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By Tetsuya Uda, Sakae Shirayama

"With the aim of producing nickel (Ni) metal directly from acidic aqueous solution containing cobalt (Co) and other impurities, selective reduction of Ni was examined. As a preliminary experiment, sodium hypophosphite monohydrate (NaH2PO2·H2O) was selected as a reductant, and reacted with aqueous solution containing 0.1 mol L-1 nickel sulfate (NiSO4·6H2O) and 0 ~ 0.05 mol L-1 cobalt sulfate (CoSO4·7H2O) for 3 hours at 90 °C. As a result, it was revealed that Ni was selectively reduced and separated from Co in the acidic region (pH= 4.8). In this study, differences of reduction behavior between Ni and Co were investigated, and the feasibility of Ni I Co separation by the selective reduction of Ni was discussed.IntroductionEfficient Ni condensation and separation from Co are essential in nickel hydrometallurgical processes. Currently, the hydrometallurgical production of Ni from oxide ore is mainly carried out by acid leaching at elevated temperature, followed by the removal of impurities using neutralization, and condensation of Ni and Co into intermediate products such as hydroxides and sulfides. Then, the intermediate product is dissolved in acid aqueous solutions, and Ni I Co separation is conducted by solvent extraction. Finally, Ni and Co are recovered by electro-winning. This complicated process consumes large amounts of alkali, hydrogen sulfide (H2S), and organic solution in a multiple-staged process'. To reduce the consumption of these chemicals, it is important to recover Ni more efficiently from acidic aqueous solution containing impurities."

Jan 1, 2014

By M. Fan, Z. Long

"This paper presents some studies on recovering valuable elements from Chinese coal by-products, including coal combustion fly ash, stone coal ash, and coal flotation tailings. Both commercialized technologies and economic potential recovery methods are described in this study. Magnetically stabilized air-dense medium fluidized bed separation, tribo-electrostatic separation, froth flotation, and hydrometallurgical methods are discussed in recovering various valuable elements in Chinese coal by-products from different coalfields. These valuable elements include iron, carbon, aluminum, rare earth elements, lithium, gallium, germanium, uranium, titanium, scandium, silicon, vanadium and phosphorus, etc. The ultimate goal is to fully utilize all valuable elements in coal by-product. Each component within coal by-product should be efficiently segregated to its highest value. INTRODUCTION Coal is mainly composed of energy-producing elements carbon and hydrogen. In addition to these elements, coal usually contains many other valuable elements, including iron, aluminum, silicon, rare earth elements, lithium, gallium, germanium, vanadium, uranium, titanium, scandium, and phosphorus, etc. These coal-associated elements are significantly enriched in coal combustion by-product fly ash because of majority of main components, carbon and hydrogen elements, being removed. Table 1 provides the chemical composition range of the main elements oxides in 12 Chinese fly ash samples collected from coal power plants located in Northeast China, Northwest China, Southwest China, and Southeast China. It can be seen from Table 1 that the major mineral components of different ashes are similar, but the bulk chemistry of different fly ashes may vary widely due to the changes of ratios of the mineral components in different coals. The major mineral components in various Chinese coal combustion fly ash are silicates, iron oxides, and unburned carbon."

Jan 1, 2017

By Hernan Escalante, Jonathan Alvis, Paulo Alcazar

Constancia Mine, operated by Hudbay Perú and located in the district of Velille, Chumbivilcas province, Cusco, is an open-pit operation characterized by low-grade ore. In this context, operational efficiency and process optimization are essential to ensure long-term profitability. This paper presents an innovative strategy based on the processing of large volumes of data (Big Data), primarily from the drilling and blasting stages. By consolidating approximately 9 million records per month into a georeferenced block model, an analytical platform was developed to directly correlate material fragmentation quality with plant mill throughput. The implemented methodology integrates multiple operational and geometallurgical data sources, enabling dynamic visualization of blasting conditions and their impact on material behavior during crushing and grinding. Through this correlation, operational patterns that maximize plant throughput while minimizing energy consumption and processing costs were identified. Beyond the direct benefits in the plant, this approach significantly improved mine planning by enabling more informed decisions regarding drill pattern design, explosive loading, and blast sequencing. Improved coordination between mine and plant departments was also observed, contributing to better alignment of operational goals and an integrated business perspective. The application of Big Data in this context represents a step toward digital transformation in mining, demonstrating that advanced analytics can be effectively implemented in large-scale, complex operational environments. This solution was validated under real operating conditions and shows high scalability potential for other operations facing similar challenges. In conclusion, this study demonstrates that systematic analysis of drilling and blasting data, when integrated with geological and operational models, can lead to substantial improvements in plant performance. This contributes directly to the competitiveness and sustainability of low-grade mining operations.

