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Development of the Boleo Process Flow Sheet and the Direct Solvent Extraction (DSX) Circuit for Cobalt and Zinc Recovery The metallurgical process designed to treat the El Boleo Cu-Co-Zn-Mn ore involves a sulphuric acid leach in seawater under oxidative and then reductive conditions to maximise metal extraction. Copper and cobalt are recovered as cathodes by electrowinning, zinc and manganese as zinc sulphate monohydrate and high quality manganese carbonate, respectively, by precipitation after a number of separation and purification stages. One of the key purification stages of the Boleo metallurgical process is the CSIRO DSX circuit. The DSX circuit was developed using the synergistic solvent extraction (SSX) technology. Initially, a synthetic solution was studied, and by adding 0.4 M LIX63 to 0.5 M Versatic 10 in Shellsol D70, large synergistic shifts were obtained for cobalt (?pH50 4.24) and zinc (?pH50 1.62). After a single contact, the separation factor of metals over manganese reached over 6,000 for cobalt and over 380 for zinc, indicating excellent separation of cobalt and good separation of zinc from manganese, magnesium and calcium. The SSX system was further optimised with the modified synthetic pilot plant solution. The extraction of cobalt and Zn after a single contact was 93 per cent and 70 per cent, respectively, while the Mn concentration in the loaded organic solution was only 0.28 g/L. A proof of principle pilot plant operation was conducted in 2004 and a demonstration pilot plant for final engineering design in 2006 with outstanding performance of the DSX circuit. For the demonstration pilot plant, the overall recovery of cobalt and zinc exceeded 99 per cent with a raffinate containing only 4 mg/L Zn and 1 mg/L Co. The DSX organic system showed no sign of degradation during the pilot plant operation, indicating good chemical stability under the anticipated commercial operating conditions. The DSX circuit will be implemented in the future Boleo processing plant.

Sep 13, 2010

By Kyle A. Kershaw

The City of Grand Forks, North Dakota obtains drinking water from both the Red River and Red Lake River through a system of raw water intakes, shallow pipelines, and pump stations. However, during flood events, the City often loses access to the system, as evidenced during the record flood event in 1997. As a result, the City decided to construct a new gravity raw water intake system, including a pump station at the base of a 65-foot-deep, 60-foot-diameter caisson, behind a new levee system. Because of high design flood elevations and connectivity of river head to underlying soils, uplift resistance was required for the caisson. A total of 37, 2-foot-diameter, augered cast-in-place (ACIP) piles were chosen to provide uplift resistance. Because of the difficulties associated with installation of piles within the confined space of the constructed caisson and basal stability concerns, installation was completed from the existing ground surface to a depth of 120 feet. Several design and construction issues arose, including squeezing ground during pile installation, placement of long reinforcing bars, and installation of a dual material pile. A dual material pile was required to ensure that the ACIP pile below the base of the caisson was structurally sound and the pile above the base of the caisson could be easily excavated during sinking of the caisson. This paper discusses the solutions to each of these issues, as well as construction sequencing, load testing and integrity testing of the ACIP piles, and the successful completion of the project.

Jan 1, 2003

By Francis E. Federspiel

Bureau of Mines personnel examined mines, prospects, and mineralized areas to determine the mineral resource potential of the Log Cabin Saddlebag, Hall Natural Area, Horse Meadow, and Tioga Lake RARE II areas in Mono County, California. These areas, along the east slope of the Sierra Nevada, are underlain by Paleozoic metasedimentary and metavolcanic rocks of the Log Cabin Mine and Saddlebag Lake roof pendants. The roof pendants are in Cretaceous granitic rocks. Pleistocene volcanic flows cap some of the older rocks, and glacial till and outwash locally cover the bedrock. The region was eroded by alpine glaciers. Four parts of the Log Cabin Saddlebag area have moderate gold and silver resource potential. Moderate potential for gold and silver resources was identified in one part of the Hall Natural Area and low potential for tungsten and molybdenum in two other parts (fig. 1).

Jan 1, 1982

By Deshmukh A. M.

