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By Mark R. Pettitt

Noise surveys conducted in underground coal mines have consistently indicated that auger mining machines subject the operator and helpers to excessive noise exposure. The machine cutting heads have been identified as the primary noise source. This report documents the research program conducted to (1) investigate the nature of the cutting head noise problem, (2) develop noise control concepts, (3) devise in-mine survivable techniques to implement the noise control concepts, and (4) build and demonstrate prototype reduced-noise auger miner cutting heads. The dynamic forces generated during coal cutting by the brittle fracture of coal are predominently low frequency. The low-frequency (less than 1500 Hz) structural response of the cutting head, therefore, determines the noise radiated by the cutting head. The most feasible methods of reducing the cutting head low-frequency response are to increase both the structural stiffness and the low-frequency damping. A technique was devised to achieve these goals. The standard plate helix was replaced by a sand-filled hollow helix of triangular cross section, and the core diameter was increased with an attendant reduction in helix depth. Extended in-mine tests demonstrated the operational capability of the reduced-noise auger cutting heads. The simple noise control concepts are valid for all continuous miner cutting heads. The sand-filled hollow helix technique, which achieved a 10 dB(A) noise reduction for the auger, can be used on any helix-bearing Cutting head.

Jan 1, 1983

By Donovan J. Benton

Photogrammetric methods are advancing rapidly and show considerable promise as a ground control research tool. The ability to quickly capture three-dimensional geometry, especially changes in geometry, in underground and laboratory settings is a significant advance from point distance measurements. Photogrammetry is being applied in both of these settings as part of the NIOSH ground control research. This paper describes these applications and the equipment and software being employed. It also describes tests conducted to quantify the accuracy of these systems. Accuracy varied with system specifics and procedures. A factory-calibrated camera produced results within 1/32 of an inch, plus 0.04%. A user-calibrated camera was found to be less accurate, at 1/20 of an inch, plus 0.24%. These calibrations demonstrate that photo grammetry can produce research quality measurements in laboratory and mine settings.

Jan 1, 2014

By H. Forrest

Lead smelting at Cookson Industrial Materials was formerly carried out using a combination of Blast and Reverberatory Furnaces. In the late 70' s these furnaces were replaced by two 20 tonne capacity Rotary Furnaces. This furnace type has proved to be more flexible in the range of feedstock that can be processed, including lead drosses, battery plate and even whole batteries. High rates of production have been achieved whilst attaining a good level of environmental control. The majority of the sulphur in the feedstock can be fixed by use of appropriate fluxes.

Jan 1, 1990

By Darrel W. Hansen

Morrow Point Dam and Power Plant are principal features of the Bureau of Reclamation's Curecanti Unit of the Colorado River Storage Project. They are under construction on the Gunnison River 20 miles east of Montrose, Colo. Johnson-MK is the prime contractor, and represents a joint venture of Al Johnson Construction Co., Minneapolis, Minn., and Morrison-Knudsen Co., Inc., Boise, Idaho. The power plant will be housed in an underground chamber in the left abutment, approximately 250 ft behind the original canyon wall. The chamber is 206 ft long and 57 ft wide. The distance from the foundation to the spring line of the roof arch varies from 51 ft in the service bay to 120 ft in the control bay. The roof arch has a rise of 16 ft. The longitudinal center line of the chamber is orientated east-west with the draft tubes discharging nearly due north. Access to the power plant chamber was possible through the cable tunnel, access tunnel, two draft tube tunnels, two penstock tunnels, exploratory tunnel, which became the ventilation tunnel, or the grouting and drainage tunnel leading to the dam. (See Fig. 1.) The shortest and fastest access was through the cable and access tunnels, and the contractor drove these two tunnels simultaneously. The cable tunnel and cable gallery excavation exposed a transverse section, at the west end of the chamber, that was 15 ft wide and extended from the crown to 5 ft below spring line. It was here that arch excavation began. The first 34 ft of advance along the arch was driven on three headings, and the muck was removed through the cable tunnel. Meanwhile, the access tunnel was completed, and a raise was driven from its crown to intersect the advancing arch excavation near the longitudinal centerline

