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By R. A. Graham, R. W. Rohde

The effect of hydrostatic pressure upon the austenite start temperature of a commercial Fe-28.4 at. pct Ni-0.5 at. pct C alloy has been determined. For pressures to 20 kbar, the austenite start temperature decreased from its atmospheric pressure value of 380°C at the rate of about 4°C per kbar. These data are analyzed by two different thermodynamic approaches; first, considering the transformation as an isothermal process, and second, considering the transformation as an isentropic process. It was found that both these approaches fit the experimental data equally well. The effect of hydrostatic pressure upon the austenite start temperature is best described by considering the mechanical work done during the transformation as that work obtained by multiplying the applied pressure with the gross volume change of the transformation. It is widely recognized1 that strain has an important effect on the initiation of martensitic transformations.* For example, the martensite start tempera- *In this paper, use of the term martensitic transformation implies the reversal of martensite to austenite as wen as the formation of martensite from austenite. ture, M,, may be increased by plastic deformation. Similarly, plastic deformation is observed to lower the austenite start temperature, A,. The effect of uniaxial stress on the M, of iron-nickel alloys has been studied by Kulin, Cohen, and Averbach.2 They found that the martensite start temperature was significantly changed by stresses well within the elastic region. Moreover, the effect of tensile and compres-sive stresses differed. These effects were explained in terms of the interaction of the applied stress with both the dilational and shear components of the transformation strain. The magnitudes of the influence of uniaxial tension, compression and hydrostatic pressure on Ms were measured in 30 pct Ni 70 pct Fe by Pate1 and Cohen.3 Their thermodynamic calculations and similar calculations by Fisher and Turnbull4 predicted the experimental results when the transformation was assumed to occur isothermally at some fixed driving force. This driving force was assumed to be supplied by a combination of the chemical free energy difference between the austenitic and martensitic phases and the work performed during transformation by the applied stress. More recently, Russell and winchel15 reported the effect of rapidly applied shear stress on the reversal of martensite to austenite in iron-nickel-carbon alloys. They performed a thermodynamic analysis of this transformation based upon the assumption that the re- versal occurred adiabatically. They concluded that the applied shear stress did not significantly interact with the transformation strain and thus did not assist in inducing the reversal. Rather they concluded that the reversal was effected by localized strain heating which resulted from the gross local shear deformation of the experiment. In either the adiabatic or isothermal analysis it is necessary to compute the work performed by the interaction of the applied stress and the transformation strains. In the case of hydrostatic pressure this interaction has been treated by two different methods. In either case the applied pressure is assumed to remain constant during the transformation. In one treatment the applied pressure is assumed to interact directly with the dilatational strain associated with the formation of an individual martensite plate.3'4 This local strain has been measured at atmospheric pressure in iron-nickel alloys by Machlin and Cohen.6 In the above treatment this local strain is assumed invariant with temperature and pressure changes. In the other treatment the applied pressure is assumed to interact with the gross volume change of the transformation.7,8 The usefulness of this latter treatment has been demonstrated by Kaufman, Leyenaar, and Harvey7 who calculated the effects of pressure upon the martensite and austenite start temperatures of Fe-10 at. pct Ni and Fe-25 at. pct Ni alloys. Excellent agreement was obtained between their calculations and their experimental data on an Fe-9.5 at. pct Ni alloy. However, this treatment suffers from the fact that the data required to calculate the volume change of the transformation (i.e., the initial specific volumes, the thermal expansion and compressibility data for both the austenitic and martensitic phases) is, in general, not available for any material except pure iron. Thus the calculations of Kaufman et al.7 were necessarily performed by assuming that the volume change of the martensitic transformation in the iron-nickel alloys was that same volume change occurring during the a-? transformation in pure iron. While this approximation may suffice for very dilute alloys it is likely to be inaccurate in high nickel alloys. We have performed measurements of the effect of hydrostatic pressure to 20 kbar on the A, temperature of an Fe-28.4 at. pct Ni-0.5 at. pct C alloy. The composition is similar to the alloy used by Pate1 and Cohen3 to determine the effect of pressure upon the M, temperature. The present measurements permit calculation of the interaction between the applied pressure and the transformation strain. Additionally, measurements have been made which allow precise determination of the gross volume change of the transformation. The data allow direct comparison between the alternate hypotheses of the interaction between the applied pressure and a dilatational transformation strain characterized by either the formation

