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By S. H. Castro

In 1997 Chile was the world's largest copper mine producer with around 3.4 million metric tomes of copper. Conventional technology (conminution-flotation- smelting-converting-electrorefining) for copper sulfide ores was used. For copper oxidized ores hydrometallurgical processes (heap leaching-solvent extraction- electrowinning) were employed. Consequently, the most important waste effluents include flotation tailings, gaseous emissions, smelter slags, acidic and alkaline wastewater, electrolytic sludges, solid residues from leaching, etc. The introduction of stricter environmental regulations are forcing the Chilean industry to minimise the generation of waste and promote cleaner production. Gas emissions such as SO2 and arsenic from smelters and process wastewater are the major problems at this stage. The environmental impact assessment of gas emissions in all six largest smelters namely Chuquicamata, Caletones, Potrenllos, Ventanas, Paipote and Chagres led to design a "decontamination plan." The implementation of this plan resulted in (i) the installation of sulfuric acid plants for SO2 abatement and (ii) the installation of electrostatic precipitators to remove arsenic oxides condensed from cooling gases. The aim of this paper is (i) to describe the type of waste associated to the various stages of the metallurgical processes and (ii) review the main abatement technologies used in medium and large size companies.

Jan 1, 1999

By Rafael Errazuriz

About eighty miles north of the city of Antofagasta, Chile, located just below the Tropic of Capricorn, there spreads a wide desert area where copper oxide outcrops can be seen with the naked eye. Numerous old mining works and dump heaps with the green of atacamite and chrisocolla shining in the blazing sun, attest to the work done by miners in the beginning of this century. The dry desert air preserves the footstep marks, paths and trails of old cartwheels from years back. The mining area known as Michilla and Panizos Blancos, is located on the high plateau at 3000 ft above sea level. Around 1920 a Bleichert ropeway was built, which carried ores from the best known mine to a wharf at the Michilla bay. High grade silicious ores were shipped to the Gatico Smelter further north or to smelters in the United States or Japan.

Jan 8, 1973

By Robert W. Freedman, Benjamin I. Ferber, Wayne H. Duerr

Vacutainers are employed by the Bureau of Mines and the Mining Enforcement and Safety Administration for sampling mine air and other atmospheres containing fixed gases, low-molecular-weight hydrocarbons, and products of combustion. Tests were conducted to study shelf life of evacuated samplers prior to sampling and also to check the stability of sampled gases prior to analysis. An unexplained phenomenon, slow accumulation of carbon monoxide in evacuated samplers, occurred after a few weeks' storage; levels were low but increased with time and could pose a problem for critical applications. Accordingly, attempts to halt CO release by additional means of treatment were made, and storage at low temperature was found to be effective.

Jan 1, 1978

By Richard L. Gordon, Charles J. Johnson

Electric power demand doubles about every ten years, and because of the associated burgeoning fuel requirements, power stations absorb over half of the coal output in the United States. Throughout the 1960's, demand for coal utilized to generate electricity grew at an average annual rate of 6.5% but coal producers held back greater expansion because they expected nuclear plants to proliferate faster than they actually did. Even so, the growth rate is expected to continue at the 1960's rate until at least 1976. The continuation of the 6.5% growth rate beyond 1976, however, will require additional orders for coal-fired plants during the early 1970's. In fact, plants consuming a total of 130 million tons of coal must be ordered in the next few years. If the requisite plants materialize, total 1980 coal output for electrical power generation will be approximately 600 million tons.

