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By G. Bjorling

The opening oxidation of a hydrometallurgical treatment of natural sulphides must for several reasons be so controlled that a maximum of the sulphide sulphur is transformed into elemental. If the oxidation is performed at low pressure and moderate temperatures and with mild reagents such as diluted nitric acid (or ferric or cupric chloride) the just mentioned condition is realized and it has been found possible to conduct the reaction so that solutions are obtained from which the metals can be recovered and the reagents required for the dissolution are regenerated. Experiments in laboratory scale with nitric-acid promoted oxidation have shown that this method is applicable to several types of raw materials, and in combination with electrodialysis both for partial neutralization and for final regeneration of the circulating acid can the requirements of low consumption of chemical reagents and formation of harmless residues be well fulfilled. The metals can be recovered as cathodic deposits or as hydroxides, and the method should be applicable also for low grade ores and concentrates. Although oxidation of sulphides by ferric or cupric ions has the advantage that it can be performed in open vessels it seems well worth the complication of working with nitric acid promotion in a low-pressure autoclave. Also complex sulphidic, oxidic and metallic materials can be treated.

Jan 1, 1973

By J. Richard Maier

Short-range mine planning (less than five years) previously was accomplished using contour and isopac maps, pencil and paper, an abacus, and our lucky quarter. Through the use of both micros and mainframe time sharing, Glenrock Coal Company (GCC) has been able to virtually put the old equipment away (except the problem solving quarter). In the process, GCC has saved many man-days and eliminated the more tedious parts of mine planning, such as picking elevations off a map with an engineer's scale and repetitive calculations. These savings have allowed GCC to do a more extensive job of mine planning as well as offer more alternatives, making GCC better prepared for possible economic changes. Mine planning, simply, involves looking at what has been done and deciding what needs to be done using various constraints. The application of this concept is not as easy as it sounds. The need for experience and insight cannot be replaced by a machine, but machines can supplement a person's ability by doing the bookkeeping and the repetitive work. Through the application of computers and their accessories, GCC has brought mine planning to a more modernized state. The following paper will detail the development and use of one system as used at GCC. Please note: In the figures and tables following, some of the data has been altered to protect confidential information used in mine planning.

Jan 1, 1983

By J. A. Brierley, S. N. McIntosh, C. L. Brierley, E. G. Baglin, E. G. Noble, D. L. Lampshire

The U.S. Bureau of Mines investigated column bioleaching as a means of recovering manganese from a domestic low-grade oxide ore. Manganese was solubilized from the ore using indigenous heterotrophic microorganisms and molasses as the nutrient source. The effects of medium flow rate, molasses concentration, and frequency of medium replacement on the rate of manganese extraction were examined. Results showed that flow rates between 0.4 and 8.1 L/min/m2 had little impact on manganese extraction, while an increase in the total amount of molasses applied during leaching directly affected the extent and rate of manganese extraction. Manganese extractions of more than 90% were achieved in 12 weeks of bioleaching in column tests using 500 g charges of ore. Sugar utilization by the microorganisms and formation of organic acid metabolites were monitored by high performance liquid chromatography (HPLC). Two methods were evaluated to recover manganese from the sugar- depleted bioleaching medium: (1) adsorption onto weak cation exchange resin, followed by stripping and precipitation techniques; and (2) direct precipitation of the manganese as MnCO, using ammonium carbonate. Both recovery methods removed at least 95% of the solubilized manganese from the medium as a carbonate salt. The stripped molasses medium was replenished with fresh molasses and recycled back through the bioleach column, successfully leaching more manganese.