Jan 1, 1968

By Dale E. Berner

A new navigation dam at Olmsted on the Ohio River will be built "in-the-wet" using a lift-in construction method by the Washington Group/Alberici Joint Venture for the U.S. Army Corps of Engineers, Louisville District. Up to 4,000-ton precast concrete dam shell segments will be prefabricated on the Illinois riverbank and lowered into the river on a marine skidway and cradle. A 4,500-ton capacity catamaran crane barge will lift the precast concrete shells and lifting frames from the cradle, and transport them partially submerged to a piled foundation pre-installed underwater. Tremie concrete will be used to compositely connect the shells, piles and sheet pile cut-off walls. This paper focuses on the pipe-pile foundations for this half-mile long navigation dam, and for the temporary precast yard and marine skidway. The dam foundations are designed to resist large ground motions from the New Madrid Fault Zone, and selected production piles are designed to serve as landing piles to support the shells during the construction process. Specific foundation issues addressed in the paper include: pile load tests; production field testing requirements; controlled fixity 24-inch diameter pipe-pile design including seismic considerations; cut-off wall design; sheet pile cellular fixed weir design; isolation jOint design; and temporary works foundation designs for both the precast yard and the marine skidway, including testing of 42-in diameter pipe piles.

May 11, 2007

By G. H. Miller

With the recent advances which have been made in science and technology and the increased use of mathematics in this area, the question of the best mathematics courses for a mining engineer to take is of major importance. The question becomes even more difficult to answer due to the recent increase in the number of different mathematics courses in the last two decades offered by the mathematics departments. Therefore, the National Study of Mathematics Requirements for Scientists and Engineers (NSMRSE) was designed to provide some answers to these questions. Approximately 10,000 scientists and engineers were selected for the Study, These individuals were placed in two categories: (1) The Awards Group, recipients of national honors or awards and those recommended by the members of the Board of Advisors as having national and international reputations in their areas of specialization and (2) The Abstracts Group, persons exceptionally productive in their research, based on the number of journal articles listed in the last five years in the Engineering Index, Scientific and Technological Aerospace Reports, Chemical Abstracts, Biological Abstracts, and the Physics Abstracts. The NSMRSE Course Recommendation Form and the Instruction and Course Content Sheet were constructed with the aid of the Board of Advisors and other consultants. For the Study, 40 courses were selected by the mathematical consultants. In order to make sure that the basic content of the mathematics courses was the same for all respondents, a brief resume of each of the 40 courses was given. The NSMRSE Course Recommendation Form consisted of seven sections. These sections were as follows: Section 1, 38 different specializations; Section 2, orientation of work (applied through theoretical); Section 3, highest degree obtained; Section 4, place of employment (academic, nonacademic); Section 5, administrative capacity (administrative or nonadministrative); Section 6, age groups (five-year intervals). Section 7 contained the 40 courses which were to be marked according to five categories: (1) Course Length, 3 to 36 weeks; (2) Applied-Theoretical Orientation, a five-point scale; (3) Course Level, freshman through graduate; (4) Knowledge of Course; and (5) Use of Course Content in Work. The Analysis The report of the data is based on the replies received from 44 mining engineers. This group was part of the Awards and Abstracts Group for all engineers. The resume of the recommended courses is reported in quintiles (upper fifth to lower fifth), since recommendations of this kind are not precise. The results of the Study are based on recommendations of the most active research men in engineering in the U.S. today; therefore, the reader should realize that these course recommendations represent an upper bound of mathematics requirements for the Ph.D. in both undergraduate and graduate work. Conclusions and Recommendations 1) Mining engineering students who plan to be active research specialists should take all those courses which are "very highly recommended" (80-10070) and "highly recommended" (60-79.9%). Those courses in the upper two quintiles and recommended by most mining engineers are: first-year calculus, third-semester calculus, elementary differential equations, applied statistics, and machine computation. Courses of "moderate recommendation" (40-59.9%) are: vectors, intermediate ordinary differential equations, the first course in partial differential equations, elementary probability, and linear programming. 2) The great majority of mining engineers indicated that they prefer a course which is concerned primarily with applications. Only the standard courses such as first-year college mathematics, calculus, differential equations, and advanced calculus received a recommendation for 50% theory and 50% practice. Therefore, all mathematics courses given to mining engineers should contain many applications and little theory. Engineers in both the applied and the combination (ap-plied-theoretical) groups indicated a definite need for applications in all courses. 3) In general, recommendations were for mathematics courses to be given for short intervals of time such as 3, 6, or 12 weeks. Only the standard courses mentioned previously received the usual one-semester or one-year recommendation. Therefore, it is of value to combine several related courses into a one or two-semester course so that the mining engineering student could acquire important mathematical knowledge at an early date in order to prepare him for his research. 4) There was little use for the newer courses in modern mathematics such as the functional analysis sequence, the modern algebra sequence, and the group theory sequence. In addition, there were uniformly very low recommendations (0-19.9%) for multilinear algebra, complex variables, mathematical logic, special functions, integral equations, approximation theory, analytic mechanics, integral transforms, and geometric algebra. Therefore, these courses should be given a low priority. 5a) Comparisons among mining engineers with different backgrounds showed that the combination ap-plied-theoretical group recommended more mathematics than the applied group. 5b) There was little difference in recommendations between the administrative group and the nonadminis-trative group. 5c) Analysis of age groups showed that those in the lower age groups gave significantly higher recommendations to courses such as the first course in partial dif-

