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SAN FRANCISCO SECTION Roy H. ELLIOTT, Chairman - T. A. RICKARD, Vice-chairman W. H. SHOCKLEY, Secretary-Treasurer, 959 Waverley St., Palo Alto, Cal. D. A4. RIORDAN C. F. TOLMAN, JR. A joint meeting of the local sections of the several national engineering societies represented in San Francisco was held at the Engineers'. Club on Thursday evening, Sept. 26, 1918. The subject for the evening, "Fuel Conservation," was ably discussed by a-number of representatives of the Federal Administration and by engineers interested in the generation and utilization of all kinds of power on the Pacific Coast. The following extracts from papers presented at this meeting have been selected as being of the greatest interest and value to members of this Institute. Problems of the Fuel Administration ALBERT E. SCHWABACHER.-America's war needs call for 100,000,000 more tons of coal this year than in 1917, and 200,000,000 tons more than in 1914, when the war started, and this increase must come from a weaker man-power than that of 1917. It must be transported by a railroad system that has not been improved since the war started, and has been burdened with inconceivably greater demands than were made upon it before the war. This tremendous increased demand must be met by most intensive work in three directions; increased production, efficient conservation, and a distribution system which will insure against lost motion. While every European country has decreased its coal production since the war began, the United States has mined 50,000,000 tons more coal, during the first year of the war, and will increase this by another 50,000,000 the present year. Every 8 days there are being mined and transported as great a weight of coal as of the entire wheat crop of the United States. Of the 735,000,000 tons of coal which must be made available for consumption by our railroads, ships, war industries and people, 100,000,000 tons will come from the anthracite fields, the remainder from the bituminous fields. In 1917 there were produced about 330,000,000 bbl. of oil, and this year an additional amount over last year's production, of approximately 23,000,000 bbl. will be required. Water power developed 5,000,000 hp., the demand greatly exceeding the available supply.

Jan 12, 1918

By Amjad Asad, Boyd Davis, Kinnor Chattopadhyay, Rüdiger Schwarze, Christoph Kratzsch, Donghui Li, Lei GAO

Sodium (Na) and Lithium (Li) are produced using molten salt electrolysis. The electrochemistry of the electrolyte is well-researched; however, there are benefits to understanding the melt flow and implications on it for cell design modifications. The basic configuration of alkali metal cells is the Downs cell. This consists of a central anode surrounded by a cathode, and this geometry was the basis for this mathematical modeling study. The behavior of gas bubbles in molten electrolyte was studied in both Na and Li cells through the use of computational fluid dynamics (CFD) techniques. The distance between the anode and the cathode was varied in the CFD model to ascertain whether strong circulatory flows would change significantly in the cell. The standard k-ε turbulence model was used to mimic turbulent flow, and a two-way coupled Discrete Phase Model (DPM) was adopted to simulate flotation behavior of chlorine bubbles and liquid metal droplets. The liquid metal distribution on the free surface was predicted using the Volume of Fluid (VOF) multi-phase model.

Mar 1, 2017

By Andrzej Wieniewski, Cezary Regula, Bozena Skorupska, Krystian Cichy

"In this paper, experiences from Polish non-ferrous metals ores enrichment plants in the copper and blende concentrates quality improvement are discussed. The blende concentrate being produced in ZGH Boleslaw S.A., with Zn content of about 54,5% is characterized by the relatively high magnesium content reaching a level of 1% resulting from the dolomite presence, while for the zinc production by electrowinning a concentrate in which magnesium content should not exceed 0,3% is required. The implemented new technology for the quality improvement of blende concentrate is based on the leaching of zinc concentrate with sulfuric acid aimed at dissolving of the contained dolomite, and then flotation of the leached concentrate. It allows to obtain a concentrate with magnesium content below 0,1% at the simultaneously increased zinc content to about 57,5%. In the paper, laboratory tests results on the development of optimal flotation flowsheet for the gypsum removal and the industrial tests results concerning the process optimization of this flotation are discussed. In turn, the copper concentrate being produced in Polish copper ore enrichment plants KGHM PM S.A., is characterized by the increased organic carbon content - above 8%. It creates problems with the smelting of this concentrate because of difficulties with the heat removal derived from the combustion of organic carbon in the flash smelting process. The implementation of segregating flotation to the industrial practice allows the effective production of two concentrates with the differentiated chemical compositions - a concentrate with increased copper content and reduced organic carbon content for the flash smelting process, and a concentrate with lower copper content and increased organic carbon content for the shaft smelting process. In the paper, conditions of the segregating flotation and the achieved results are described."

