Search Documents

By P. M. Rosário

The extraction performances exhibited by a phosphoric (D2EHPA), a phosphonic (Ionquest 801), a phosphinic (Cyanex 272) and a dithiophosphinic (Cyanex 301) acid derivative towards indium recovery from a diluted sulfuric solution are evaluated and compared. Equilibrium extraction isotherms were obtained. The chemical reactions involved and the approximate stoichiometry of the In(III) extracted species by the four ligands are presented and discussed. Stripping of In(III) from loaded D2EHPA and Ionquest 801 has been accomplished successfully, but has not been so effective from loaded Cyanex 301. Plots of %E vs. pH were established for D2EHPA, Ionquest 801 and Cyanex 301, denoting their behavior towards the extraction of similar mass concentrations of In(III), Fe(III), Fe(II) and Zn(II). Cyanex 301 is the least selective towards In(III), whereas D2EHPA and Ionquest 801, both for a pH = 0.5, do not extract Zn(II) at all.

Jan 1, 2003

By Boyd R. Davis

Like many pyrometallurgy researchers, Ralph Harris? work extended over both light metals (lithium and magnesium) and base metals. His work looked at feed preparation, primary production, and secondary treatment. The thermodynamic principles of chemical metallurgy allowed Ralph to move between these two groups of metals. However, these metals have few similarities when projects are being developed. The traditional ?deposit-based? drivers for base metal operations do not apply to the same degree with light metals projects. While high purity, low cost feed is important to light metals projects, it should not be considered as the main reason for a smelter project. While it is clearly understood that technology (energy costs) is the driver for aluminum production, it is less considered for other light metals. This paper will look at the break down of base and light metals? production costs to try to quantify the balance between feed costs and technology for each metal group.

Jan 1, 2013

By L. A. Arrington-Webb

Forty-four states produced clay products during 1994 for a total value of $1.6 billion. This was a 3% increase in total tonnage and a 7% increase in value from 1993. Kaolin Domestic production of kaolin during 1994 was estimated to be 9.3 Mt (10.2 million st), according to the US Bureau of Mines (USBM). Georgia remained the leading producer with 7.5 Mt (8.2 million st), followed by South Carolina with 535 kt (589,000 st). Kaolin used as a paper coating or filler pigment accounted for 51% of domestic consumption. Other uses included grogs (14%), fiberglass (5%) and plastics (4%). A reclassification by an Alabama producer of fire clay to kaolin accounts for the introduction of kaolin used in grogs. This also accounts for the apparent decrease in the use of kaolin in paper from 60% in 1993. However, the actual amount of kaolin used in paper was the same.

Jan 1, 1995

By W. D. Gould, A. Kapoor

Acid mine drainage (AMD) is characterized by low pH and high concentrations of sulfate and dissolved metals such as iron, manganese, aluminum, zinc, and copper. Chemical treatment of AMD achieves pH neutralization and toxic metal removal but also produces large quantities of bulky sludge that requires long-term storage facilities and monitoring. Chemical treatment of AMD achieves only partial removal of sulfate (SO4) and total dissolved solids. Sulfate reducing bacteria (SRB) have been used for the removal of sulfate from industrial process wastewaters. The biological sulfate reduction process generates sulfide and alkalinity. The sulfide produced in the biological sulfate reduction process is used to precipitate metals present in AMD as their respective sulfides and the alkalinity generated is used to neutralize the AMD. This review article will present an overview of biological sulfate reduction processes using SRB, bioreactor configurations, AMD treatment studies, and full-scale systems in operation for the treatment of acid mine drainage.

Jan 1, 2004

By Peter Stubbs

Mr. Agelopas is to be congratulated on a fine paper. Although the presentation was simple and concise, you will all appreciate that a great deal of hard work went into the development of this highly successful repair method. Earlier this year Bethlehem invited a group of our people to witness lug repairs at their Sparrow's Point plant. We have since made lug replacements on a trial basis using their method. The repaired moulds are now back in service. We will compare their performance with regular moulds and with moulds repaired by a technique developed by Dofasco weld shop personnel. I would like to explain briefly some of the various types of ingot mould repairs presently undertaken at Dofasco. The first problem will be familiar to most of you. The lower inside edge of a mould wall may be damaged by spalling, a runout or by the washing action of steel deflected from a badly worn stool cavity. We repair this type of damage by welding.