Jan 1, 1971

THE problem of reaction rates in the open-hearth process is essentially that of trying to form a fairly clear picture of the "chemical mechanisms" in the bath. Quantitative data on reaction rates would not be very useful even if they were available; however, what few , approximate data there are, can be used in combination with data given in Chapters XVI and XVII to sketch a picture of the "chemical mechanics" of the open-hearth process that is consistent with essentially all the present available evidence. The result may later be found incorrect in many details but even so it will illustrate certain useful methods for obtaining a clearer understanding of the process. As discussed in the last portion of Chapter XIII chemical reactions in general involve the following factors: 1. The reacting molecules are mixed together in space in such fashion as to favor collisions among them. 2. A certain number of collisions occur per unit time among the reagent molecules, depending on their concentration and on temperature. 3. A certain percentage of these collisions result in reaction, these being the collisions between those molecules possessing at the moment energy levels above certain minimum values. The temperature factor enters mainly through (3), and its effect is very marked. (What is called temperature is really the mean energy content of all the molecules of the substance involved; at any one temperature a certain proportion of the molecules will have much higher energy content than the mean value.) Various reaction rates measured at around room temperatures have been found to be speeded from 1.6 to 4.0 times by an increase of only 15 to 20°F., simply because increasing temperature produces a rapidly increasing percentage of molecules with energy levels above the minimum needed to produce chemical reaction in a collision.

Jan 1, 1944

By Ben. B. Cox

The principal events during the year consisted in the exploitation of the Kirkuk field, the regular operation of the four-million-ton pipe line to the Mediterranean, and the discovery of low-gravity oil on three other structures in the West Tigris (Shergat) area. The Iraq Petroleum Co., Ltd. continued the systematic exploitation and exploration of its Kirkuk field, maintaining a carefully unitized operation. Bottom-hole pressure differentials and low gas-oil ratios were maintained. All crude was produced by flowing The cleaning up following the construction of the Mediterranean pipe line, which began deliveries in August, 1934, was completed during the first quarter of 1935. The line easily maintained its rated capacity for the remainder of the year. The Mosul Oilfields, Ltd., through its operating subsidiary, the B.O.D., Ltd., expanded its exploratory organization from 9 to 16 drilling rigs and discovercd 20" A.P.I. crude on the Sadid, Hibbarah and Qasab anticlines. Whether these discoveries will be commercial pools remains to be proved. The Qaiyarah-Najmah-Jawan field, which was discovered by the I.P.C. in 1928, was extended arid production was found in the Eo-Cretaceous as well as the "Main Limestone" (Eocene, Oligocene and Lower Miocene). Gas caps were found under each of the crests of the West Tigris structures. Negotiations are in progress between the Mosul Oilfields, Ltd. and the Iraq Government for the extension of the Anatolian Railway from the Turkish border to Mosul, with a view to tanking the heavy West Tigris crude to the Mediterranean. The subsidiary of the Anglo-Iranian Oil Co., Ltd.', the Khanaqin Oil Co., Ltd., continued to operate its Naft Khaneh field near the Iranian (Persian) border to supply the local Iraq market through the Rafidain Oil Co., Ltd. Somewhat more than 28 million barrels of crude was produced in Iraq during 1935. Crude delivcred to the pipe line for export during the years 1934 and 1935 was: Year BaRrels 1934................................................. 7,096,669 1935................................................. 27,014,904 Total as at Dec. 31, 193.5.............................. 34,111,573 ° Converted at an avcrage of 7.0 bbl. per ton.

