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By C. M. Shigley

The record of the largest magnesium plant in the country utilizing sea water as a primary raw material stands as another victory in the struggle for large-scale production of pure chemical elements from the oceans. Bromine was the first element to be economically and commercially recovered when, in 1933, a six million pound per year unit was built on the Atlantic Coast near Wilmington, North Carolina, by the Ethyl-Dow Chemical Co.' The bromine was reacted with ethylene to produce ethylene dibromide, a necessary associate of tetraethyl lead in ethyl antiknock fluid. Within eight years that plant was doubled and redoubled, and another large unit was put into operation at Freeport, Texas, taking bromine from the Gulf of Mexico. In 1940, in fortunate anticipation of the impending demand for magnesium and the limitations of the production from natural brines, the Dow Chemical Co. turned again to the sea, and designed and erected a plant at Freeport to produce 18,000,000 lb. of magnesium per year from sea water.2 In March 1941, two months after the new plant had been put into successful operation, construction of an 18,000,000-lb. Government-financed addition was started. Late in 1941, as a part of the $400,000,000 defense program intended to produce 600,000,000 to 700,000,000 lb. of magnesium per year, Dow was asked to build and operate for the Government a 72,000- ooo-lb. plant near its original plant at Freeport. Within a few days after the Japanese made their attack at Pearl Harbor, preparation of a site was started at Velasco, Texas, for the construction of the Texas plant of the Dow Magnesium Corporation—the largest known magnesium plant utilizing sea water as its raw matcrial. Less than six months after the first piling was driven, urgently needed magnesium was in steady production. Five months later, the plant had exceeded its rated capacity. It remained above rated production until the general magnesium curtailment was applied to Government-owned plants in September 1944. Credit for the construction and operation record of the Dow magnesium plant must be divided among the efforts of a very determined group of men, an extremely favorable location, and a simple process. It is with the two latter aspects of the plant that this article will deal. The site for the new enterprise was chosen near Velasco, Texas, on property bordering the Brazos River at a point approximately 6 miles inland from the original magnesium plant and 7 miles inland from the Freeport Harbor on the Gulf of Mexico. This location was far enough away from the operating units to reduce both interference from construction and the vulnerability of closely bunched manufacturing operations to the then feared air attack. Yet the distance inland was not too great for the economical construction of a barge canal from the harbor to serve both the transportation of raw

Jan 1, 1949

This section is addressed to the computing needs of corporate (top) management which are less specialized than the computing needs of operating or divisional management described in the previous sections. It is essential that the computer be used as a tool to serve corporate management and that information and results are presented in a succinct form. A key responsibility of the manager of computer applications is to communicate well with corporate management. A common trap for computer management is to allow the development and implementation of sophisticated and academically interesting computer applications which do not enlighten corporate management in its decision-making task. Thus it is essential to devote sufficient time and effort to designing and specifying a computer system before developing and implementing the system.

Jan 1, 1979

By Y K. Leong

Occasionally additives are used in the wet processing of iron ore tailings and slurries, for examples, in the thickening of tailings with flocculant to recover process water, and in the smooth pumping of concentrated slurries. They can mitigate slurry behavioural issues that could significantly affect the plant operation and production. The nature of iron ore business requiring the plant to have a high throughput to be economical, large amounts of slurries are therefore processed every day. The quantity of additives needed will correspondingly be large and so are the associated costs. This could have a significant impact on the plant profitability. If additives are used they must be very costeffective. NaOH is among the lowest cost chemicals available, at ~US$400 per ton. In this paper we will look at use of composite additives involving phosphate compounds with NaOH added to reduce the cost, for the control of iron ore slurries rheology. The NaOH worked synergistically with the phosphate compounds. The effectiveness of these composite additives in viscosity reduction can be neutralised by another cheap additive such as lime or a Ca(II)-based salt turning the slurries back to being a paste. Tailings paste is an ideal material for safe storage in the dam. These composite additives can also be used to facilitate the recovery of iron ore at commercial grade from tailings (Leong, 2020a, 2021a).

