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By L. Filip

The roast-leach-electrowinning (RLE) process for zinc was modified to treat two typical complex concentrates containing zinc, lead, copper, gold and silver. Laboratory testwork results indicated that the optimum roasting temperature ranged from 700 to 800°C, in order to produce acceptable residual sulfur levels. The calcined concentrate was subjected to a three-stage leach sequence. The resulting leach solution was purified by hematitic precipitation and directed to the recovery of copper and zinc by solvent extraction and electrolysis. Alkaline smelting and subsequent electrolytic purification recovered the lead and precious metals from the leach residue. A flowsheet was developed based on the laboratory testwork results, and demonstrated in a large-scale pilot plant. The recoveries produced during the pilot plant operation ranged from 90 to 92% for zinc and copper, 85% for lead and 90% for gold and silver, respectively.

Jan 1, 1999

By Guichao Wang, Geoffrey M. Evans, Graeme J. Jameson

"In this paper we present a new method for studying the detachment of particles from bubbles in a rotating turbulent eddy. The eddy is formed in a wall cavity in a two-dimensional water tunnel with transparent walls. When water flows through the tunnel, a vortical flow field develops in the cavity. The properties of the eddy can be modulated by changing the free-stream velocity of the water in the tunnel. Bubbles are pre-loaded with one or more particles in a fluidized bed flotation device located beneath the vortex cavity. Loaded bubbles are released one at a time into the cavity, and the motion of the bubbleparticle aggregate is studied using a high-speed video camera. The diameters of the particles and the bubbles, and the number of particles initially attached to the bubble, can be varied. The trajectories taken by the bubbles are quite complicated. In some cases, the bubble moves to the centre of the eddy, and particles rotate around its axis. If the rotational speed is sufficient, particles may detach due to centrifugal force. However, other modes were observed, including inertial detachment due to rapid changes in direction of the surface of the bubble, because of changes in trajectory of the bubble as a whole, or because of pulsations and oscillations of the bubble surface. Clusters of bubbles held together by particles were seen to form and reform. In the traditional explanation for the detachment of particles in flotation cells, it is assumed that particles detach from bubbles rotating in an eddy due to centrifugal force (Schulze, 1977). Although the conditions assumed in Schulze's theory may exist, it is only one of a range of phenomena that can lead to the detachment of particles from bubbles in a turbulent vortex.INTRODUCTIONThe recovery of particles by flotation methods is dependent on the particle size. The recovery in the existing flotation machines reaches a peak for particle size, typically in the range of 20 to 100 µm. This size range varies as a function of the particle’s properties (type and composites). For coarser particles, the recovery drops very quickly (Gaudin, Groh & Henderson, 1931; Jowett, 1980). If the upper size limit can be increased for flotation, dramatic savings in the grinding energy can be achieved."

Jan 1, 2016

By Lin Li, Ahmad Ghahremaninezhad

"In this paper, the electrochemical behavior of ferric and ferrous couple on the pyrite surface was studied by application of the chronoamperometry technique in an acidic solution at room temperatures and atmospheric pressure. The effects of the pyrite origin, ferric and ferrous ions concentration on the electron transfer kinetics of Fe3+/Fe2+ reaction were probed. Tafel behavior of all the test conditions were developed. The results showed that the ferric-ferrous reaction on pyrite electrodes with different origins have a common mechanism, despite different reaction kinetics. The exchange current densities of the redox reaction have the same magnitude of about 10-5 A·cm-2, which is far lower than the value reported for the gold and platinum electrodes, but larger than that of the chalcopyrite electrode. The cathodic transfer coefficients are between 0.4 and 0.5, while the anodic transfer coefficients appear unusual with the lowest value being 0.23. It was also demonstrated that an increase of one order of magnitude of iron concentration has no clear effect on the exchange current density and cathodic transfer coefficients of Fe3+/Fe2+ redox reaction.INTRODUCTIONPyrite, FeS2, is mostly considered as a gangue mineral which frequently coexists with valuable minerals and metals, such as gold, copper and nickel. Its separation from valuable minerals can be a costly process (Chandra & Gerson, 2010). In refractory gold ores, the fine gold particles are locked inside the pyrite structure. Oxidative leaching of pyrite is a hydrometallurgical method to destroy the structure of pyrite and expose the fine gold particles to the cyanide solution in the downstream cyanidation circuit. Pyrite oxidative leaching can be achieved by oxidation of pyrite via oxygen and ferric ion(McKibben & Barnes, 1986). In fact, pyrite oxidation by oxygen and ferric is a significant source of acid mine drainage(AMD), which adversely causes serious environmental problems(V. P. Evangelou, 1995).The pyrite oxidation mechanism is accomplished in three consecutive steps: (i) pyrite is oxidized by oxygen and ferrous ion formation (Eq. 1); (ii) ferrous oxidation by oxygen and ferric ion formation (Eq. 2); (iii) pyrite oxidation by means of ferric ions (Eq. 3). Hence, both oxygen and ferric participate in the pyrite oxidation process (Moses & Herman, 1991):"

