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By X. Xu, J. K. -W. Wong, J. -Y. Delenne, K. Soga

Hydraulic fracturing (HF) is a mulit-scale and multi-physics process which makes numerical modelling challenging. Conventional numerical models focus on multi-physics nature of HF but the multiscale nature is compromised by idealization of reservoir to be continuous, homogeneous and isotropic. However, natural fractures take a significant role in the success of HF for exploration of unconventional resources like Shale gas. Advancement in microseismic monitoring provides useful data for simulation in a much greater details. There is an urgent need to develop a suitable numerical tool for multi-scale threedimensional simulation to better understand the roles of discontinuities and heterogeneity in reservoir and its interaction with HF, especially to address the environmental concerns such as induced seismicity. In this paper, a simple discontinuum numerical method – Lattice Element Method (LEM) is proposed to model HF in a large scale three-dimensional model. A reservoir is modelled as a lattice network composed of 1D Hookean’s spring. Fracturing is modelled simply by removing lattices that meet a specified threshold as determined by the critical energy release rate of the rock. By introducing disorder in the model, mesh dependency in modelling fracture growth is minimized. Fluid flow is simplified as flow in pipe network and the permeability of pipe is related to fracture aperture by cubic flow law. Therefore, fracture flow and rock deformation are fully coupled. In this paper, four simulations of the same configuration except with different degrees of reservoir heterogeneity are presented. Fractures formed are diffusive and two groups of fracture are identified – connected fractures and isolated fracture without clear spatial correlation. The former forms a ‘fracture cloud’ and contributes to fluid flow and modeled by pipe network. The flow of fluid is highly tortuous and pipe network is sparely connected. The degree of reservoir heterogeneity controls the growth of ‘fracture cloud’ and pipe network. Microseismic monitoring often shows diffusive fracturing during HF on site and hence the outcome of the proposed model can be compared to such monitoring results.

Jan 1, 2015

By O. MacIntosh

The Round Mountain gold mine, located 90 km (55 miles) north of Tonopah, NV began large-scale production in 1977. During 2008 Round Mountain Gold Corp. (RMGC) relocated the primary crusher facility approximately 300 m (1,000 ft) to make room for the next phase of openpit mining activities. This facility was installed in 1988 and used a log-crib retaining wall and dump pocket. RMGC selected Hilfiker Retaining Walls and Collins Engineers, Inc. to provide design and materials for a new 17-m- (56-ft-) high mechanically-stabilized embankment (MSE) wall to support the haul trucks at the new location. The construction contractor was EarthTech West Ltd. of Norwood, CO. An MSE wall with a cast-in-place concrete face was chosen as a durable, yet less expensive alternative to the reinforced concrete dump pocket that was originally designed for the project. The arrangement of the MSE wall is of an unusual configuration to meet a variety of operational and maintenance requirements. This paper outlines the selection process, design and construction of the MSE wall.

Jan 1, 2010

By Pratheesh George

Solid state galvanic cell with CaF2 as the electrolyte was employed for determining the thermodynamic properties of Nb-Al binary alloys in the temperature range of 973-1073 K. The activities and activity coefficients of Al in NbAl3 were determined. The experimental procedure and the design and construction of the experimental setup have been also explained in detail. Aluminum activity in NbAl3 increased with increase in temperature and shows a strong negative deviation from ideality. The activities of aluminum in NbAl3 were determined to be 0.0165 and 0.0289 at 973 and 1073 K respectively. The stability of NbAl3 has been compared with other available intermetallic systems.

