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By Diego Berti Salvaro

The morphology, dimensions and chemical composition of tribolayers strongly depend on the pressures and temperatures acting on the contact. They are formed by reactions between the surfaces in contact with each other as well as with the atmosphere, lubricants and possible contaminants. In this paper the influence of test time (180, 500, 1000 and 2500 h) into the formation and characteristics of tribolayers in pairs DLC-stainless steel tested under refrigerant gas R134a atmosphere without presence of lubricating oil was analyzed. The characterization was performed using scanning electron microscopy, energy dispersive spectroscopy (SEM-EDS) (morphology and chemical composition) and white light interferometry (dimensions). The tribolayers thicknesses ranged from 100 to 500 nm and they were composed by elements originated from mutual transfers between the tribological pairs as well as oxides, being more pronounced on the stainless steel surface. The results show that the tribolayers are chemically stable (maintained the same composition over time) and the thickness remained stable after a thousand hours of testing.

Jul 31, 2018

By Robert Hopler

GEO. M. MOWBRAY’S REFRIGERATOR CAR FOR THE SAFE CONVEYANCE OF EXPLOSIVES. It is a fact well known to all miners who have used nitro-glycerin, or any of its adulterations, commonly known as dynamite, rendrock, Hercules’ powder, dualin, vigorite, etc., that when congealed, these compounds cannot be exploded, and in this congealed state — say at temperatures below 40° F. — they can be handled with no more danger than a box of soap or a can of lard. If, then, the atmosphere by which this class of explosives is surrounded, during transportation, be maintained below 40° F., explosion is practically annihilated. Therefore, I constructed a refrigerator car, with cells for every box of the explosive; and two years of railroad transportation confirms our ten years’ experience in teaming in wagons, that this class of explosives can be transported in perfect safety, as above described.

Jan 1, 2011

By K. Fagerlund, L. Rosenback, T. Mäkinen, Y. Anjala

This paper deals with the nickel smelter and refinery concepts Outokumpu has applied at Harjavalta and several other plants. Also other process routes and modifications developed and tested by Outokumpu during the recent years are highlighted. Outokumpu started nickel production in Harjavalta in 1959. Until 1995 the Flash Smelting - Peirce-Smith (PS) converting route was applied. High grade nickel matte from the converting step was further refined by means of leaching and electrowinning to produce cathode nickel. In 1995 the nickel production capacity was increased from 17 000 t/a to 52 000 t/a based on the Direct Outokumpu Nickel Smelting Process (DON). In the DON process PS converting is eliminated and high grade nickel matte with low Fe-content is directly produced in the flash smelting furnace (FSF). Metal values from the smelting slag are recovered in the electric furnace (EF) as iron containing Ni-matte. The DON process can be operated with either two matte concept, where high grade FSF matte and EF matte are produced, or a single matte concept, where EF matte is recycled to the smelting furnace and thus only one type of high grade matte is obtained. The additional refinery capacity at Harjavalta is based on hydrogen reduction producing.

Jan 1, 2005

By Arthur McKee

As HEAT is the controlling factor in all smelting operations, it will be .most helpful to make a new set of calculations on the basis of a .unit of fuel burned at the tuyeres to carbon monoxide. This ties together the only two factors in this operation that seem to be constant with respect to each other-the fuel at the tuyere and the air or its oxygen content. If our usual smelting operations, using natural air heated to reasonably obtainable temperatures, furnish sufficient heat above this critical temperature for the purpose, it is doubtful whether additions of oxygen will be of marked benefit. A unit of fuel will not produce a single heat unit more if burned with pure oxygen than if burned with natural air and less heat will be available per unit of fuel by the amount of heat that is carried in by the preheated nitrogen in the natural air of the blast. This is more readily apparent if considered in connection with a heat balance sheet per unit of fuel at the tuyere. The heat available in the stack, as shown by the committee's report, is less by reason of the lower fuel consumption per unit of output assumed in this calculation. The balance sheet for enriched air shows a shortage of the amount of heat usually carried in with the blast; also a lack in the hearth of sufficient heat to melt the 18 per cent. additional metal and slag and in the shaft to the extent of the shaft heat required to heat the 18 per cent. additional stock to the melting point. These heat deficiencies are provided for by the largely increased conversion of carbon monoxide into carbon dioxide, which is assumed, as shown by the following figures: Calculation for natural air: Carbon dioxide 18.4 per cent. (after having eliminated the carbon dioxide from limestone) and 20.8 per cent. of carbon monoxide. Calculation for oxygen-enriched air: Carbon dioxide 28.4 per -cent. and carbon monoxide 23.2 per cent. (no carbon dioxide from stone as lime is charged instead).