Jan 1, 1970

By Dong-min Lee

As the construction industry is becoming more large-scaled and complex, the BIM technology has been utilized throughout the industry. Since 2008, the construction industry in South Korea (Korea) has required carrying on BIM-based project continually. According to this trend, BIM S/W market, as well as BIM library market is also gradually activated. Many countries have already been establishing Web-based BIM library market, also Korea has been trying to establishing this Web-based BIM library market. In this study, through market research of Web-based BIM library market of advanced countries including the U.S.A. and U.K., establishment strategy of BIM library market to be derived by late starters that introduce BIM such as Korea, Japan and China was deduced based on current establishment status of BIM library market in Korea. In addition, deal with an issue that a clear revenue-sharing system between business principals of Web-based BIM library market is not available at the current stage was presented as a factor of inhibiting activation of BIM library market. So in order to offer a reasonable revenue-sharing strategy in BIM library market as conceptual level, a methodology and process of applying Game theory being used for deriving. It is expected that a reasonable revenue-sharing model between business principals would be presented as its standard of BIM library market to be more activated in the future.

Aug 1, 2013

By Vaughan R. Voller

"Numerical methods for dealing with a temperature dependent conductivity are discussed. An approach based on a local application of a Kirchhoff transformation at the discrete level is presented. The application of this transformation - that does not require any inversion- is demonstrated on solving a two-dimensional test problem.IntroductionMuch is said in the recent literature on the modeling necessity of obtaining appropriate thermo-physical properties; in particular the requirement to account for properties that are ""strong"" functions of the depended variables, e.g., Temperature. Of course obtaining appropriate thermo-physical properties serves no purpose unless they can be accurately integrated into a discrete numerical calculation. The purpose of this paper is to examine how temperature dependent conductivities that exhibit discontinuities or rapid changes can be handled in a numerical code.The discussion will be made in the context of a control volume finite element method [1]. After a brief outline of control volume finite element fundamentals basic methods of dealing with discontinuous or rapidly changing thermal conductivity are discussed. This is followed by the presentation of the recently proposed local Kirchhoff method [2,3], The paper concludes with an investigation of the performance of the various conductivity schemes in solving two dimensional problems. This testing clearly shows the advantages (accuracy and implementation) in using the local Kirchhoff method."

Jan 1, 2001

By J. G. Conaway, P. G. Killeen

"Gamma-ray spectral logging, a useful technique for uranium exploration and evaluation, has generally been underutilized by the Canadian mining industry. Provided that the technique is properly applied, it is capable of yielding reliable quantitative information regarding the distribution of uranium and other radioelements along the borehole under most conditions.In practice. there are numerous factors which potentially can degrade the quality of the log and thus any quantitative interpretation based on it. Fortunately, the appropriate choice of logging equipment and technique can avoid many such problems, and corrections can be applied to the data to compensate for most of the others."

Jan 1, 1980

By Xiao Min You, D. R. Swonbourne

Smelting of Cu anode slimes involves the use of a slag to hold the oxidised Cu, but some Ag is also inevitably oxidised to the slag. The solubility of Ag in sodium silicate slags at 1 100 and 1 150 degrees C has now been determined over a very wide range of oxygen partial pressures. Silver was found to be present in the slags both as neutral atoms and as AgO(0.5). The activity coefficient for atomic Ag was a very strong function of slag composition and temperature, whereas that for AgO(0.5) was much less affected by slag composition and was almost independent of temperature over the limited range examined. The results reveal that the dissolved Ag cannot be fully recovered by reduction of the slag with very reducing gases