Jan 1, 2006

By John McEwen, Ian R. Jonasson, David H. Watkinson

"Mine Gallen is a zinc-rich pyritic volcanogenic massive sulphide deposit that occurs in a fault-bounded block of intermediate volcanic rocks. The block is completely surrounded at the present erosion level by the eastern part of the Lac Dufault granodiorite. The volcanic succession includes a massive feldspar porphyry that is probably a subvolcanic intrusion, an andesitic flow unit and lapilli tuffs. The latter are variably sericitized and pyritic, especially in the vicinity of the massive sulphide into which they grade.The ore body is predominantly pyritewith local sphalerite contents as high as 20%; minor chalcopyrite and trace galena are disseminated, but are found mainly along late cleavage. Most ore is a breccia of massive to banded pyrite-sphalerite, veined by massive and complexly banded sulphides. These structures formed by repeated blocky jointing, cracking, sealing, healing and annealing as hydrothermal fluid repeatedly passed through a developing sulphide mound. The deposit is interpreted to have grown on the seafloor in a manner similar to active mounds in the Galapagos rift.RESUME La Mine Gallen exploite un gisement de sulfures massifs volcan géniques comprenant essentiellement de la pyrite riche en zinc. Ce gisement se trouve a /'intérieur d’un bloc de roches volcaniques de caractère dacitique a andésitique, limite par failles et entoure de tout cote par la granodiorite du Lac Dufault. La séquence volcanique comprend des coulées andésitiques et des tufs à lapilli ainsi qu'un porphyre feldspathique massif sub-volcanique. Les tufs sont sericitises et pyritises, tout particulièrement au voisinage des sulfures massifs."

Jan 1, 1990

By Norman F. Schulz

The technical excellence of separation achieved in a mineral concentration process, or any other process where two constituents of any kind are physically separated from each other, is expressed uniquely and quantitatively by the Separation Efficiency: ES = (R ? Rg) where R is the percentage of the valuable constituent and Rg the percentage of the waste appearing in the concentrate. The Separation Efficiency meets all the usual requirements of a true efficiency and is independent of the nature of the process used. It can be visualized as the percentage of the feed material that, in effect, actually undergoes complete separation while the rest of the feed is distributed randomly and unchanged into the two separation products.

Jan 1, 1969

The objective of current efforts by AQUILA Mining Systems Ltd. is the continued development of computer-based systems and techniques to automatically process and interpret monitored performance data from surface blasthole drills and mining shovels, and the management and coordination of these pieces of equipment by GPS (Global Positioning Systems).

Jan 1, 1995

By Christopher Jon Preston

This paper describes a type of ammonium nitrate (AN) produced in a patented experimental atomization/aerodynamic process. This AN exhibits outstanding properties for use as a main ingredient to a new family of AN-based commercial explosives. Micro-particle ammonium nitrate (MP-AN) is produced by atomizing either an 83% or 85% AN solution which has been doped with a two component surfactant NSol 1000 (NSol). NSol imparts some water-resistance as well as provides a means of increasing density and bulk strength. Increased detonation velocities, well in the range of emulsion explosives, can be achieved. The maximum manufacturing temperature is less than 100°C. The methodology has the potential of being environmentally friendly since any effluent can be recycled back into a make-up tank to be re-used by the closed loop method. The process has a small footprint.

Jan 1, 2015

By Alejandro Lagos

El modelamiento estructural de una zona es esencial para la búsqueda de zonas favorables para la mineralización. En ese sentido, el presente texto describe la geología estructural de las áreas de Cajamarca, San Marcos y Bolivar y su posible relación con la génesis de los yacimientos de minerales ubicados en ese sector y así diseñar un modelo estructural de las aéreas mencionadas apoyado por el método de mapas paleogeológicos.