Jan 1, 1971

By A. M. Stone

Following the conceptual idea of a Continuous Elution Process early in 1982, the system was successfully pilot plant tested at Western Mining's Kambalda gold plant in December 1982. As a consequence of these tests the Ok Tedi elution ciruit design was changed from batch operation to continuous operation resulting in a reduction in the number of similarly sized elution columns from five operating with one standby to one operating with one standby and halving the process steam requirements. In addition to providing significant capital and operating cost savings the continuous process was simpler to operate than the batch process.

Jan 1, 1989

By W. Spencer

An examination is made of quality standards in castings produced by the South African foundry industry, and some examples are given of the consequences of poor quality to the user. Corrective measures are suggested.

Jan 1, 1981

By Giacobbe Braccio, Alessandro Blasi, Assunta Romanelli, Massimo Morgana, Corradino Sposato

The solvent extraction technique is the only industrial way used to separate and purificate yttrium from other rare earths. In order to improve this process several extractants have been tested during last years. In this work, the behavior of sec-octylphenoxy acetic acid (CA-12) in Yttrium recovery from high concentrated heavy rare earth mixture was investigated. Sodium hydroxide solution was used in order to presaponify organic phase composed by CA-12 and Tributyl phosphate (TBP) diluted in kerosene. In the investigated condition, TBP confirmed its role of phase modifier not significantly altering the extraction behavior of CA-12. The CA-12-TBP system showed a high affinity in extraction for lighter rare earths such as Sm, Eu, and Gd, leaving yttrium in aqueous phase. Using a feed concentration (P [RE]) of 1 M, organic mixture is capable to extract around the 70% of metals in a single extraction test showing this extraction sequence Y < Lu < Yb < Tm < Er < Ho < Dy < Tb < Gd < Eu < Sm. Moreover for [CA-12] = 1.79 M and [RE] = 2 M the instability of extraction system occurs.

Mar 1, 2017

By Maria das Graças da Silva Valenzuela, Guillermo Ruperto Martin Cortes, Francisco Rolando Valenzuela-Diaz

Bentonites are an important kind of industrial clays with more than a hundred different uses. In the oil and gas industries they are used as thixotropic additives for drilling fluids and also as sorbents for purification of flows and effluents. Due to the mechanical and thermal properties that they exhibit, bentonites will become in a near future important fillers in clay/polymer nanocomposites which could be used in the oil and gas industry for replacement of various metal components. In this paper a chocolate color bentonite from the state of Paraiba in Brazil was characterized by diverse techniques such as XRD, DSC/TGA, surface area, and cation exchange capacity and it was studied its potential use as thixotropic additive for oil and gas drilling fluids and assorbents of oils. The bentonite showed good potential for use in those applications.