Existence of human beings and their relationship with the nature is symbiotic. The lack of perspective and negligence of nature disturbs the equilibrium of environment and causes unprecedented disasters. Geotechnical engineers are directly concerned with hazards of nature as elements of foundation and of nature are inter related. Rational design and construction of foundation can be accomplished only after properly assessing influence of environment This paper briefly delineates impacts of environment and human activities and presents salient features of management of impacts through the system of deep foundation. Limitation of negative effects and enhancement of positive developments necessitates eco-consistent planning of engineering projects based on the geotechnical aspects of environmental impact management.

Jan 1, 1996

By H. Eklund, R. T. Hukki

This article presents a simple arithmetic derivation for the relationship between sharpness of classification and circulating load, as well as world-wide industrial data which are compatible with the derived equation. It is shown that the sharpness of classification decreases with increasing circulating load. Based on the evidence available a comparison is presented between the performance of the present-day hydraulic classifiers. In a continuously operated closed circuit grinding system the tonnage and the fineness of the components may be indicated as follows: Eq. 8 expresses the relationship between sharpness of classification and circulating load in closed grinding circuits. If CL = 0, E = 100% according to the definition used. This, however, is a purely theoretical case because any apparatus to be called a classifier must produce the conventional two products. Furthermore, if CL = m, E =0%. In order to visualize the meaning of Eq. 8, the effect of factors d (fineness or percentage of under-size of classifier overflow at size x) and b (fineness or percentage of undersize of classifier sands at size x) should be studied. By the most rigid standard, factor d should be given the value of 100%. By so doing the size of classification is defined as that screen size x through which 100% of the classifier

Jan 1, 1965

By Gene E. McClelland

4.1 INTRODUCTION Metallurgical testing is required on any ore, waste or tailing material before amenability to heap leaching treatment can be accurately determined. The amount of testing necessary to determine and optimize heap leach amenability and conditions for any feed material is determined by the ore type, grade, size of deposit, and the overall financial commitment a particular company is willing to make. It is very easy to either "under-test" or "over-test" a particular deposit or feed material. A good heap leach testing program will provide the necessary design information without "bogging" down in too much detail. The three basic stages of ore testing include: • Preliminary--bottle roll tests and small column percolation leach tests; • Detailed--larger column tests, different feed sizes, and feed size optimization; and • Pilot-Scale--Column or field heap. The following subchapters describe the stages of heap leach testing necessary to put a viable property into production. 4.2 PRELIMINARY METALLURGICAL TESTING The two types of preliminary tests that can be undertaken include bottle roll or cyanide agitation tests and small column leach tests. Each of these is described below, along with information about what the test results provide in terms of furthering knowledge of ore qualities. 4.2.1 Bottle Roll Tests The first step in a heap leach testing program is preliminary bottle roll tests at a relatively coarse feed size to determine the ore's leachability. Bottle roll tests are usually conducted on reverse circulation drill cuttings samples (= 1/4 inch (6 mm) in size). Bottle roll tests provide initial information about precious metal recovery, recovery rate, and reagent requirements. The recovery results are to be considered maximums because attrition grinding creates fines and liberates recoverable values that would not be liberated from the material during a static leach. Bottle roll tests can be conducted on up to 25 lb (11 kg) ore charges of up to two inches (50 mm) in size. However, the coarser the feed the more attrition grinding occurs during rolling.

Jan 1, 1988

By S. L. Miller

The development of a pilot gold geostatistical ore reserve system proved that geostatistical methods worked well for the routine production of annual ore reserves on gold mines of the Gold Fields of South Africa (GFSA) group, and that the techniques could also be practically implemented, understood and accepted by Survey Department personnel. Many side benefits of the pilot system became apparent, and a variety of useful management information was provided by manipulating the data values that were already captured. It was decided that it was a priority computing project to develop a standard production system (GORS) for routine use by all the GFSA gold mines. Experience with the pilot system enabled detailed functional specifications for GORS to be laid down. These, together with group computing policy determined the terms of reference and constraints for the GORS development. System design could not be finalized until new and appropriate mainframe database software and graphics workstation equipment and software had been found. With these in place the basic system was structured to take best ad- vantage of the interactive features of the workstation, the number-crunching power of the mainframe and the flexibility offered by a relational database and associated 4GL tools. Application sub-systems were developed for data capture, statistical applications, geostatistical calculations, contour plotting and graphical queries. GORS is being introduced to the mines in a phased manner with suitable documentation, training and support structures to enable it to be routinely and effectively used on a day-to-day basis by all group gold mines.