Jan 26, 2026

By T Perera, B Fan, S Thang, T Hsia

Minerals are valuable resources and critical elements for a broad range of biological and technological applications, including technological developments to improve energy efficiency and the global movement to promote a low-carbon economy. However, in order to extract these critical metals, large amounts of waste and toxic chemicals are generated, as well as the use of high energy and large amounts of water consumption. Froth flotation is one of the most commonly used processes to separate and collect high-value minerals, but it still has some limitations, including low flotation efficiency performances using existing collectors and other reagents. Therefore, there is an urgent need to design and develop new metal-specific collectors to more efficiently separate and recover valuable minerals and to allow bulk water recovery from flocculated tailings. In this research, we propose to use our newly designed and synthesised novel collectors derived from a type of vitamin E (α-tocopherol), a relatively inexpensive and non-toxic natural molecule. As a potential collector-building block, α-tocopherol has a long hydrophobic carbon chain that facilitates the attachment to air bubbles during the froth flotation process. In addition, the phenol group of this molecule can be easily modified to incorporate various functional groups for targeting different types of minerals. Furthermore, α-tocopherol can be converted into a monomer for polymerisation by the reversible addition-fragmentation chain-transfer (RAFT) process, which can provide us with polymer based-collectors with high precision control of molecular weight and architecture. So far, small-scale qualitative experiments on α-tocopherol-based collectors have been performed with good results, which indicates the feasibility of these compounds as novel collectors for improved froth flotation processes.

Aug 24, 2022

By Xuling Chen, Yi Wang, Xiaohui Fan

"The current control method of grate-kiln iron ore oxide pellet production is lack of accuracy and normalization due to the limited detection conditions. Therefore, mathematical models of grate-kiln temperature field are presented. With calculation of gas-particle heat transfer as well as enthalpy changes of moisture evaporation and magnetite oxidation, the thermal history of pellets throughout grate-kiln process can be acquired and used for production status estimation. Taking the calculated results as well as detected data in production as inputs, process parameters such as running speed, fan opening and coal injection rate as adjusting objects, expert system for grate-kiln pellet production is outlined. And the preheating section dominated control strategy is explained. Results of production application show that the stability rate of gas temperature in gas hood of preheating section is increased from 91.0% to 94.2%, compressive strength and first grade rate of pellet are increased by 3.62% and 2.36%, respectively, while FeO content is 18.18% lower. Control guidance of this expert system can solve production anomalies effectively, stabilize grate-kiln iron ore oxide pellet production and improve pellet quality.IntroductionSteel industry in China has developed rapidly in recent years. China’s crude steel production in 2010 is nearly 627 million, which is 44.2% of the world total production. Burden with higher quality is demanded by enlargement and modernization of blast furnaces. And oxide pellet production has become a growing concern. In 2010, the total production of pellet in China is 110 million, and about 60% is produced by grate-kiln process."

Jan 1, 2012

By E R. Ramanaidou

Two unknown iron ore samples were found by a geologist from Ok Tedi Mining Limited copper, gold and silver mine at an old wharf site dedicated to a 1970s drilling program in Lake Murray in Papua New Guinea (PNG). These iron ore samples could not come from a PNG mine and it was decided that a study should be undertaken to understand their origin. Lake Murray is the largest lake in PNG with a total surface area of 647 km2. It has a high-water 2038 km long convoluted shoreline with seasonal water level changes (Osborne, Kyle and Abramski, 1987) and it is located around 200 km south of the Ok Tedi mine (5°13’25”S, 141°09’37”E). The petrology, mineralogy and chemistry of two Fe samples (Ok Tedi 1 and Ok Tedi 2) included optical microscopy, X-ray fluorescence (XRF) analysis and a comparison with worldwide iron ore deposits. The two rock samples were cut to produce two subsamples: (1) a polished thin section; and (2) a pulp that was used for XRF analysis including major, minor and trace elements. Ok Tedi 1 and Ok Tedi 2 were petrologically and chemically compared to a range of known iron ore samples from Australia, Brazil and South Africa. The petrological study of Ok Tedi 1 indicates that it is composed of granoblastic recrystallised hematite and the overall texture is uniform without any obvious original ‘sedimentary’ texture. Ok Tedi 2 is a ‘specular’ or platy hematite with recrystallised and fused grains. Using both petrological and chemical clues, the two Ok Tedi samples likely originated from the Iron Quadrangle in Brazil.

