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By E. C. Pattee

A mobile spectroscopic laboratory was completed by the Bureau of Mines in 195 to provide a rapid, inexpensive means of field testing samples for beryl¬lium and other associated metals of possible commercial importance. Spectro-copes have been used in laboratories for many years in various types of research and routine analyses, but this spectroscope is probably the first mobile unit. The laboratory provides for spectroscopic, radioactivity, fluorescent, and limited chemical tests of samples. The unit has been a valuable reconnaissance tool. It has been used to search for beryllium, cesium, columbium, tantalum, rubidium, and lithium in Idaho, Washington, and Montana. Several very low grade deposits of these elements were found, and occurrences of other important elements were identified; however, none are of economic importance. The spectroscope permits the detection of elements by analysis of visible light produced when elements in a small powdered sample are volatilized in an electric arc., A total of 70 elements can be detected; 29 can be detected at or below 0.01 percent, Electric power for the arc is supplied by a gasoline motor-driven generator, Equipment is housed in an aluminum van, mounted on a 4-wheel-drive vehicle for easy maneuverability on mountain roads, A trailer with crushing, pulverizing, and splitting equipment permits the reduction of samples to a small representative pulp.

Jan 1, 1963

By James F. O'Neill

Brown iron ore resources in Barbour , Butler , Crenshaw , and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama . The aggregate footage drilled was 18,010 linear feet . When developed , reserves of 12,664,000 long tons of crude ore were indicated , containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet . Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons . Beneficiation of samples by simulated log washing and use of a 1 / 8 - inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese . Screen- test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200 - mesh screen . Clay was prominent in micron - size slimes . Silica was deleterious in the minus 20 - mesh size . While an indicated 2,198,000 dry long tons of usable iron ore can be recovered , sink - and - float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing . However , applicable commercial processes have not been demonstrated .

Jan 1, 1965

By J Robertson, D Williams, H D. Plewes

The co-mixing of tailings and waste rock involves the intimate blending of tailings and waste rock to create a new material (Co-Mix) with superior physical and hydraulic properties. The new material has a low hydraulic conductivity, low compressibility, high water retaining capacity and high shear strength. Co-mixed tailings and waste rock restrict oxygen entry and water seepage to minimise acid generation and metal leaching. When compacted, Co-Mix materials have low volume change characteristics with respect to total stress and matric suction together with high shear strength. Co-mixed tailings and waste rock may be used to construct cover systems, internal barriers and seals, confinement structures or a full depth waste repository. The theoretical properties of Co-Mix blends are investigated. The results of a laboratory program to characterise the physical and hydraulic properties of co-mixed tailings and waste rock are presented. Various ratios of tailings were blended with different waste rock materials. Hydraulic conductivity tests were conducted at confining pressures ranging between 0 and 400 kPa. The saturated hydraulic conductivity for the Co-Mix materials was found to vary between 4 + 10-5 m/s and 5 + 10-9 m/s depending on blend ratio, waste rock type and confining pressure. These results together with other physical properties show excellent hydraulic and strength characteristics can be achieved for Co-Mix materials.

Jan 1, 2003

By B. T. McClure

Oxidizing catalytic converters are sometimes used by underground mine operators as an emission control device to reduce odor, hydrocarbon (HC), and carbon monoxide (CO) emissions from diesel equipment. The objectives of this report are to quantitatively assess the effects of catalytic converters on diesel exhaust emissions and to make recommendations for their use. Information in this report is from a literature survey and contract research supported by the Bureau of Mines. Catalytic converters are effective in reducing CO, HC, and odors when the exhaust temperature is high enough so that the converter remains above 250° C. Converter temperature is dependent upon engine duty cycle. Catalytic converters increse sulfate emissions and slightly in- crease oxides of nitrogen (NOx) emissions. If low sulfur fuels are not used, the increase in sulfate and nitrogen dioxide (NO2) emissions can offset any advantages of the catalytic converter as measured by the emissions quality index (EQI). In addition, in vitro bioassays have shown that catalytic converters produce soluble organic compounds, which have increased mutagenic activity with respect to untreated exhaust. Based upon criteria recommended by a joint Canadian-United States research panel, catalytic converters should only be used in special circumstances in underground mines. Vehicles equipped with catalytic converters should operate under moderate to heavy load conditions, and use fuel with a sulfur content less than 0.1 pct.