Jan 11, 1924

By K. Spence

"The notion of “value” has always been a subjective and contentious issue. Indeed, value is in the eye of the beholder. There are as varied methods and practices for valuing property, as there are industries in which they are applied. For example, there is replacement value, insurance value, salvage value, appraised value, book value, and fair market value, to name a few, although in the mining industry, valuations usually refer to fair market value.In the Canadian mining industry, at present, there are no comprehensive regulations or guidelines that specify which approaches or methods are appropriate for use in the valuation of mineral projects. In January 1999, The Mining Standards Task Force of the Toronto Stock Exchange and the Ontario Securities Commission recommended that the Canadian Institute of Mining, Metallurgy and Petroleum (CIM) establish a committee to review and advise on approaches and methodologies for the valuation of mineral properties. Among the approaches to be considered are included the following: the discounted cash flow approach, the cost approach, the option pricing approach and the market comparables approach. In addition, methodologies differ depending on whether the project is at the exploration stage or the producing stage.The CIM Special Committee on the Valuation of Mineral Properties (CIMVal) expects that its final report will form the basis for a Canadian code or standard for the valuation of mineral properties."

Jan 1, 2002

By H von Blottnitz, J L. Broadhurst

Eco-efficiency has been proposed by the World Business Council on Sustainable Development as an environmental performance indicator framework that contributes to sustainability by assisting corporate decision makers improve the environmental performance of their operations and processes, while also extracting additional economic value. Given that the recent engagement of the minerals industry with sustainability has highlighted the need for requisite tools and methodologies, it is therefore of interest to assess whether eco-efficiency indicators can drive sustainability performance improvement during process design within the minerals industry. Previous work indicates that the choice of sustainability performance indicators to be used for decision making needs to be governed by the decision context; ie the performance indicators need to be fit-for-purpose. Here, the strengths and weaknesses of eco-efficiency indicators are analysed using case studies. First, a more rigorous definition of eco-efficiency indicators for the minerals industry is proposed based on indicators currently offered in the literature. Two case studies are then selected to reflect typical decision situations encountered within minerals process design. For each case study, eco-efficiency indicators are computed and are compared to more traditional graphical representations of the economic and environmental performance of process design alternatives considered. The sensitivity of these indicators to various process design parameters is also investigated. Results confirm that the meaningful application of eco-efficiency indicators is strongly dependent on the decision context in which the process data is generated. Results also show that eco-efficiency indicators can be related to technical process design parameters to allow for richer communication of performance information for various decision trade-offs; however, in some cases, graphical approaches that provide more insights into the environmental-financial trade-offs should be preferred. The research thus contributes to guiding the selection of the appropriate tools for more environmentally sustainable design of minerals beneficiation processes.

