central mill building also houses a machine shop, mill maintenance shops, a mobile equipment overhaul shop, an engine and majo1•-component overhaul shop, and a warehouse. Major changes to the milling ci1•cuits since start-up have been the addition of a larger secondary cone crusher, ct third dryer, adding a rotary distributor to the feed of the screening section and adding an automatic start-up sequence for all equipment except crushers and fans. The operation of the mill is coordinated from a central control room, where a ""mimic"" panel indicates the operation of all major units in both the ore preparation and the screening sections. Product quality is controlled by continuous sampling and frequent labo1•atory analysis, which provide data fm• the adjustment of aspirating hoods and mill feed rate. Operating problems unique to this location, and common to a sub-arctic environment, are discussed."

Jan 1, 1976