Sep 18, 2023

By Stanley R. Riggs

Onslow Bay is a broad, shallow, high-energy shelf system bounded by the Cape Lookout and Frying Pan shoals. It is generally a sediment-starved shelf system dominated by hardbottoms with a scattered and discontinuous veneer of mobile Holocene sediments. Phosphate-rich beds of the Miocene Pungo River Formation crop out in a belt 150 km long and up to 50 km wide across the continental shelf in Onslow Bay, North Carolina. Previous research has demonstrated that a few of these beds contain vast quantities of potentially economic phosphate resources that occur in the surface and shallow subsurface sediments. Onslow Bay contains five phosphate-bearing beds predicted to include up to 20.7 billion tons of in-place phosphate concentrate with total sediment grades ranging up to 22.9% P2O5 and adjusted average concentrate grades of 29.8% P2O5. These phosphates are lithologically and chemically similar to phosphates currently being mined in the nearby Aurora phosphate district in North Carolina. Various lithologies of the Pungo River Formation and associated rock units of Oligocene and Quaternary age crop out on the sea floor to form extensive hardbottom habitats that dominate almost 100% of Onslow Bay. A large proportion of these hardbottoms appear to be sea floor deserts, whereas others are virtual oases with rich associations of benthic organisms. These important differences in benthic community structure appear to be greatly influenced by one or more of the following variables: 1) geologic framework (geologic formation, hardbottom composition, morphology, and spatial orientation relative to dominant currents and waves), 2) texture, movement, and accumulation of surface sediments, and 3) flow rates and chemical composition of discharged submarine groundwater.

Jan 1, 1992

By M. Abzalov

"Control of analytical data quality is usually referred to in the mining industry as Quality Assurance and Quality Control (QAQC), and involves the monitoring of sample quality and quantification of analytical accuracy and precision. QAQC procedures normally involve using sample duplicates and specially prepared standards whose grade is known. Numerous case studies indicate that reliable control of sample precision is achieved by using approximately 5% to 10% of field duplicates and 3% to 5% of pulp duplicates. These duplicate samples should be prepared and analyzed in the primary laboratory.Bias in the analytical results can be identified by inclusion of 3% to 5% of the standard in each sample batch. Several different standards are used, with values spanning the practical range of grades in the actual samples. A blank (a sample in which the concentration of metal of interest is below detection limit) should also be included. Standard samples alone cannot identify biases introduced during sample preparation, and therefore approximately 5% of the duplicate samples (coarse rejects and pulp) should be processed and assayed at another, external, reputable laboratory.This paper discusses techniques used for estimation of errors in precision and accuracy, and overviews diagnostic tools. It is shown that one of the most commonly used methods, the Thompson-Howarth technique, produces consistently lower results than other methods. These results reflect the nature of this method, which relies on the assumption of a normally distributed error, and thus produces biased results when errors have a skewed distribution. This study concurs with the suggestion of Stanley and Lawie (2007: Exploration and Mining Geology, v. 16, p. 265-274) to use the average coefficient of variation (CVAVR(%)) as the universal measure of relative precision error in mine geology applications: Le contrôle de la qualité des données analytiques est habituellement désigné sous l’appellation d’Assurance et Contrôle de la Qualité (ACQ), elle implique le suivi de la qualité des échan¬tillons et la quantification de la reproductibilité et la précision analytiques. Les procédures des pro¬grammes d’ACQ impliquent habituellement l’usage de duplicata et de standards analytiques dont la teneur est connue. Plusieurs études de cas indiquent qu’une bonne fiabilité du contrôle de la précision des échantillons est atteinte par l’usage de 5% à 10% de doublons sur le terrain et de 3% à 5% de doublons de pulpe. Ces duplicata devraient être préparés et analysés au laboratoire principal.Un biais des résultats analytiques peut être identifié par l’inclusion de 3% à 5% d’échantillons standard dans chaque envoi d’échantillons. Plusieurs standards sont utilisés, avec des valeurs couvrant l’étendue des teneurs habituellement rencontrées dans des échantillons réels. Un blanc (un échantillon dans lequel la concentration d’un métal donné est sous la limite de détection) devrait aussi être inclus. L’emploi exclusif d’échantillons standards ne permet pas l’identification de biais résultant de la préparation des échantillons, de telle sorte qu’environ 5% des duplicata (rejets grossiers et pulpes) devrait être traités a un autre laboratoire indépendant et fiable.Cet article passe en revue les techniques utilisées pour évaluer l’erreur liée à la précision et a la reproductibilité, et effectue aussi un survol de divers outils diagnostiques. Il ressort de cet examen qu’une des techniques les plus fréquemment utilisées, la méthode Thompson-Howarth, fournit des estimés systémati¬quement inférieurs à ceux provenant des autres méthodes. Ces résultats sont un reflet de la nature de cette méthode, laquelle assume une distribution normale de l’erreur, biaisant ainsi les résultats lorsque l’erreur présente une distribution asymétrique. La présente étude recommande de privilégier l’usage du coefficient moyen de variation (CVAVR(%)) en tant que mesure universelle de la précision relative de l’erreu"