Jan 1, 1993

By Masanori Harata

A fundamental study was conducted on a new process for producing scandium (Sc) metal or aluminum-scandium (Al-Sc) alloy by the calciothermic reduction of scandium oxide (Sc2O3). In this study, aluminum (Al) and calcium chloride (CaCl2) were used as the collector metal and flux for the reduction, respectively. A mixture of Sc2O3, Al, and CaCl2 in a tantalum crucible was placed inside a stainless steel reaction container, and the feed mixture was reacted with calcium (Ca) vapor at 1273 K for 6 h. After the reduction experiment, the reaction product (CaO), CaCl2 flux, and excess Ca reductant were removed from the obtained alloy sample by leaching with an aqueous solution. The formation of Al3Sc in the Al matrix phase of the alloy was confirmed by X-ray diffraction (XRD) and electron microprobe analysis (EPMA). This result indicates that Sc2O3 was successfully reduced to metallic Sc and alloyed in situ to form liquid Al-Sc alloy during the reduction. When Al was not used in the reduction experiment, a complex oxide (CaSc2O4) was formed, and the reduction was incomplete. This study demonstrates that the Al-Sc alloy can be directly produced by calciothermic reduction using CaCl2 flux and Al collector metal.

Jan 1, 2006

By Pollard D. M

The effects of pH, temperature and the form of zinc used on the kinetics of cementation of cadmium from process liquors were investigated. Batch tests were conducted in stirred beakers, and the cementation reaction was found to be first order controlled. The rate controlling step was thought to be the diffusion of zinc ions from the zinc surface to the bulk solution. The pH was found to have a significant effect when using Prime Western zinc or zinc dust. High reaction rates were favoured at low pH levels and a minimum rate was observed at a pH level of approximately 5 to 5.5. The pH was found to have little effect when using high grade and cathode zinc. The reaction rates increased significantly with increasing temperature; a reaction temperature of 55¦C resulted in almost complete removal of zinc from solution. Effective cementation rates were only acheived with cathode zinc after pickling in acid. The nature and specification of zinc used determined the cementation rate of cadmium, resulting in the following order: 1. Zinc dust 2. Prime Western zinc at pH 3 3. High Grade zinc at pH 3 4. Pickled cathode zinc 5. Prime Western zinc at pH 3 6. High Grade zinc at pH 3 7. Cathode zinc "as received".

Jan 1, 1989

By E. M. Yates, H. M. Hamilton

"For the assent of any new mining project it is essential to determine a realistic value of revenue from the sale of concentrates.A description of the market factors influencing the concentrate terms will be presented along with a detailed review of historical terms of a smelter contract for zinc concentrates. OverviewFor the assessment of any new mining project it is essential todetermine a realistic value of revenue from the sale of concentrates.This applies at all stages of assessment through to the final feasibilitystudy. In forecasting revenue for a zinc mine the followingfactors must be considered:(a) mill recovery and zinc concentrate grade;(b) metal price forecast for all payable metals;(c) smelter terms; and(d) other selling costs.Normally, data from test work are used to determine mill recovery and concentrate grade.Market forecasting, and indeed all economic prediction is an inexact science and probably will always remain so. We have our econometric models our input/output models and a lot of other tools. But they are of no help in predicting the unpredictable. OPEC's huge increase in the price of oil was certainly the most dramatic example of this. It had a tremendous effect on the cost of producing most products world wide and on the price of these products. Any forecasts made prior to the OPEC action were obviously proven wrong."

Jan 1, 1994

The 1997 Rapid Excavation and Tunneling Conference (RETC) was held at the Mirage Hotel, Las Vegas, NV. The RETC is a biennial event jointly sponsored by SME and the American Society of Civil Engineers (ASCE). Conference attendance was 573 members, nonmembers and students, an increase of seven attendees from the 1995 conference in San Francisco, CA. Exhibitors occupied 51 booths at the Las Vegas RETC. The 1997 conference encompassed 58 presentations in 15 sessions. Participants were given details on achievements and advances that have resulted in new design solutions, alternative work practices and increased productivity within the industry. The page at the end of this article tells how to get your copy of the RETC proceedings, either hardbound or on CD-ROM. Or, if you wish, for the first time a CD-ROM is available with the complete RETC proceedings from 1972 to 1997. This two-disk, archival volume has key-word search capability, is in portable file format and is compatible with PC and Macintosh platforms. RETC program sessions included design and planning, ground support, tunnel boring machine (TBM) case histories, conventional excavation, new technology, difficult ground, geotechnical, shafts and raises, future/special projects, new Austrian tunneling method, international projects, soft ground case histories and water and gas. What follows are highlights of some of the RETC presentations.

