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By L. Mukka

The existing main mine ventilation system for the production areas to the Kiruna mine was constructed during the period 1994-1996 and extended with 4 more shafts, including fan stations, for the sea ore body from 1997-1998. Two papers have been presented from this project at the 7th US Mine Ventilation Symposium in 1995 and at The 6th International Mine Ventilation Congress in 1997. In 2005, pre-studies for a new main haulage level were started. Different haulage methods were presented including ventilation systems. The pre-studies showed that the existing ventilation system, including fan stations for the new main haulage system in the production area, could be extended. However, a new system for the central area, which was not in the initial investment program, would be needed. In the beginning of 2006, a decision was made to design a new ventilation system for the central area to make it possible to get air to the development work for the new main haulage system, independent of the haulage method. This system was operational by the beginning of 2007. The new main haulage system, which was decided to be located on level 1365 m, only requires that the existing shafts be extended - the capacity of the fans seems to be enough. However, the problem is that the existing level 1045 m and the new level 1365 m have to be in operation in parallel for approximately 7-8 years. The challenge for the moment is determining how to ventilate the production areas for both levels at the same time, while simultaneously constructing the extended system. This paper will describe the problems associated with the extension of the main ventilation system and some potential solutions for these problems. The new main haulage level 1365 m must be in operation by 2012.

Jan 1, 2009

By D. Chadwick, J. W. Matousek

Between 1860 and 1890 -- from the time of the American Civil War to the last decade of the 19th Century -- nickel production in North America was dominated (even monopolized) by the output of the industrial complex of the Gap Nickel Mine near Lancaster, Pennsylvania and the American Nickel Works in Camden, New Jersey. In some years, from one sixth to one third of the world's metallic nickel supply came from this enterprise. Mining and smelting were conducted at Lancaster; a matte of high iron content was shipped to Camden for pyrometallurgical and hydrometallurgical refining to produce nickel metal, copper sulfate, and cobalt oxide. The high purity nickel product was rolled into sheet for marketing, primarily for coinage, as nickel had few other uses at that time. The undertaking experienced all of the problems that face the mining and metallurgical industries of today: declining reserves, high labor and fuel costs, high transportation costs, fluctuating demand and prices, pollution concerns, and foreign competition. The technical features of the geology; the mining, smelting, and refining operations; and some of the economic aspects are assessed. The view is taken from that of the present time -- seeking those lessons from history that we are supposed to learn or face the prospect of repeating the mistakes of the past.

Jan 1, 2005

By Alexandre Rizek Schultz

Silat, Siderúrgica Latino-americana, selected Russula as the main engineering contractor for their 700,000 tpy Greenfield steel plant dedicated to long and flat steel production. The project is currently under construction in the district Guararu in Caucaia in the metropolitan region of Fortaleza. The project will be developed in two phases. First phase: 600,000 tons per year rebar mill and 60,000 tpy steel mesh line; Second phase: 700,000 tpy melt shop (90 ton/hr EAF and 4 strand continuous caster for billets up to 180 mm x 180 mm).