Jan 1, 1936

The principal events during the year consisted in the exploitation of the Kirkuk field, the regular operation of the four-million-ton pipe line to the Mediterranean, and the discovery of low-gravity oil on three other structures in the West Tigris (Shergat) area. The Iraq Petroleum Co., Ltd. continued the systematic exploitation and exploration of its Kirkuk field, maintaining a carefully unitized operation. Bottom-hole pressure differentials and low gas-oil ratios were maintained. All crude was produced by flowing The cleaning up following the construction of the Mediterranean pipe line, which began deliveries in August, 1934, was completed during the first quarter of 1935. The line easily maintained its rated capacity for the remainder of the year. The Mosul Oilfields, Ltd., through its operating subsidiary, the B.O.D., Ltd., expanded its exploratory organization from 9 to 16 drilling rigs and discovercd 20" A.P.I. crude on the Sadid, Hibbarah and Qasab anticlines. Whether these discoveries will be commercial pools remains to be proved. The Qaiyarah-Najmah-Jawan field, which was discovered by the I.P.C. in 1928, was extended arid production was found in the Eo-Cretaceous as well as the "Main Limestone" (Eocene, Oligocene and Lower Miocene). Gas caps were found under each of the crests of the West Tigris structures. Negotiations are in progress between the Mosul Oilfields, Ltd. and the Iraq Government for the extension of the Anatolian Railway from the Turkish border to Mosul, with a view to tanking the heavy West Tigris crude to the Mediterranean. The subsidiary of the Anglo-Iranian Oil Co., Ltd.', the Khanaqin Oil Co., Ltd., continued to operate its Naft Khaneh field near the Iranian (Persian) border to supply the local Iraq market through the Rafidain Oil Co., Ltd. Somewhat more than 28 million barrels of crude was produced in Iraq during 1935. Crude delivcred to the pipe line for export during the years 1934 and 1935 was: Year BaRrels 1934................................................. 7,096,669 1935................................................. 27,014,904 Total as at Dec. 31, 193.5.............................. 34,111,573 ° Converted at an avcrage of 7.0 bbl. per ton.

Jan 1, 1936

By George Burgess

THE Pyrometer Committee was. formed Sept. 20, 1918, at the suggestion of Dr. H. M. Howe, Chairman of the Engineering Division of the Research Council, for the purpose of developing a pyrometric method suitable for open-hearth steel practice so that the effects of temperature in the various stages of the processes of steel making might be correlated quantitatively with the other factors influencing the production of sound .steel. As finally constituted the Committee consists of Dr. George K. Burgess, Chief Division of Metallurgy, Bureau of Standards, Chairman. Dr. Paul D. Foote, Chief of Pyrometry Section, Bureau of Standards, Secretary. Dr. H. M. Howe, Chairman Engineering Division, National Research Council, ex officio. Prof. G. H. Clevenger, Chairman Metallurgical Section, National Research Council, ex officio. Mr. F. E. Bash, Leeds & Northrup Co., Philadelphia, Pa. Mr. R. P. Brown, The Brown Instrument Co., Philadelphia, Pa. Prof. G. H. Brown, Rutgers College, New Brunswick, N. J. Mr. R. C. Drinker, metallurgical engineer, Boston, Mass., Dr. W. E. Forsythe, Nela Research Laboratory, Cleveland, Ohio. Mr. J. T. Hall, Taylor-Wharton Iron & Steel Co., High Bridge, N. J. Mr. J. S. McDowell, Harbison-Walker Refractories Co., Pittsburgh, Pa. Mr. Malcolm McNaughton, Joseph Dixon Crucible Co., Jersey City, N. J. Mr. A.' H. Miller, Midvale Steel Co., Philadelphia, Pa. Mr. F. E. Walduck (since deceased), The Norton Co., Worcester, Mass.