Jan 1, 1997

By Tejs Vegge

The lack of suitable means of storing hydrogen for use in the transport sector is generally viewed as a primary showstopper for a hydrogen economy. Recent developments within solid state hydrogen storage in complex hydrides and metal ammines have sparked new hope of a long term solution, but as of now, no materials fulfill all the DoE targets for onboard storage [1]. A detailed physical understanding of the ab-/desorption processes and the role of the essential catalytic additives is an essential prerequisite for the development of new optimized hydrogen storage systems. Here, we illustrate the potential of utilizing the synergy of combining state-of-the-art in theoretical methods and experimental techniques in the analysis and design of materials for hydrogen storage. Recent advances in computer hard- and software has made it possible to treat many of the essential problems in such materials, i.e. structural stability, hydrogen dissociation and diffusion, with high accuracy methods like density functional theory. We rely on such results to guide our synthesis of new materials, and to interpret our experimental results from, e.g. time dependant in situ x-ray diffraction, synchrotron/neutron experiments, and advanced materials testing. Through a continuous feed-back optimization loop between theory and experiments, the obtained nano-scale insight is used to expedite the design and development of novel materials for hydrogen storage.

Jan 1, 2006

By John Reynders

Our entry into the World War suddenly brought home to us in a startling way the vital importance of manganese. Since the war, much has been written and said upon the subject of manganese and a great deal of time and money have been spent in attempts to find an adequate substitute for this metal in the manufacture of steel; none has been found. It is true that ways are known by which it is possible to make small amounts of good steel without manganese; but taking into consideration the diminishing quality of iron ores and fuels. as' well as the increasing exaction of specifications for finished products, it may safely be assumed that high-grade manganese ore will be more and. more a necessity in the production of steel as time goes on. Taking world resources as a whole it may be well to point out that the problem of obtaining needed supplies of manganese from a strictly commercial viewpoint is now less serious than it was before the war. Formerly it was feared that world resources of high-grade manganese ore might be exhausted in a relatively short time, but, largely as a result of the stress laid upon the importance of manganese during the war, the world's available supply of high-grade manganese ore has been greatly augmented by new discoveries and fuller development of previously known deposits.

Jan 5, 1927

Improve the efficiency of stainless steel pickling (chemically cleaning) operations by providing the industry a quick and convenient method to estimate pickling solution behavior and to estimate recommended ranges of nitric and hydrofluoric acid concentrations for effective pickling of stainless steels. Background Iron, chromium, and nickel in stainless steels react with nitric and hydrofluoric acids during pickling. Ions of these dissolved metals complex or combine with the acid anions. When the total metal concentration reaches about, 50 grams per liter of pickling solution, the solution no longer serves its purpose and is considered spent. Knowledge of cation and anion species in these pickling solutions contributes an insight into pickling chemistry and allows estimates to be made of the most effective ranges of acid concentrations. The Bureau developed a computational model of the complex equilibrium chemistry occurring among iron, chromium, and nickel and the pickling solution. Total concentrations, in grams per liter, of nitrate, fluoride, iron, chromium, and nickel were used as input; output was 17 cation and anion molar concentrations. The model, in the form (if an equilibrium program on a mainframe computer, was used extensively to facilitate Bureau research by determining chemical complexes in numerous stainless steel pickling solutions. However, the program's availability to members of the stainless steel industry, its intended users, was limited because of lack of mainframe compatibility and the difficulty of program maintenance.