Jan 1, 2009

By Byron B. Morton

NICKEL-BEARING alloys are associated with petroleum in the fields of exploration, production, and refining. In the first- named field the geologist of today makes use of such instruments as the seismograph, torsion balance, and magnetometer, the selection of proper alloys and metals for the manufacture of which is an important matter. Nickel-bearing alloys are useful for parts that require resistance to corrosion or that must have non-magnetic properties. Where special co- efficient of thermal expansion are de- sired, they are obtained by using alloys high in nickel (20 to 60 per cent), since, by varying the nickel contents, alloys can be obtained ranging fro111 "Invar", with a low expansion between -40 and 175 cleg. F., to those with coefficients of expansion exceeding that of steels. The latter are obtained by additions of chromiurn to the alloys. Alloys containing 50 to 80 per cent of nickel, which possess high magnetic permeability, find application in certain instruments where this property is important.

Jan 1, 1935

By H. M. Smith

The production of oil during the early development of new oil fields is usually accompanied by large quantities of natural gas. Since in most fields gas under pressure is the main source of the energy causing the oil to move through the sands into the wells and thence to the surface, coincident production of natural gas will continue as long as present-day producing methods are used. Generally the use of this gas is restricted, since markets are not readily available. Consequently, a large portion of the gas produced is often wasted by being blown into the air. The magnitude of gas waste is well brought out in the following statement by Miller:5 Only a few outstanding examples need be cited to show the enormous production of gas that accompanies the discovery of new sources. In April, 1927, the Ventura field produced approximately 210,000,000 cubic feet of gas a day; and during the summer of 1927 Alamitos Heights reached a peak gas production of 102,000,000 cubic feet a day; on December 1, 1928, as a result of the summer's deeper drilling in the Long Beach field, surplus gas production amounted to 125,000,000 cubic feet a day. It is estimated that in January, 1929, the Santa Fe Springs field will have a daily gas production of 387,000,000 cubic feet from the recently discovered Buckbee oil zone. Of this amount 274,000,000 cubic feet a day will be the surplus above the amount required for field and plant fuel, taken out by utility corporations, and that used in repressuring the Meyer sand which lies above the Buckbee zone.

Jan 1, 1931

By M. L. Apel

A conceptual approach to the bioremediation of uranium mill tailings (UMT) is presented., This approach focuses on, biosorption to remediate the. effluent solution and bioleaching remediate the. solid fraction. Comparative biosorption studies were performed with synthetic single metal solutions using a commercially available biopolymer. The maximum rate of metal sorption by calcium alginate was found to be 5.43, 6,39, 6.48, and 9.74 mg dm-3 min-1 for U022*, Ba2+, Cd2+ and Zn2+, respectively. Activation energy (AEa) for barium uptake by calcium alginate beads was determined to be 11.5 kJ, indicating a diffusion controlled reaction mechanism. Thermodynamic values (AG+ AH+ and ASt) of the metal-alginate activated complex, as reported in the literature, were found to be in agreement with those calculated from this research. Results show that this biopolymer can be effectively applied in the removal of select metals prevalent in uranium mill tailing effluents and associated waste streams.

Jan 1, 1991

By U. Ulusoy

Surface roughness and acuteness are known as the two of the main properties of the particle morphology affecting the behavior of the powders in the process. Since the techniques used for the morphological characterization of powders by 2-dimensional microscopic measurement from the polished sections that have some disadvantages, the 3-dimensional analysis has often relied on measurements of particle morphology. A review of literature data was presented for high-grade barite and pyrite particles ground by ball and autogenous mills to determine the morphological properties using a new 3-D approach based on BET nitrogen gas adsorption and Permaran methods. Micromeritics Flowsorb II 2300 instrument which employs BET nitrogen adsorption technique was used for the specific surface area measurements and the roughness of the particles. Permaran (manufactured by Outokumpu Oy) was used for the measurements of airflow resistance of powder samples for the acuteness. Spherical glass beads were used as reference sample for the acuteness measurements. The obtained parameters, which are surface roughness and acuteness, were corre-lated with the floatability performance of those mineral particles. The flotation performances of those particles ground in different mills (ball and autogenous) were also evaluated by a Hallimond tube. The results showed that lower roughness and acuteness values caused higher flotation recoveries for both barite and pyrite particles that were tested independently in different type of the mills. In other words; particles with smooth surfaces resulted in better floatability for barite and pyrite minerals studied.