Sep 18, 2023

By S. W. Parr

FRom a study of sulfur with reference to its specific combination in coal, published as University of Illinois Bulletin No. 111, 1919, it is now possible to determine the various forms of this constituent with a good degree of accuracy. This fact suggests two questions: (1) Are the same analytic methods applicable to coke? (2) Is there any correlation between the forms of sulfur as it occurs in coal and the residual sulfur found in the finished coke? The answer to the second question might be helpful in answering a still further question as to what chemical route the sulfur travels during the carbonization process. While the special studies along these several lines are by no means complete, a few preliminary statements are herewith presented. They may, at least, prove suggestive of further possibilities from a continuation of research along these lines. There is no reason, chemically, why the analytic methods devised for coal should not apply to coke and a fair amount of experience in connection with such use affords confirmation of this statement. The procedure in the case of coal may be briefly outlined as follows: Combinations of sulfur as sulfate, or sulfides other than FeS2, are readily dissolved without disturbing either the pyrite sulfur or the sulfur that is in organic combination by means of dilute hydrochloric acid— 1 part of concentrated HC1 to 10 parts of water or approximately 3 per cent. acid. Digestion at 60" C. for 24 hr. insures the complete removal of the sulfur thus combined. In freshly mined coal the amount of such sulfur is very small; weathering processes, however, may very materially increase the amount of sulfate present. Sulfur in the form of iron pyrites, or marcasite, may be quantitatively removed without oxidation of the organic sulfur as follows: A dilute solution of nitric: acid is prepared having 1 part of concentrated HNO3 to 3 parts of water or with an approximate specific gravity of 1.12. The coal sample, ground to 100 mesh, is digested with this solution at room temperature for 3 or 4 days, filtered and evaporated to dryness, taken up with water, and acidified with hydrochloric acid. It is now ready for precipitation with barium chloride in the usual manner. If sulfate is present in the original sample to an appreciable amount, it should be removed by the procedure outlined above. It is not necessary here to give the methods for determining the two

Jan 1, 1920

By John J. Sense

The Mission unit of the American Smelting and Refining Co., located 20 miles south of Tucson, Ariz., is a high-volume, 15,000 tpd operation which utilizes a relatively light equipment fleet. As such, management is very conscious of the mechanical and operational availability of the equipment in use. One of the key items in attaining this efficiency is a complete and reliable record of mechanical and operational machine availability which is an invaluable guide for: 1) Estimating future equipment and personnel requirements of an operating property. 2) Planning an expansion program of an operating property. 3) Estimating equipment and personnel requirements of a new property. 4) Selection of replacement equipment. 5) Comparison of separate operating properties.

Jan 3, 1964

By Rolf Andreas Lauten, Guy Kluck

"Formation of scales may have important detrimental effects in many mineral processing applications. A well-known problem is the need for frequent maintenance to remove scale from processing equipment. Another challenge may relate to encapsulation of valuable minerals in precipitating scale. In this work, we explore the ability of some crystal growth inhibitors to prevent or lower the degree of scale precipitation. In many situations pregnant leach solutions contains substantial concentrations of calcium, magnesium, sulfate and carbonate in addition to dissolved valuable elements, e.g. gold, copper, zinc. Together with non-dissolved gangue minerals, some slurries may also contain particulate gold, copper etc. During normal processing of the pregnant leach solution it may be exposed to temperature gradients or similar promoting precipitation of various scales. Valuable minerals may become entrapped in precipitates and thus become inaccessible to the lixiviant. Use of a crystal growth inhibitor may lower the degree of encapsulation of valuable elements.Using a simple model system, supersaturated with respect to gypsum, the effect of some crystal growth inhibitors on the prevention of scale is evaluated in terms of amount precipitated gypsum, the particle size of the precipitated gypsum and the carbon gold loading capacity.INTRODUCTIONGold bearing sulfide ores are often roasted or pressure oxidised prior to leaching. The purpose of this unit operation is to prevent loading the leaching circuit with sulfides that consume cyanide. Pressure oxidation or roasting chemically converts the sulfides into sulfates and at the same time, the pH of the slurry ends up in the acidic range. Typically, lime addition is the preferred means to raise the pH to around 10 where gold leaching takes place. Combination of large amounts of calcium ions from the lime with sulfate ions from the ore induces precipitation of gypsum. Compounds like calcium carbonate may also precipitate if carbonate ions are present in the slurry. Depending upon the composition of the ore, compounds like calcium carbonate and other types of scale may also precipitate on gold surfaces on the slurry particles. A layer of scale on top of exposed gold surfaces will prevent dissolution in the cyanidation that takes place during leaching. Naturally, such a precipitation may lower the gold recovery."