Jan 1, 2008

By Douglas Bartley, Robert McClure

This paper discusses the advances in programmable, testable high accuracy electronic detonator technology. The operation and safety of electronic detonator systems are required to meet rigid safety standards and withstand the demanding environment of in-field applications. These requirements are discussed through comments on existing safety requirements in Europe.

Jan 1, 2000

By S. Jeon, J. Kim, H. Lee

Though the importance of the engineering rock mass properties such as deformation modulus, cohesion and friction angle is emphasized, the researches on the reliability of these values are rarely performed. By using modified Takagi-Sugeno (TS) fuzzy inference system, a fuzzy model was developed based on the data obtained from domestic tunnel construction sites, and the ability of prediction was compared with the empirical equations conveniently used for estimating these values, which finds that fuzzy model is better than empirical equation. Sufficiently large database, however, is required for training the fuzzy model for more accurate prediction. Obwohl die Wichtigkeit der technischen Eigentümer der Felsenmassen wie zum Beispiel Verformungsmodulus, Bindekraft und Reibungswinkel betont werden, wird die Forschung auf der Zuverläßigkeit dieser Werte selten durchgeführt. Mit modifiziertem Takagi Sugenos (TS) Flaumigenschlußsystem wird die Flaumigenmodelle von den Daten, die von inländischen Tunnelbaustellen erhalten werden, entwickelt. Zum Schätzen dieser Werte ist es viel günstig, Flaumigenmodell zu benutzen, als zu adoptieren die empirische Gleichung für die Fähigkeit der Voraussage. Genügende große Datenbank wird aber zum Ausbilden flaumigen Modells für genauere Voraussage erfordert. Quoique l'importance sur la caractéristique d'ingénierie de la masse de roche comme le module de déformation, la cohésion et l'angle de friction, soit soulignée, la recherche sur la confiance de ces valeurs est rarement effectuée. Avec le système modifié de Takagi-Sugeno(TS) fuzzy inférence, le nouveau modèle fuzzy s'est développé. Après avoir estimé sa valeur, nous pouvons savoir que ce modèle fuzzy, basé sur les données venant du chantier de construction de tunnel national, est mieux que l'équaton empirique. Pourtant plus de données de base sont indispensables pour produire le modèle fuzzy plus précis.