Jan 1, 1989

By Ren T. X, Jozefowicz R

In many branches of engineering, there has to be an understanding of the motion of fluids in order to solve problems. Many safety and health problems in the mining industry are typical examples that involve the understanding and analysis of fluid flow, such as explosions, the spread of fires, dispersion of gas and dust, and ventilation patterns. Computational Fluid Dynamics (CFD) is concerned with the use of computers to produce information about the ways in which fluids flow in given situations. Until recently CFD has been widely applied to a variety of industrial sectors and increasingly to problems in the health and safety areas. With the arrival of more powerful computers and CFD packages, CFD techniques are no longer practised solely in a research environment, but can be used by engineers in many industrial fields. This paper introduces the basic concepts and general procedures involved in the use of CFD technology. A comparison is given as a guide to the major features of a number of widely used commercial CFD codes. Areas of potential CFD applications are identified in a range of safety and health problems in mining industry. An example is presented to illustrate the use of this technology. It is believed that the exploitation of these areas using CFD approach will contribute significantly to the solution of today's many mine health and safety problems.

Jan 1, 1995

By J. M. Gaines, C. H. Herty, M. W. Lightner, H. Freeman

Few subjects have attracted the attention of metallurgists more than oxygen in steel. From the days of Mushet and Ledebur interest in this subject has been increasing, and as additional knowledge has become available, the problem has naturally grown more complex. Instead of using the simple term "oxygen" we now distinguish between iron oxide, silicates of various kinds, oxysulfides, oxygen as gas and oxygen in solid solution in steel. There are five general methods for determining oxides in steel: hydrogen reduction; vacuum fusion; various wet-extraction methods, including electrolytic methods; methods depending on volatilization of the iron away from the oxides; and metallographic methods. For oxygen in solid steel each of these methods has both advantages and disadvantages. The hydrogen-reduction method is of no use on steels above about 0.20 per cent. carbon;' furthermore, it gives only FeO and possibly some MnO. The vacuum-fusion method2 is expensive and gives total oxygen, with the exception of some A12O3, and does not differentiate between the various oxides in which the oxygen exists. Most of the wet extraction methods3 give only the more insoluble oxides SiO2 and A12O3, though the iodine method gives MnO to an uncertain degree (information that may be more misleading than no information

Jan 1, 1930

By Hashimoto H, Arai Y, Sikong L

For utilization of solid carbonaceous materials produced in processes of cracking heavy oil, such as petroleum pitch, as powder fuel, it is necessary to develop a process for fine grinding of these materials. It is known that grinding' additives are effective for fine grinding of cohesive and heat-sensitive materials such as petroleum pitch, therefore in this study, effective methods for fine grinding of petroleum pitch with some grinding additives were investigated. Experiments were carried out by using comminution kinetics based on mass balance. From the results of the investigation by using a batch ball mill, it was found that sodium stearate, calcium stearate and carbon black were effective additives for the improvement of grinding efficiency. Optimum concentration of the grinding additives was also found to give a required particle size of products. Concerning to the action mechanism of these additives, it is considered that the additives which adhired to, or were absorbed on the surface of petroleum pitch particles not only prevented cohesion of the particles but improved dispersion of the particles as well. From the results of the investigation by using a laboratory screen mill which is a representative built-in classifiered impact crusher, carbon black was found to be an effective additive for the improvement of grinding efficiency and mill performance. It is also considered that the improvement of classification efficiency by carbon black affected the mill performance.