Jan 1, 2014

By R. E. Ray

As coal reserves at shallow depths continue to be exhausted, a number of U.S. coal mining companies are beginning to develop coal seams previously thought to be coo deep to mine economically. Because of increased cover load, mines operating in deeper seams face unique ground control problems. In addition, the volume of methane gas contained in coal beds increases with depth, and ventilation requirements are much more stringent for deep underground coal mines than for shallower mines. When the longwall mining method is used at great depths, ventilation, ground control, and operational considerations must all be addressed in the design of longwall panels. This paper examines the influence of these factors, particularly ventilation and operational considerations, upon the feasibility of two, three, and four-entry longwall development panels in Jim Walter Resources' four deep mines.

Jan 1, 1986

By A. Bhagwat, S. Tadolini

"Steel members of the ground support systems in underground mines are routinely exposed to corrosive environment that may range from acidic to alkaline. Corrosion of steel bolts leads to metal loss and thereby, reduction in strength and useful life. Protective coatings are commonly applied to the steel bolts to combat corrosion. However, coatings are expensive and often cumbersome in practical applications. Instead, Minova has developed an innovative technology based on sacrificial anodes. The anodes were designed from non-ferritic alloys that are inferior to steel on the Galvanic Series. This paper will present data from field testing to show significant benefit of the technology. Potential applications in current products will be discussed. INTRODUCTION Corrosion is a physical alteration of a steel material from electrochemical reaction with its environment that often results in reduction of the mechanical and physical properties of that material. Mine roof bolts, the subject of this investigation, are particularly susceptible to corrosion as they can be exposed in their working environment to ground water and air with high humidity. As other researchers have determined, corrosion increases markedly in sulfide ore bodies due to acid runoff. There are several types of corrosion that a rock bolt is likely to undergo when used for ground reinforcement in underground mines (Aziz et al., 2013). Of all the types of corrosion, pitting is particularly dangerous as it can remove capacity for the bolt to deform with subsequent strata movements. Sudden failure of a bolt is likely to occur when severe pitting corrosion is experienced. The type and nature of corrosion depend on the nature of the ground condition and bolt encapsulation. Generally, the type of corrosion and severity of the corrosion varies along the axis of bolt. Almost all of the mine roof bolts used in mines, with the exception of fiber reinforced polymers, are made from steel. The corrosion of iron is an electrochemical phenomenon with the overall equation:"

Jan 1, 2018

By James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity ? up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonnes of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle ? particle contact. The small gap, high electric field, counter current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in the North America and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Sep 1, 2012

By A. C. Gagnon, H. Saroglou

"The focus of this paper is on the analysis of geometrical discontinuity properties for the rock mass located within an open pit mine located in Western Africa. Discontinuity data were collected using various techniques including oriented core logging, borehole televiewer surveys, surface pit wall mapping and photogrammetry. The geological setting was initially studied prior to the data analysis to produce threedimensional ground models of the regional and mine site geology along with block diagrams illustrating predicted fracture patterns. Stereographic and statistical discontinuity data analysis of the geometrical properties of the rock mass was subsequently performed to identify unique structural domains throughout the open pit area. The discontinuity data collected throughout the studied open pit area were primarily discontinuity orientation, frequency and spacing and the investigation focused on the reasons for observed differences between the various data collection techniques. Stereographic analysis was used to assess the preferred geometry of discontinuities filtered by lithology, data collection technique, borehole, discontinuity type and pit wall (footwall or hanging wall). The observed fracture pattern is explained adequately by the geological setting. The need for accurate ground models for the design of open pit slopes is highlighted.INTRODUCTIONThe Tasiast Mine is an open pit operation located in north-western Mauritania, approximately 300 kilometres north of the capital Nouakchott. The Tasiast mine, which is owned and operated by Kinross Gold Corporation (Kinross), began commercial operations in 2008. The Tasiast mine is located in an area characterized by flat desert terrain within the western reaches of the Sahara Desert region. The current mine site includes mill buildings, shop facilities, waste dumps, tailings facilities and two main open pit operations (Piment and West Branch). The West Branch pit is the focus of this paper. The current open pit plan for West Branch indicates a final pit measuring approximately 2.5 km long by 1.4 km wide and 510 m deep."