Mar 1, 2018

By A. B. Cecala

Video technology coupled with data logging exposure monitors have been used to evaluate worker exposure to different types of contaminants. However, previous application of this technology used a stationary video camera to record the worker?s activity while the worker wore some type of contaminant monitor. These techniques are not applicable to mobile workers in the mining industry because of their need to move around the operation while performing their duties and tasks. The Helmet-CAM is a recently developed exposure assessment tool that integrates a person-wearable video recorder with a data logging dust monitor that are worn by a miner in a backpack, safety belt, or safety vest to identify areas or job tasks of elevated exposure. After a miner performs his or her job while wearing the unit, the video and dust exposure data files are downloaded to a computer and then merged together through a NIOSH-developed computer software program called EVADE (Enhanced Video Analysis of Dust Exposure). By providing synchronized playback of the merged video footage and dust exposure data, the EVADE software allows for the assessment and identification of key work areas and processes, as well as work tasks that significantly impact a worker?s personal respirable dust exposure. The Helmet-CAM technology has been tested at a number of metal/nonmetal mining operations and has proven to be a very valuable assessment tool. Mining companies wishing to use this technique can purchase a commercially available video camera and an instantaneous dust monitor to obtain the necessary data, and the NIOSH-developed EVADE software will be available for download at no cost on the NIOSH website.

Feb 27, 2013

By AIME AIME

MATTERS pertaining to mine ventilation were, taken up at the annual meeting Wednesday morning with E. A. Holbrook in the chair. In the absence&apos; of its author, G. E. McElroy, the first paper, entitled "Economic Size. of Metal Mine %Airways," was read by title by the chairman. The second paper, "Intermittent Mine Ventilation," by Oscar A. Glaeser, was &apos;abstracted by Dan Harrington. It related to metal-mining practice, being inapplicable to coal mining, of course. B. F. Tillson asked how the ,quantity of air was measured and con- trolled in the different splits and Mr. Harrington stated that an anemometer presumably was used and that split- ting was controlled by adjusting the steel doors to the desired position by means of screws. George &apos;S. Rice asked if the fan were underground, and Mr. Harrington replied that it was. Although he had at, one time recommended that it be placed&apos; on the surface, certain factors led the management to keep it underground, a. location that has several advantages in this particular case.

Jan 1, 1932

By Leo F. Reinartz

Part II of a four-part series on the history of steelmaking in the US, points out the inadequate safety and living conditions that existed in steel mills at the turn of the Century. Also defined are furnace and process developments. OPERATIONS in steel plants today are highly mechanized. Men work in light, clean, orderly melting shops, making it difficult for old timers to convince young men that primitive, hazardous conditions existed in steel plants at the turn of the century. Working conditions then were very poor as compared to present day standards. In small plants especially, sanitary, locker, and washroom facilities, first-aid practices and stations were un- known Accidents were frequent and severe. Workers had a fatalistic attitude toward getting hurt. He who had an accident was looked upon as a hero. A dirty bandanna often served as a bandage. Infections were frequent. Electric cranes were in their infancy and broke down often Cables had not as yet replaced chains. Pig iron and scrap iron were loaded by hand in the stockyard, and stockyard locomotives were un- known; mules served as the usual motive power. It was not unusual to see recorded a delay of ½ hr in charging a furnace because of a balky mule. Furnace operations A few plants had primitive charging machines, but most furnaces were charged by placing scrap or pig iron on the paddle of a long peel, which rested on a bar across the furnace door opening. Laborers at the handle end of the peel, using the bar as a fulcrum, would heave the material into the furnace by a down and sideward motion of the peel handle. In time they became expert in placing these materials in the furnace, but it was hard, hot work, and a long time was required for charging. Cold charges of 25 tons required more than 12 hr for melting and re- fining the steel. Ports, doors, and frames were not water cooled. The charging and working area in front of the furnace was covered with steel plates. They were hot and often warped by the intense heat of the un- insulated checker chambers directly below. In the summer, working conditions on the charging floor were almost unbearable. Silica refractories were of poor quality. Because of this, and the inadequate training of furnace men in fuel control and furnace operations, roofs, front and back walls, and ends burned out rapidly. Dolomite machines were unknown; consequently, furnace banks and hearths were fettled with dolomite by the use of hand shovels. The round system required six or more men. Each man took a shovelful of dolomite and, in his turn, deposited it on the back wall and bank by a dexterous forward swing and twist of the shovel. The upward swing of the shovel partially protected his face from the searing heat of the furnace coming out through the wide-open door. Considerable skill and stamina were required to do this job properly. Reverse valves, usually of the cast-iron butterfly type, were located below the charging floor. They were operated by long levers on the charging floor level men they became warped, because of heat and abuse, great strength and skill were required to reverse them. Furnace operations were difficult. The quality and quantity of producer gas coming from irregularly stoked, hand-operated gas producers was uncertain and unreliable. Furnace Linings and ports were quickly burned out. Poor bottom and side-wall refractories, indifferent and inexperienced crews, as well as irregular re-