Sep 14, 2009

By R. J. Fruehan

The oxygen activity and concentration were measured in Fe-Cr-0 melts in equilibrium with an oxide phase at 1600°C (2912°F). The activity was determined by ,use of the following solid oxide -electrolyte galvanic cell CY-Cr8,(s) I ZrOz(CaO) I Fe-CY-G(saturated)(l) The oxygen concentration decreases with increasing Cr concentration to about 270 ppm 0 at about 7pct CY and then increases gradually. The activity coefficient of oxygen (fo) decreases with increasing Cr. In melts containing up to about 20 pct Cr, log f is approximately a linear function of wt pct Cr with a slope (e q 2) of —0.037. The activity of chromium was calculated and found to exhibit a small negative deviation from Raoult's law. From the activity and solubility data for low chromium melts, the free energy of formation of chromite, FeCr204, was found to be -79.8kcal per mole where pure liquid chromium and oxygen at I wt pct in Fe are the standard states. ThE effect of chromium on the chemical behavior of dissolved oxygen in liquid iron is of great importance in controlling the deoxidation of steels containing a significant amount of chromium. Chen and chipman' equilibrated Fe-Cr melts in the presence and absence of slag with hydrogen-water vapor mixtures. They concluded that at 1595°C chromite was the oxide phase in equilibrium with Fe-Cr alloys containing less than 5.5 pct Cr while at higher chromium concentration Cr,O, was the stable phase. In the composition range 0 to 10 pct Cr they found that the interaction coefficient, was equal to -0.041. Turk-dogan,' Schenck and Steinmetz,, and pargeter4 measured egr) in a similar manner and found the value to be -0.064,-0.04, and -0.052, respectively. McLean and Be11 evaluated egr) from their data on the equilibrium of Fe-Cr-Al-0 alloys with H2/H20 mixtures and found it to be -0.058. However, McLean and Bell's value should only be considered an estimate because the effect of aluminum on the activity coefficient of oxygen is about a hundred times greater than that of chromium. Consequently, an error in the value of egl) used, which at the present time is not well-known, or an error in aluminum analysis, which is present in very small quantities, will result in a significant error in egr). Fischer et a1.6 determined the interaction coefficient (eEr) in Fe-Cr-0 melts not in equilibrium with an oxide phase and containing less than 18 wt pct Cr at 1600°C electrochemically. They determined a value of -0.031 for egr). Hilty et aL7 measured the oxygen content of Fe-Cr melts in equilibrium with an oxide phase containing up to 50 pct Cr. They found that the solubility of oxygen decreased as the chromium content increased to about 6 pct Cr and then increased gradually. They concluded that the equilibrium oxide phase was chromite below 3 pct Cr, distorted spinel from 3 to 9 pct Cr, and Cr,04 above 9 pct Cr. Adachi and lwamotoa also investigated this system, but did not find Cr30,. They X-rayed the equilibrium oxide phases and did not find the presence of Cr,O,. They also X-rayed the oxide phase extracted from a 65 pct Cr melt which was heat treated and did not find metallic chromium as would be expected if Cr3O4 were the equilibrium oxide phase as indicated by the reaction : 3Cr3O4 — 4Cr2O:, + Cr [lj It was the purpose of the present investigation to determine the effect of chromium on the activity coefficient of oxygen in Fe-Cr melts by measuring the activity and solubility of oxygen equilibrated with an oxide phase in the composition range 0.18 to 50.5 wt pct Cr at 1600°C (2912°F). The activity of oxygen in the melts was determined by use of the following galvanic cell: The relationship between the partial pressure of oxygen in equilibrium with the melt and the reversible electromotive force of the cell (E) is where 11 = 4, F is the Faraday constant, pb, is the oxygen pressure in equilibrium with the meit and is the oxygen pressure in equilibrium with Cr203 as determined from the free energy data compiled by Elliott et al? The oxide phase in equilibrium with pure chromium was assumed to be Cr If Cr30, were the equilibrium phase the activities derived would be approximately the same, since the best estimated free energy of formation of Cr,O,, if it does exist, is approximately % the free energy of formation of The activity of chromium in Fe-Cr alloys at 1600° C was also determined from the measured electromotive force. The activity of chromium (aCr) is related to the electromotive force as follows: , The oxide phase in equilibrium with pure chromium and Fe-Cr melts from 10 to 52 pct is assumed to be Cr203 so that n equals three. If future work proves the existence of Crs04 in equilibrium with Fe-Cr melts and pure chromium, the experimental results can be reevaluated using a value of $ for n in Eq. 141. A value of ^ for n will make the activities about 10 pct higher. In order for Eqs. 131 and [4J to be valid the electrolyte, ZrOa(CaO), must exhibit predominantly ionic conduction at the temperature and oxygen partial pressure of its use. Previous work1' has demonstrated that ZrOz(Ca0) is predonlinantly an ionic conductor