Jan 1, 2015

By Prof. Dr. -Ing. habil. Sascha Henke, Johannes Beck

The growth of Building Information Modeling (BIM) during recent years opens possibilities for integrating new digitally driven design approaches. While parametric design and algorithmic design slowly gains popularity in numerous ACE-applications, e.g. bridge design, it is rarely used by geotechnical professionals. This article presents an approach for implementation of parametric design in the BIM-based geotechnical design process. The methodology is applied to pile design and enables a real time design analysis according to DIN EN 1997-1 and EA-Pfähle 2012 considering boundary conditions such as pile position and layout, pile geometry, soil stratification and soil properties. By using intelligent attributes and scripts to control, calculate and assign them, the design analysis is directly executed in the BIM-software environment, in this case Autodesk Revit with Dynamo. This BIM integrated design approach allows multi-criteria evaluations of pile designs using aspects such as costs, environmental impact or constructability in addition to the commonly examined structural analysis criteria. As the proposed models are fully parametric, generative optimization algorithms can be applied to identify the ideal design for the entirety and each of the piles. Finally, the potential and limits of this methodology with respect to modeling, analysis, simulation and optimization are discussed.

May 1, 2022

By Dalton. J. L., H. P. Dibbs

An account is given of investigations into the application of two neutron methods to the on-line analysis of slurries. One deals with the application of the neutron moisture gauge principle to the determination of the water content of iron oxide slurries, and the other with the application of gamma radiation from thermal-neutron-capture to the determination of the composition of aqueous slurries of iron oxide, copper oxide, zinc oxide and sulphur. Linear relationships were found between the composition of the slurry and the neutron count-rate in the first study, and between the slurry composition and the prompt-gamma-ray count-rate in the second study. A mathematical relationship has also been developed which relates changes in the prompt-gamma-ray counts from hydrogen to changes in slurry composition.

Jan 1, 1973

By Kefton H. Teague

An article entitled "The Rule of the Geologist in the Industrial Mineral Field" by G. R. Gullet, was published in the August, 1967, issue of the Canadian Mining Journal. Mr. Gullet defined industrial minerals as follows: "Industrial minerals are largely non-metallic minerals and rocks that find value because of their physical or chemical properties." This definition is brief, but all-inclusive. Mr. Gullet continues, "They include all useful minerals and mineral commodities except those used as fuels and those from which metals are extracted. Factors in the evaluation of an industrial mineral deposit are generally as different from those used in the evaluation of a metal deposit as is the assessment of a potential oil field. The key to the successful development of an industrial mineral, deposit is more often a balance of accessibility, transport, and proximity to markets than to any natural quality advantage of the deposit itself."

Jan 1, 1972

By C. P. Fang

"For lower stages of multinozzle micro-orifice impactors, as many as two thousand nozzles are uniformly arranged within a cluster diameter of 1.06 inches. In the impaction region the mass flowrate of the spent air increases along the radius and reaches a maximum at the periphery. This crossflow can significantly deflect the air jets of the outer nozzles, hence the characteristics of impaction changes.Investigators in heat transfer and fluid mechanics have studied the influence of crossflow on jet deflection and found the dimensionless deflection of the jet centerline X/Dn is a function of (S/Dn)(l/m) . only, here X is downstream coordinate measured from the center of the jet orifice, Sis the jet-to-plate distance, Dn is the orifice diameter and m is the jet/crossflow mass flux ratio defined as:"

Jan 1, 1989

By V. H. Forsythe

Mr. Chairman, members of SME, and guests It is indeed a pleasure to have the opportunity to appear before this group. The topic of this paper is, "Current Trends in Related Industries and Their Influence on Electric Shovel Design and Size". Before getting into the major items, it is well to point out that this text will deal with loading shovels primarily, since their application is almost universal in major open pit mining operations throughout the world. Related industries influence our design in many ways. For the sake of simplicity, these industries will be broken down into two major categories. The first category to be discussed will include industries that will indirectly influence design and size, while the second category will include industries whose products can directly be incorporated by the engineer in the design of shovels.