Jan 1, 2016

By Ian Masters

Rotary furnaces are widely used throughout the metals industry. These furnaces vary in size and geometry, but are fundamentally the same from a thermodynamic viewpoint. A generic method is proposed that can be used to model all furnaces of this type, provided that the correct material and process parameters are known. Various approaches have been attempted in the past based on a continuum (FEA or CFD) approach. However, the complex fluidlsolid interactions present in a rotary vessel are not easily solved using these methods, which work best where the material boundaries are well defined. In this paper a lumped parameter model is proposed. Variations within a section of the model are ignored, but to ensure thermodynamic correctness, the heat transfer between sections is carefully considered. For example, it is reasonable to assume that the whole of the melt pool is at the same temperature, due to rotary mixing. This may then be modeled with a single set of parameters, and the detail is contained in obtaining the correct heat transfer mechanisms from the rest of the furnace.

Jan 1, 2002

By T. Yalcin, S. Brunet

The flocculant-assisted hydrocyclone involves the addition of a flocculant to the cyclone feed for the purpose of obtaining a clear cyclone overflow, and thereby eliminating or reducing thickener requirements in tailings disposal operations. This paper describes the testing of this concept on the iron ore tailings of Quebec Cartier Mining Company's Mount Wright Concentrator. The current practice at Mount Wright makes use of conventional hydrocyclones and thickeners for the disposal of their tailings, which are generated in a spiral gravity separation circuit. The test work was conducted primarily on their cyclone overflow product which becomes the feed to the thickeners. A detailed study was carried out to determine the sedimentation properties of these tailings in terms of their response to a variety of flocculating reagents, and to varying conditions of pH, pulp density and flocculant dosage. The tailings were then processed in a laboratory hydrocyclone with the aid of flocculants. The use of a shear resistant flocculant, in particular, was found to yield cyclone overflows with low solids contents. Based on the test results obtained, a conceptual flow sheet has been proposed for the treatment of the iron ore tailings at the Mount Wright Concentrator.

Jan 1, 2004

By J. L. Heaver

All complete plant foods require phosphorus, nitrogen and potassium. And phosphate rock is the primary source for the phosphorus of the inorganic fertilizers. As more and more world food production is grown with these chemical fertilizers and since the Florida field supplies over 30% of the phosphorus component, let us look at the vital phosphate industry. Mining of phosphate rock in Central Florida began in 1891 and production has continued to grow at a steady pace. In 1965 a phosphate mine was opened in Hamilton County, North Florida and one in Beaufort County, North Carolina in 1966 . Since the beginning of mining in 1891, approximately 700 million metric tons of phosphate rock have been produced of this amount one-half was mined in the last 11 years. While the field was not deliberately "high-graded," the best of the known deposits were mined first. Those now being mined, and those yet to be mined, cost more to operate and the product is of lower grade. The U. S. Bureau of Mines' data for 1977 lists "Florida" phosphate rock production as 40.6 million tons; 86% of U. S. production and 85% of "Florida" capacity. The U. S. Bureau of Mines includes North Carolina production in "Florida" statistics so as not to reveal individual data for the one mine operating there. Approximately one-half of "Florida" production is exported, either as rock or as rock equivalent in upgraded products. Deposits of phosphate rock necessary to support present and future production are catalogued as: reserves, paramarginal reserves and resources. Reserves denote deposits which can be mined at a profit now. Paramarginal reserves are defined by the U. S. Bureau of Mines and the U. S. Geological Survey as: that portion of sub-economic resources that a) borders on being capable of production economically, or b) is not commercially available solely because of legal or political circumstances. The " b)" part of this definition may now be expanded to include environmental controls and requirements. Resources are deposits which cannot be mined at a profit at present. Listed in Table I are reasonable values for each of the three categories of phosphate deposits in the northern and southern parts of Central Florida. North Florida and North Carolina.