Jan 1, 2014

By R. D. Van Zant

The method for smelting zinc in horizontal retorts developed several centuries ago is still in use. This process consists essentially of the reduction of zinc oxide by carbon at 1,200° to 1,400° C. in a fire-clay retort. The reaction is highly endothermic, and a high radiation loss occurs in transferring the heat of reaction through the fire-clay walls. In recent years, silicon carbide retorts with much better heat-transfer characteristics than fire clay have been supplanting the old retorts. The practical impossibility of recovering the carbon monoxide formed in the reduction causes a large loss of fuel. Intermittent smelting is done in small retorts that are manually charged and discharged, and the furnace crews must be specially trained if efficient results are to be obtained. During the past 20 years several processes have been introduced that have substantially improved the horizontal-retort process. One of these, developed by the New Jersey Zinc Co., consists of a continuous process in which a briquetted mixture of zinc sinter, reducing agent, and binder is coked at 750° to 900° C. and charged into a vertical silicon carbide retort. A supply of displacement air or exhaust combustion gas is introduced at the base of the retort at an appropriate pressure in order to keep the zinc vapor from condensing on the cooled residue in the lower part of the retort. Any .oxidizing constituents in the displacement gas are converted to carbon monoxide by reaction with the carbon in the charge. The spent residue is continuously removed at the bottom of tl1e retort. The chief advantages of this process are said to be increased output per man-day, improved working conditions, high recovery of zinc, increased thermal efficiency, and long retort life.

Jan 1, 1950

By J. H. Kempton

The scrutiny given to model predictions of pit-lake water quality has focused attention on the uncertainty associated with long-term predictions. Although comparison of probabilistic predictive modeling of water quality in existing pit lakes indicates that short-term predictions can bracket most parameters, uncertainties in wall-rock reactions and the stability of groundwater composition and climate remain unquantified. This overview of the uncertainties associated with longer-term predictions is presented as support for those considering policy decisions that must be made in the absence of reliable estimates of future conditions.

Jan 1, 1998

By J. Hadjigeorgiou, J. Wesseloo

Mining companies employ a multitude of risk management tools. The effectiveness of these tools for decision-making and communicating risk has not been addressed. This paper investigates the use of verbal probabilistic expressions in communicating geomechanical risk. Analysing survey data obtained from a group of mining geomechanics professionals, it identifies limitations of common probabilistic expressions. The paper concludes by making specific recommendations to avoid the use of certain expressions that may result in increased uncertainty, thus compromising the use of risk management tools.

Jan 30, 2026

By W J. Riva

This paper reviews the circumstances that led to the development and construction of a commercial-scale vertical shaft carbonizer at Conmore, Alberta. This form coking process may be regarded as having potential application in other areas. Coal pelletizing offers a promising method of decreasing coal agglomeration costs under certain circumstances. Pellets can be rolled easily from -35-mesh coal, provided that a minimum of -200-mesh coal is present. Bentonite was found to be the best binder and was most effective when added in amounts of about 2 per cent. The water content of the coal pellets was observed to vary from 18 to 23 per cent. As a by-product of this investigation, it seems possible that fine coal could be converted into stoker feed by this process. A short investigation of the effect of heating rate on the carbonization of pellets was conducted. The low maximum heating rates in certain temperature ranges, necessary to avoid crack formation in the pellets as reported by other

Jan 1, 1964

By J. Forster, C. A. Pickles, Mackowiak. K.