Jan 1, 1964

By Douglas R. Schmitt

In general, knowledge of the state of stress within the Antarctic lithosphere remains largely unconstrained due in part to Antarctica?s inaccessibility and because of the paucity of seismic focal mechanism solutions. As such, an important component of the ANDRILL project was to acquire new information on the stress directions and magnitudes within the upper crust. Extensive fracture mapping of the core and oriented ultrasonic televiewer logging were carried out to provide strong constraints on both stress orientations and the faulting regime. The first hydraulic fracturing stress determinations in Antarctica were also carried out to provide complimentary stress magnitudes. These measurements were accomplished using a wire-line transported hydraulic fracturing system consisting, essentially, of two synthetic polymer packers that were inflated to isolate the 1-m long pressurization interval. The tests were conducted at the end of the drilling and logging in a ~130-m section specially drilled below 1000 mbsf (nearly 1500 m from the rig floor) for hydraulic fractures. This zone was drilled primarily through competent, dense, and low permeability diamicts. The core fracture and televiewer logging information was used to site twenty separate measurements. Classic hydraulic fracturing pressurization records with unambiguous breakdown and fracture closure pressures were obtained in about half of the measurements. The remaining tests provided fracture propagation and closure pressures that are consistent with the classic breakdown curves, but they did not include a clear breakdown pressure and are indicative of the reopening of either natural or drilling induced fractures in the wellbore wall. The preliminary analysis of the results are in generally good agreement with the stress directions indicated by the core fracture logging and the stress regime suggested by the character of the drilling induced core fractures.

Jun 1, 2012

By C. E. Ells, A. Sawatzky

The effect of neutron irradiation on tensile properties of the Zr-2.5 wt pet Nb-0.5 wt pet Cu alloy has been evaluated for integrated neutron fluxes up to 3 x 1020 n per sq cm (E > 1 Mev). Specimen temperature during irradiation was normally 300°C. The material was studied both in annealed and in quenched and aged conditions. When the alloy (fab-ricatedfrom sponge zirconium) is quenched from a temperature =40°C below the a + ß/ß transformation and aged 6 hr at 535oC, neutron irradiation up to the maximum studied has little effect 071 reduction in area, although there is a drop in uniform elongation and the yield strength is increased by = 25 pct. Conversely, irradiation of the alloy in an annealed condition can result in much greater changes in properties, with yield-strength increases of up to 200 pet. The dose dependence of irradiation hardening obeys the saturation equntion proposed by Makin and Minter to explain hardening in copper and nickel: Act = C[1 - exp(-Døt)/1/2 A rnodel is proposed to explain the effect of niobium content and metallurgical condition on irradiatiotz behavior. THE Zr-Nb alloys form a class of material susceptible to marked strengthening by quench and age heat treatment. With niobium concentrations as low as 2.5 wt pet, strengths can be developed which are double those of annealed zircaloy-2.1 Since the neutron-capture cross section of the Zr-2.5 wt pet Nb alloy is nearly identical to that of Zircaloy-2, significant gains in power-reactor neutron economy could be obtained by replacing stressed in-reactor components of Zircaloy-2 with the heat-treated Zr-Nb alloy. When the solution heat-treatment temperature is in the high (a + ß) phase, then the tensile properties of the quenched (and aged at 500°C) material have been shown to be relatively insensitive to neutron irradiation.1-3 Addition of small quantities of copper to the binary Zr-2.5 wt pet Nb alloy gives a useful reduction to the corrosion rate in air and carbon di- oxide,&apos; and a ternary alloy of composition Zr-2.5 wt pet Nb-0.5 wt pet Cu was chosen for one component in the Douglas Point Reactor. This application utilizes both the corrosion resistance to a moist air-carbon dioxide environment and the strength developed by a quench and age heat treatment. By suitable choice of solution heat treatment and aging temperatures, tensile properties of the ternary alloy can be made nearly identical to those considered as optimum for the binary alloy. One effect of the copper addition, however, is to give marked changes in the aging kinetics of the alloy.&apos; For this reason, it appeared that neutron irradiation might promote overaging in the ternary alloy, particularly at the elevated service temperature (=300°C). This paper describes the effect of neutron irradiation on the tensile behavior of the Zr-2.5 wt pet Nb-0.5 wt pet Cu alloy in several metallurgical conditions pertinent to its use as a reactor material. The metallurgical conditions included those for which aging occurs in the unirradiated material, and fully annealed conditions for which a higher degree of thermal stability could be expected. 1) EXPERIMENTAL Two batches of alloy were used, both made from sponge zirconium. The fabricator&apos;s analysis of principle constituents showed no significant difference between the two batches, Table I. The rod material was rolled to 1.5 in. diam, and then swaged to final sizes of 0.5 to 0.375 in. diam at nominal temperatures of 785" and 625°C for the AM and AS batches, respectively. Subsequent hydrogen analyses at CRNL confirmed that the hydrogen concentration of the as-received rod was indeed <20 ppm. However, it was found that the (a + ß)/ß transus for the AM material was approximately 25°C lower than that of the AS material, indicating rather more difference in oxygen concentration than given in Table I. Except for a small difference in yield-point behavior, the tensile prop-