Jan 1, 1961

By J. J. Talja

An investigation of oxidation of various nickel concentrates was carried out using differential scanning calorimetry (DSC). The aim of this study was to determine the ignition temperature and investigate other oxidation behavior of various sulfide-based nickel concentrates. Variables in the experiments were mineralogy, particle size and partial pressure of oxygen with temperature increasing linearly at 25 K/min from 323 to 1023 K (50-750 °C). The igni¬tion temperature was determined to represent the starting point of rapid oxidation. The reac¬tion enthalpies of the concentrates were determined and the amount of heat generated up to various time were used to calculate the extent of reaction. Mineralogical changes at various stages of oxidation were also investigated. For this purpose a second set of DSC-experiments were carried out in which each experiment was interrupted at a desired temperature between 673-873 K. From these tests the weight loss of samples were determined and changes in the individual constituent of sulfide minerals were analyzed. For pentlandite-based Ni-concentrates the ignition temperature was 705-710 K (approximately 435 °C). Pyrite was the first sulfide to oxidize. Reactivity of the violarite-based concentrate was greater than those of the pentlandite-based concentrates. The stoi-chiometry of pentlandite changed before ignition because of preferential oxidation of iron. Rapid oxidation of the pentlandite mineral occurred at about 823 K (550 °C). By 900 K about 90 % of the iron in pentlandite was converted to hematite, and NiS containing some iron was formed.

Jan 1, 1994

By M. Bozorgtabar

Metal Matrix Composites (MMC) have a ductile matrix containing ceramic particles, Due to their improved wear properties, Al?SiC composites have economical applications in many industrial uses where wear is a problem, One of the most serious difficulties in manufacturing Al-SiC composites is obtaining adequate &apos;wetting&apos; of the particles by the melt. In this research work, a stir casting system was designed for the improved manufacturing Al-SiC composites, The effect of some production variables such as the addition of SiC particles to the aluminum melt on wettability, was also studied. The results showed that the manual addition of particles would not be successful in manufacturing and that a system of adding silicon carbide particles through controlled temperature, atmosphere and improved mixing was needed.

Jan 1, 2005

By W. Clark Ashby

Productivity is a fascinating concept. Like motherhood or apple pie, we know it as a good thing. Just what it means is not so clear. To a coal miner we assume it means tons of coal hauled from the mine. To the company president it means profit after capital, labor, and other costs have also been reckoned. To the government economist it means output in a balance of payments. What does it mean to the biologist, and can reclamation really be productive? In this paper we discuss productivity from a biological viewpoint, give some yield data for various types of reclamation plantings, and discuss how our demand for or acceptance of differing kinds of productivity is tied up in bigger questions of land use, environmental stability, and resource allocation.

Jan 1, 1981

By C. S. Corbett

There is much comment at present in the ranks of the oil industry regarding unit operation of oil fields and the benefit that would accrue if it could be extensively applied. It seems certain that, as an immediate corrective of the present situation, overproduction could be effectively curtailed with all the advantages of proper conservation of petroleum resources and with no important loss to anyone connected with the industry. Unit Operation in Certain Foreign Fields Many an oil operator in America would doubtless like to have exclusive control of one or more oil-bearing structures for development in accordance with the economic position of the industry and especially in accordance with the best production practice known. A few operators now have this privilege, particularly in certain foreign fields, and are following lines of procedure which show that they are aware of the great opportunity that is theirs. We find in an article by Professor Strigeoff,1 and in a paper read by Captain Comins2 before the American Petroleum Institute, the outlines of procedure adopted, respectively, by the Soviet Government for the nationalized Russian oil fields and by the Anglo-Persian Oil Co. for its fields in Persia. Comprehensive plans for the unit operation of other oil fields may have been described publicly but no such descriptions have come to the attention of the writer. New fields are coming more and more into the hands of single operators or of a few who control large activities and who appreciate fully the need for cooperative action and are willing to forego the lure of a large quick profit from high flush production in order to secure the advantage of better stabilization in the industry and a larger though more deferred profit by operating the field as a unit. Much can be done toward efficient development of an oil field controlled by a few operators who are willing to cooperate for that purpose, but the best result can be obtained only by pooling their interests in the field

Jan 1, 1930

By Alla D. Mah

The heat of formation of scandium sesquioxide (Sc203) has not been measured previously, and existing values for gallium sesquioxide (Ga203) are subject to large uncertainties. As a consequence, thermodynamic calculations involving these oxides hare lacked scientific exactness. This paper reports newly determined values of the heats of formation of gallium and scandium sesquioxides at 298.15° K., by combustion calorimetry. The corresponding free energies of formation are derived from heat and entropy data.