Jan 1, 1972

By John R. Riede

Most beneficiation plants utilize automatic controls to varying degrees-some have the bare minimum of controls, others qualify as semi-auto- mated operations; a very few are nearing what may be termed "fully-automated" status. But for those plants that produce a filter cake product, the lack of suitable instrumentation for measuring and con- trolling the moisture of the filter cake has been a major stumbling block to fully-automated operations. Today in many cases, this bottle-neck can be removed because various moisture measuring devices are now available to permit automation of the filtering stage. What are these devices? . . . Where can they be used? To answer these questions, two types of operating plants-one, semi-automated and the other, almost fully automated-can be examined. Both plants employ disc filters from which is produced a magnetic concentrate for pelletizing. (The control schemes and equipment depicted in this article are similar to those usable in drum filter plants.)

Jan 3, 1967

By V. G. Papangelakis

The implementation of a flow-through yttria-stabilized zirconia (YSZ) sensor for pH measurements in high temperature and concentrated electrolyte systems relevant to hydrometallurgical processing of nickeliferous laterites is discussed. Instrumentation involved the use of a custom made flow-through titanium electrochemical cell. Accuracy and validity of the pH measurements at temperatures up to 250C were assessed using concentrated sulphate process solutions ranging from synthetic binary sulphuric acid ? water solutions to progressively multicomponent metal ? sulphate solutions simulating laterite Pressure Acid Leach conditions. The measurements were also compared with theoretical models using recently obtained thermodynamic data. A difference of ±0.25 pH units was observed between measured and calculated pH values at temperatures. This is an acceptable difference given that these are the first direct high temperature pH measurements ever on the concentrated acidic sulphate solutions. This result is encouraging more research for the development of industrial electrochemical systems for direct pH measurements in autoclaves.

Jan 1, 2003

It has long been recognised that applications of the Net Present Value (NPV) investment decision making methodology can have serious deficiencies in situations where investment can be delayed and, once made, various options allow increases or decreases in the level of output. NPV valuation can undervalue the project if it does not incorporate future flexibilities or ""options"". It is important to realise that a proper valuation of a project (ie, valuation of its future cash flows) must incorporate an analysis of optimal future decisions involved in managing the project. Current valuation cannot be divorced from a consideration of future decision making. There is now a considerable amount of literature, mainly academic, identifying and exploring ways of remedying these deficiencies in the application of NPV. While the necessity of period by period analysis is sometimes acknowledged, little if any practical illustrative model building has been published to date, aside from algorithms using continuous time stochastic processes which deny access to the uninitiated.

Jan 1, 1994

By Nobuaki Sato

For decontamination of SO2 containing waste gases from industries such as ferrous and non-ferrous metal companies, desulfurization with hydrogen production by the reaction of Br2 and SO2 was proposed as bromine-sulfur (BS) process. In this process, SO2 is fixed as H2SO4 in the presence of Br2 and H2O forming H2SO4 and HBr. Then hydrogen is produced by the decomposition of HBr and Br2 as byproduct is recycled. The reaction of Br2, SO2 and H2O was found not to occur in liquid phase but to occur in vapor one. The production ratios of H2SO4 and HBr showed a maximum at temperatures around 60 oC. The highest production ratio was obtained at 70 oC with a mixing ratio of Br2:SO2:H2O=1:1:10. The experimental results were discussed with thermodynamic consideration.

Jan 1, 2006

By R. Chiarizia

Third phase formation, i.e., the splitting of the organic phase in two layers, is a common feature observed, under conditions of high loading, for many solvent extraction systems of both analytical and industrial interest. Although this phenomenon has been investigated in a large number of works, a structural and physico-chemical description is still lacking. In this work, small-angle neutron scattering (SANS) data for the tri-n-butylphosphate (TBP)-n-octane,Th(NO3)4-HNO3 solvent extraction system have been interpreted using the Baxter model for hard-spheres with surface adhesion. The increase in scattering intensity in the low Q range, observed when increasing amounts of HNO3 and/or Th(NO3)4 are introduced into the organic phase, has been interpreted as arising from interactions between small reverse micelles containing three TBP molecules plus solutes in their polar core. This intermicellar attraction, under appropriate conditions, leads to third phase formation.