Jan 1, 2003

By C McMahon, S G. Walters

Mineral maps of æintactÆ and large particle textures have been produced routinely from optical microscope images. Polished thin sections of large particles (1 - 3 mm) provide a balance between representative sampling and the preservation of primary rock textures. Optical microscopy is an efficient way to generate mineral maps suitable for geometallurgical applications. The automated optical mineral identification was carried out using a Leica DM6000¬ microscope with a high precision stage suitable for direct tiling of image frames and good registration of multiple image layers. Standard images collected were 10 x 10 frames (20 mm x 16 mm). Four image layers were recorded: ætransmitted light plane polarisedÆ, ætransmitted light crossed polarsÆ, ætransmitted light crossed polars with 1l tint plateÆ and æreflected lightÆ. All image analysis was carried out using Definiens Professional V5¬. The four image bands were read directly in 12 greyscale bands. A segmentation algorithm produced objects based on homogeneity across all bands. These objects were then classified using a complex set of rules (Process Tree) that are based on image brightness in all 12 bands. Opaque and non-opaque minerals were classified in the same sample. Using this protocol up to 12 minerals can be satisfactorily classified in one sample. The opaque minerals were recognised using colour ratio and reflectance intensity in the reflected light image. Non-opaque minerals are more difficult because of the complex variable colours of many minerals and the complexity of interference colours. However, object-oriented classification using three transmitted light image layers and multiple rules is a powerful technique for recognition of these minerals.

Jan 1, 2008

By Stephen Utter

One function of mining is to supply oil shale of the required grade and characteristics to surface retorts. The mining methods must he safe, efficient, and environmentally acceptable. Although the Bureau of Mines no longer conducts research on methods of mining fossil fuels, including oil shale, its many years of activity in that field resulted in a significant body of findings. This article summarizes some of these findings, with respect to oil shale mining. The large areal extent of Green River formation oil shales and the diversity of geologic, hydrologic, topographic, and other conditions, preclude the use of any one single mining and waste management technique. Instead, in most instances, methods and equipment will be chosen to meet site-specific conditions. Such methods include conventional surface mining (open-pit and strip), underground mining (room-and-pillar, sublevel stoping, caving) and in situ extraction (true in situ from surface drill holes and modified in situ from underground retorts containing rubblized oil shale). Combination or hybrid systems may prove suitable. Both surface and underground backfilling of spent shale waste may be practiced. Tremendous amounts of oil shale must be mined, processed, and the waste shale properly disposed of in order to meet projected industry production goals. For example, about 1.4 tons of oil shale averaging 117 L of shale oil per ton are required to produce one bbl of oil. A plant with a daily production of 8 dam' (50 000 bbl) of oil would thus require some 68 kt of raw shale daily. This is more than the average daily production from any underground mining operation.

Jan 1, 1981

As an environmental "pollutant", noise is different. For one thing, it is localised (as opposed to transfrontier) and, for another, relatively low levels can trigger very strong human reaction. The reactions, which are annoyance-based, range from mild to violent and do not always correlate well with the levels experienced. This paper draws on technical aspects of noise to consider control and control principles and balances them with the subjective nature of the perceptions and reactions. It is critical to bear in mind that health effects resulting from noise are secondary to the primary human reaction. It is also important to appreciate that annoying noise levels are usually well below those which cause hearing loss. Large mines tend to be remote from cities and towns and the country surrounding such mine sites is often inhospitable. In general, residences near large mines are committed for use by mine personnel and annoyance from mining noise would be rare. Noise problems at long term operations are often a result of secondary activity or land use. As a pioneer mining community develops, secondary and service industries may be established and a township created. With changes in way of life, the perception of problems also changes. Therefore, it is never too early to plan for noise abatement, particularly because noise is only one of a number of environmental and community concerns. Ihny environmental problems are associat- ed with development or expansion of smaller open cut facilities such as hardrock quarries. There is an ever-present need to reduce product cost by mining or quarrying deposits close to the end user and many local authorities have to operate quarries for undertaking their civil engineering responsibilities.

Jan 1, 1987

PRESIDENT WHITESIDE: I am sure we are very grateful indeed for this very interesting talk that Mr. McClure has given us. If anyone has any questions to ask Mr. McClure I am sure he will be glad to answer them at this time. MR. WEITZEL: I want to ask Mr. McClure whether in the instance he described by-passing the drier, whether there was any rest period between the crusher and the furnace, whether the powdered coal that was not dry was allowed to rest in the pipe or was blown directly into combustion chambers. MR. McCLURE: Yes, it moved directly; there might have been some difference had we given it an opportunity to rest. We just had to get in and get out so as not to interfere with operations. MR. WEITZEL: Your idea is, even though you did use a high moisture lignite, you could store it under water if you eliminated surface moisture later. That is a new idea to me; I always had thought that you had to reduce the moisture down under 2 per cent, and to try to store it with anything more than that, any higher moisture, you would have to break the stuff loose again, as it gets so hard it won't move. MR. McCLURE: It might develop I am absolutely wrong; I am just saying what I observed, and I may have had some unusual condition, which I did not detect; something may actually develop which will make my statement of drying lignite entirely wrong. It was quite a surprise to me, surprise to every-