Jan 1, 1988

By Jeremy G. Kress

We propose the discrete element method (DEM) as a complimentary alternative to analytical solutions and FEM models for the analysis of pile response. DEM is a novel approach to the engineering design of deep foundations which can be used to provide insight into the mechanics of soil-soil and soil-structure interaction. It is common to use analytical, empirical, and semi-empirical methods to predict pile behavior, where if granular properties, pile length, or load orientation change, then significant adjustments are made in the design sequence. DEM provides a more uniform approach in granular soils. Based on constitutive force-displacement relationships and laws of motion in rigid and elastic bodies, few changes must be made for a wide variety grain types, pile types, embedment, and load orientation. Preliminary results for simulation of a single pile are qualitatively consistent with results from conventional design procedures and also provide significant information not available from other analyses (e.g., local information about interface failure during shear). Importantly, these analyses are portable to a variety of pile types and installation procedures, which may not be the case for empirical approaches. Given consistent increases in computing power and rapid advances in model speed and sophistication, the DEM should prove to be a robust method for design and the analysis of pile response in granular soils.

Jan 1, 2010

Arsenic bearing minerals such as enargite (Cu3AsS4) and tennantite (Cu12As4S13), which may associate with major copper minerals such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and bomite (Cu2FeS4), usually report to the copper concentrate in conventional flotation due to their similar flotation properties. Arsenic in a copper concentrate causes environmental problems and also problems in the subsequent pyrometallurgical process. Voltammetric studies were carried out to investigate the oxidation characteristics of enargite, tennantite, chalcopyrite, chalcocite and bomite. Contact angle measurements and micro-flotation tests were conducted to examine the flotation characteristics of enargite and chalcopyrite under controlled pulp potentials. Selective flotation of enargite from chalcopyrite under varied pulp potentials was conducted to investigate the feasibility of arsenic removal from a copper concentrate. The test results indicate that the non-arsenic bearing copper minerals ( chalcopyrite, chalcocite and bornite) were easier to oxidise than arsenic bearing minerals ( enargite and tennantite) in an alkaline solution. Enargite floated well at a potential as high as +0.45 V vs. SCE while chalcopyrite was completely depressed at a potential higher than +0.43 V vs. SCE. Selective flotation revealed that enargite can be successfully removed from chalcopyrite through controlling the pulp potential at +0.30 ~ +0.50 V vs. SCE.

Jan 1, 2007

By Thomas H. Dubaniewicz

The National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory, conducted a study of past mine explosions to identify the ignition locations and ignition sources responsible for the most severe explosion events resulting in death. Since the Scotia disaster of 1976, many fatalities from underground coal mine explosions have been linked to nonpermissible electrical equipment ignition sources located in intake air courses. With few exceptions, explosion protected equipment is generally not required in intake air courses of gassy underground coal mines in the US. Cigarette lighters were another prevalent ignition source for fatal explosions ignited in intake air courses. Several mine rescue/ recovery teams have encountered electrical ignition hazards. The study provides evidence that intake air courses of gassy underground coal mines fit the description of certain Hazardous (classified) locations described in the US National Electrical Code®. Class I Division 2 or Zone 2 explosion protection tech¬niques may be used to design intake air equipment so that it does not present an ignition source under normal operation, before mine power is shut down in emergency situations. Nonpermissible circuits in intake air courses that are likely to remain energized during emergencies, e.g. battery powered equipment, should be protected by more stringent Class I Division 1, Zone 1, or Zone 0 techniques, to protect rescue/recovery personnel.

Jan 1, 2009

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to maximise health and safety performance in the mining industry through implementing continual improvement in management of major unwanted events. A comprehensive knowledge base has been captured for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This will be extended to outburst, coal burst and bumps, interface displays and controls, tailings dams and inrush in 2013. RISKGATE presents substantive and leading edge controls to assist industry stakeholders in the design, management and reporting of organisational and regulatory compliance requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry. All major Australian mining companies are contributing topic experts to this broad industry initiative. In the first 24 months, nine coal mining companies nominated over 80 different experts who contributed over 400 days of individual time to the knowledge capture workshops. RISKGATE is the largest single Australian Coal Association Research Program (ACARP) occupational health and safety (OHS) initiative to date.