Jan 1, 2003

Silica and limestone fluxing levels in copper smelting slags were studied. Copper concentrates with flux additions were smelted to matte (55.5 per cent Cu) and slag in a pilot scale submerged combustion furnace.Results indicated that oxidic and sulphidic copper levels in slags were minimised with a slag Si02 level of 36 per cent and a SiO2/CaO ratio of 5.5. Total copper losses in slags were 0.6 per cent under these conditions.To produce the desired slag chemistry, additions of bulk silica and limestone to copper concentrates of fluctuating grades were predicted numerically. The method employed the solution of two simultaneous equations, each respectively for silica and limestone calculations.The predicted flux additions were applied in a further series of tests and the resultant stages were found to be satisfactory. The method is applicable to smelting 'operations which employ two flux bins, with weigh feeders, so that slag chemistry may be controlled with the flux/concentrate feed mix.

Jan 1, 1985

By Philip D. Lindahl

The US Bureau of Mines (USBM) began research to improve the safety and efficiency of transporting coal from underground coal mines using a balanced air-lift hydrohoist (ALH). ALH includes a U-tube pipeline that can be installed through an existing shaft or two surface-drilled holes connecting the mine level to the surface. Bench- and pilot-scale models were tested to evaluate the feasibility of hydraulically hoisting a coal-water slurry in a riser pipe by injecting compressed air microbubbles. A prototype injector was developed that continuously compacted -50-mm (2-in.), run-of-mine coal in a screw feeder and injected a thick coal slurry into ALH. Initial production rates of 40 t/h (44 stph) through a 200-mm-(8-in.-) diam riser pipeline were achieved with a50-m- (165-ft-) high pilot-scale model. The potential productivity was expected to increase to 100 t/h (110 stph) through modification of the coal injector.

Jan 1, 1995

Our presiding officer for this session is someone we are all proud to be associated with. One who is dedicated to Public Service and Safety in the State of Colorado, and known in the mining field and the Colorado Mining Association. We are very pleased to introduce Mr. Donald Haske, Chief Mine Inspector for the State of Colorado: Donald Haske: Officers, Members and guests. It is certainly my pleasure to be here today and an extra special pleasure to be presiding over this session. As some of you know, from natural up, heavy equipment is rapidly coming to the field of mining. This may seem a long way off at the present, but it certainly isn't. We are getting all the old annuals (Bi) together to be compiled for a guide and public attraction. However, we are unable to locate an (1894 panel). If any of you know of any of these please let us know.

Jan 1, 1967

By Parker GJ

The financing of smaller resource projects has proven to be a difficult problem for promoters and financiers alike as very often such projects have not met the requirements of available financing methods and promoters have equally found it difficult to establish credibility, management and technical ability with potential financing sources. Solutions to the dilemma in which many of these projects find themselves are not readily apparent but will need to be found if the full potential of Australia's resources is to be realised. INTRODUCTION The growth of so called project financing in its present form is normally considered to be a phenomenon of very recent times, however, paradoxically there are references to what could be called financing in the old testament. To confuse the issue further financing small resource projects may not, and very often are not undertaken on a project financing basis. It is therefore quite apparent that one should be completely clear on:

Jan 1, 1982

By M. Pineau, G. A. Monteith, M. Laliberte, G. Houlachi

Conventional physico-chemical treatment methods, either hydroxide or sulfide precipitation, can hardly achieve a high removal of selenium from the liquid effluents which can be generated in some metallurgical operations. In weak acid solutions, selenium exists mainly as anionic species (selenite Se03-2 and selenate SeCV2) which, therefore, cannot precipitate as metal hydroxide or metal sulfide compounds. At the same time, neither selenite nor selenate form stable precipitates with the common cations (Ca, Mg, Fe, etc.) that are typically used in water treatment. At Noranda Inc., CEZinc Division in Valleyfield, Canada, the introduction of new discharge requirements for effluent toxicity initiated a R&D program which resulted in the full-scale implementation of a new treatment method for selenium removal. The goal of this paper is to present this new method which is now being patented by CEZinc. The process chemistry will be presented along with pilot-scale developments and full-scale operational results.