Jun 21, 1905

The modern theory of sampling of particulate minerals essentially consists of a recent generalization of the procedures for applying and calibrating the formula usually known as ?Gy?s Formula? for sampling variance control, in which the central concept is a parameter called the liberation factor l. A model which can be experimentally adjusted was proposed by one of the authors several years ago, based on geostatistical considerations. This new model, which relates the liberation factor to the sizes of the fragments and mineral grains, solves the usual difficulties faced in the past, and permits predictions that are well verified in practice. Unfortunately, an older, arbitrary and less general formula is still widely used. The vast majority of today?s misapplications of Sampling Theory of Particulate Materials can be traced back to the use of this antiquated and generally incorrect model. Following a brief history of the models used for the liberation factor and a description of its main variable, the liberation size, and to illustrate the importance of proper modelling of l, this paper presents demonstrative calculations of the absurdity of the incorrect model using the particular case of gold mineralization as an example, followed by some more positive examples of application.

Jan 1, 2002

Virtual reality (VR) simulators represent a powerful tool for training humans to perform tasks which are otherwise expensive or dangerous to duplicate in the real world. The idea is not new. Flight simulators have been used for decades to train pilots for both commercial and military aviation. These systems have advanced to a point that they are integral to both the design and the operation of modern aircraft (Adams, Klowden and Hannaford, 2001; Mastaglio and Callahan, 1995). This technology has been successfully extended and utilised in the mining industry in a range of successful applications (Bise, 1997; Denby and Schofield, 1999a; Schofield, 2005; Henning et al, 2002; Kaiser, Vasak and Suorineni, 2005). There are a number of lessons that can be learned from other industries that have successfully utilised virtual technology for a number of years. Specific rules of thumb regarding the specification, development, application and operation of these simulators can be garnered from other industrial training systems and examined in a minerals industry context (Tromp and Schofield, 2004; Schofield, 2006). This paper intends to discuss some of these generic rules in the context of a number of recently developed virtual reality mining applications.

Jan 1, 2008

By G. W. Govier

Measurements of the settling rates and the rheological behaviour of heavy media formed of fine suspensions in water of each of magnetite, ferrosilicon, and galena have been made. For media ranging from 1.6 to 2.8 specific gravity the settling measurements gave initial settling rates of from 0.5 to 0.01 ?cm. 'Per minute for magnetite; from 4.0 to 0.8 cm. per minute for galena; and from 35 to 1.6 cm. 'Per minute for ferrosilicon. These measurements indicate the ?relative stability of the suspensions and should be helpful in establishing the useful specific gravity range for each medium. Measurements of the consistency of the media were made with a Fann Model 35 rotational viscometer. Aibnormal or non-Newtonian behaviour was observed in the case of each media, the apparent viscosity being dependent upon the rate of shear or the intensity of motion. Measurements were made over the rate of shear range of 10? to 1,000 reciprocal seconds. The apparent viscosities of the magnetite media ranged from 450 down to 4?0 centipoise at 2.30 specific gravity, and from 2,450 down to 700 centipoise at 2.80 specific gravity. In the case of the galena media, the variation was from 40, through a minimum of 6, to 10 centipoise at 2.20 specific gravity, and from 950, through a minimum of 180, to 450 centipoise at 3.6 specific gravity. The ferrosilicon suspensions exhibited apparent viscosities ranging from 42, through a minimum of 5.6, to 9 centipoise at 1.9 specific gravity, and from 160, though a minimum of 35, to 85 centipoise at 2.8 specific gravity. The dependency of apparent viscosity or consistency upon intensity of motion is considered to be of particular significance in applications of heavy media where the medium is in rapid motion.

Jan 1, 1957

By Steve Linehan, John Toedter, Kelly Williams, Mark Herman, Laura Connor, Catherine E. Johnson