Jan 1, 1987

By T. V. Lord

Minerals containing uranium have been successfully pre-concentrated by flotation at Queen's University, Kingston. In particular, uraninite, uranothorite, euxenite, and fergusonite, have responded to flotation to yield grades of 0.2 to 6.0 .per cent U .o. with recoveries of 85 to 98 per cent, from heads analysing approximately 0.10 per cent U3Os. Of the ten or so radioactive samples examined to date, two distinct groups were recognizable, firstly, those samples in which uranium was the sole constituent of economic interest, and, secondly, those in which Columbium (with minor amount of tantalum) was present in addition to uranium. For the purpose of this paper, the results of investigation on two samples of each of the above groups have been selected as typical.

Jan 1, 1945

By S. K. Das, A. J. Gesing

This paper provides an overview of North American markets for magnesium and aluminum alloys along with life cycle material flow diagrams. Additionally, we review the production processes of magnesium and its alloys from various magnesium-bearing raw materials, including scrap. The main focus of the paper is on the collection, recycling and processing of post- and pre-consumer metal scrap containing magnesium. We discuss the latest status and economic analysis of RE-12™, a scrap-based process for recovering magnesium from aluminum alloys and its potential application to can sheet, automotive (body and closure sheets) and aluminum foundry markets.

Mar 1, 2017

By Mustafa Kumral, Mehmet Balci

Strategic mine planning focuses on cutoff grade selection, capacity planning and block sequencing. Despite significant knowledge accumulated, potential value can be added to mineral sourcing by addressing various aspects. A case study on a metallic deposit with a lognormal grade distribution examines if grade/metal distribution influences cutoff grade selection. Six data sets with different shape and scale factors, but the same ore tonnage and metal quantity, are analyzed. Results indicate deposits with lower shape and scale factors are more sensitive to metal price and discount rate changes. The study also investigates the effect of economies of scale (EoS) on project value, focusing on the ratio of variable cost to total cost (capacity factor). Two regression analyses are conducted for optimal capacity planning and cutoff grade selection. The first shows capacity planning is highly sensitive to the EoS of mining and mineral-processing costs, with grade variability and metal distribution being negligible. In the second analysis, grade variability and EoS of mineral processing costs are vital for cutoff grade selection.

Sep 1, 2024

By R. Trueman, D. B. Tyler

Numerical modelling was used to determine the magnitude and direction of stresses around drives both adjacent to and distant from open stopes in the South Crofty tin mine. Modelling predicted that drives near the stopes are situated in a stress-relaxed zone. The peripheries of drives that are sited in solid rock away from the influence of stoping are in compression. Key-block modelling was used to determine the typical geometries of critical blocks and distinct element modelling was used to determine block stability. The conclusions derived from modelling fitted the observational data. This indicated that key-block theory is a valid tool for analysing the stability of roadways in the South Crofty mine. The support requirements for drives located next to stoped-out areas were formulated using a risk analysis approach to key-block formation. The results were compared with support guidelines derived using empirical design methods. Good agreement was obtained for the roofs of the drives but not for the sidewalls. The concept of a critical excavation width was formulated: once an excavation is larger than the critical size the length of rockbolts need not be increased as the excavtion dimensions increase. This may be the case in all rock mases.