Jan 1, 2000

By Xu Weihong

After being pre-treated, composite electro-deposits of semi-bright nickel/nano-SiO2 with bright nickel or with amorphous Ni-P alloy, and Composite electro-deposits of Zinc were prepared on Nd-Fe-B magnetic material. The effect of cathodic current density, nano-SiO2 concentration, stirring strength and surfactants on the corrosion resistance of electro-deposits were studied. In addition surface appearance and structure of the composite coatings were analyzed by SEM. The present investigation shows that the corrosion resistance of composite electro-deposits of semi-bright nickel/nano-SiO2 with amorphous Ni-P alloy was the best, the solution system of semi-bright nickel/nano-SiO2 with bright nickel was stable and its electro-deposits also had an excellent corrosion resistance, composite electro-deposits of Zinc not only had good corrosion resistance, but also low cost, thus making it an excellent electro-deposit for medium or low-class Nd-Fe-B magnetic material.

Jan 1, 2006

By John C. Brulia

PowerAN is a tradename of Atlas Powder Company for a new line of explosive products comprising blends of emulsion and ANFO in a variety of bulk and packaged grades. The bulk PowerAN grades are either augered or pumped depending upon emulsion content. Augered PowerAN blends contain up to 60% emulsion. Pumped PowerAN grades have an emulsion content of 75% or higher. The blending of PowerAN is usually accomplished at the borehole to satisfy specific borehole conditions. Packaged PowerAN grades are produced in several types of mix plants in diameters of 4" and greater. PowerAN 300 (30% emulsion) and PowerAN 500 (50% emulsion) are the two most popular grades and their chief application is as an economical, high energy replacement for ANFO HD in wet holes. PowerAN combines the cost effectiveness of ANFO with the high performance of emulsions, permitting the blasting engineer to strike an optimum balance between drill pattern expansion and increased productivity according to need.

Jan 1, 1985

By Howard E. Kremers

Since the discovery of the first-known rare earth elements more than a century ago, these metals have always been of academic interest. It is not so well known, however, that a rather stable, respectably large industry based on rare earths and their related materials has been in operation for more than 60 years. Rare earths, of course, are the elements having atomic numbers 57 through 71--lanthanum through lutetium in the periodic table. The most important commercial members of this group are mixtures of the lower atomic-numbered rare earths, and cerium. Although yttrium is not a rare earth, it occurs with rare earths and its properties are so similar to them that. it must be included in a discussion of these elements. In addition, thorium is important to most producers of rare earths because their ores generally contain this element. Thorium extractive metallurgy and technology is closely related to rare earth chemistry due to the frequent similarity of properties.

Jan 4, 1962

By Earl C. Hutchison, Gene Smith

Extensive blasting was required to construct an underground tunnel for a 90 inch sewerage relief line. The tunnel and required excavation extended under an upper middle-class residential area in Atlanta, Georgia for more than a mile and a half and required the use of more than a half million pounds of explosives in the immediate vicinity of houses and residential apartments valued at more than 16 million dollars. Other houses and property valued at more than 80 million dollars were within range to claim blasting damages. An effective blasting damage control program was carried out which limited the number of blasting damage claims to less than 2-1/2% of the total number of potential claims. All but three of the small number of blasting damage claims which were made were effectively denied without any resulting legal actions and less than $3,800 was paid for settlement of the three claims.

Jan 1, 1981

By Vladimir L. Konyukh

Robotics is topical for mining owing to deterioration of miner's safety as a depth of winning, limited functions of traditional mechanization and automation, rise of miner's labor cost. Mining robot is an autonomous mining machine with a free programmable control that provides a multifunctional use of working head. After analysis of world publications the database “Technological applications of robotics in mining" has been built. In most cases robots are suggested for imitation of miner's motions. The following shapes of robotics had been classified for mining: technological robot as a flexible controlled mining machine, remote manipulator, mine rescue robot. The problems of both non-repeated environment recognition and telepresence without direct visibility must be solved. The more a robots integration is the less investments and the more efficiency are. Computer simulation of robotics-based mining is founded on a base of 6 robots functional models, Petri nets and library of 30 robotized technologies. There are some examples of mine robotization in the paper.

Jan 1, 1996