The future development of nickel laterite deposits is crucial with regards to satisfying impending nickel demands. The commercial implementation of new hydro/pyrometallurgical processes in recent years has led to significant improvements in the extraction of nickel from the laterite ores. One potential alternative pyrometallurgical processing route would be to selectively reduce the nickel and produce a concentrate with nickel contents similar to those attainable in the conventional flotation of sulphide ores. However, even bench scale studies have not yet been able to produce a high grade (>15% nickel) concentrate from a low grade laterite ore. The present research involved the microwave vacuum reduction roasting of a nickel laterite ore to yield a high grade concentrate, rich in nickel. Firstly, the effects of temperature and pressure on the nickel grade and recovery were investigated using a thermodynamic model. Secondly, briquettes containing a mixture of charcoal and a low grade silicate nickel laterite ore were reacted in a microwave vacuum system. The experimental variables studied were the input microwave energy, pressure and absorbed microwave power. Thirdly, the ferronickel in the reacted briquette was concentrated by magnetic separation and nickel grades of up to 21% could be achieved.

Jan 1, 2015

By Karsten Beckhaus

"Abstract Tremie concrete for special geotechnical works needs special properties, especially during the casting process. Today’s execution standards for bored piles and diaphragm walls, EN 1536 and EN 1538, as well as the draft version of concrete standard EN 206, all comprise regulations for deep foundation concrete which have not been changed for decades. Considering the recent development in concrete technology at the same time and its actual state-of-the-art, it is essential to develop new normative specifications and specification requirements.GeneralTo allow the required integrity and quality after placing and hardening, concrete for structural elements like bored piles or diaphragm walls, used as foundations of high-rise buildings or as retaining structures for large and deep building pits, must have adequate workability and stability.In addition to requirements on mechanical properties and on durability, both of which have increased within the last decades, concrete must be suitable for being cast in deep or extremely deep excavations, see figure 1. Today’s specialist foundation engineering machinery makes it possible to drill or cut down to in excess of100 m depth. Concrete technology has developed and allows the use of high performance concrete for deep foundations. But is this capability represented by actual regulations?It has become very common for the industry to supply or use concrete with low water cement ratios, nevertheless highly flowable and set-retarded for several hours if needed. Very low water cement ratios allow design strength of 60 MPa or higher (Larisch, 2011), and a very low porosity which is required for a long service life in aggressive conditions, e.g. by chlorides.To achieve best performance, it is obvious that the concrete must completely fill the excavation and fully embed the reinforcement. As vibration of deep foundation concrete is (usually) not allowed and was anyway inefficient, deep foundation concrete must be designed to self-compact under hydrostatic pressure. Generally, it must be considered that after placement the concrete’s quality cannot be influenced anymore. Therefore, both the pouring procedure and the concrete quality must be adequate."

Jan 1, 2014

By D Wyborn, P A. Dowd

The characterisation of rock fracture networks is an important component of rock engineering applications involving stability assessment or fluid flow analysis. However, the derivation of a reliable rock fracture model remains a very challenging problem in practice. This paper describes a Bayesian framework, in the form of Markov Chain Monte Carlo (MCMC) simulation, for the construction of such a model. Model conditioning using different data sources is discussed including seismic events recorded during hydraulic fracture stimulation, rock face fracture mapping data and downhole geophysical survey data. The freeware FracSim3D is used for the simulations.

Sep 26, 2011

By D. Pawelus, J. Butra, R. Debkowski, M. Szpak

Impact of horizontal stresses on stability of underground workings in mines is a very important issue in underground mining. Identification of the initial state of stress in the rock-mass should be one of the main actions taken into account while designing and carrying out the mining activity in underground mines. The paper presents the tests on three dimensional stress pattern in Polish copper mines, owned by KGHM Polska Miedz S.A. Group, carried out in 2012. The research program covered 7 measuring stands in two mines; their average depth was about 1000 m. The main aim was to identify the values and directions of horizontal stresses in order to optimize the extraction and to improve the safety. The overcoring method with the use of CSIRO HI type probe was applied. The paper also describes the measuring technique which was developed for the purpose of specific mining and geological conditions of KGHM mines, taking into consideration the natural hazards encountered there as well as technical and operational capabilities with regard to drilling equipment. The experience gained during the underground measurements and the issue of making such measurements in underground copper mines in Poland are presented in the paper. The stress patterns obtained during the underground measurements are of application importance for the process of designing the spacing of mine workings and improving their stability and mine support selection.