Jan 1, 1978

By Henrique Silva Furtado

Concerning production of low phosphorus steel critical grades at ArcelorMittal Tubarão site, bottom blowing system plays a very important role. For those systems with independently controlled tuyeres, some non-uniform bottom blowing patterns seem to be promising in improving metal-slag mixing; however, based on computational fluid dynamics (CFD) results of ArcelorMittal Tubarão’s post oxygen bottom blowing, this may not be generalized. Also, from industrial trials it became clear that higher the bottom blowing flow rate, the closer were the end point P to the equilibrium. Despite this result an analysis of the apparent mass transfer coefficient has shown a week correlation with the classical power stir correlation suggesting a more complex kinetic limiting step for phosphorus removal.

Jul 30, 2018

By R. G. Sandberg

Many gold-bearing ores throughout the Western United States contain small quantities of mercury. The presence of mercury not only decreases the gold-loading capacity of the activated carbon, but complicates the fire refining of cathodes and creates a potential health hazard. The Bureau of Mines investigated methods to limit mercury extraction during gold ore leaching and to remove mercury from cyanide leach solu-tions. Mercury dissolution was reduced from 40 to 10 pct by decreasing NaCN concentration from 20 lb to 0.34 lb per ton of solution at a pH of <11. When 0.1 lb CaS per ton of ore was added to a leach slurry, mer-cury extraction was reduced from 27 to 0.4 pct. Less than 0.5 pct of the mercury was solubilized when <0.1 lb CaS per ton of are, along with lime and NaCN, was added to a simulated grinding circuit.

Jan 1, 1984

By Jr. Gabler

World resources of cobalt appear ample for the foreseeable future; however, political and economic events have caused concern over the availability and reliability of an uninterrupted supply. Because of this concern, the U.S. Congress requested that the U.S. Bureau of Mines initiate a study of the flow of cobalt in the economy that would delineate and quantify the production areas where metal values are lost. As a result, the Bureau has developed a computerized commodity flow model. A major attribute of this model is that it is amenable to updating as supply, demand, and/or production data change. This report follows the flow of cobalt through its metallurgical and chemical applications and highlights areas where significant losses occur due to downgrading, export, or disposal. The study indicates that about 4,300,000 lb of cobalt-bearing materials are lost each year, representing 24 pct of U.S. domestic demand.

Jan 1, 1990

By W. E. Anable

The Bureau of Mines researched methods for recovering copper from cyclone and electrostatic-precipitator dusts of primary copper smelters as part of its program to maximize minerals and metals recovery from primary and secondary domestic resources. Small-scale studies showed that use of 110 pct stoichiometric sulfur and 123 pct stoichiometric carbon, based on producing a 40-pct copper-iron matte, resulted in the recovery of 95 pct of the copper contained in the dust. Typical mattes contained less than 10 pct of the arsenic, 30 pct of the bismuth, and 45 pct of the antimony and tin contained in the dust. Matte was converted to blister copper by injecting up to 200 pct of the stoichiometric oxygen requirement over a period of 2 to 3 hours. Up to 76 pct of the copper contained in the dust was recovered as a crude blister copper containing about 2 pct arsenic, 0.5 pct antimony, and less than 0.1 pet bismuth and tin. A matte-white metal product resulted from carbothermically reducing dust with coal, lime, and silica. Up to 95 pct of the copper was recovered in the combined product.