Aug 16, 2017

By H. B. Bell, P. C. Lidster

A study has been made of the use of ThO2-Y2O3 solid electrolytes to determine activity of chromium in Fe-Cr and Ni-Cr alloys in the temperature range 1300° to 1700°K. This method has been shown to give results which agree with the best vapor pressure measurements. SEVERAL investigations1"5 have been made of chromium activities in Fe-Cr alloys. Most of these have been made by vapor pressure measurements using knudsen cell techniques while one has been made using gas equilibration with H2/H2O gas mixtures. In the present investigation electromotive force measurements have been made on this system using a thoria yttria solid electrolyte. This system was -chosen to establish the technique of measurement at low oxygen potentials, before extending it to Fe-Ni-Cr alloys. The cell used was Pt Cr • Cr2O3 ilThO2 • Y2O3 llalloy • Cr2O3 IPt Since the oxygen pressure of the chromium-chromic oxide mixture lay in the range 10"19 to 1027 atm in the temperature range investigated, thoria yttria electrolytes were used. It was soon found during the investigation that considerable care was required to prepare satisfactory electrolytes and a study was made to find the best method of preparing pellets of TI1O2-Y2O3 solid solution of as near theoretical density as possible. Various compositions in the range 2 to 15 mole pct Y2O3 were studied but the experimental measurements were made with electrolytes containing 4 to 5 pct Y2O3. The method of preparation finally adopted was to use thorium oxalate and yttria as raw materials. The thorium oxalate was decomposed at 900°C for 6 hr to give a reactive powder. This powder was then mixed with the appropriate amount of yttria and ground in an agate mortar for about 4 hr. The powder was moistened with absolute alcohol as a lubricant and pressed in a metal die at a pressure of 7 tons per sq in. The pellets were then heated at 1100°C for 24 hr followed by 24 hr at 1250°C. After this firing cycle the material was reground and repelleted and again fired at 1100° and 1250°C followed by heating for 7 days at 1600°C. It was found in later experiments that a further firing of 4 hr at 2000°C improved the density further and gave pellets of only 2 pct porosity. After firing, the pellets were polished on emery paper and finally with the 2 µ diamond paste. The polishing was followed by a final firing of 24 hr at 1500°C. Investigation showed that this final treatment minimized reaction between the electrolytes and chromium oxide. It was believed that this was because of a lowering of the surface energy of the electrolyte surface. Two types of investigation were carried out to check that the pellets were satisfactory oxygen ion elec-

Jan 1, 1970

By K. D. Peaslee, V. L. Richards, C. H. Rawlins, S. N. Lekakh

"Steel-making processes generate carbon dioxide air emissions and a slag co-product. The aim of this project was to develop a functional sequestration system using steelmaking slag to permanently capture carbon dioxide emitted in steelmaking offgas. A possible parallel benefit of this process would be rapid chemical stabilization of the slag minerals with reducing swelling or leaching.This paper summarizes the original results of the project, including mineralogical and structural features of carbon sequestration with steel making slag, mathematical modeling of reaction phenomena using a modified shrinking core model, METSIM modeling of several possible industrial applications, a thermo-gravimetrical study of the reaction between slags and different gases, and design and testing for a lab scale apparatus consisted of two reactors.1. IntroductionThe U.S. produces 9-14 Mt of steelmaking slag annually, which represents approximately 10-15 wt. % of crude steel output.1,2 Primary uses for steelmaking slag include high quality mineral aggregate, Portland cement, unconfined fill, soil conditioning, and pH neutralization of abandoned mine drainage.3,4 The key factor prescribing slag use is the alkaline-earth metal (e.g. Ca and Mg) oxides content, which contribute to overall basicity and cementitious strength. However, as-produced steelmaking slag is chemically unstable. Calcium and magnesium oxides readily form hydroxides and carbonates through reaction with atmospheric gases. Both hydroxide and carbonate formation produce substantial mechanical swelling leading to heave failure in confined construction applications, thus many states dictate stockpile aging for 3-6 months prior to commercial use.5,6 Sequestration of carbon dioxide is a natural corollary to forced carbonation. The conversion of CaO/MgO to carbonates serves both to stabilize the slag, and permanently capture and store the CO2."