Jan 9, 1919

By R. E. Whitehead, G. J. Prior

"Abstract -Biotite from aplite that appears to have crystallized simultaneously with disseminated Cu-Mo mineralization at MacLeod Lake in northern Quebec yields K-Ar dates in the range 2032 ± 44 Ma to '2f1:)1 ± 47 Ma. The mean value, 2065 Ma, is some 400 Ma younger than the 2485 ± 64 Ma date obtained from a hornblende concentrate separated from a granodiorite sill that is spatially, but apparently not genetically, associated with the disseminated Cu-Mo deposit. The mean biotite date of 2065 Ma at MacLeod Lake, a K-Ar date of 2055 Ma reported from an area 50 km east of MacLeod Lake and published dates of about 2000 Ma for galenas from the Chibougamau Cu-Au ores, suggest a widespread thermal and mineralization event, in that part of the Superior Province east of James Bay, that differs from the common late Archean mineralization that is related to volcanism and metamorphic-intrusive activity.Sommaire - Les datations au K-Ar sur des biotites qui auraient cristallisé en même temps que la minéralisation disséminée en Cu et Mo dans une aplite mise en place au Lac MacLeod, au nord du Québec, s'échalonnent entre 2032 ± 44 Ma et '2f1:)1 ± 47 Ma. La datation moyenne, soit 2065 Ma, est d'environ 400 Ma plus récente que la datation obtenue pour un concentré de hornblende extrait d'un fùon-couche de granodiorite qui est spatialement mais ne serait pas génétiquement as­ sociée à la minéralisation disséminée en Cu et Mo. La datation moyenne de la minéralisation au Lac MacLeod, soit 2065 Ma, la dataion au K-Ar à 2055 Ma citée pour une région à 50 km à l'est du Lac MacLeod, de même que les datations d'environ 2000 Ma établies pour des galènes qui se trouvent dans le minerai aurifère et cuprifère à Chibougamau, suggèrent un phénomène thermique répandu qui aurait produit la minéralisation dans cette région à l'est de la Baie James, dans la province du lac Supérieur. Ce phénomene serait différent de celui qui aurait produit la minéralisation répan­ due d'âge archéen tardif qui elle serait associée à l'activité volcanique et à l'activité intrusive accompagnée de métamorphisme."

Jan 1, 1992

By P J. Dailey, S L. Burchell, R F. Chiappetta

High-speed motion picture photography and its application to the mining, quarry, construction, and explosive industries has proven to be a valuable diagnostic tool. The techniques developed allow one to evaluate blasting performance, compare explosive efficiencies in relation to burden velocity, and estimate optimum delay times to provide adequate forward relief.

Jan 1, 1983

By Kazuhide Nakaniwa

In this research, we devised a measurement method using total stations (TSs) which have ?the Baum? which is a concentric circle reticle, as substitute for crosshairs. The Baum owes its name to the similarity between the concentric circles and trees (Baum in German). By setting one circle on both of edges of cylinders, operators can set their sights on points on the center line of the cylinders, and also can measure positional coordinates of the points. Also, by measuring two different points on the center line, operators can measure the position and tilt of the axes of the cylinders. Furthermore, we developed a pile driving navigation system. Foundation piles are used for various structures, and their forms are generally cylindrical. Especially, although it is difficult to drive tilted pile foundations, their usage are expected to expand due to their high earthquake resistance. Yet, a method to accurately measure the tilts of piles has not been established. However, we proved that operators can obtain adequate accuracy to control foundation piles through the measurement experiment using this system. Using this system, the information of the pile is measured using a TS, transferred to a PDA, and displayed from the operator?s view of the piling machine.

Aug 1, 2013

By Werner A. Ruemmele

Eisenhower Memorial Tunnel, called Straight Creek Tunnel during construction is located 60 miles west of Denver, Colorado at 11, 160 ft. elevation. It is 8, 510 feet long, and carries two lanes of 1-70 traffic under the Continental Divide. This paper describes improvements and changes made in construction methods for utilities, concrete lining, ceiling, wall covering and paving to allow maximum offsite fabrication and activity overlap resulting in a one-year faster completion for traffic. The substantial changes proposed on a design-and-construct basis by the contractor and put into effect after State approval were: 1. Substitution of ductile iron and thick-wall P.V. C. pipes for clay pipes allowing placement and operation before hole-thru. 2. Outside pre-assembly of large rebar mats, using a novel tension-splice with cable clamps. 3. Arch concrete placement method modified to make 4, 322 ft. of lining in 10 weeks possible. 4. Safety barriers precast and epoxy coated offsite instead of cast-in-place and tile faced. 5. Prestressed hollow ceiling slabs with porcelainenamel coated steel sheets assembled offsite, instead of in-place glazed tile and in-place cast concrete ceiling. 6. Glazed tile wall panels 8 ft. long by 11 ft. high assembled off site and erected using vacuum pad mounted on special lift. 7. Asphalt paving while other work proceeded, instead of reinforced concrete slab and asphalt overlay. Work started in January 1968, but advance came to a one-year standstill for major structural redesign and negotiations of a new agreement during 1970. Using multiple drift construction followed by top-heading and bench excavation, it then progressed to hole-thru in July 1972. As a result of art 18-month overlap of activities the tunnel was opened for traffic only eight months later in March 1973. Gibbons and Reed Company of Salt Lake City, Utah sponsored the joint Venture of Al Johnson-Gibbons and Reed-Western Paving-Kemper during 1971, 1972, and 1973. The tunnel was the subject of a previous paper delivered at the RETC '72 in Chicago by R. C. Hopper, T. A. Lang, and A. A. Mathews, describing geology, unusually severe structural loading and multiple-drift tunnel excavation.