Aug 1, 2013

By Arnold Hoffman

A RESPONSIBLE steel executive recently declared that scrap shortages, despite fantastic prices reaching up to $50 per ton, are responsible for the loss of 140,000 tons of steel a month and that in March 1947 alone 25 more steel furnaces could have been operating were it not for scrap scarcities. His answer to this serious situation was to ask for a speedier flow of scrap and also abolition of Government control over pig iron distribution. It would be more logical, perhaps, if an answer to this growing problem of scrap deficiency were sought within the steel industry itself. As long ago as 1933, L. B. Lindemuth, a consulting steel metallurgist, warned the steel industry that a shortage of scrap was inevitable and that beyond 1938, adequate supplies for open-hearth furnaces could not be expected. The outbreak of war, with consequent phenomenal demands on the industry, accelerated production of steel and further worsened the scrap situation. Today we are suffering from a condition which could have been prevented had the industry been more far-seeing and provided for an inevitable contingency. However, better late than never, and measures can now be taken to alleviate permanently scrap shortages in the future. This can be done by greater utilization of heavy sinter which experience proved is an excellent substitute for scrao and lump ore.

Jan 1, 1947

By H. McIntire, R. Preston, D. Roberts

"Repeated 3D terrestrial digital photogrammetric surveys were conducted on hard rock mine pillars to characterize damage during secondary mining. Damage was quantified by measuring Depth of Failure, DOF, from spalling material and crack intensity, D21. These damage values were then correlated to visually assessed Pillar Damage Ratings and numerically estimated pillar loads. Measured damage, particularly Depth of Failure, correlated well with Pillar Damage Ratings. Numerical predicted pillar stress vs. damage exhibited the expected trend with shorter pillars being stronger. High resolution photographs and 3D models were also used to characterize damage mechanisms, which were found to be structurally constrained. INTRODUCTIONThe Doe Run companies Southeast Missouri Operations consists of six room and pillar lead mines (Brushy Creek, No. 29, Casteel, Buick, Fletcher and, Sweetwater) (The Doe Run Company, 2014). The mines are hosted in the Carbonates and Shales of the Viburnum trend with mining depths varying from 180 to 300 m. Pillars are commonly cut square with widths varying from 7 to 9 m and heights generally between 5 and 18 m, resulting in extraction ratios between 80 and 85% (Roberts et al., 1999). Figure 1 presents an idealized stratigraphic section through the Viburnum trend and Figure 2 shows a plan view of the five areas spanning the three mines included in this study."

Jan 1, 2015

By Jameel Menashi

Aqueous solutions of Na2Cr04 can be reduced with CO to produce hydrous Cr203 and NaHCO3/Na2CO3. CH3OH, HCOO and HCHO in the presence of CO2 also reduce Cr 6+ and yield similar products. It is shown that the rate of Cr6+ reduction can be represented by the expression -d[Cr6+]/dt=k[Cr6+)1/2[R] where [R] is the aqueous phase concentration of CH3OH, HCOO- or CO. With these three reductants, the activation energies for the reduction processes are comparable and are of the order of 100 kJ/mole. Rapid reduction rates are attained at temperatures in excess of 220°C and, with these three reductants, a green acid-insoluble readily filterable hydrous Cr203 is formed. With HCHO significant reduction of Cr6+ occurs at about 80-100°C and an acid-soluble violet modification of hydrous Cr2O3 is formed. The reduction process is reasonably selective: solutions of Na2CrO4 contaminated with Mo6+ and W6+ can be reduced to yield a Cr2O3 product with significantly reduced contaminant levels. These findings are utilized as a basis for a process for recovering chromium from secondary source materials.

Jan 1, 1984

By G. Akdogan, C. Dorfling, L. Bumhira

Hydrometallurgical recovery of rare earth elements from phosphors obtained from end-of-life fluorescent lamps involve leaching followed by extraction of dissolved metals from solution. The similar properties of rare earth elements make selective recovery of individual elements challenging. The aim of the paper was to investigate the extraction of primarily Ce and Tb from a hydrochloric acid leach solution also containing other REEs (Y and Eu) as well as impurity metals (Ca and Al). Batch solvent extraction tests were performed with di-(2-ethylhexyl) phosphoric acid (DEHPA) at various extractant concentrations, pH conditions and organic-to-aqueous ratios. Extraction isotherms and separation factors for the range of conditions tested in the project are presented in the paper. Separation of individual REEs was not possible at the conditions investigated, but a mixed REE product can be obtained in a single extraction stage operated at a pH of 0.5 using 1 M extractant at an O/A ratio of 1; these conditions resulted in complete Y and Eu, 95 % Ce and 99 % Tb extraction with Ca and Al coextraction below 7 %. A better quality mixed REE product can be produced by operating at lower pH and extractant concentration conditions, but this would require a larger number of extraction stages. Keywords: Cerium, fluorescent lamps, phosphors, rare earth elements, solvent extraction, terbium