Jan 1, 2008

By AIME AIME

BEFORE proceeding with the papers scheduled for the ore and foundry session*, the teller's report on the election of officers for the ensuing year was presented, a; follows: Chairman. G.C. F. MacKenzie; vice-chairmen, C.S. Robinson, J. T. MacKenzzie, C. E. Meissner; executive committee, A. L. Field, R. F. Harrington, E. F. Kenney lit. Waterhouse announced that the fall meeting will be devoted to alloy steel. This meeting will be held in Chicago the week of Sept. 22 in connection with the National Metal Congress. He also announced that oxygen in steel will be the central idea of the meeting which will be held in New York next February. The first paper, entitled "Sintering Limonitic Iron Ore at Ironton, Minn.," was presented by Perry G. Harrison (T. P. 284), the author. Sintering was first un¬dertaken in 1024 to treat Cuyuna range iron and manganiferous ores low in silica and high in moisture and containing objectionable qualities of fine... A Dwight-Lloyd machine was first installed. This machine was replaced by a larger one having a width of 72 in. The power cost was decreased from about $11.22 per ton of sinter on a 42-in. machine to about X0.14 for the 72-in. machine. The tons of sinter per man-shift was increased from 11.86 to 16.77. Improvements embodied in the larger plant reduced the cost of sintering to $0.41. The analyses of iron ore and manganiferous ore and the sinter produced from these materials was used to show the increase in value at the mine resulting from sintering. Crude iron ore actually unsalable was increased in value f.o.b. mine from a theoretical figure

Jan 1, 1930

By G. S. Takenaka

When Bridger Coal Company transformed their operations from surface mining to an underground longwall operation their plans included not only the addition of new mining equipment but also surface fans for a blowing (supply) air ventilation system. The original system concept included a propane gas fired air heater to preheat the intake air during cold weather and a dual parallel fan and duct system. One fan operated to ventilate the mine while the other fan was for stand-by emergency operation. Equipment proposals were submitted in March, 2005 based on the dual parallel fan system. Discussions conducted during the equipment selection process revealed that several alternative system design concepts were available. The alternative concepts included innovation features that not only saved space and cost but also reduced operating expense as well. Many of the features were incorporated into the final design of the system. A comparison of the original system concept and final installation design are presented in the paper in addition to details of the features and the derived benefits.

Jan 1, 2009

By SeyedBijan Mahbaz

Development of Geomechanical Earth Models (GEM) is a prerequisite to reservoir management, involving issues such as stress path analysis, prediction of induced seismicity and sanding initiation, and coupled flow-stress modeling that leads to more realistic predictions of oil rates and rock response. Part of GEM development is the stipulation of the 3-D lithostratigraphic disposition (geometry) which is used to choose the geomechanical units. The digital geological model is then populated with quantitative and semi-quantitative data on rock properties, fluid properties, saturations, initial conditions (p, T, [_]) and other information. Both fluid and solid properties are needed this requires integration of geomechanics skills with geophysical and rock physics skills, and this article deals with a subset of this integration process, with an example from two wells in southwest Iran.Rock physics approaches are used to predict reservoir rock and fluid properties with wellbore and 3-D seismic data, which are also used to interpolate rock mechanics properties to the inter-well regions. The first step in a generic rock physics approach is diagnostic and involves the introduction of a suitable Rock Physics model.Acoustic impedance (AI), shear impedance (SI), and density (_) are the fundamental rock properties usually derived using AVO equations, and these parameters, along with attenuation coefficients, can then be correlated to static rock mechanics properties that define deformability and perhaps even strength. In this study, Poisson Impedance is introduced as a new seismic attribute used for lithology and fluid differentiation in the FahliyanFormation (reservoir rock) in two oil wells in the southwest of Iran. To do this, a novel rock physics model was developed for this naturally fractured carbonate reservoir.Currently, these data are also being used to correlate to a limited rock mechanics data base to develop a more extensive GEM to serve as input to more general geomechanical and reservoir modeling tasks.