Minimum safe distance (MSD) calculations are used widely in military applications to determine safe standoff distances for breaching personnel. Accurate safe distances and an understanding of blast wave propagation are critical to preventing traumatic brain injury. These calculations are often based on spherical charges in open air. However, applications including explosive breaching use planar charges rather than spherical. Previous studies analyzed the shock propagation of a square planar charge of sheet explosive and concluded the anisotropic pattern conflicted with the Kingery Bulmash (KB) and MSD spherical models. It has been determined that these predictions do not adequately predict the realistic pressures in all directions and the trend has shown to be consistent across multiple charge geometries. In this series of experiments, pressures were collected from reference spheres and rectangular geometries of detonating cord and sheet explosive commonly used in breaching and improvised demolition for this comparison. This common configuration showed pressure differences at varying angles to the charge with the highest pressures measured at the 90° position perpendicular to the “door” to be breached. Lower pressures were found at the 0° and 15° positions where the breachers would normally be standing. The reflected shock from a surface such as a door was incorporated in a semi-confined situation and added to the shock observed by the breachers. Urban environments include many surrounding structures for these reflections to occur and further testing is necessary in such an environment to determine the full-scale impact. These findings may be useful to develop improved MSD calculations for breaching applications based on charge geometry, orientation to the blast, and nearby structures.

Feb 6, 2023

By Ashok Kumar, Rajendra Singh, Arun Kr. Singh

"A simple analysis of site conditions and capability of the mechanised depillaring (MD) operation found that this approach is suitable to address the strata control issues in coal pillar extraction under the weak and laminated roof strata of Pinoura mine. A continuous miner (CM) with a ram car and quad-bolter are used for single pass pillar extraction (first time in the country) to achieve a relatively faster rate of depillaring. A total of eleven panels are depillared under weak and laminated roof strata with a fair-rated rock mass rating (CMRI-RMR). It is observed that there is less influence of roof caving over the surrounding mining structures, especially those located out-bye the side of the extraction line. An attempt is made to quantify the goaf influence by field studies, which show that the maximum value of mining-induced vertical stress is 2.83 MPa, and the range of influence remains limited to around 15 m from the line of extraction. However, the problem of roof instability under the influenced zone was experienced due to the inherent nature of the weak roof strata. The chances of trapping of CM under weak and laminated roof strata of the panels is reduced by deriving a threshold value of the roof dilation, on the basis of a simple statistical analysis of the obtained field results. However, few incidences of roof collapses are observed over the CM due to the unpredictable behaviour of the geological structures below the freshly exposed strata, which also caused an obstruction in the speed of the extraction. This paper presents results of the field and laboratory studies, conducted for a successful application of the single-pass pillar extraction method, along with details of some CM trapping cases below the weak and laminated roof strata.INTRODUCTIONCoal is the major natural resource to meet the growing energy demand of India and this trend is likely to continue for the next 20 years in the country. A major part of the Indian coal belongs to Gondwana period, and only a small part belongs to Tertiary period. The estimated coal reserve in India per the exploration work done up to a maximum depth of 1200 m is 315.149 billion tonnes, including the proven coal reserve of 143.058 billion tonnes (CMPDIL, 2017). Even in presence of these huge resources of coal in India, there is a considerable gap between production and the users’ demand of coal. Most of the mines are operated by conventional semi-mechanised Bord and Pillar (B&P) methods; thus, the mining industry has gained a considerable amount of operational experience (Singh, Singh, and Dhar, 1996) and knowledge about strata behaviour (Singh and Singh, 1999; Singh et al., 2008) using this method. However, recently, the Indian coal mining industry has introduced some mechanised depillaring (MD) operations, where the level of production is relatively high. This approach of depillaring improves safety along with the production and productivity of a depillaring operation (Ram et al., 2017). The nature of the overlying strata of these depillaring operations vary greatly: from highly laminated, weak, and easily caveable to massive, strong, and difficult to cave."

Jan 1, 2018

By James A. Madonna

Information gathered while studying geological parameters that govern fine gold deposition in the a1luvial environment can be applied to the technological development and selection of fine gold recovery systems. It is recognized that substantial gold losses occur in the minus 1.5 mn (minus 12 mesh) fraction using conventional sluicing systems. Within the past two decades much attention has been given the design and efficiency of these thick bed concentrators. Studies and comparisons drew information from several foreign and domestic placer operations. These studies concentrated on: 1) the physical and chemical properties of alluvial gold 2) the parameters that control fine gold deposition 3) the geometrical form, components and general working structure of conventional sluicing systems 4) the physical properties which contribute to the overall efficiency of a sluice system 5) the comparison of three major styles of conventional sluicing systems. A dramatic improvement regarding fine gold recovery and water quality was observed when using modern multiple-channel sluicing systems in place of conventional single-channel sluicing systems.