Jan 1, 1970

By E J. Hill, F Huang, A Otto

Geochemical data from drill core samples is used in mineral exploration to enable geologists to understand subsurface geology. However, it is challenging to analyse these data sets rigorously and consistently. Manual data interpretation relies on the knowledge and experience of logging geologists. When multiple geologists are involved, it is possible to introduce inconsistencies in logged lithology type and scale of logging (‘splitters’ versus ‘lumpers’). Machine learning (ML) is a powerful tool for analysing high dimensional data (ie data with many variables) and large data sets (ie data with many samples). However, ML methods applied to drill hole samples do not incorporate spatial information and this can result in high misclassification rates and small-scale ‘noisy’ results. We demonstrate the use of multiscale spatial analysis (wavelet tessellation) as a pre-ML step to analyse spatial information. This step helps reduce misclassification and filter out unwanted small-scale variation in the data. In an experiment, we used wavelet tessellation and supervised ML to predict litho-geochemical rock types from geochemistry data. The data set is from the Valhalla uranium deposit near Mount Isa, northern Queensland. First, geochemical knowledge and statistical analysis was used to select appropriate geochemical elements for litho-geochemical classification. Second, the elements were processed using multiscale spatial analysis. Third, we trained a Random Forest model with the data set and found that the model performs worse in predicting rare rock samples than common ones. We applied over-sampling and down-sampling methods in aim to overcome this issue. As a conclusion, the combination of multiscale spatial analysis (to define rock unit boundaries) and Random Forests (to classify rock units) is a good method for rapid and accurate analysis of drill hole geochemistry.

Mar 22, 2022

By A. Thielen

In experiments for the production of steel the principal problem has always been the introduction into, or removal from, the iron of a definite quantity of carbon. Although the solution of this problem had engaged a more or less blindly and empirically directed effort for a long time, it was only with the development of analytical chemistry that the rôle which carbon plays in the constitution of steel was disclosed in its full significance, and that many of the problems confronting the steel-maker were thereby more clearly defined than before. For a long time, and to a certain extent even to this day, the percentage of carbon in steel has been the controlling means of deter mining its quality and hardness. In many cases the percentage of carbon alone has been relied on for judging large consignments, such as the large deliveries of wire-billets and blooms to America during the past twenty years; and though to-day the influences of the other constituents are recognized and many other considerations are taken into account, and though, moreover, some special steels, such as the Hadfield manganese steel, apparently dispense to a certain extent with the assistance of the carbon, yet fix our Bessemer, Thomas, Siemens and crucible steel the carbon still remains one of the most important constituents, and I venture to say it is indispensable. In order to produce in the Bessemer converter a steel of a certain required percentage of carbon, two methods, as is well known, present themselves. By the one the decarburization process is stopped when the desired carbon limit in the bath has been reached ; by the other the bath is completely decarburizecl, and then a calculated amount of carbon added in the form of spiegel, ferro manganese, etc. In Germany the latter method only was adopted, and it was retained when the Thomas-Gilchrist process for the production of low-Phosphorus steel from high-phosphorus iron eame into use, since from the nature of the new process complete decarburization is neces-

Jan 1, 1891

By M. Hopf

The use of water-cooled copper components as sidewall elements of submerged arc furnaces and other pyrometallurgical applications has become increasingly common. The high cooling efficiency of copper has made it possible to increase the service life of furnace refractories when compared to conventional refractory linings. However, even the self-healing effect of ?freezing? worn areas of the lining does not necessarily protect the copper coolers against wear or corrosion completely. In order to avoid furnace explosions, various methods have been used to monitor the wear of coolers. Unfortunately, these have not been able consistently to identify localized wear. Thos Begbie (South African) and SAVEWAY (German) jointly developed technology to embed a line sensor into the copper cooler during the casting process. This system allows an exhaustive monitoring of the copper cooler. A SAVELINE sensor is placed inside the copper-cooling panel between the water-cooling passage and the hot face of the panel. The sensor follows the meandering shape of the cooling water channels. In the first instance, the sensor provides analogue information as the thickness of the copper reduces. Secondly, this wear signal will be confirmed by a signal of interruption if the sensor is washed away. Because of the structure of the sensor, a self-diagnosis is possible and indications can be confirmed (double proofed).Subsequent to the manufacture of some test pieces, coolers for a large submerged arc furnace were manufactured. The sensorized coolers have been installed at the intermittent surface (slag line) where the largest amount of corrosion has been encountered. The system has been operating since December 2005 in what is considered one of the largest submerged arc furnaces in South Africa. Keywords: Pyrometallurgy, furnace, copper coolers, freeze lining, monitoring, Saveway