Jun 1, 2012

By S. Frimpong

Cable shovels are used for primary excavation in in-situ and/or pre-fragmented formations in surface mining operations. Poorly fragmented hard rock formations and random occurrence of hard boulders in soft formations cause extreme variability of material diggability, resulting in varying shovel stress loading. The stress loading of a shovel’s front-end assembly could result in fatigue failure. Conventional design process, which uses physical shovel simulation studies, is very costly and time consuming for achieving statistically significant results. In this paper, rigid and flexible multi-body dynamic theories are used to develop component stress loading and deformation models of the cable shovel, and solved in the ADAMS/NASTRAN/FLEX environments. Detailed simulation experiments are carried out to examine the performance, reliability, durability and efficiency of the P&H 4100A under varying in-situ formation conditions. The results show areas of high stress fields with a maximum stress of 313.31 MPa at node 441 within the hoist rope. The reliability of the results is confirmed by comparing existing test data. The study is significant because it provides a solid foundation for further study of failure life analysis of the cable shovel components.

Jan 1, 2007

By B. C. Jena

In a chromite smelting process for the production of high-carbon ferrochromium, the slag composition profoundly affects operating conditions and the economic performance of the process. For a Canadian chromite concentrate, optimum slag composition and operating temperature were determined by process simulation with a computer model, which is based on parameters, such as the minimisation of slag volume, liquidus temperature, electrical energy consumption and chromium losses. Chromium recoveries are identified for slag compositions spanning wide concentration ranges within the quaternary system MgO-AI2O3- SiO2-CaO. The simulated data are compared with the experimental results.

Jan 1, 1994

By W. A. Bain

"AbstractProduction from the Excelsior Reservoir has amounted to approximately one million barrels. This production has caused a 'Pressure •drop of 10 p.s.i. from the original pressure of 1,245 p.s.i.g. Volumetric balance calculations indicate that the pool as being produced by a water drive whose strength is •probably unsurpassed in Western Canada. It has also been shown by 'unsteady state' calculations that the reservoir will still be above the saturation pressure of 915 p.s.i.g. at the time of depletion. The average permeability of the producing formation is approximately 1,000 millidarcys and, consequently, well draw-downs are very low. The field is essentially a bottom-water drive and calculations have shown that gravity drainage will greatly assist the recovery of oil. Water flooding data on several cores •have placed the flushing efficiency at •approximately 50 per cent, which indicates a recoverable oil-in-place of 17.7 million stock tank barrels. Calculations and field data indicate that the MER for the early life of this field is probably as high as 8,000 to 10,000 stock tank barrels per day.IntroductionTHE EXCELSIOR NISKU oil reservoir is located about twenty miles northeast of Edmonton. The field was discovered in November, 1949, by Imperial Excelsior N.o.1 well, in Lsd. 13, Sec. 3, Twp. 56, R. 22, W. 4, at a depth of 3,850 feet.Since discovery, development has continued on a 40~acre spacing pattern. At the end of 1951, drilling over approximately 80 per cent of the estimated productive area of 1,680 acres had established 32 we1ls capable •of production. The field •has been fairly well delineated by dry holes on all but the eastern flank ."

Jan 1, 1952

By C. McAllister, D. Preece, J. Berendzen

"The Multiple Blasthole Fragmentation (MBF) model models multiple explosive charge contributions and the effect on fragmentation of delay timing with its associated scatter for each blasthole. The model uses near-field blast vibration attenuation parameters and the ground p-wave velocity as inputs for part of the in situ rock property to model rock fragmentation. It models most blast design parameters explicitly and simulates the effect of wave reinforcement due to the interaction of simultaneously arriving waves or diminishing cooperative contribution from long delay intervals between charges within a blasthole or among blastholes. The fragmentation size is calculated at three-dimensional grid points within a blast, and the fines and oversized blocks are treated explicitly. The model takes a surveyed irregular geometry of the free face of a blast as the calculation boundary.This paper presents a case study on applying the MBF model at an openpit mine. Near-field vibration measurements from signature hole blasts were conducted to obtain the stress-wave magnitude and attenuation parameters as well as ground sonic velocity. A production blast was then monitored with the corresponding fragmentation measured, serving as site-specific inputs to the MBF model. Various blast design scenarios were then simulated to develop ones that provide better fragmentation to improve mill throughput for the mine. IntroductionThe semiempirical fragmentation models currently found in the literature (Cunningham, 1987; Lownds, 1995) cannot explicitly model contributions from multiple blastholes with varying delay intervals. Most of these models are not three-dimensional. Furthermore, these models predict an average fragmentation size within a volume surrounding a blasthole and use the average size to generate a size distribution over the volume. The percentage of fines and oversize blocks is included in the distribution. Typically, such models are inadequate for predicting fines and oversize blocks (Cunningham, 1987)."