Jan 1, 1988

By Shosei Serata

The application of conventional rock mechanics methods to complex ground is very difficult. Yet. In most underground mining, the ground is complex. Therefore. conventional methods are not only difficult to apply but are also generally ineffective in improving underground operations. Similarly, conventional rock mechanics instrumentation has not significantly contributed to improvement of mining practice. Rock mechanics instrumentation in underground mining operations is often considered to be" merely an expensive nuisance. A new system of mine instrumentation is changing this traditional view. The new instrumentation method, called the SPDR method, was originally devised by Dr. Shosei Serata to meet the specific requirement of establishing the Stress Control Method of mining upon a solid quantitative foundation. This instrumentation method has contributed substantially to the widespread success of Stress Control mining under widely varying ground conditions in different types of underground mines (1.2.3.4). The instrumentation method provides an effective means for optimizing Stress Control mining patterns, simultaneously achieving reduction in production costs and substantial improvements in safety (5). The principles and methods of the new instrumentation method are described below, with field examples.

Jan 1, 1986

By Gregory M. Molinda

The Coal Mine Roof Rating (CMRR) was developed 10 years ago to fill the gap between geologic characterization and engineering design. It combines many years of geologic studies in underground coal mines with world-wide experience with rock mass classification systems. Like other classification systems, the CMRR begins with the premise that the structural competence of mine roof rock is determined mainly by the discontinuities that weaken the rock fabric. However, the CMRR is specifically designed for bedded coal measure rock. Since its introduction, the CMRR has been incorporated into many aspects of mine planning, including longwall pillar design, roof support selection, feasibility studies, extended-cut evaluation, and others. It has also become truly inter-national, with involvement in mine designs and funded research projects in South Africa, Canada, and Australia. This paper discusses the sources used in developing the CMRR, describes the CMRR data collection and calculation procedures, and briefly presents a number of practical mining applications in which the CMRR has played a prominent role.

Jan 5, 2007

By Albert Sauveur

As director of the Division of Metallurgy of the Technical Section of the Air Service, American Expeditionary Forces, from August, 1917, to January, 1919, I devoted much time to the study of the steels best suited to the construction of aircraft. It became apparent at a very early stage of my investigation that the practice of builders varied greatly in regard to the number of different steels to be used, to the kinds of steels, and to their treatment. Some manufacturers employed as many as fifteen steels while the builder of one of the newest motors, favorably passed upon in the United States, assured me that two or, at the most, three kinds of steel was all he needed to produce satisfactory results. In the matter of treatment, the manufacturers were also greatly at variance.. Some treated their steel with considerable refinement, while others paid but scant attention to this feature. Some manufacturers case-hardened many parts, while others used the case-hardening process sparingly, if at all. Nickel-chromium steels were used at some works for case-hardening while at other plants this treatment was applied exclusively to carbon steels. Air-hardening nickel-chromium steel was used extensively by some and not at all by others. Considerable variance existed likewise in regard to the steels used for admission and exhaust valves. The conclusion was obvious, that no two manufacturers of airplane motors held like opinions as to the steels to be used or as to the treatment they should receive. Was it to be inferred from this that the many committees and associations that had been created, in part at least, for the standardization of aircraft steels had failed to make proper recommendations or that the manufacturers had ignored their recommendations? Confining our inquiry to the committees and associations that had dealt with this question in England, France, and the United States, it was found that in Great Britain the British Engineering Standards Committee, now the British Engineering Standards Association, had devoted much time to the problem of satisfactory standards for aircraft steels. In April, 1918, this Association presented a set of specifications

Jan 9, 1919

By L. D. Cruz

In Exxon's Los Bronces Expansion Project in Chile, a stochastic simulation is performed to resolve the complex decision problem of matching the mine to mill system capacities from both technical and economic standpoints. The unique combination of weather conditions at the mine and the 30-km belt conveyor network for ore transport to the mill necessitates this analysis in the planning phase to optimize the design capacity of the sys tem. Appropriate statistical distributions of major equipment performance, snow storm duration, power outage, etc, ate developed from actual mine local records and manufacturers specifications. The interactions of operational constraints including ore storage capacities, number and sizes of individual equipment, ore variations, and mine and mill production rates are studied more realistically than in a traditional planning approach. Details of the computer modeling and typical results of simulation studies are discussed.