Jan 1, 1923

By Roy E. Williams, Muriel S. Robinette

Ground-water contamination from uranium operations could be avoided with proper site analysis techniques. Contamination from tailings disposal sites is carried downgradient within permeable hydrostratigraphic units which can be located and delineated with a combination of drill holes and borehole geophysical logs. Engineering safeguards can be designed into a disposal site by determining if permeable hydrostratigraphic units exist which will dominate the flow system and provide seepage paths for contaminates. It is more cost-effective to accurately assess seepage potential with geophysical logs before contamination becomes a problem than to be faced with a major clean-up effort after contamination has occurred. If a uranium waste impoundment already has a ground-water contamination problem, then borehole geophysical logs may be used to delineate the contaminated zones which need to be cleaned up. It is less expensive to withdraw the contaminated plume from only within the affected zones rather than attempt to dewater the entire area. Consequently, the geophysical logs are invaluable in assessing which zones should be pumped and where packers should be set for construction of piezometers to allow monitoring of water-quality changes. A surface geophysical technique is being tested and developed for monitoring of seepage frum uranium tailings impoundments. Geoelectric soundings and profiles from direct current resistivity surveys can locate anomalous areas for the placement of drill holes to better assess seepage. This reconnaissance technique should eliminate random hit-or-miss drilling at sites where monitoring is required. Tests and experiments are being done on developing the capabilities of this technique to incorporate complex resistivity data to assess cultural impedence noise which complicates simple resistivity data.

Jan 1, 1980

By Webster Hodge

MALL generators and motors are required to Soperate, in some critical applications, at temperatures where cold-worked silver-bearing copper re-crystallizes. Copper containing up to 30 oz Ag per ton has been used for many years to build the highest grades of commutators and slip rings. With failure of commutators impending because silver-bearing copper cannot withstand the stresses imposed at these higher temperatures, Cr-Cu was tried as a substitute with varying degrees of success. Cr-Cu proved difficult to fabricate because a critical heat treatment was necessary to obtain sufficient ductility. Besides, its rupture strength was shown to be low at operating temperatures, its electrical conductivity lower than desired, and its cost high. Furthermore, it often contained hidden flaws. The Nippert Electric Products Co. set out to find a better material by undertaking a research project with the stated objective of providing a material suitable for commutators that would have 1) a softening temperature above 750°F (400°C), 2) a minimum electrical conductivity of 90 pct of that of pure copper, 3) a strength not less that that of cold-worked silver-bearing copper, and 4) a materials cost of not over 1.5 times the cost of copper containing 25 to 30 oz Ag per ton. No commercial alloy met these specifications. However, it was found that copper containing from 0.18 to 0.35 pct Zr could be produced quite easily in the laboratory, and promised to fulfill the major requirements noted above. Interest naturally centered in the lower part of this composition range, since such alloys gave somewhat better electrical conductivities, and were lower in

Jan 1, 1958

By W. Hrynewich

"The Central Canada Potash facility, a division of Noranda Metal Industries Limited, is located 3 kilometres south of the junction of Highways 16 and 2, about 75 kilometres south-east of Saskatoon, Saskatchewan. The site occupies 26~ hectares of land and includes well-equipped machine and electrical _shops, a 325,000-tonne muriate storage and reclaim warehouse, a stores warehouse, processing plant (mill), two mine shafts (one for production, the other for servicing and personnel transport), as well as a two track product loading complex. Access to the site is by road and railway (CN and CP Rail). Suppliers of operating and maintenance use both means of transportation, whereas muriate shipments are entirely by railway.Currently five continuous mining machines - one a Goodman 526 borer and four Marietta 911-A units produce some 10,500 tonnes of ore per operating day. A smaller Voest-Alpine Af.1-100 boom type miner is used for floor cutting which was previously done by a production unit. In order to maintain safe, competent ground conditions only 35 percent of the total ore is extracted. At this rate mine reserves are deemed adequate for about 100 years. The plant has operated since August 1969 and has a current practical annual capacity of 1,270,000 tonnes of muriate. As of June 30, 1981, some 11.9 million tonnes of muriate had been produced from 31.4 million tonnes of ore. Of the total muriate, 6.1 million tonnes was granular, 4.8 million was coarse, and 1.0 million was standard. No standard product has been made since August 1978."