Oct 1, 2016

By Lyon F. Terry

ACCEPTED current practice for A the valuation of mineral property is based upon Hoskold's theory and valuation tables first published in 1877, and popularized by Herbert Hoover's "Principles of Mining" issued in 1909. In more recent years the procedure has been developed further in the course of the extensive valuation work required for Federal taxation purposes. The 1-aluation of oil and gas properties and of mines is based upon the same principle-the estimation of the present worth of future net revenues. However, in valuing oil and gas properties the method used for discounting future revenues differs somewhat from that adopted for mines, owing principally to the nature of the re- source. production from oil and gas properties usually declines from year to year, whereas coal and ore de- posits are adapted to a more uniform rate of output.

Jan 1, 1940

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By Jr. Matthews

The Candelaria copper-gold deposit is located in Region m of Chile, 805 kilometers north of the capital, Santiago. Candelaria was discovered in 1987, following a six month exploration program. In late 1986, induced polarization (IP) surveys outlined an anomalously high response within the area of interest. The first test hole bad three intersections totaling 49 meters, with an average grade of 1.97% copper. Drilling eventually outlined approximately 390 million tonnes, grading 1.09010 copper and 0.26 grams/tonne gold. Production began in early 1995 and is estimated at 120,000 tonnes copper and 80,000 ounces gold annually.

Jan 1, 1996

By B Manda, K L. Sandvik, K Musiwa

Mining and processing of pyrite ore at Iron Duke Mine, north east of Zimbabwe, generates large quantities of acidic mine water as a result of the oxidation of iron sulfides on exposure to air and water used in the drilling and blasting operations. The acid mine drainage (AMD) contains elevated levels of dissolved Fe, Al, Mn and sulfate and has characteristic pH values ranging from about 0.50 to 3.00. Handling and disposal of such a drainage places significant impacts on the economics of the mining operation due to the corrosive nature of the drainage on infrastructure, the limitations placed on water reuse and discharge to the environment under a new law governing effluent discharge. Treated sludge at Iron Duke is chemically unstable, changing pH from ~7 to ~3 within four days after deposition in the evaporation ponds. The effluent does not meet the permitted level of neutral pH, 500 mg/l sulfate and less than 2000 mg/l total dissolved solids. Excessive acid seepage from the evaporation ponds has resulted in contamination of the ground water below the ponds area, which shows high mean annual levels of iron (368.67 mg/l), sulfate (1702.89 mg/l) and low pH (2.86) in addition to other pollutants. This poor quality seepage infiltrates into the nearby Yellow Jacket River, contaminating the public water source. Furthermore, a deterioration of the land area and vegetation adjacent to the tailings dump is also observed. Understanding the controls on the neutralisation of acidic drainage and long-term sludge stability after placement in evaporation ponds is essential to minimise costs of closure requirements and for the protection of environment and human health. This study examined the effects of the master variables pH, redox potential, acidity and alkalinity on acid neutralisation. The results indicate that ferrous hydroxides are not as stable as ferric hydroxides and that proper oxidation of iron also leads to better sludge stability, higher treatment efficiency and a manageable sludge viscosity. Metal hydrolysis and secondary mineral formation at the evaporation ponds under a wide range of pH and redox conditions is responsible for equilibrium shifts in metal reactions, resulting in high potential for metal leaching and mobility. Mechanisms of metal attenuation are also discussed.