Jan 1, 2020

By Mark Zablocki, Dakarai McCoy

Ground vibrations are an unavoidable effect of driving piles and may pose a risk to nearby infrastructure and the comfort of adjacent occupants. Driven-pile-induced ground vibrations are known to vary widely based on ground conditions, pile material, and installation means and methods. A monitoring sensor to record ground vibrations during pile driving is necessary for understanding potential impacts to sensitive infrastructure and should be considered when implementing a monitoring program anticipating ground vibrations. The implementation of a vibration monitoring program historically relies on experiential-based decision-making, which may result in the costly vibration monitoring of low-risk infrastructure. Prior understanding of anticipated ground vibrations is necessary to create an appropriate monitoring program. A framework is proposed for organizing data from past monitoring programs and quantifying the anticipated risk of driven-pile-induced vibrations. An example of risk quantification from data imported to ]a cloud database is presented by comparing driven steel H-pile and prestressed precast concrete vibration monitoring measured and collected by Haley & Aldrich between 2010 and 2020. The methods presented within the example can be applied to quantify a first order approximation of risk for ground vibrations at proposed driven pile sites based on the measured performance of previous sites with similar ground characteristics and pile installation methods. The presented novel data managements tools allow for a quick aggregation of vibration data with similar site conditions.

Sep 8, 2021

By James F. Neill, O&apos

Brown iron ore resources in Barbour, Butler, Crenshaw, and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama. The aggregate footage drilled was 18,010 linear feet. When developed, reserves of 12,664,000 long tons of crude ore were indicated, containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet. Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons. Beneficiation of samples by simulated log washing and use of a 1/8-inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese. Screen-test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size. While an indicated 2,198,000 dry long tons of usable iron ore can be recovered, sink-and-float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing. However, applicable commercial processes have not been demonstrated.

Jan 1, 1965

By S A. Ravishankar, W Perez

Flotation is one of the main concentration processes to purify kaolin clay via the removal of naturally occurring impurity minerals containing Ti and Fe. Currently, there are two types of collector chemistries used in the industry to float coloured impurity minerals. These are traditional tall oil fatty acids (TOFA) and specialty hydroxamate (AHX) based collectors. AHX based collectors have long been known to be the most selective collectors to float Ti and Fe based coloured impurity minerals (CIMs) as compared to TOFA based systems. AHX based collectors provide, not only improved selectivity and simplified process, but also more importantly, make it possible to treat certain kaolin resources that do not respond to standard TOFA systems. However, the relatively higher cost of straight AHX collectors has restricted broader application of these collectors in kaolin clay and other oxide flotation applications for a long time. Recent technological advancements, in both making and formulating AHX products more economically, increased the usage of these collectors in kaolin applications. Modified AHX products offer more economical alternatives and process options to provide high purity kaolin clay products for specialty applications based on cost-performance criteria. In this paper, the flotation performance of a series of newly developed AHX formulations is provided along with the characteristics of AHX flotation in general. In addition, flotation performance of earlier AHX collectors is provided based on published literature as background data.

Jan 1, 2005

By A. E. Raddatz

The Federal Bureau of Mines, as part of its goal to minimize undesirable environmental impacts associated with mineral processing, has investigated a soda-smelting technique for processing ilmenite into pig iron and a titanium slag that is suitable for a feed to a sulfate-process titania pigment plant. By this procedure, the generation of ferrous sulfate waste and its associated disposal problem is obviated. Molten titania slag was quenched, water leached, and filtered to yield a sodium titanate intermediate product containing about 70 wt-pct Ti02, 1 wt-pct Fe, and 20 wt-pct Na20. This intermediate product, high-soda titanate (HST), was mixed with H2S04, calcined, quenched, and water leached to produce a low-soda titanate (LST) product that contained only 2 wt-pct Na20. Both the HST and LST were evaluated as feed materials for preparing titania by the sulfate process. About 95 pct of the Ti02 was extracted from HST and LST by digestion in concentrated or 50-wt-pct-H2S204 solutions. About 95 pct of the solubilized Ti02 was subsequently recovered from the titanyl sulfate solutions by hydrolysis. Barren solutions from hydrolysis, containing about 26-wt-pct H2S04, were upgraded by vacuum-thermal evaporation or electrodialysis. The regenerated acid solutions were used to digest additional HST and LST.