Jan 1, 1962

Alfred Stansfield, Montreal, Canada:—In Professor Howe&apos;s paper on the position of Ae3, he shows its industrial importance in determining the temperature to which steel should be heated for " grain refining." Several years ago I carried out a research on the " burning " of steel and found that while hypo-eutectoid steel should be heated to Ae3, hyper-eutectoid steel that has been very much overheated must be reheated to the curve Sa on the carbon-iron diagram, in order to redissolve the pro-eutectoid cementite and thus to obtain recrystallization and grain-refining. This treatment was necessarily only partly successful, and I should like to ask whether the conditions of heat treatment for refining overheated high-carbon steels have been ascertained. Speaking of the &&apos;Persistence of Solidificational Segregation " Professor Howe quotes an experiment made by Mr. Stead in which a bar of 1.2 per cent. carbon steel was immersed in a large mass of molten blast-furnace slag and allowed to cool with it. The steel was heated ; above the solidus (curve An on the carbon-iron diagram), but below the liquidus (curve AB). A drop of eutectic carbon-iron alloy, rich in carbon, had liquated out and hung below the bar. This agrees exactly with my own observations on the burning of steel, but my interpretation differs somewhat from that of Professor Howe. Professor Howe considers that the fusion of a part of the metal (rich in carbon) shows that the solidificational irregularities of composition had persisted through the rolling and heat treatment of the steel, as otherwise no part of the steel would have been sufficiently fusible to melt. It does not appear to me that such an explanation is necessary. A piece of steel represented in temperature and composition by any point within the area ABa will ultimately resolve itself into a solid phase and a liquid phase in equilibrium with each other. It may appear that if the steel were absolutely uniform no fusion could take place, but, the smallest nucleus of high-carbon, fusible alloy would ultimately bring about this separation into liquid and solid phases, by diffusion of the carbon from the solid to the liquid areas. A nucleus sufficient for the purpose might be provided by an area of pro-eutectoid cementite which had not become diffused during the

Jan 1, 1914

By B McIntosh

Sustainability in its simplest assessment has been defined as æmeeting the needs of the present without jeopardising the needs of future generationsÆ. For the mining industry alone, this statement could indeed be interpreted by the many cynics in our community as an oxymoron; as miningÆs very existence requires the extraction and consumption of finite resources. However for the future of industry as a whole, the integration of mining, minerals processing and manufacturing presents us with a unique opportunity to achieve sustainability through the continued supply of metals and materials for society, in a manner which can achieve positive social outcomes through a triple bottom line approach.The Kwinana Industrial Area has been Western AustraliaÆs premier heavy industrial precinct for more than 40 years and its prevailing level of prosperity will ensure it remains a significant contributor to the State economy through the 21st century.The Kwinana industries depend on each other for the production of essential raw materials vital to their manufacturing and refining process, an innovation that also has significant environmental benefits.Formed in 1991, the Kwinana Industries Council strives to foster positive interaction between member companies and with the local community.The aims are:to co-ordinate the activities of Kwinana industries on a range of common issues; provide effective liaison with the local community; promote a positive image of Kwinana industries; highlight contributions to the community by Kwinana industries; and work towards the long-term viability of the Kwinana Industrial Area. The Kwinana Industries Council facilities these aims by focusing on developing and employing leading edge technology, giving workplace health, safety and environment top priority, and taking a committed, responsible and pro-active approach to environmental protection, whilst forging a two-way partnership with the local community.The sustainability of industry is the key objective for the Kwinana Industries Council and through the involvement of the 13 member companies industry strives to:achieve efficient processing of resources to provide a range of goods and services needed by the community; achieve acceptable and decreasing level of environmental impact; provide jobs and income for our community; and engage co-operative projects that benefit the local communities, the State and Australia.

Jan 1, 2004