Jan 1, 2006

By Joseph H. White

In its investigations looking to the improvement of health condi- tions and the increase of efficiency in the mining industry, the Bureau of Mines, in cooperation with the Bureau of Public Health, is studying sanitary conditions in and about mines with the intent of pointing out how those conditions that are a menace to the health of the miner may be most efficiently removed or remedied. An out- line of sanitary betterment work at mining villages in the Birming- ham district of Alabama has already been published by the bureau," and in this bulletin are presented suggestions on the planning of mining towns and the construction of miners' houses. The bulletin does not pretend to be a treatise on the so-called "housing problem," and mentions sociologic issues only incidentally. It is assumed that the influence of proper shelter on health is understood and that not a lack of appreciation so much as a lack of knowledge of the best remedies is responsible for many of the undesirable conditions that exist at mining towns. The purpose of this bulletin is to supply facts on the building of well-lighted, well- ventilated, warm, attractive, and economical houses for miners, these houses being assumed to be units of an industrial village or town the building and management of which are under the control of a corporation, so that special conditions hold which do not apply to houses built and owned by individual miners. From this it is not to be inferred that the company-controlled town is the best system or the only one in vogue. The discussion of this side of the subject in all its phases is too involved to be included in this paper. One element in favor of the company-controlled town is its possible immediate responsiveness. Hence this assumption. Also the assumption is made that a-new isolated town is being built, and hence the selection of the site, the arrangement of the streets, and the situation of the houses are discussed before the house itself is treated, for one of the most important factors in obtaining an economical sanitary house is a well-selected town site. Many of the suggestions, however, may be applied in improving conditions in existing towns, in building new houses in old towns, or in repairing old houses. Emphasis must be laid on the fact that as a rule a mining village has a shorter life than a manufacturing town. Economy is emphasized frequently because the discussion is predi- cated upon the assumption that the miner himself is to pay for all that he gets. House rent will doubtless be expected to bring in a reasonable return on all money invested in streets, sidewalks, water supply, sewer system, and houses; in other words, the town is to be run on a business and not on a paternal or charitable basis. "Fair and reasonable" precludes, of course, the idea of excessive returns. Some companies do not consider it good policy to realize as high a rate of interest as an independent realty company would be war- ranted in realizing. Under some circumstances part of the town improvements might be charged as "expense of the industry," that is, to the consumer. The isolation of a mining town introduces a unique responsibility. As the miners are practically obliged to rent the company houses, the officials of the company ought to scrutinize all expenditures in- volved so that house rent may be reduced to a minimum. In a way the town builders are placed in the position of trustees. They deter- mine, within certain limits, what proportion of a man's wages shall be spent on house rent. This consideration should restrain fanciful and unnecessarily expensive building; the other extreme should like- wise be avoided. True economy should be distinguished from cheap- ness. Ugly, insanitary, uncomfortable shacks should not be built even if, because of their cheapness, there is a demand for them from tenants. The obligation of the industry to society as a whole as well us to the tenant ought to forbid this. A cheerful, strong, healthy, virile race will not rise out of the filth and squalor of cheap hovels. An insanitary environment often does its damage slowly and silently; vitiated air does not, like mine gas, announce its deadly work by an explosion. As Talbot⚫ says: Health depends in part on freedom from infection. The probability of obtain- ing that freedom will be greatly increased by maintaining the body at a high state of vigor, or "vitality," as it is popularly called. This implies the promo- tion of all agencies which have to do with the physical well-being as well as with the control of sources of infection. Many men realize that in building houses for their workmen they are invested with a peculiar responsibility that must be wielded wisely, and in large developments they call into consultation the land- scape architect, the sanitary engineer, and the building architect, as well as the mining engineer.