Jan 1, 1982

By B. W. Jong

As part of the Bureau of Mines program to develop substitute or improved performance refractory materials for metallurgical applications, the Tuscaloosa Research Center has evaluated the effect of additives on sintering and strength properties of aialon (silicon aluminum oxynitride) compositions fabricated by a conventional powder metallurgy technique. Additions of Y203, Gd203, CeO2, MgO, ZrO2, ZrSiO4, and MgA12O4 to a sialon composition containing 70 pct ß-Si3N4 + 30 pct a-A1203 increased sintered densities by as much as 50 pct over densities of undoped material. The studies also indicated that sintered densities reached a maximum between 20 and 30 mole-pct a-A1203 when a series of sialon compositions of a-Si3N4, having 6.7 to 57.9 pet a-Al203, were doped with Y203, Gd2O3, and MgO. In studies to establish the effect of the crystalline phase of the silicon nitride and alumina used, tests were made using a- and ß-Si3N4 and a- and ?-A12 03 as starting materials. The tests indicated that when using an addition of 5 wt-pct Y203, best results were obtained with a sialon composed of 74.4 mole-pct a-Si304 and 25.6 mole-pct ?-A1203. In other tests made with this sialon composition MOR values of 28,120 and 29,500 psi at 25° C, and 23,520 and 16,850 psi at 1,400° C, were obtained when doping with 5 wt-pct ZrSiO4 and ZrO2, respectively.

Jan 1, 1980

By Peter Zhang

As simpler and easier reserves are exploited to depletion, underground coal mining continues in more complex geologic settings and conditions. Roof bolting for long-term entry stability is always a challenge. For long-term entries of a mine such as belt, track entries and return airways, roof could be under-supported if one uses the same bolting plan as in short-term entries or even seem over-supported with increasing use of longer, stronger bolts along with mesh, pans, straps or trusses. In most underground coal mines, roof deteriorates over time with cutters developing deeper in entry corners; roof sagging and popping out between bolts; entry width increasing due to rib sloughage; and separations developing deeper up into the roof. In deteriorated long-term entries, roof falls could occur at certain locations and re-bolting could be costly or sometimes unfeasible. Therefore, it is important to choose an appropriate bolting plan during development based on mining and geologic conditions if the entries will be used for the long-term. In both short-term and long-term entries, primary roof bolting is critical in building a strong and effective beam. But in long-term entries, supplementary bolting is necessary in certain cases to ensure roof stability can still be maintained even if a roof failure develops beyond the primary bolted horizon. This paper deals with roof bolting for long-term entries based on studying the progressive roof failure and roof falls under different geologic conditions. The paper presents bolting considerations in terms of bolt type, length, diameter and spacing as well as bolting strategy to minimize the risk of roof falls in long-term entries.

Jan 1, 2011

By M. S. Moats, F. Elnathan

"The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.INTRODUCTIONCatalytic titanium anodes (CTAs) were developed in the 1960’s to replace graphite anodes in chlor-alkali cells. CTAs exhibited much better dimensional stability than graphite leading to lower operating potentials by promoting smaller electrode gaps and better operational efficiencies as they had to be replaced less often. CTAs are simply Ti substrates coated with precious metal oxides (such as IrO2 and RuO2) mixed with other components (such as TiO2 and TasO5) (Trasatti, 2000).CTAs are used in many other electrochemical industries, including water disinfection, wastewater treatment, cathodic protection and metal plating. RuO2 based coatings are typically used for chlorine evolution. IrO2 based coatings are for the most part utilized for oxygen evolution (Comninellis & Nerini, 1991; Forti, Olive, & De Andrade, 2001; Kotz, Stucki & Carcer, 1991; Trasatti & Lodi, 1981)"

Jan 1, 2016