Jan 1, 1981

By S. L. Bessinger

Introduction In the design and specification of a ventilation system for an underground mine, it is necessary to make reasonably accurate estimates of the pressure losses in the various airways of the mine. These estimates can be made with little difficulty for open airways with simple geometric cross-sections, such as those cut by continuous miners or tunnel-boring machines. The situation is much different on a longwall face, where the airway's complex geometric cross section and the presence in the airway of obstructing equipment having a variety of shapes make it difficult, if not impossible, to estimate pressure loss using traditional methods of calculation. Head losses in mine entries are calculated using Atkinson's Equation. [22H= KPLQ (English) H= KP 3Q (SO (1) 5.2AA] where H = pressure loss, in. of H2O (Pa); K = friction factor, lbf•min2/ft4 (kg/m3); P = perimeter, ft (m); L = airway length, ft (m); Q = airflow quantity, ft3/min (m3/sec); and A = flow cross-sectional area, ft2 (m2) In this equation, the friction factor, K, is an empirical constant that describes the aerodynamic roughness of the airway. Typically, the K-factor for a given airway is determined by measuring the factors H, P, L, Q and A in Equation (1) and calculating K. Tables of friction factors calculated in this way are found in textbooks and handbooks that deal with mine ventilation analysis. Unfortunately, very few K-factors have been measured on longwall faces, and the accuracies of those that have been measured are entirely site specific, because of the wide variety of equipment found on longwalls. The development of a technique for prediction without mine-site measurements of the friction factor for any longwall face, regardless of its configuration, will thus be very useful in the design of ventilation systems for mines in which longwall mining is practiced. Calculation of pressure losses using Atkinson's Equation (1) and empirically determined K-factors provides accurate and useful approximations in cases where the airways have relatively simple cross sections. However, a careful analysis using the principles of fluid mechanics shows that such calculations are based on two assumptions that are not strictly correct when there are obstructions in the airway. The first assumption is that the air velocity distribution in the cross section, particularly around the perimeter, is uniform. This assumption results from the fact that the tabulated K-factor values found in the literature are based on field measurements with uniform conditions. Such uniformity does not exist in longwall airflows. The second common assumption is that the K-factor, and corresponding head loss, is independent of the Reynolds Number (NR) for a given flow. In fact, this assumption is not strictly correct, and is particularly erroneous in the case of irregular protuberances into the airflow, such as those found on a longwall face. The errors arising from the assumptions may be avoided by using K-factors calculated by a newly devised method, described below, which takes into account the fundamental principles of aerodynamic drag analysis. This new technique has two advantages: first, it is flexible enough to model any longwall, regardless of equipment configuration; second, it employs terminology and equations familiar to those who perform mine ventilation analysis, using K-factors, for which ventilation engineers have an intuitive understanding, rather than drag coefficients. To provide guidance for development of a longwall drag model, data were taken on two modern longwalls operating in substantially different conditions. Pressure measurements at Mine B were made with 200-foot (61-m) sections of 1/8-in. (3-mm) diameter plastic tubing, attached to a Dwyer Magnehelic gauge. Pressure drops were measured in 200-foot increments down the face, and summed to give the drop for the entire face length. This technique was found to produce small, repeated errors because of the number of segments required to span the longwall. At Mine A this problem was avoided by using a single, continuous, plastic tube for the entire face length. The psychrometric properties of the air were measured for both Mines A and B. A calibrated, standard vane-anemometer was used to measure the airflow on both faces. Finally, numerous dimensions were measured on both faces, and face profile drawings were obtained to allow detailed evaluation of the face equipment geometry. From this information, accurate evaluations of the average wetted perimeter and average area of the longwall face airways were made. Since the airflow is not confined to inside the powered supports at all points along the face, a quadratically weighted average of the airflows measured at various stations along the face was calculated: [n2Qavg =Qi Ii / It(2)i=1] where [Q, avg = average airflow for analytical purposes, ft3/min (m3/sec); Q= airflow at station i, ft3/min (m3/sec); 1= length of segment represented by Q, ft (m); h= length of longwall face, ft (m): and n= number of quantity measurement stations.] The quadratic weighting scheme was chosen because the