Jan 1, 1981

The paper covers the history and develop- ment of electrical and diesel-powered hydrau- lic percussion rock drills. It examines main design aspects and problems encountered in pro- ducing an efficient and reliable machine to fully cover the nominal hole sizes required for underground development, production drill- ing and for general quarry work. The main design features and advantages of a hydraulic rock drill are relatively low input power requirement to energy per blow (this being achieved by the use of an electric or diesel- powered hydraulic system) and a specially con- structed piston using a powered damper cylinder to absorb the recoil forces from the drill steel and reduce stresses on the drill, feed and hydraulic boom. A further important design feature is the anti-jamming device which controls the drill both during manual and automatic operation. This anti-jam device works on feed and rotation press and prevents the drill bit becoming jammed in broken or soft ground. These features and many other mechanical and environmental benefits are highlighted when comparing hydraulic percussion rock drills with current pneumatic machines. The hydraulic rock drill gives an overall high penetration and production rate, with an added bonus for ergonomy and environmental conditions such as lower noise level, no fogging from air and oil exhaust (which naturally gives better air for breathing),plus improved vision when in under- ground situations. Hydraulic rock drills and systems have been fully tested in many mines, quarries and contract sites during the past years. They h6! been improved and modified and are now provi~ to be very reliable and economical piece drilling equipment whò in mines and quarries.

Jan 1, 1978

By A. W. Deurbrouck

The Bureau of Mines analyzed 13 samples collected from three Randolph County coalbeds. The Peerless and Sewell bed samples were generally of metallurgical quality as received from the mines or could be easily upgraded. How-ever, the Lower Kittanning coa1bed samples proved to be quite inimical to upgrading to metallurgical quality.

Jan 1, 1966

By Danny A. Riley, James R. Sanger, Hani S. Matloub, Michael Agresti, David Rowe, Lin-Ling Zhang, Yuhui Yan, Paula Galaviz, Judith Marchant-Hanson, Ji-Geng Yan

Until now there has been controversy about which tests should be performed to diagnose early Hand-Arm Vibration Syndrome (HAVS). Initial screening questions, especially about tingling and numbness, routinely given to patients prior to examinations proved to be a very important tool in the diagnostic process1, 4. However, standardized tests that are simple, quick, valid and reliable are needed to support a diagnosis of HAVS. Purpose: To find the most valid and reliable tests to diagnose HAVS. Material and Methods Five major tests were performed on Group I and Group II. Group I: Control group of 12 volunteers including students, nurses, secretaries and physicians with no history of using vibrating tools (age 20 to 50y, mean age 38.5y; 5male, 5 female.) Group II: 12 workers (age 17 to 65y, mean age 39y; 9 male, 3 female) were sent by a local trade union with a history of using vibrating power tools on their jobs for varying amounts of time (mean 12.2y, from 0.5 to 35y.) Pre-enrollment survey showed that each had more than 4 complaints commonly associated with use of vibrating tools (including numbness, tingling, weakness, pain, finger color or nail changes, temperature change, and difficulty moving.) 1. Sensory nerve conductive tests: Amplitude and nerve conductive velocity (NCV) were evaluated. 2. Cold Stress-Temperature recovery time tests were done on the index finger of the dominant hand following these steps: Confirm water bath is within 4-5º C. Place the finger temperature probe on pad of the index finger of the dominant hand. Record temperature every 15 seconds. Place subject’s hand in the cold- water bath for exactly five minutes. Record temperature every 15 seconds for ten minutes. 3. Blood test: Venous blood was taken by a 21-gauge needle with the yellow collection tube adapter. S-ICAM, Sera Thrombomodulin, Norepinephrine levels were evaluated by Henderson Research Centre, Canada. 4. Finger Sensory Evaluation: Semmes-Weinstein monofilament test and 2-point discrimination tests were performed on bilateral fingers. 5. Digital blood pressure test: blood pressure was measured in bilateral index fingers. Results 1. Median nerve sensory conductive amplitude from palm to wrist : GI: mean 96 ± 31µm; GII: mean 43± 30µm; for dominant hands. GI vs GII: P<0.001