Jan 4, 1993

By O Omidi, P D. Katsabanis

The effect of delay time on fragmentation has been discussed for a long period but rarely in a satisfactory and unbiased way. Despite the efforts of many researchers, delay selection for fragmentation improvement or optimisation remains a controversial issue. Large-scale tests have been plagued with scarcity and scatter of observations, while small-scale tests have been associated with boundary effects and energy losses. Theoretical work is often used to produce explanations for available measurements or tries to simplify wave propagation and wave interaction to guide observation and practical work. The present work analyses results obtained from a relatively large number of small-scale experiments in blocks made of grout, and re-analyses results of previous experiments, to conclude on the effect of delay on fragmentation. It is shown that the main contribution of the delay is found in the fragmentation of the larger fragments of the blast, while the small fractions show almost no effect. Samples, where copper liners were used to inhibit penetration of detonation products in the rock mass, showed effect of delay only when short times were used and steady but poor fragmentation when long delays were used. Based on small-scale experiments, it appears that the fragmentation is optimised when a hole fires prior to the radial cracks, produced by the previous hole, reach the free face of the blast. Gas penetration may result in the development of few more fractures that affect the fragmentation of the largest particles of the blast.CITATION:Katsabanis, P D and Omidi, O, 2015. The effect of delay time on fragmentation distribution through small- and medium-scale testing and analysis, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 715–720 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Martin P. Raffield

Placer Domes? Campbell Mine, situated in northwestern Ontario, is undergoing an assessment of the efficiency of the operation which is necessitated by the low gold price and a reducing ore reserve grade. A decision has recently been taken to move away from a functional based departmental structure (underground, engineering, geology, etc.) towards a team-based system where crews, engineers, geologists and supervisors are responsible for the planning and operation of a particular area of the mine. The objective is to improve communication and understanding of the goals and achievements and to ensure a forum is available for the generation of ideas. It is intended to increase the accountability and decision-making ability of the teams in an effort to achieve the mines? safety and production targets. This paper presents a critical review of the progress of this organisational change process and its successes and failures at the time of writing.

Oct 1, 2001

By T. P. Lim, A. J. Vivyurka, N. K. Davé

Chemical and radioisotope stratification studies were carried out in an abandoned uranium tailings pile at Elliot Lake, Ontario, Canada. The tailings, with an average thickness of 7 m over an area of 16 hectares, were deposited approximately 20 years ago on a layer of black peaty material which overlays deposits of permeable glaciofluvial sands. Geohydro-chemical investigations of this tailings area have been ongoing since 1978. The radioisotope profile study was conducted on three adjacent sites. Solid core samples, collected with a split spoon sampler at various depths, were analyzed for various chemical and radioisotope constituents. The results indicated by 2 distinct zones of stratification; an upper zone, where the constituents were uniformly distributed, and a lower zone, near the peat-tailing interface, which showed increasing concentration with depth. Within the peat layer, the concentration decreased rapidly with no significant levels of contaminant penetration below the peat layers observed, though the samples were limited. The pH profile showed that the top 5 m of the tailings have been oxidized, the average soil pH in this zone was 3.4 compared to 5 .8 underneath it. The groundwater hydrology of the system was observed to be complex showing downward and lateral flow in the dry season and lateral and upward flow during the spring and periods of heavy rainfall. The results are discussed in terms of a model based on the combined segregation and settling process of the tailings fine fraction, and the geohydro-chemical interaction of the solid and liquid phases.

Jan 1, 1981

By Kaustubh Joshi, Pradip, Beena Rai, Kesri L. Menaria, Venugopal Tammishetti

"Beneficiation of alumina rich iron ore slimes is a major challenge for the Indian iron ore industry. High alumina is deleterious for the performance of both blast furnace as well as sintering plants. Slimes generally contain 5 - 10% alumina, and hence despite assaying as high as 60% Fe, those are dumped in tailing ponds. The slimes are typically less than 37 microns. Selective flocculation of iron ore slimes using highly selective reagents is thus an option worth exploring. Our research is directed at employing state-of-the-art molecular modeling techniques for the selection/design of selective reagents for this separation. We have earlier reported our results on starch as a selective flocculant for iron ore slimes. In this paper, we present our results on the selective dispersion-flocculation of natural iron ore slimes using guar gum flocculant. With careful selection of various process parameters such as flocculant dosage, dispersant dosage, pH and settling time, we were able to obtain a concentrate assaying >66% Fe and <3.5% Al2O3 with an yield of 65 to 68% (recovery of iron values more than 70%) from a natural iron ore slime sample assaying 58% Fe and 7% Al2O3."