Jan 1, 1914

By P. Patnaik, F. Cuneo, D. M. Wang

Microwave (MW) energy has been used widely for several decades for communications, food processing, wood drying, vulcanization of rubber and medical therapy. Recently, this technology was found to be capable of successfully sintering ceramic and metallic powder materials, with the advantages of reducing soaking times and sintering temperatures. Unlike conventional heating, MW radiation works through the absorption of the microwave energy by a material placed in an electromagnetic field within the microwave cavity. A far more efficient heating process is produced due to the unique ability of microwaves in selectively heating a pecific part of the material with desirable dielectrical properties. This exploratory research was initiated with the objective of locally sintering the thermal barrier coating of gas turbine components using MW radiation. This novel technique may allow repairing of the component without subjecting the entire piece to unnecessary elevated temperatures and reduction of process time and cost. Y ttria stabilized zirconia was used in this study and sintering was conducted using a multimodal 1.2 kW microwave facility. Three configurations of heating setup were experimented and the preliminary results will be discussed in this paper.

Jan 1, 2006

By K. Negishi, H. Izui, Y. Komiya

"Aluminum has the disadvantage of low strength. In order to obtain the high strength composites, crystals were refined in the composites. Grain refinement was approached at two process points, generating new grains and grain growth. It is important for refinement how to control the grain growth. Spark plasma sintering (SPS) technique and TiB2powder addition prevent grain growth. To investigate effects of strain and additives to the alloy, aluminum powder was sintered at 70 MPa and 80 MPa, changing the content of TiB2additive powder by SPS method. As the results, the crystal grain size was finer in the composite sintered at higher sintering pressure and with larger amount of additive, though over 1.0mass% TiB2addition dissuades grain refining. These grain refinements improve hardness and tensile strength of sintered aluminum alloys.INTRODUCTIONAluminum matrix composites have low density, high specific strength, and low cost. Their applications are growing continuously in the field of automotive and aerospace industries. Recent studies to improve their good mechanical and tribological properties use different ceramic materials such as Al2O3(Das, Munroe, & Bandyopadhyay, 1996; Ashwatha & Anthony Xaviorb, 2014),SiC(Hassani, Bagherpour, & Qods, 2014), B4C(Ehsan, Masoud, Touradj, Amir Hossein, & Ali, 2015),TiC(Ehsan, Ali, Masoud, Kamyar, & Touradj, 2017), and TiB2(Fei & Zhong-Hua, 2013).On the other hand, grain refinement is also an important techniques for improving the properties of aluminum alloys. Finer grains improve the mechanical properties of the alloy. For cast and wrought alloys, addition of grain refiners in molten alloys accelerates generation of nucleus and suppresses grain growth. Al-Ti-B alloy is generally added as grain refiners in the molten aluminum alloys(Easton & Stjohn, 2001). Especially, TiB2has very high melting point, low density, and excellent hardness. Therefore, TiB2was selected as additions into aluminum alloys. Liquids reaction leads to high cost, oxidation, discoloration of molten alloy, and clustering of additive powder as compared with solid reaction such as sintering. However, sintering of aluminum alloy powder with ceramic powders is difficult for oxide layer surface. Recently, we take attention to spark plasma sintering (SPS) as advanced sintering process. SPS process can easily sinter a high quality specimen at a lower sintering temperature and in a shorter time than conventional sintering processes. By SPS process, we have sintered titanium powders that are as difficult to be sintered by any other processes as aluminum powders, and improved mechanical properties by adding hard ceramic powders TiC and TiB(Kamegawa, Izui, Komiya, Kobayashi, & Arimoto, 2015; Sampei, Izui, Komiya, Shigimura, & Suzuki, 2015). Furthermore, it is important to consider not only pure aluminum but alloys for solid-solution or precipitation strengthening. Actually, pure Al does not have enough strength compared with the alloys. Al-Cu alloy and Al-Mg alloy demonstrate adequate strength for industrial and commercial sectors. Al-Mg alloy retains good formability, and has high resistance to corrosion. It is therefore used for many applications. We must consider alloying processes. The most cost effective process is blended elemental technology where alloying elements are added to base powder as elemental or master alloy powder (Smugeresky & Dawson, 1981; Yasue, Radjai, Miwa, & Sakaguchi, 2003; Bolzoni, Esteban, Ruiz-Navas, & Gordo, 2012)."