Jan 6, 2006

By M. Redfearn

"DUST COLLECTION EQUIPMENT LIST Primary Dust CollectorModular Mikro-Pulsaire - Model 2G1-96TR Capacity: 20,000 c.f.m.Bags: Total of 288; 8' x 4 1/2"" diameterMaterial: Dacron HCE feltAir to cloth ratio: 7.55/1Bags are changed every 6-9 months. Sent to A & L Services for cleaning at a cost of less than 1/3 the price of a new bag. No new bags have been required since start-up 4 years ago.Blow hack: 35 c.f.m. at 100 p.s.i.Fan: Joy Manufacturing, Model 3300, Type 4S, Backward inclined fan.Impeller: 33"" diameter36"" diameter Inlet33"" diameter Outlet at 3200 f.p.m. velocity1945Motor:,60 H.P., 1780 r.p.m.Capacity: 23,400 c.f.m.Design:,20,000 c.f.m.,•Actual:,17,500-19,000 c.f.m. depending on bag condition.Dust Slurry Agitator: Port-a-flo Model 050-350Major Maintenance:The fan was sped up from 1830 to 1945 r.p.m. and balanced at the higher speed. Several months later the impeller destructed beyond repair. A new shaft and impeller was installed, casings straightened, and bearings reused. Unit is currently running at 1945 r.p.m. No definite cause for the impeller failure has been found, although it might be attributed to improper balancing."

Jan 1, 1976

By W. K. Summers

During the past few years monitoring systems have been installed to measure the effects of environmental changes on the ground-water resource. The design of a monitoring system depends upon the designer&apos;s perception of how the environmental factors merge with his perception of the ground-water flow system. The validity and representativeness of measurements made during a monitoring program depend upon the validicy of the designer&apos;s perceptions and concepts. To optimize the design of a ground- water monitoring program the designer should make preliminary measurements to confirm his assumptions.

Jan 1, 1985

By G. S. Scott

Safety problems in the mining and allied industries have led the Bureau of Mines to investigate over a period of years; the flammability (explosibility) of many types of combustible atmospheres principally at ordinary pressure; the results of these investigations have been made available as a bulletin. However, more recently, the demand for information on the flammability of gaseous mixtures at high and low pressures has increased greatly. In particular, the rapid development of high-altitude aviation has brought demands for information on the flammable (or explosive) characteristics of certain gases and liquids at low pressures. The present report gives the results of about 900 tests made to determine the flammability of the lighter paraffin hydrocarbons mixed with air and nitrogen at pressures of 400 200, 100 and 70 ram. Hg. The gases tested include natural gas, methane, ethane, propane normal butane and isobutane. The minimum pressures at which these gases are capable of propagating flame whorl individually mixed with air also were investigated.

Jan 1, 1952

By Yukika Miyashita, Takahiro Inoue, Kenji Namikawa, Masashi Matsumoto, Junichi Koseki, Yoshihiro Terashima

"In order to construct an underground two-layer expressway branch junction structure with a height of 14.7 m and a width of 22.3 m, two shield tunnels in each layer were combined by using a non-cut-and-cover enlargement method in sedimentary soft rock. Before and during the construction work, preliminary analysis, in-situ investigations and laboratory tests were conducted to ensure the construction safety and to evaluate the deformation characteristics of sedimentary soft rock. The construction project was safely executed without any water leakage or collapse of tunnel working face. The predicted results from preliminary analysis were almost similar to the measured values. From the detailed investigation of measured results, it was confirmed that the deformation characteristic of the sedimentary soft rock was observed to a small extent as the ground deformation derived from construction work. INTRODUCTION In recent years, some newly constructed urban expressways in Japan are being planned as underground structures due to the consideration of roadside environment. The construction of such underground expressways is frequently conducted using a shield tunneling, a typical one of non-cut-and-cover methods, to prevent any adverse effect to traffic in arterial roads, operation of nearby commercial establishments, and daily lives of local residents during construction work. For underground urban expressway, the connections with existing road network on ground surface or on elevated sections are indispensable, which require the construction of an underground branch junction with large cross-section. This raises a technical difficulty regardless of the open-cut or non-open-cut construction method."