Jan 1, 2006

By Pengfu Tan

Converter slag chemistry control has played an important role in optimizing converter operations. A thermodynamic model of copper P-S converter has been developed to predict the behavior of magnetite in the converter slag. Predictions of bath temperature, slag and matte compositions, and magnetite content in the slag have been validated by industrial data. The effects of fluxing strategy, returns and skim charges, oxygen enrichment, and temperature on the magnetite formation in the slag have been predicted and discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2005

By N. Jayaraman, V. Srikant, A. Radhakrishna

Addition of a 500 MW unit to the existing units at Ramagundum Thermal Power Station requires blasting of large volumes of rock very close to sensitive installations like Turbo generator, Generator transformer and Power cycle equipments. Levelling of the areas and excavations for footings are, therefore, to be carried out cautiously. The existing sensitive installations should be protected against ground vibrations and flyrock. The paper describes the details of a few of the many blasts carried out successfully wherein the ground vibrations were restricted and flyrock was avoided.

Jan 1, 2003

By M. Krasowska, K. Malysa, M. Krzan

The paper presents fascinating, in our opinion, observations on mechanism and course of processes occurring during bubble collision with hydrophobic and hydrophilic solid surface. Hydrophobicity of particle surface is a necessary condition for the particle attachment to bubble. We have observed that even in the case of such hydrophobic solid surface as Teflon, the bubble attachment didn't occur at first collision. In distilled water the bubble bounced a few times without attachment. Influence of a-terpineol and n¬pentanol on bubble local and terminal velocity and the phenomena occurring during bubble collisions with hydrophobic and hydrophilic solid surfaces was studied. Bubble collisions with the solid surfaces were monitored and recorded using the high-speed (1182 frames per second) camera. It was found that in distilled water the velocity variations of the "approach-bounce" cycles were identical for Teflon and glass. Four distinct "approach-bounce" cycles were detected both at Teflon and glass surfaces. Moreover, the amplitude and frequency of the velocity variations were identical on collisions with the hydrophobic (polished) and hydrophilic surface. There was no immediate three phase contact formation, with the hydrophobic Teflon surface, what we found really astonishing. Roughness of Teflon surface seems to be important parameter, which affects probability of the bubble attachment as a result of a presence of micro-and/or nano-bubbles at the surface. It was detected that the presence of the micro-bubble affected attachment of the colliding bubble even in distilled water. Presence of a small amount of a-terpineol or n-pentanol affects dramatically the bubble velocity, but their role in mechanism of the bubble attachment needs further study.