Jan 1, 2018

By A. K. Fallaw, D. L. Taylor, G. Wang, L. R. Moore, S. Dobson, C. B. Parkinson

"Over the years, the decline of high grade ores have become an increasing problem in the global mining industry. As such, techniques and chemistries must change in order to continue to meet the market demand and quality. Reverse cationic flotation of quartz and silicates is one of the most important techniques for generating the industry standard product from minerals such as iron and phosphate ores. Amine collectors are the global standard in such processes. However, as the ore quality continues to decline so must the chemistry change to meet the change in ore composition. This paper will focus on the introduction and full scale application of a novel amine collector towards a cleaner flotation process in phosphate beneficiation with Crago process. The results suggests the collector is capable of improving the phosphate recovery, in this cleaner circuit, to approximately 94% with minimal sensitivity to the everyday changes in feed grade.INTRODUCTION The days of mining high grade minerals are long gone, but the demand continues to increase. Phosphate ore, for example, is most dominantly demanded from the agriculture industry as a fertilizer component (i.e. diammonium phosphate, DAP) (FAO, 2014). Some literature suggests that global food production must increase by approximately 70% by 2050 (Cordell, 2009). It is also suggested that the peak global phosphorus production will occur around the year 2033, which is the period at which the easily accessible reserves have been depleted. Currently, phosphorus is commonly mined with a BPL (Bone Phosphate of Lime) concentration of 12-20% and a remainder typically being gangue minerals such as silica, clays, metal oxides, calcareous minerals, and carbonaceous minerals. These gangue components can lead to various negative processing and utilization consequences. Calcium, from carbonaceous minerals, is problematic due to the elevated levels of sulfuric acid required to convert the phosphate rock to the acid form (SRI Consulting, 2009). Calcium can also lead to elevated dosages of flotation reagents due to the desire of the fatty acid to coordinate to calcium minerals. Carbonate leads to increased levels of foam during the wet acid process. Silica is associated with the level of insols (acid insolubles), which must be less than 10% in the final concentrate that will be transferred to the chemical plant for acidification. Phosphate ore can generally be classified as carbonaceous or siliceous (El-Shall, 2003). Siliceous ores are commonly processed through various sizing steps followed by multi-staged flotation (Figure 1) (FIPR, 2014 & Güven, 2010). Though the higher grade phosphate pebble is declining, many mines are still able to size good enough to produce some amount of such pebble. Unlike most metal flotation processes where grinding is a necessity for an optimal process, Florida phosphate flotation does not generally require aggressive grinding and can typically operate at 0.1-1.0 mm. The rougher flotation step applies pH modification to achieve the optimal pH of 8.8-9.3 followed by conditioning with a fatty acid type collector, which builds a hydrophobic waxy layer on the surface of the particle to assist in the flotation. This generally achieves higher than 85% recovery of a product with 50-60% BPL and 15-30% insols. Unfortunately, DAP production generally requires 3.5 tons of phosphate rock containing greater than 63% BPL to produce 1 ton of phosphoric acid (ArgusMedia, 2014). Thus, further purification is required to achieve the grade by the chemical plant for fertilizer production. After the fatty acid is scrubbed off the phosphate particles using sulfuric acid (pH 2.5-3.5), the pH is generally operationally readjusted to 6.5-7.2 by washing with “fresh” water. A second collector is applied prior to the cleaner, which is a reverse cationic flotation process. This collector is typically a cationic amine based reagent, which should have an affinity for silica containing mineral"

Jan 1, 2015