Jan 1, 2016

By K, J. MAUNDERS

This paper briefly describes a computerised model of the South African electricity system which has been developed jointly by the Atomic Energy Board and the Electricity Supply Commission. The results of an analysis of this system have been subjected to a fairly extensive sensitivity analysis which reveals that up to the year 1990 between 680 and 700 million tons of coal will be required for electric power generation, together with between 7 000 and 10 000 tons of uranium. This result is fairly insensitive to data variations, but the prediction of a cumulative requirement up to the year 2000, of between 1 300 and 1 800 million tons of coal and 25 000 to 70 000 tons of uranium, proves to be very data-sensitive.

Jan 1, 2014

By T. Szaplonczay, D. E. Light

The auto-oxidation of sulfur dioxide to form sulfuric acid in commercially produced barren and recycle liquors, containing 1.66 and 4.56 gpl Fe respectively, from Elliot Lake was studied. A gas mixture, containing 3.5% SO2 and air was introduced into these liquors through a frit at a rate of 6.0g SO2 per hour per liter of solution. The barren and recycle were heated to 60°C. At the end of the first 24 hours of the process the concentrations of acid produced were 158 and 220 gpl H2SO4 for the barren and recycle respectively. Corresponding conversion efficiencies were 70 and 83%. In the period from 24 to 36 hours the rate of acid production decreased so that the H2SO4 concentrations at the end of 36 hours were 180 gpl for the barren and 260 gpl for the recycle; average conversions for the initial 36 hours were 55 and 68% respectively. Many investigators1&apos;2&apos;3 have considered the oxidation of sulfur dioxide to form sulfuric acid in aqueous solutions containing metallic ions. A summary of the work performed on this subject prior to 1946 has been presented by Keyes4 who described the auto-oxidation process as follows. Keyes also suggested that in this second reaction ferric ion serves as a catalyst for the conversion of sulfur dioxide to sulfuric acid. Neytzell-de Wilde and Taverner5 have reported on the use of auto-oxidation to produce a 4 to 5% sulfuric acid solution for use in a cyclic leach process at South African uranium plants. This paper describes investigations carried out to determine the feasibility of using the auto-oxidation process to produce sulfuric acid solutions of as high concentration as possible using commercially produced uranium plant barren and recycle liquors from the Elliot Lake region of Ontario. These liquors contained 1.66 and 4.56 gpl respectively of iron, chiefly in the ferrous state. This investigation is of particular interest to the uranium producers in Elliot Lake where the ores contain 3 to 4% sulfur, as sulfides. Flotation of these sulfides and roasting of same to produce SO, bearing gases have been successfully demonstrated using conventional methods.6&apos;7 Barren and recycle solutions, as described previously, are also produced in large tonnages by these uranium producers. The experimental method and apparatus used to examine the auto-oxidation process will be described first. Then the tests carried out on laboratory prepared aqueous solutions containing ferric sulfate to determine optimum conditions will be presented. The next section will describe the tests using the commercial barren and recycle liquors. A final section will summarize the conclusions of the work. EXPERIMENTAL APPARATUS AND PROCEDURES Two types of solutions were used in the tests, a laboratory prepared aqueous solution containing definite amounts of ferric sulfate, and commercially produced iron bearing solution obtained from a uranium leaching plant in the Elliot Lake area. Two liters of a solution to be examined were placed in a 3 in. diam by 30 in. long glass cylinder with a cross-sectional area of 7 sq in. A mixture of air, and SO2 supplied from a lecture bottle for convenience, was introduced into the bottom of the vessel through a standard 30 mm glass frit, 700 sq mm in area. The temperature of the apparatus was controlled by a heating tape and variable transformer. Exhaust gases were vented to atmosphere. At the end of the test period the gas flow was shut off and the solution was analysed for H2SO4, Fe ++, and Fe +++, by conventional means. Four variables were examined using the laboratory prepared aqueous solution of ferric sulfate. First, the effect of SO2 concentration, from 1 to 1076, in the feed gas mixture was considered. Second, the temper-

Jan 1, 1964

By W. R. Opie

Fundamentals of blast furnace smelting of low grade copper and precious metal scrap and residues are reviewed with emphasis on emission control, by-products produced, slag cleaning for high recovery of metal values and the evolution of an off-gas system to eliminate hydrocarbons that result from decomposition of plastics in the blast furnace- charge. Problems with tin, antimony and nickel in the smelter-refining cycle are discussed.

Jan 1, 1985