Jan 1, 1979

By T. Bhambhani, J. Jankolovits

Sphalerite flotation using copper sulfate has been performed in the industry for decades and the mechanism of Cu activation is well established. Despite its ubiquity, many practical questions surrounding copper sulfate persist. It is not clear how iron selectivity is achieved in zinc circuits given the propensity of iron sulfides to be activated by copper. Also, the large variation in copper sulfate dosages across different plants and ore types cannot be explained. Lastly, Zn flotation with greatly reduced copper sulfate dosages attracts significant interest and has been demonstrated in certain laboratory settings, but no information is available on why those laboratory solutions have not been adopted in plant practice. Flotation studies are presented that demonstrate that Zn flotation with very low copper sulfate dosages is possible when using certain novel collectors that are not practised in the industry. However, these reagent schemes are impractical because of a heretofore unappreciated and critical role that copper sulfate plays in Fe rejection. With both very low and standard copper sulfate dosages, copper sulfate influences both Zn flotation and Fe rejection. The results highlight the multifaceted role of copper sulfate in zinc flotation and the need to holistically consider complex systems’ behaviour to understand flotation reagent mechanisms and optimise plant performance. Keywords: Sphalerite flotation, metal activation, copper sulfate, iron rejection

Jan 1, 2020

By James F. Neill, O&apos

Brown iron ore resources in Barbour, Butler, Crenshaw, and Pike Counties were investigated in a drilling program and geological study by the Federal Bureau of Mines in cooperation with the Alabama Geological Survey and the University of Alabama. The aggregate footage drilled was 18,010 linear feet. When developed, reserves of 12,664,000 long tons of crude ore were indicated, containing from 26.9 to 29.0 percent iron and 0.2 to 1.6 percent manganese under a maximum overburden of 40 feet. Total inferred crude ore for the four counties was calculated to be 827,700,000 long tons. Beneficiation of samples by simulated log washing and use of a 118-inch screen yielded from 46.8 to 51.7 percent iron and 0.2 to 2.6 percent manganese. Screen-test studies indicated no appreciable interlocking between the iron and manganese minerals and the waste particles of materials retained on a 200-mesh screen. Clay was prominent in micron-size slimes. Silica was deleterious in the minus 20-mesh size. While an indicated 2,198,000 dry long tons of usable iron ore can be recovered, sink-and-float tests show that it may be possible for 4,654,000 dry long tons to be recovered by other than log washing. However, applicable commercial processes have not been demonstrated.

Jan 1, 1965

By J Tiihonen, J OÆCallaghan, T Haakana

Outotec is today capable of providing technologies, process equipment and engineering for the construction of pressure oxidation leaching (POX) plants in any location in the world. Outotec works with customers from mine to pure metal, participating in plant design from the process development phase (including test work execution/supervision) to plant commissioning and operations. Either key equipment technology packages with basic engineering or entire POX plants can be supplied.The addition of pressure oxidation equipment to OutotecÆs product portfolio adds to and complements already existing significant experience in general hydrometallurgical process and proprietary equipment design and supply.In addition to providing key pressure vessels, piping and valves to a POX plant, Outotec can offer an enhanced and proven autoclave agitation system that maximises oxygen mass transfer and utilisation. Novel energy and water recovery technology can also be tailored to a customerÆs specific needs. Importantly Outotec owns and operates extensive test work facilities and can provide test work to ensure the optimum POX flow sheet and materials of construction. Outotec ensures that best available technology (BAT) concepts are used in POX design to improve the availability of the process and minimise unpredicted shutdowns.CITATION:Tiihonen, J, Haakana, T and OÆCallaghan, J, 2013. Outotec pressure oxidation - more out of sulfide ore, in Proceedings World Gold 2013 , pp 197-206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Rob van Opbergen, Edo Engel

The highly dynamic economic climate of recent years has tightened the operating envelope for steel producers world-wide. Steel producers continue to experience immense pressure to respond quickly to changing circumstances and the focus has shifted towards efficiency improvement and maximizing flexibility in operations. The ability to safely stop, restart and ramp-up production facilities has become essential. Establishing this level of flexibility, without sacrificing efficiency, requires sound process control, fit-for-purpose process management practices and solid know-how and experience regarding special situations in blast furnace ironmaking operations. The same business environment that demands this increased flexibility has made it increasingly difficult for steel producers to sustain sufficient knowledge about these situations. While many experienced, senior operational staff have retired, a new generation of ironmaking specialists has acquired its hands-on experience over more recent decades, during which these process situations have been much less frequent than before. Over the past 10-15 years, the requirement in the industry for external operational support during e.g. blast furnace blow–downs, salamander tapping and restarts after planned and especially unplanned stops, has become increasingly frequent. This article presents a number of these cases from a process management perspective as well as with regard to project organization and optimized cooperation between internal and external teams of experts.

Oct 1, 2019