Jan 1, 1965

By Riyad N. Ahmad-Bitar, Shadia J. Ikhmayies

"CdS/CdTe solar cells were built by depositing a 200 nm layer of Sn02:F on glass substrates by the spray pyrolysis (SP) technique, a 500 nm CdS:In layer by the same technique and a 1-1.5 µm CdTe layer by vacuum evaporation. The cells were CdCh heat-treated in nitrogen atmosphere for 30 minutes at 350 -.C. The photoluminescence (PL) spectra were measured at the CdS/CdTe interface for two cells with different values of the CdTe layer's thickness at temperature T = 60 K. A deconvolution peak fit was performed from which it is found that the peaks are characteristic of the solid solution CdSxTei-x· The parabolic relation that relates the bandgap energy with the composition was used to estimate x, where xis [S]/([Te]+[S]) and [Te], [S] are the concentrations of Te and S atoms respectively. The results show that the interface is smooth and the change of the bandgap occurs gradually.IntroductionCdS/CdTe heterojunctions represent a combination of materials promising various applications, and for solar energy conversion in the first place [1]. In photovoltaic cells the CdS material acts as a wide bandgap window. Direct bandgap CdTe with high optical absorption coefficient is used as an absorber [1]. Solar cells with efficiencies of 10 to 16% have been obtained with CdTe grown by close space sublimation, electrodeposition, vacuum evaporation and rf sputtering methods [2]. In this work the CdTe layer was prepared by vacuum evaporation because it results with films of minimum impurities, while the Sn02:F and CdS:In layers were deposited by the spray pyrolysis technique because it is a low cost method which enables intentional doping and large area thin films."

Jan 1, 2011

By J. A. Drozdiak, W. Tse, P. P. Rosario

"In a recent publication (SAG 2015), we presented a non-conventional high pressure grinding roll (HPGR)-ball mill circuit as a lower capital cost alternative to the “standard” HPGR circuit. The circuit was designed for the treatment of a hard ore and relatively high tonnage (50,000 t/d). That paper provided details such as flowsheets, layouts, and equipment lists for the two options and compared their calculated capital costs demonstrating significant savings for the proposed circuit. This paper extends the analysis to a third option, a traditional semi-autogenous ball crushing circuit, giving the same level of details and now including the operating cost estimates for all three options for a more comprehensive analysis. Moreover, this work also provides information about the strengths and weaknesses of the non-conventional HPGR circuit when compared to the “standard” HPGR option.This study demonstrates that the proposed non-conventional HPGR-based circuit not only provides a lower overall capital costs for the project if compared to a “standard” HPGR circuit but also brings the capital cost to the level of the traditional semi-autogenous grinding (SAG)-ball mill circuits. In addition, the innovative HPGR circuit provides similar operational cost savings of the “standard” HPGR and thus a significant advantage when compared to the SAG option. With the current capital cost sensitivity for most greenfield projects, the proposed alternative circuit should help make HPGR-based circuits more competitive and thus promote the utilization of a technology that enables higher energy efficiency and reduced greenhouse gas emissions. INTRODUCTIONThe application of high pressure grinding roll (HPGR) technology in comminution circuits is well established for the processing of cement, diamonds and iron ore (Broeckmann & Gardula, 2005), and over the past 10–15 years, this technology has slowly been applied to hard ores in high-tonnage precious and base metal operations. Unfortunately, under the current economic climate, the ability to finance large capital projects has become very difficult and companies tend to have an easier time securing funding if the capital expenditures (CAPEX) are low with a proven process method. The traditional semi-autogenous grinding (SAG) mill / ball mill circuits easily fit into this mould, having been installed in countless plants around the world over the past 30 years with relatively low capital requirements. In contrast, it has been well-documented that HPGR-based circuits are capital intensive with complex material handling systems (Seidel, Logan, LeVier, & Veillette, 2006). Although these circuits benefit from reduced operating costs with the increase in energy efficiency and the elimination of steel grinding media (Rosario, Boyd, & Grundy, 2009), if the company is unable to secure financing to build the plant, these advantages remain out of reach. With the current trend to retrofit existing SAG circuits with a secondary crushing circuit to achieve design throughput, the opportunity to circumvent this gross inefficiency by making HPGR-based circuits more capital friendly would greatly benefit the industry."