Jan 1, 1992

By John C. Sawyer

A brief review is given to show that catastrophic oxidation of stainless steel in the presence of lead oxide is similar in many respects to catastrophic oxidation as caused by MoO3 and V2O5, Experimental data are presented to show that lead oxide accelerates the normal oxidation process of stainless steel by chemically altering the normally protective oxide film formed on the base metal. Data are given to show that similar reactions occur during oxidation of stainless steel in the presence of MOO3,and V2O5. THE mechanism by which pure metals oxidize at high temperatures has been the subject of intensive research for many years and much has been accomplished towards understanding the processes involved. The mechanisms by which alloys oxidize have also been investigated, but due partly to the fewer number of investigations and partly to the complexity of the oxide systems present, available knowledge is not as extensive as with pure metals. When oxidation processes are further complicated by atmospheres contaminated with sulfide, halide, or oxide vapors, the knowledge of fundamentals becomes meager or altogether lacking. Thus, it is not surprising to find that the catastrophic oxidation of stainless steels in metal oxide vapors of MOO, and V2O5 is not a well understood phenomenon despite the fact that a number of investigations have been undertaken. The literature in dealing with the subject of catastrophic oxidation is primarily concerned with the effects of MOO3 and V2O5, but does mention that other metal oxide vapors, one of which is lead oxide, appear to promote a similar type of accelerated oxidation. While this latter effect is virtually unknown, the deleterious effect of lead oxide is of considerable commercial importance, as it is believed to be one of the fundamental reasons for exhaust-valve failure in gasoline engines. For this reason studies have been in progress for many years attempting to better understand the mechanism involved. Modern exhaust-valve alloys"2containing 20 to 25 pct Cr plus nickel and/or manganese are in effect high-grade austenitic stainless steels exhibiting ex- cellent oxidation resistance in air at exhaust valve operating temperatures of 1100° to 1700°F; yet these same alloys are prone to corrode during engine service because of the conditions attending their operation. These conditions are such that the valves become coated with deposits of complex lead compounds mainly derived from gasoline additives of tetraethyllead, ethylene dibromide, and ethylene dichloride. Literature searches3-7 and discussions with various investigators show that considerable difference of opinion exists as to the nature of the lead-bearing deposits found on the surface of exhaust valves and the atmospheres to which they are subjected; yet, all seem to generally agree that corrosion, a gradual transformation of alloy to nonmetallic products of corrosion, is a consequence of the presence of lead compounds. This majority opinion seems to be substantiated by laboratory engine tests which show that corrosion does not occur to any appreciable extent when lead-free fuels are used. The first observations of catastrophic oxidation reported in the literature were probably made by pfeil,8 but it was Leslie and Fontana9 who undertook the first detailed study of the phenomenon. Their work was chiefly centered on the acceleration of oxidation which took place when stainless steels containing more than 3 pct Mo were heated in air with restricted circulation. These investigators reported that the presence of other oxides near the surface would further accelerate the rapid oxidation which occurred. While they recognized that the effect was attributable to the presence of molybdenum, it was Rathenau and Meijering" who emphasized the fact that the presence of molybdenum in the alloy was incidental to the presence of MOO3 vapor in the atmosphere surrounding the specimens. Evans,11 as well as Cunningham and Brasunas 12 studied similar