Jan 1, 2014

By John M. McAnerney

In 1955, the U.S. Army started to experiment in Greenland with tunneling in glacial ice and later in frozen glacial moraine. By 1960, long adits and experimental rooms had been successfully excavated. Full mechanization with coal-cutting machinery was most efficient in ice but drilling and blasting were necessary in bouldery moraine. In 1963, the U.S. Army Cold Regions Research and Engineering Laboratory, (USA CRREL; redesignated U.S. Army Terrestrial Sciences Center July 1, 1968) started a tunnel in the frozen silt of central Alaska near Fairbanks. The original adit of 360 ft (109 m) was successfully driven in the permafrost by a twin-rotor tunnel-boring machine, the Alkirk Cycle Miner. The workings were enlarged in 1966 and 1967 by standard mining techniques in which jackhammers, steam points, and augers were compared. A mechanical coal cutter was tried to supplement drilling and blasting. In 1968, airblasting techniques were used successfully for breaking out the frozen silt. All mine products were loaded mechanically and hauled by self-dumping shuttle car. Pneumatic methods of transport were tried for both dust removal and for conveying blast products up to 3-in. maximum size. Studies of the effects of natural winter ventilation through a shaft showed that tunnel closure could be reduced by lowering the adjacent ground temperature. It is concluded that underground openings in frozen ground should be cut and maintained at well below freezing temperatures to hold deformation to a minimum. HISTORICAL BACKGROUND This chapter deals with aspects of tunneling not previously discussed in the conference papers in this book. The chief differences are that the three tunnels lie entirely within frozen material and are relatively small, since they were constructed mainly for research. The primary objectives of the research were to develop underground shelters for military per-

Jan 1, 1970

By J Nortier, J Dray

There is no single factor that determines the appropriate capacity for a mining project. It is driven by the size of the resource, the capacity of the market, the availability of capital, the availability of power, the availability of water, and a myriad of other considerations. There is also no single solution to the question of how big the project should be. However, to develop a project, the study team needs to select the configuration options that it regards as the best for the project. To be able to make this selection, the study team should consider the range of available options and do so at a level of detail that gives it confidence in the conclusion but does not lead to multiple detailed design exercises. Having considered the range of options, and with a clear definition of the project owner’s objectives and constraints, the work to be carried into feasibility studies can be focused appropriately. This paper discusses the process of completing strategic mine planning to identify project configuration options to assist in the selection of the processing plant throughput rate (Capacity Study) for a large greenfield open pit mine. The processes described in this paper allow for the basis of design to be set for subsequent studies that meets the objectives at a risk profile acceptable to the owner.

Jun 22, 2022

By Frederick Crabtree

WHEN Professor Stock asked for a paper on the above subject, it was too late to prepare by June 1, or near that time, one that would involve any appreciable amount of experimental work or original research; but the suggestion was made that a review of the literature bearing on the subject might be submitted in good time, and that later this could be supplemented by any experimental data obtained during the summer, if experiments were carried out. In accordance with this suggestion, there are submitted the following notes on references found in the literature of recent years bearing on sulfur in gas. It is to be, understood that, ill general, these notes express the opinions of the authors whose papers are abstracted, not necessarily the opinions of the abstractors. Very little published information was found bearing directly on producer-gas sulfur, so this has been supplemented, in certain phases of the subject, by references to illuminating gas. Methods of analysis and processes for the elimination of sulfur from the gas are, without much doubt, very closely related in these two products. As in illuminating gas, sulfur is found in producer gas mainly as hydrogen sulfide, mixed with a much smaller and variable quantity of carbon bisulfide.1 The presence of minute quantities of other organic-sulfur compounds has been intimated, but no definite statement is made concerning these. The amount of sulfur present in producer gas is variable and depends on several conditions. The primary factor is the quantity of sulfur in the fuel, but the form in which the sulfur exists, the temperature of the producer, the air-steam ratio, and the efficiency of the scrubbing process are all determining factors. When the coal used contains less than 0.5 per cent. of sulfur, the sulfur in the gas will not exceed the quantity found in the average illuminating gas.2 Sulfur in producer gas may safely