Jan 1, 2016

By E. Marè, D. R. Groot, R. Engelbrecht, T. Coetsee

Hydrogen peroxide is often used as an oxidising agent in experimental waste electronic equipment (WEE) leaching work. However, the high cost of peroxide is a negative factor in its consideration in further process development. A few studies have reported on the efficient application of peroxide addition schedules to ensure optimum reagent consumption. Large quantities of unleached substrate material contained in WEE feed material result in a large dead volume of material in the leaching reactor. This factor necessitates fast reaction rates to enable the use of a high feed material throughput reactor to enhance overall project viability via hydrometallurgical processing. In this study the effects of hydrogen peroxide addition schedules on base metal leaching efficiency and solution temperatures were tested at laboratory scale. The results showed that overall peroxide consumption can be optimised to lower levels by matching peroxide additions to the particular feed material’s leaching behaviour. A simplified integrated model for peroxide decomposition is used to explain its effect on solution temperatures and leaching rates. Keywords: Peroxide consumption, waste electronic equipment, copper leaching, integrated model

Jan 1, 2020

By A. T. Yu

As the first loads of Noamundi iron ore rumbled into the new 54-in. Gyratory Crusher on March 30, 1968, one of India&apos;s largest and most modern iron ore processing complexes began operations. The completion of the $13 million mining and processing complex brought to a successful conclusion the second chapter of a phased expansion program initiated in 1958 by India&apos;s gigantic Tata Iron and Steel Co. The completed complex will yield annually 2.5 million tons of washed, sized ore and sinter fines destined for Tata&apos;s furnaces at Jamshedpur. Hewitt-Robins Div. of Litton Industries was awarded the turnkey project on the basis of world- wide competitive bids. Eighty miles southwest of the city of Jamshedpur, Noamundi lies on an approximate geographic grid of 22º-5&apos; latitude north and 85º-30&apos; longitude east. The mine is approximately 600 ft above sea level.

Jan 11, 1968

By Karl-H. Daum

Over many decades, numerous feasibility studies have demonstrated, that the production of sulphuric acid remains the most viable option of sulphur recovery from smelter off gas and abatement of SO2 emissions to the atmosphere. This is particularly more pronounced as smaller but more concentrated off-gas flows are to be treated from smelters, and enhanced sulphuric acid processes be-come available. Off-gas handling systems represent a significant capital and operating cost burden to the metallurgical operation. Modern pyrometallurgical smelter processes for sulphide ores based on the use of oxygen-enriched air, produce relatively small off-gas flows with high SO2 concentrations in the smelter gas of 30?60 %-vol. of SO2. This is a prerequisite for substantial cost reductions in the smelter off-gas handling and treatment system. As an alternative to sulphuric acid production, numerous scrubbing concepts with alkali or dual-alkali combinations as well as organic absorbents have been proposed. Also the reduction of the SO2 to elemental sulphur has frequently been studied. Very few of those alternative processes have been built in industrial scale, but all were generally characterized by none sustainable operation due to cost reasons, problems with issues related to chemicals used and by-products or poor availability. Thus the traditional concept of converting the SO2 to sulphuric acid is most common, although regarded as un-economic, but is at least a proven, environmentally sustainable and reliable way of sulphur gas processing. With the high acid price levels these days, operating companies are even able to generate significant revenue with their otherwise ?fatal? acid.

Jan 1, 2009

By James R. Craig

Petroleum coke is becoming an increasingly important source of light hydrocarbon products as product crudes become heavier and of poorer quality. The use of petroleum coke to generate synthesis gas results in the formation of residual slags that are enriched in silica, alumina, sulfides, oxides, and free metals. The characterization of these slags and their con? stituent phases is an essential step in considering the ultimate use or disposal of such slags and in understanding how to alter the properties of the slags to optimize the efficiency of gasifiers. Depending upon temperatures and bulk compositions, quenched slags typically consist of silicate glasses, calcium silicates, iron-nickel oxide-sulfide masses, aluminate spinels and free metals. Whereas the glasses contain relatively uniformly dispersed metals and sulfur, the iron-nickel oxide-sulfide masses highly concentrate nickel and sulfur. The aluminate spinels very effectively concentrate vanadium and chromium, thus depleting glasses or other adjacent phases. The abundance as well as the make up of the slags strongly affects the physical behavior of the slags within the gasifiers

Jan 1, 1989