Jan 1, 2016

By S. Kauvosaari, M. Olofsson, O. Haavisto, M. Kosonen, J. Martikainen

The target in grinding circuit operation is usually to maximise the throughput and energy efficiency while keeping the product particle size on an optimal level for downstream operations. Furthermore, feed ore variations in size and hardness need to be compensated in order to stabilise the process. This is a challenging task for any circuit and requires good instrumentation, combined with careful control design. This study investigates the control of a two-stage iron ore grinding circuit with an AG and pebble mill at LKAB Kiruna KA3 concentrator in northern Sweden. A new control approach based on multivariable model predictive control (MPC) is designed, implemented and evaluated for the circuit. Additionally, advanced instrumentation including a volumetric charge measurement for grinding mills is utilised. The MPC control approach starts with step tests that are used to model the effect of manipulated variables (MVs) like feed rate, water addition and primary mill speed on controlled variables (CVs) such as final product particle size, power consumption and volumetric charge of the mills. In the control implementation phase, the models are then utilissed together with current process measurements and known operating limits to predict optimal future changes for the manipulated variables in order to reach the desired process output values. It is shown that the new control approach improves the stability of the circuit and reduces energy consumption. Keywords: Model predictive control, grinding, optimisation

Jan 1, 2020

By François Charette

High stress conditions in weak rock masses lead to large deformation and breakdown of the rock material, while stress release events in hard rock mines can lead to sudden and usually violent rock failure. Typical support systems combine various reinforcement and support mechanisms to provide the required convergence control and retainment, but results are often mitigated by failure of surface liners, shotcrete and tendons. The paper reviews differing requirements of support and reinforcement for different failure types. In addition, the mechanical performance of a new reinforcing tendon is presented and analysed in view of the field requirements. Field tests results are presented.

May 1, 2011

By V. Nasri, P. Jarast, M. Bakhshi

The Montreal metro Blue Line Extension toward the northeast consists of the construction of five new underground stations. The project includes 6 kilometers of the tunnel which will be constructed using a Tunnel Boring Machine (TBM). In line with the commitment to integrating sustainability best practices, Envision verification is pursued this project. The Envision reference framework was developed to cover all the sustainable development aspects of an infrastructure project and each phase of its life cycle (planning, design, construction, operations and maintenance, and end-of-life). As a part of this endeavor, low-carbon concrete and shotcrete mixtures are proposed for the linings of TBM and SEM tunnels as well as stations and auxiliary structures. The CO2 emission of the low-carbon concrete and shotcrete mixtures were compared with their typical mixtures and the total CO2 emissions reduction related to the tunnel lining is determined. The study is of strategic significance for achieving emission reduction in the tunnel industry.

Jun 13, 2023

By D J Williams

Coal washery wastes comprise tailings, finer than 0.5 to 0.1 inn depending on the sophistication of the washery, and coarse reject, typically finer than 50 mm. Subaerial disposal of coal tailings slurry at about 30 per cent solids by mass results in the formation of a delta with an average slope of about 1 in 100, representing one extreme. The ravelling of coarse reject on loose-dumping, results in an angle of repose slope with an angle of about 37" (1 in 1.3), representing the other extreme. The pumped co-disposal of coal tailings and coarse reject results in the formation of an upper delta with an average slope of about to one in ten, between the two extremes. The depositional behaviour of these three waste streams is discussed and compared in this paper. The important depositional and material parameters, and a theoretical description of the processes involved, are also presented. Comparisons are made between the depositional behaviour of the various coal washery waste streams, and natural depositional systems, such as rivers, alluvial fans, and scree slopes.