Jan 1, 1974

By M. Muskat, H. H. Evinger

A METHOD of calculating productivity factors for oil, gas, and water systems in the steady state is presented as an illustration of the quantitative application of the fundamental data on the flow properties of heterogeneous- fluid systems. While the numerical results of the calculations cannot be applied directly to field conditions, because they are based on permeability data for unconsolidated sands and involve specific assumptions regarding the nature of the reservoir fluids, the methods of analysis and interpretation should have significance in considering certain specific field situations when the necessary field and laboratory data become available. Moreover, it is felt that even under the idealized conditions to which the numerical calculations refer they should serve to give at least the orders of magnitude of the effects of gas-oil ratio and connate water on observed productivity factors. Within the indicated limitations, the computations imply that the foregoing factors can explain only a part of the apparent discrepancy between the homogeneous fluid productivity factors and those obtained recently in field measurements on the West Coast.

Jan 1, 1942

By Albert Sauveur

(Cleveland Meeting, October, 1912.) ALTHOUGH many metallurgists know that some pearlitic special steels can be made troostitic, martensitic, and even austenitic, without quenching, and, therefore, without exposing them to the dangers of the quenching-bath, the practical significance of such possibility does not seem to have received the attention it deserves. Let us recall briefly the mechanism of the transformation alluded to. In Fig. 1 (after Guillet) is shown the constitutional diagram of nickel-steel that; is, of alloys of iron, carbon, and nickel. Any steel the composition of which falls within the area LPO is pearlitic after slow cooling; any steel the composition of which is represented by a point within the area MLO is martensitic, and any steel within the area MNO is austenitic. Starting with pearlitic steel, then by increasing the carbon-content or the nickel-content, or both, the metal becomes martensitic and eventually austenitic; that is, its composition crosses first the boundary-line LO and then the line M0-and it remains martensitic or austenitic after slow (air) cooling.1 We have inn this way imparted to the metal without quenching it the properties of hardened carbon-steel. In other words, the steel is now self-hardening. Nickel cannot be introduced into solid steel, but by the well-known process of case-hardening it * Professor of Metallurgy and Metalllography in Harvard University. + Assistant in Metallurgy and Metallography in Harvard University. 1 The boundaries between the various zones are not, as a matter of fact, as sharp as indicated in the diagram, because pearlite is not transformed abruptly and in its entirety into martensite when a certain critical composition is attained, nor is martensite suddenly and completely converted into austenite. Greater refinement in the construction of the diagram would undoubtedly result in the introduction of troosto-pearlitic, troostitic, and troosto-martensitic zones between the pearlitic and martensitic areas and-of a martenso-austenitic zone between the martensitic and austenitic areas. Fur the purpose of this note, however, the existence of these transition-conditions may be ignored.