Jan 1, 1962

By N. Dashbold, E. Rudnik

"Waste electric and electronic equipment currently comprises the fastest-growing waste stream in the world, but at the same time it is seen as an important source of metals for the recycling industry. E-waste is usually treated pyrometallurgically, with hydrometallurgical methods used to a lesser extent. This paper reports the results of research on the selective recovery of copper from smelted low-value electronic waste. Pyrometallurgical pretreatment of the scrap allowed the removal of plastics and the increase of metal content in the material. The obtained alloy of copper, zinc, tin and silver was a multiphase solid consisting of two brass phases and inclusions rich in iron, lead and silver. Copper alloy was further anodically dissolved in ammoniacal chloride solution. It resulted in high degradation of the material and accumulation of the metals mainly in the slime. The slime was then leached in acid or ammoniacal chloride and sulfate solutions followed by selective copper electrowinning. Hydrochloric acid was the most efficient solvent for the slime, but ammoniacal solutions were more selective for copper. Copper could be leached with 96 to 100 percent and 87 percent efficiency from the slime by the chloride and sulfate solutions, respectively. Copper with 90 to 99 percent purity at current efficiency of 42 to 76 percent was obtained from the acid solutions, while copper with 98 to 99 percent purity at current efficiency of 60 to 86 percent was deposited from the ammoniacal baths. IntroductionObsolete electrical and electronic equipment makes up the fastest-growing waste stream in the world (Baldé et al., 2015), due not only to the introduction of wider ranges of new types and models of a variety of electronic products but also to the shortening of their life-spans, sometimes referred to as planned obsolescence by producers (Keeble, 2013). About 42 million tons of electronic waste, or e-waste, are estimated to have been generated globally in 2014 (Baldé et al., 2015), and it is expected that in the European Union alone the waste electrical and electronic equipment (WEEE) stream will reach more than 12 million tons by 2020 (European Commission, 2015). Accurate evaluation of e-waste generation (Wang et al., 2013) and its global transport (Breivik et al., 2014) is difficult, mainly due to a lack of high-quality data related to its market and socio-economic dynamics.Many countries introduced legislation to control e-waste flow, collection and recycling. For example, Directive 2012/19/EU on waste electrical and electronic equipment (European Parliament and the Council of the European Union, 2012) obliges all E.U. members from 2016 to maintain a minimum collection rate of 45 percent of the total weight of WEEE collected. From 2019, the minimum collection rate to be achieved annually shall be 65 percent of the average weight of electronics placed on the domestic market in the three preceding years, or alternatively 85 percent of WEEE generated in the territory of the particular member."

Jan 1, 2017

By P. M. May, V. Gella

The deportment and speciation of trace elements during mining and minerals processing is becoming an area of increasing concern with regards to potential health and environment risks. The use of chemical modelling can enhance our basic understanding of the deportment and speciation of trace metals under conditions present in gold processing solutions, and assist in laboratory and field investigations. In this paper, we report the results of chemical speciation modelling using the JESS software package for the trace toxic elements Pb, Cd, Hg, Se and Te in cyanidation solutions of varying salinity and relate the models to experimental data. The speciation of mercury is examined in detail.

Jan 1, 2011

By C. S. Compton, T. E. Marshall, D. R. Dolinar, R. Grau, L. J. Prosser, A. T. Iannacchione, D. C. Oyler

Unrecognized roof beam failures resulted in 69% of the falls of ground injuries occurring in underground U.S. stone mines from 1990 to 1996. Field investigations at 45 underground stone mines suggest that excessive beam sag or deflection is the principal unstable roof behavior characteristics associated with miner injuries. Laminated roof structures, common in most underground stone mines, allow the immediate roof to separate into distinct beams. The timely determination of roof beam deflection could provide stone miners with advanced knowledge of potentially hazardous roof. Existing methods to assess roof conditions consist of observational and monitoring techniques. Observational techniques include open drillholes, sounding, wedging, and borescopes. Monitoring techniques include scratch tools, extensometers, telltales, Miners Helpers, and Guardian Angels'. Miners have difficulty utilizing these techniques because roof beams are located an average of 8 m (26.5 ft) above the miner's head in environments that are dark, dusty and noisy and these deflections are measured in millimeters of movement. To help mitigate the potential for falls of ground injuries to underground stone miners, the National Institute for Occupational Safety and Health (NIOSH) has developed the Roof Monitoring Safety System (RMSS) to aid in monitoring dangerous levels of roof beam deflection. If enough site-specific information is collected and placed on highly visible maps, individual mining operations could establish general guidelines for responding to specific roof beam deflection occurrences. This would help in implementing a pro-active, comprehensive roof control plan for reducing falls of ground injuries.