Jan 1, 1998

By R. T. Stain

Dynamic methods of load testing piles using a drop hammer to generate the input force have been in use for many years. These systems are based on the wave equations developed at the Case Institute of Technology, Cleveland, Ohio in the late 1960's and are well documented. Such tests are generally restricted to preformed driven piles, the driving hammer being a convenient means of generating large input forces. In 1979 the CEBTP (France) was sponsored by the FNTP (Fédération Nationale des Travaux Publics) to undertake research into existing classical methods and to develop a test that would be equally applicable to bored cast in place piles. The result of this research programme is a methodology known as SIMBAT, and which was included in a series of class A prediction trials in Belgium in 1987 (Refs 1 & 2, Paquet 1987, 1988). The purpose of this paper is: a) to examine the type of 'dynamic'/'static? load test correlations that can be obtained. b) to highlight the differences between the classical' methods and the 'SIMBAT' technique.

Jan 1, 1989

By G S. Lane, G D. Richmond, J Dioses

This paper discusses the methods used in the design of flotation plants, including benchscale batch and locked cycle tests and pilot plant trials. Two case studies are presented, one for the Cadia Hill Gold Mine and the other for the Hellyer copper, zinc and lead plant. These case studies present different problems with widely different target grind sizes, liberation characteristics and HellyerÆs sequential flotation circuit versus CadiaÆs æsimpleÆ copper/gold flotation circuit. They have a common theme in that pyrite forms the principal floatable concentrate diluent. Hellyer ore contains finely disseminated chalcopyrite, sphalerite, galena, and tetrahedrite. The flotation plant design was based on extensive benchscale testwork (including locked cycle tests) on drill core and many months of operation of a 30 tonne per hour æpilot plantÆ, using the old Cleveland Tin Mine process plant suitably modified for the duty. The Cadia concentrator was designed on an extensive benchscale variability testwork program, approximately a dozen locked cycle tests conducted on drill core and two weeks of continuous pilot plant trials on three separate samples obtained from an adit into the orebody. The orebody is a monzonite porphyry with disseminated chalcopyrite/bornite/pyrite of very low grade (0.17 per cent Cu, 0.73 g/t Au). Methods used to establish the appropriate flotation circuits for the treatment of the Hellyer and Cadia ores, as well as the interpretation of the testwork data, are discussed in this paper. Plant performance is reviewed in the context of predicted versus operational performance.

Jan 1, 2002

By Tim Martin, Dave Tahija

"In April, 2014, Hecla's Greens Creek mill, near Juneau, Alaska, switched from sulphuric acid to the use of dissolved carbon dioxide for lead flotation circuit pH control. The Greens Creek mine uses paste backfill, in which mill tailings are mixed with cement and used to fill mined areas. Some backfill inevitably becomes part of mill feed during subsequent mining cycles, resulting in high feed pH levels and increased dissolved calcium in the lead flotation circuit. Sulphuric acid is traditionally used to lower pH in such cases but it produces undesirable side effects, including poorer lead-zinc separation and unstable froth. The amount of sulphuric acid used at Greens Creek was limited due to these effects, resulting in higher than target pHs when feed backfill content was high. Dissolved carbon dioxide can be added without these limitations so pH levels have been under much better control since the switch. Additionally, lead-zinc separation and froth characteristics have significantly improved.IntroductionThe Greens Creek Mine, owned by Hecla Greens Creek Mining is an underground mine located on Admiralty Island near Juneau, Alaska, producing silver, gold, lead and zinc in the form of lead and zinc flotation concentrates and a gravity gold concentrate (McDonald, Morgen & Hancock, 2012). The lead and zinc concentrates are produced in conventional flotation circuits preceded by a graphite removal flotation step.The underground mine utilizes cemented paste backfill, of which a certain amount is inevitably re-mined in later mining cycles and returned to the mill, mixed with fresh ore. The Portland cement used in the paste backfill is highly basic so that, from the point of view of the mill, the net effect is to introduce a good deal of lime to run-of-mine mill feed, producing a very high natural pH. This high pH needs to be lowered to obtain good metallurgical results."