Jan 9, 1919

By J. M. Roberts, N. Brown

The stress-strain behavior of zinc single crystals was measured over a strain range of 10-6 to 10-2. The phenomenon of macroyielding was observed in detail and plastic strains were detected at almost zero-stress. Closed hysteresis loops were observed during loading and unloading in the strain region of about 10-5. From the hysteresis a frictional stress on the dislocation of about 6 psi was obtained. A preliminary analysis indicates that impurities are primarily responsible for the friction. Nonelastic Strains as much as 10 -4 were recovered depending on the amount of prior deformation. Part of the recovered strain occurs instantaneously upon unloading and the remainder occurs at zero stress. The time dependence of the recovered strain was measured. THIS investigation is concerned with the details of plastic deformation preceding the ordinary yield point as measured with the usual strain sensitivity of about 10-4. The approach leads to internal friction observations in the hitherto neglected frequency range below 10-1 cycles per sec. It is believed that if the phenomenon of macroscopic yielding is to be understood, then the stress-strain curve in the neighborhood of the macroyield point should be greatly magnified. It may then be possible to determine whether macroscopic yielding is a unique event or whether it is a process which begins gradually at a lower stress. In the case of low-carbon steel a unique event obviously occurs at the macroscopic yield point as indicated by a drop in the load, but copper appears to exhibit a gradual transition from the elastic to the plastic state. In zinc the yield point is rather abrupt although the data indicates that some plastic deformation precedes large scale yielding.&apos; One of the purposes of this investigation is to determine whether there is an abrupt transition from the preyield microstrain region to the region of macroscopic deformation. Such a rapid transition would support the concept that there is a critical stress for yielding. The concept that yielding is a unique event associated with such phenomenon as activating a Frank-Read source, freeing the dislocation from solute atoms, dislocations cutting through dislocations, or dislocations moving freely by one another, has been expounded widely on theoretical grounds. It is hoped that highly sensitive measurements of strain in the neighborhood of the macroscopic yield point will shed some light on the event known as the "Yield Point". EXPERIMENTAL METHOD 1) Specimens—High-purity zinc was cast into spherical graphite moulds in air and grown into spherical single crystals by the Bridgman method under a positive pressure of Argon gas. Spectro-graphic analysis of cleaved sections from four crystals showed a purity of 99.994 pet Zn. The specimens were acid machined with an 1/8 in. gage section in a form similar to those used by Parker and co-workers.2 Bausch type grips were fastened to the specimen by Epon VI adhesive. The specimens were oriented so that only [1120] (0001) slip occurred. Fig. 1 shows two of the specimens in the grips. Prior to each test, the gage section of the specimen was given a concentrated HNO3 chemical polish followed by alcohol rinsing and air blast drying. 2) Test Method- The shear tests were performed on an Instron testing machine and the experimental set-up was made very "hard". Strain could be measured to a sensitivity of 10 -6 by means of a capacitance gage extensometer. The design and calibration of this type of extensometer to measure microstrain, as applied to pure shear and tensile tests of metals, will be the subject of a separate paper—therefore, only a brief account will be presented here. The method essentially consists of attaching a

Jan 1, 1961

By Samir Garcia, Alain Mestanza

This technical work was carried out in an open pit copper mining unit, located in central Peru, which has a daily production of 440 thousand tons per day. Currently the pit consists of three mining phases, however, in phase 05 north, there is the construction of a shaft with a height of 375 meters, the function of this structure is to collect and drain the water coming from the pit, there is the importance of preserving its stability and keeping it operational, guaranteeing the sustainability of the operation. For this, a controlled blasting plan was developed that goes from level 4530 to level 4455 to place the central well on a bench, reactivating the pools.

Jan 21, 2025