Jan 1, 1987

By Stéphane Servant, Jacques Ouellet, Ferri Hassani

This paper presents essentially the logistic and practical aspects involved for in situ testing of mine paste backfill with a self-boring pressuremeter. The investigation discussed in this paper is part of an extensive and ongoing research project to identify and validate an in situ testing technique for cemented mine backfill such as hydraulic or paste backfill as well as Insitu behavior of backfilled stopes. After a literature review on field testing of soils and past experiments on mine backfill in situ testing, the self-boring pressuremeter was selected as the most appropriate instrument for this task. The authors presents in this paper the technical aspect involved in a field trials that was conducted in a Canadian underground mine using paste backfill. The results of this first successful trials show that self-boring pressuremeter test can provide high quality and reliable backfill characteristics results, using analytical techniques developed for soils (Ouellet et al., 1998). The parameters obtained were: estimation of the lateral stress in the ground, the soil stress-strain response and the soil strength. The logistic and equipment required to conduct such testing underground is fully described. Performance achieved in the field and technical difficulties encountered are highlighted. Recommendations for future experiments with such instruments are given. Some potential technical improvements to better adapt this in situ testing technique to mine backfill are proposed.

Jan 1, 2001

By J. B. Hiskey

The hydrometallurgical application of thiourea in processing precious metal ores and concentrates has reached the development stage. This paper reviews recent technical literature covering the process development of thiourea leaching. In addition, recent fundamental contributions are discussed. Most of the interest in thiourea leaching has involved treating high grade concentrates that have sufficient value to just the use of thiourea as a reagent. An important development in thiourea technology is the addition of SO2 to the leaching solution. This procedure effectively reduces the decomposition of thiourea and eliminates the problems of passive surface layers that limit the leaching efficiency. Results for the thiourea leaching of a bulk sulfide concentrate and a residue from the autoclave leaching of a smelter flue dust are also reported. As determined by a standard bottle roll cyanidation test, the bulk concentrate was extremely resistive to cyanide leaching yielding only 16% gold and 2% silver extraction in 24 hours. Leaching with a relatively concentrated thiourea solution (1MCS (NH2)2) resulted in 83% gold and 75% silver extraction in four hours. With the treated flue dust residue, gold extraction was about 60%. Gold and silver extraction with cyanide was sensitive to both cyanide concentration and oxidizing conditions. Cyanidation resulted in 59% gold extraction and 77% silver extraction in 24 hours.

Jan 1, 1985

At 9.45 pm on Thursday, 12 July 1962 glass began to flow in an endless stream from a massive melting tank in a new Whangarei factory and a vital new industry was born û right on schedule. It wasn't good glass. It was ridged. It cracked. It rippled. It obstinately refused to emerge upstairs in the cutting room in one solid continuous sheet. But all through the night, drawing speeds were adjusted, temperatures changed. And on Friday morning, at 8:30, it finally came through as sheet û not perfect as yet, but sheet glass all the same. The rest is only a matter of time. Unfortunately, the buoyant enthusiasm displayed by the founders of the sheet glass industry in New Zealand, and the technical expertise of their European consultants, failed to bring the glass quality up to commercially acceptable standards and within six months, the company was in receivership. Taking over the role of producing New Zealand's sheet glass requirements, New Zealand Window Glass Company was formed as a partnership between two companies with long experience in sheet glass manufacture û Pilkington Brothers (NZ) Limited and Australian Consolidated Industries Limited. This paper sets out to identify the raw material requirements and controls necessary for the successful manufacture of sheet glass, and the availability and supply of suitable materials for use at Whangarei.

Jan 1, 1978

By G. M. Wilemon, B. J. Scheiner

The Bureau of Mines conducted investigations on extracting phosphate values from fine-particle wastes generated during the mining and beneficiation of phosphate ore by leaching dried wastes using a H2SO4-methanol mixture. Although phosphatic clay waste contains up to a third of the phosphate originally present in the ore, recovery of these values represents a significant challenge due to the fine grain size of the material, the particles averaging less than one micrometer in diameter. Waste samples obtained from two Florida producers yielded phosphate extractions of 71 and 84 pct, respectively, when leached under ambient conditions and at a stoichiometric acid ratio of 1.4:l. Elevated temperatures did not improve the amount of phosphate extracted. Undesirable A12O3, Fe2O3, and PlgO impurities were largely rejected; higher grade wastes gave acids that meet established industry impurity standards and lower grade samples yielded acids that marginally fell short of the standard. Separation of the crude acids from the insoluble residues was accomplished via vacuum filtration through either filter paper or commercial filter cloths. Both filtration rates and solids retention were improved by the addition of 0.5 lb/ton of poly(viny1 acetate) (PVAc) or poly(ethy1ene oxide) (PEO) to the methanol-acid slurries. These results show potential for substantially increasing the reserves of an important domestic resource.