Jan 1, 2016

By J. A. Zimrner, R. J. Tirnko

The roles of main mine fans in underground mines are to induce airflow and continuously re- move hazardous gases and dust. While most larger mines use multiple fans to accomplish these tasks, many smaller mines employ only a single fan. This paper concentrates on those mines having only one fan to provide ventilation needs. If this fan should cease to function, it is likely that methane concentrations will in- crease in some areas of the mine. As a safety precaution, Federal Regulations require that personnel must be- gin evacuating the mine within fifteen minutes after fan stoppage. Powered haulage can be used to transport workers to the mine portal as long as travel is through areas where hazardous levels of methane are not expected. To determine where methane will accumulate along haulageways during a fan stoppage, air samples must be taken at specific areas and analyzed for hazardous gases. During this study, procedures were developed for measuring methane levels along the haulegeways that are used to exit a mine following stoppage of the main mine fan. Methane levels were measured in four different mines at selected underground locations during four planned fan stoppages. In these mines the measurements taken only at the specified locations showed that, if workers had used electrically powered haulage to exit the mine following a fan stoppage, the methane accumulated along haulageways during fan stoppages would not have significantly increased the risk of an ignition.

E. S. BARDWELL,* Great Falls, Mont. (written discussion ?).-There are several points in. connection with the manufacture of ferromanganese in the electric furnace which it seems to me. might prove of interest in this connection. Recent observation of a, number of electric furnaces varying considerably in size and transformer capacity, and all working under the same conditions, shows the small furnaces to be much more efficient in operation than the large furnaces. The furnaces examined were all of the same type. The crucibles consisted of tanks varying in size from 71-z by 15 ft. by 4 ft. deep, to 12 by 20 ft. by 9 ft. deep, with linings formed of carbon electrode butts. The smaller furnaces had transformer capacity rated at 1500 k.v.a.; the largest furnace had a transformer rated at 3000 k.v.a. All of the furnaces were operated on three-phase, 60-cycle current, the three electrodes being in a straight line. The voltages varied from 65 volts in the smaller to 100 volts in the larger furnaces. The charges consisted of manganese ore, coal, iron turnings, and limestone in proper proportions. The small furnaces, operating at low voltage, were making good recoveries. The slag loss was low and the volatilization loss almost nil. The larger furnaces, operating at higher voltages, showed increased loss of manganese in the slag and greatly increased volatilization loss when working on the same charges as the smaller furnaces, or on charges similarly calculated. The exact reasons for this state of affairs are difficult to state; a number of factors probably contribute to the results obtained in the large furnaces. First as to the effect of the higher voltage on manganese content of the slags. Increasing the voltage of the furnaces apparently tends to promote irregular working. The current takes the path of least resistance; this means superheating in certain areas in the crucible and insufficiently high temperatures in adjoining areas. The partially reduced manganese in the cooler areas passes into the slag and escapes further reduction.

Jan 11, 1918

By Robert W. Waytulonis

This publication contains 1,000 citations of technical and semi-technical literature treating diesel-powered equipment usage underground both generally and specifically. These citations were gathered by U.S. Bureau of Mines personnel over the period of 1978-1983. The citations concern diesel engines as powerplants for underground mining use; their design, emission characteristics and control, maintenance, usage; and health and safety aspects. All citations have been abstracted and arranged 1n a subject classification system with extensive cross-referencing.

Jan 1, 1983

By E. P. Jennings

Large deposits of titaniferous iron-ore occur at Caribou, an old silver-mining camp in Boulder county, Colo., 17 miles west by south of Boulder, and a few miles northwest of the tungsten-mines. Professor Regis Chauvenet1 published a part analysis of the ore many years ago, but gave no description of the wall-rock. Caribou hill, which contains both the silver-bearing veins and the iron-ore deposits, is a low dome of gabbro surrounded by the Archæan schists and gneisses of the Front range of the Rocky mountains, the peaks of which, a few miles west of Caribou, attain an elevation exceeding 12,000 ft. The gabbro stock is roughly elliptical in outline, with approximate diameters of 1 and 3 miles. The crest of the dome is 10,500 ft. above sea-level, and the town and ore-cleposits are 500 ft. lower. Outcrops of the iron-ore occur in the town and extend NW. for 2,000 ft., where they disappear under the swampy meadows of Caribou park. Portions of the deposit are covered by drift, but one continuous outcrop is 900 ft. long and from 200 to 250 ft. wide. A second deposit is 0.25 mile south of the town along the eastern slope of the hill. It is not as well defined as the north bed, but is approximately 1,000 ft. long and from 100 to 200 ft. wide. The easily disintegrated ore does not form prominent outcrops, but the outlines of the deposits are readily traced by the large amount of ore fragments that cover the ground. Trenches and pits sunk on the outcrop expose a roughly banded magnetic iron-ore, with pyroxene as the principal gangue-mineral. The Gabbro. This rock was classified in the field as a gabbro from the presence of pyroxene and striated feldspars, and for convenience the field-name will be retained.