Jan 1, 2015

By M Weeks

Melbourne Water Corporation, through the Pipelines Alliance, has commenced construction of a new drainage pipeline to provide additional flood protection within the Sandgate Avenue Main Drain catchment, in order to mitigate against the risk of flooding of Frankston’s central activity district (CAD).The project involves the construction of a 1550 m long, 2.5 m internal diameter tunnel, commencing upstream at the Monash University Peninsula Campus and traversing approximately west to the outlet located at Kananook Creek. The tunnel was excavated by a dual slurry-earth pressure balance tunnel boring machine (TBM), with the depth to tunnel crown ranging from 0.7 m to 14 m below the natural surface level. The TBM navigated 500 m radius curves, with a maximum drive length of 608 m. The tunnel lining consists of 2.5 m internal diameter, 250 mm thick reinforced concrete jacking pipe.The geotechnical conditions along the tunnel alignment consisted of mixed face ground conditions, predominately clay, with clayey sand and sandy clay and some sand deposits near Kananook Creek.This paper presents the challenges associated with the operation of the slurry separation plant during tunnel construction. In particular, the paper focuses the impact of slurry separation on tunnel advance rates, the lessons learnt during construction with regards to slurry separation and on the decision to adopt a dual slurry-earth pressure balance shield TBM. In addition this paper highlights the importance of having a thorough understanding of the slurry separation requirements on a slurry TBM project prior to selecting the necessary plant.

Mar 8, 2011

By Fabio Santillán, Mario Mauro, Raffaella Granata

"This paper presents the utilization of slurry walls methods for the recent remediation of three high hazard active dams in the United States. Tuttle Creek Dam, located in Manhattan, KS, required seismic retrofit. To this extent, transverse shear walls were installed on the downstream slope using self-hardening slurry (SHS) to reinforce the liquefiable foundation soils. Herbert Hoover Dike, located around Lake Okeechobee, FL, is subject to potential failure because of internal erosion, piping and slope instability at high water levels. The innovative use of the hydromill equipment with SHS allowed the successful construction of the cutoff wall through heterogeneous soils and rock. At Bolivar Dam, located in Bolivar, OH, under-seepage negatively affects the structural stability of the dam, and a partial seepage barrier wall is required through the upstream slope of the dam. In this case, the Contractor selected the plastic concrete seepage barrier, excavated by a combination of clamshell and hydromill equipment. The main features of the three projects are summarized in Table 1. IntroductionTuttle Creek Dam was constructed by the U.S. Army Corp of Engineers (USACE) on the Big Blue River in North-East Kansas in the 1950s for flood control. Tuttle Creek Dam is a zoned earthfill embankment, 7,500 ft long and about 137 ft high with a crest width of 50 ft (Fig. 1). It is located in an area of moderate seismicity associated with an old continental rift zone located just to the east of the dam. The USACE, under the Dam Safety and Assurance Program, determined the need for remediation. Site investigations and geotechnical analyses identified the upper alluvial foundation sands as being susceptible to liquefaction when subjected to the Maximum Credible Earthquake.In 2005, USACE awarded a construction-manager-at-risk/early Contractor involvement contract. The USACE and the Contractor closely cooperated to identify the most effective technologies, materials and configurations to be used in the remediation. The original remediation design required both the upstream and downstream slope stabilization of liquefiable foundation. Results of refined seismic deformation analyses revealed that the stabilization of the downstream slope and toe was needed to protect the downstream seepage control system and to provide assurance that a liquefaction-induced flow slide would not occur (Stark et al., 2012)."

Jan 1, 2016