Jan 1, 1989

Improve safety at mineral operations that use cyanide leach solutions to recover precious metals from finely ground ores, Approach Provide an alternative, non-acidic means of cleaning processing systems such as the State-of-Maine filter system, thereby reducing the exposure of workers to toxic hydrogen cyanide gas (HCN), The Problem Many gold and silver mining operations use cyanide solutions to dissolve gold and silver from ores. The precious metals frequently are recovered from pregnant leach solutions by the Merrill-Crowe recovery process, whereby gold and silver is precipitated with zinc dust. When that method is used, suspended particles in the leach solution must be filtered out before zinc precipitation can occur. This filtering is accomplished with small packaged plants, such as the State-of-Maine (SOM) filtering system. Unfortunately, the filters become clogged with calcium carbonate scale after about 2 to 10 days of operation and must be cleaned before further precious metals recovery operations can continue, Cleaning the system is a hazardous task because the acid is not compatible with the alkaline cyanide leach solutions, and toxic hydrogen cyanide (HCN) gas may be produced when the acid and solution are mixed. That gas, if breathed or contacted with the skin, can cause cyanosis which may induce nausea and even asphyxia and death. To reduce this danger, the Bureau of Mines has devised a safer method of cleaning clogged filters,

Jan 1, 1986

By Karl R. Becker

Detonators representing a sampling of various domestic commercial delay detonators were fired at various direct-current (dc) firing levels. Results of firings using well-below-recommended firing levels showed marked increases in delay times above the nominal values. There was also a marked increase in variation, to the extent that out-of-sequence firings would be essentially assured in any typical blasting round at these low firing levels. Within the range of recommended levels the effects of current increases were not considered to be of great importance relative to other overriding effects, such as the significant difference noted in average values of detonators from different lots having the same nominal delay. This effect, when combined with the normal variation noted among members from the same lot, would cause out-of-sequence firings with detonators from a neighboring delay period. Where comparisons with results from another study were possible, it was found that both studies observed quite similar variations in delay times about the average values, and a lower probability of out-of-sequence firings for the shorter delay period groups. The criterion of the previous study for assessing the likelihood of observing out-of-sequence firings, when applied to the Bureau of Mines data, properly identified two neighboring delay period groups where out-of-sequence firings would occur.

Jan 1, 1981

By Carl H. Samans

THE INFORMATION AVAILABLE on the rolling characteristics of the precious metals-gold, silver, the platinum metals and their alloys-is incomplete and mostly from scattered sources. In the present paper an effort has been made to assemble and correlate it and to fill in some of the gaps that exist. GENERAL ROLLING CHARACTERISTICS SOME EFFECTS OF IMPURITIES Gold and its alloys are generally considered to be hot short and hence are usually rolled cold. Cold rolling of the yellow, green, and pink gold alloys. Which customarily contain gold, silver, copper and zinc and frequently some nickel as well, introduces no new problems since reasonable reductions are quite feasible and the alloys show little tendency to fire crack in subsequent annealing. The white gold alloys. which usually contain little or no silver and 10 pct or more nickel, are very susceptible to fire cracking1 and hence wrist he given relatively heavy reductions, i. e., 8-10 pct or more per pass with a total reduction of about 50 pct between anneals, to minimize this tendency. In addition, it is preferable to keep the bar as flat as possible during rolling. Although no comprehensive study appears to have been made of the effects of impurities on the cold rolling characteristics of gold alloys, the observations of Nowack2 on the effects of small

Jan 1, 1948