Jan 1, 1913

By Moorrees C

The end uses of magnesia are determined by both its chemical and its physical proper- ties. There is seen to be an increasing need for products of high chemical purity. Prod- ucts containing 90-95 per cent MgO can be routinely produced by physical beneficiation and calcination of most magnesite ores, the dominant source of magnesia. However, pro- duction of grades containing more than 98 per cent MgO with low impurity levels is not readily achieved physically. Such products can only be readily produced by chemical processing techniques. This presentation outlines the types of impurities present in magnesite deposits and the general concepts that are involved in chemically upgrading them. Of the potential leachants, only hydrochloric acid and aqueous carbon dioxide appear to be commercially attractive.

Jan 1, 1987

By Doug Smith, Ross MacFarlane

"The Star Lake Mill was commissioned by Cameco (formerly Saskatchewan Mining Development Corporation) in 1986 to process a small high grade gold deposit in a remote location of Northern Saskatchewan. The lean approach to the 200 t. p. d. CIP mill to minimize capital and operating costs employs a number of unique features which are described along with highlights from the initial two years of operation.1.0 INTRODUCTIONThe Star Lake Mine is located 520 kilometers north of the City of Saskatoon (Fig. l) with the nearest population centre in La Ronge 130 km to the south. Gold showings were first discovered in the area in the 1940's with the Star Lake ""21 Zone"" ore body discovered in 1983. The Star Lake Mine started operations in 1986 becoming the first primary gold producer in Saskatchewan in over 40 years. The mine is operated by Cameco (formerly SMOC) with 50\ ownership in a joint venture with starrex Mining Corporation (35\) and Uranerz Exploration and Mining (15%).The limited reserves coupled with the remote location and the price of gold ($300-$350 u.s./oz) at the time the project feasibility was being assessed required a lean approach to make the short term operation successful. This paper describes the approach taken in the design and construction of the Star Lake Mill and describes the mill operation with highlights of the initial two years of operation."

Jan 1, 1989

By Venda Oliveira P. J., Correia A. A. S., Danisi C. M.

"AbstractA laboratory study has been undertaken to establish common understanding of the creep phenomenon of a Portuguese soft soil chemically stabilised with binders. In order to study the effect of different stress levels on the strength and on the creep behavior of the stabilised soil, oedometer creep tests and unconfined compressive tests were performed at different curing times. Results show that the creep stress level does not influence the unconfined compressive strength. In addition, the creep phenomenon increases the unconfined compressive strength of the treated soil. Two different secondary compression indexes were recognized from the one-dimensional compression curve which increase with an exponential trend with the creep stress level.IntroductionConstruction on soft soils requires a mandatory soil stabilization work to improve mechanical characteristics of the natural soil. Deep mixing method is a worldwide employed ground improvement method, nevertheless the creep phenomenon hasn’t been yet thoroughly analyzed. Most of the published papers have focused on the analysis of the compressibility and the strength of the soil-binder mixtures without considering the creep phenomenon. However, numerical results (Venda Oliveira et al. 2009) have shown that although settlements that occur during the creep stage (namely creep strains) are less in case of treated columns, they are still important especially due to the high loads applied to the stabilised soil. The few published studies about creep behavior of soil-binder mixtures reveal that the stabilization of an organic soil with cement induces a reduction of creep deformations, which is related to the amount of cement used and that the increase of the organic matter of the soil has a negative impact on soil stabilization, further inducing a slight increase in the creep deformations (Venda Oliveira et al. 2012).As part of the current research the effect of different stress levels on the creep behavior of a soft clayey-silt soil was studied. The binder mixture used to enhance the properties of the soil had a specific composition and quantity. Unconfined compressive strength tests (UCS) and UCS creep tests were carried out at pre-set curing times in order to analyze the creep behavior of the soil-binder mixture. In particular five different creep stress levels were studied to understand its influence on the strength and on the compressibility of the stabilised soil. In addition, considerations about the secondary consolidation index are also presented."

Jan 1, 2014