Jan 1, 2004

By J. C. Li, Y. Zou, L. He

"The effect of rock joints is significant in characterizing dynamic behaviors of discontinuous rock masses. To reveal the relation between the transmission coefficient and the contact situation of the joint surface, an experimental study on stress wave propagation across an artificial rock joint was carried out using a modified Split Hopkinson Pressure Bar (SHPB) apparatus. All the bars and specimens were norite cored from the same site, and one surface of the specimen which contacted to the transmitted bar was sawn with a number of notches to simulate the artificial rough joint. According to a wave separation method, two strain gauges were mounted on each pressure bar at a specific spacing, then the incident, reflected and transmitted waves across the joints were obtained from the test data. It was found that the contact situation of the rock joint surface makes a different on the wave propagation. Finally comparisons of the transmission coefficients with different contact area ratios and different joint thicknesses were made respectively. The results show the effects of contact area ratio and thickness of joints on wave transmission.INTRODUCTIONJoints affect the dynamic mechanical behaviors of the rock masses significantly. When propagates across the rock masses, wave usually attenuates in amplitude and frequency due to the presence of the joint as a discontinuous interface in the rock masses. Rock joints are the main factor that affects the behaviors and properties of rock masses. Many researchers have focused on the mechanical properties of rock joints under quasi-static conditions. Nowadays, the effect of joint dynamic properties on wave propagation across rock masses is gradually taken into account in theoretical and numerical studies.The effective contact area, joint roughness, and properties of the asperities and filling materials have been found to influence the normal stiffness of joints (Bandis et al. 1983). As suggested by the International Society for Rock Mechanics (ISRM), the roughness of the discontinuities can be generally characterized by large-scale “waviness” and small-scale “unevenness” (Brown 1981). Many researchers focused on the roughness of rock joints that affects the mechanical properties of rock masses and wave propagation. For example, Brown and Scholz (1985, 1986) presented theoretically and verified experimentally a closure model of contact between two random nominally flat elastic surfaces, which showed that the joint closure property depended both on the surface topography and material properties. Pyrak-Nolte et al. (1997) presented the quantitative aperture data for three-dimensional interconnected fracture networks, which were imbedded in intact opaque rock samples several centimeters in length, using x-ray computerized tomographic (CT) imaging. Fardin et al. (2001) systematically investigated the effect of scale on the surface roughness of rock joints and concluded that samples should be equal to or larger than the stationary limit for surface roughness to be accurately characterized on a laboratory scale or in the field. Zhao et al. (2006) conducted excellent ultrasonic tests across intact cement mortar specimens, singlefracture specimens, and two-fracture specimens."

Jan 1, 2015

By Roma T. Dec

Many industrial wastes may require preliminary processing to change their particle size, density, surface properties or flowability to become more suitable for treatment and recycle. This can be achieved by pressure agglomeration using roll presses. In the following paper an overview of various roll press processing methods like briquetting, compacting, compacting-granulating or densification is presented together with basics of process and equipment design. The emphasis is focused on major factors influencing compaction process and responsible for pressure build up and final product quality. Finally, two examples of roll press application for briquetting of steel plant wastes and compaction of alumina base catalyst tailings are introduced.

Jan 1, 1996

Frank Williams, Johnstown, Pa. (Communicatioll to the Secretary): As the manager of the company which manufactured the " American " magnesite and the silica-brick mentioned by Mr. Pennock, I beg to say that he was quite right in placing a mark of interrogation after " American " (page 268). While the users of magnesite in this country are at a disadvantage as to cost by reason of not having any large bodies of sufficiently pure material at hand, the manufacturing concern referred to has secured an advantage as to quality by a mixture of the different foreign magnesites, which vary considerably in their composition and physical structure. The American (?) magilesite tested was a sample of the next

Jan 1, 1897

By S. A. Pirzada

A thermal plasma assisted laminar flow reactor has been used to evaluate the kinetics of converting alumina to sodium aluminate in flight. Free energy minimization calculations were used to determine experimental conditions. The experimental variables include: alumina particle size, alumina/sodium nitrate molar ratio, temperature and residence time. A mathematical model for the conversion was developed and validated. Experimental and mathematical results are presented.

Jan 1, 1996

By Dominic Ammon, Mark Rothbauer, Paul Landers P. E.

Across the Potomac River from the location of the DFI47 Annual Conference (October 2022), in Alexandria, VA, two large permanent anchored walls with a decorative shotcrete face were recently constructed for the North Hill project, a new multi-family and townhome development. The project was executed with a design-build approach for the Fairfax County Redevelopment and Housing Authority with review by the Fairfax County Geotechnical Review Board. The project was constructed in highly variable Potomac group sediments that include high plasticity clay/silt terrace deposits overlying coarser grained materials. The soils were over consolidated and exhibited potential for slickensides from relief of horizontal stresses from past erosion. The wall system was designed to include deep soldier piles and permanent long strand anchors considering past slope instability in the area. As the construction progressed, problematic soil conditions and water issues required modifications to drilling methods. The two permanent walls spanned 800 and 1,000 feet long with a maximum height reaching 40 feet.

Oct 1, 2022