Nov 1, 1912

By Matsuo T, Uga Y

The tunnelling work to construct a sewage trunk line designed by the Sewage Bureau of Kobe City along north side slope of Rokko mountain range incorporated an all ground condition type (broad spectrum) TBM with slurry transport system with jet pump manufactured by Kawasaki Heavy Industries, Ltd. Boring dia. of the tunnel measured to 2.0 m. The construction planning and implemen- tation were done by Ohbayashi Corporation, the general contractor. The heading way was 3342.4 m in overall length.; construction work ran from April '84 to June '85. The max. daily progress marked 31.9 m and the max. monthly progress 493.1 m according to the relevant record. The machine proceeded with the work under geological conditions featured with conglomerate, rhyolite, tuff breccia and slate, whereby soft soil zone mostly of clay was encountered in a limited area. In the latter case, however, steel segments were substituted for supporting steel ribs. The tunnel was routed beneath a meandering road with the result that more than 40% of overall length show a curvature of 50 to 200 m radius.

Jan 1, 1987

By Reynold Q. Shotts

Chemical methods, based on the relative rates of oxidation of fusain, bright coal, and dull coal by nitric acid, have been devised to determine these coal components.1-4 Results obtained by oxidation methods for fusain have been checked against results obtained from microscopic methods on duplicate samples of the same coals, but to the author's knowledge this has not been done for bright and dull coal components. For this reason it is not certain that the two methods of analysis identify essentially the same chemical or physical units. It would be highly desirable to see results of the application of both methods to duplicate samples, but in the absence of any such data the author has attacked the problem indirectly. From the U. S. Bureau of Mines samples were obtained of three Alabama coals which the USBM had analyzed optically and reported on over the past 30 years. These samples were subjected to analyses by oxidation rate methods. Results of this work, and comparisons with the USBM analyses, have been published. This was the first indirect approach to the problem. The present report attempts a second indirect approach by way of internal validation.

Jun 1, 1955

By William M. Clark

In 1988, the Chemical Manufacturers Association (CMA) launched Responsible Care®, a program of guiding principles created to address the publics' concern about the manufacture and use of chemicals. The Product Stewardship Management Practice code is a key component of the program. Along with the other five comple­mentary codes - Community Awareness and Emergency Response (CAER), Pollution Prevention, Employee Health and Safety, Process Safety, and Distribution - it has been initiated to protect the health and safety of member companies employees, neighbors, customers, the public and the environment. Possibly no other Management Code requires greater collec­tive effort or comprehensive commitment to implement than Product Stewardship. With its mandated cradle-to-grave control, every employee is required to consider all of the potential cir­cumstances involving product and processes, from raw material supply to customers final use or consumption of product. Degussa Corporation, a long time CMA member, fully endors­es the Responsible Care initiative and is most active in imple­menting the various codes. In fact, the guiding principles of the program are an integral part of the company's business strategy. Degussa recognizes that its long-term success and the health of each of its products, the company and the chemical industry itself, is contingent on the successful implementation of the program. Furthermore, the company believes its role in society and the economy can only be justified and sustained if it improves the overall quality of peoples' lives. Consequently, it is a dictum that Degussa products must provide a net benefit over their entire life cycle - from inception to final disposal - both in terms of their utility and their impact on health, safety and the environment.

Jan 1, 1998

By Clarence O. Babcock

This Bureau of Mines report presents the initial development of a two-dimensional method of analysis for inclusions in plates in which the deformed shape of an open hole and the separate structural behavior of inclusion and plate with hole are used to obtain the stresses and strains in the inclusion only. In this report the solution for a circular inclusion is presented because a direct verification of the results with previous solutions was possible. The numerical results were in exact agreement with those obtained with the equations of Sezawa and Donnell. The equations developed are less complex than those of Sezawa and more general, for a circular inclusion, than those of Donnell. Stresses and strains in the inclusion are in terms of the elastic constants of the inclusion and the plate and the biaxial stress field applied far away. The elastic constants can be all different. An important conclusion from this work is that a difference in Poisson's ratios between inclusion and plate may be as important as a difference in Young's moduli between inclusion and plate in producing the inclusion effect. Many problems in mining and rock mechanics can be treated as inclusion problems. The understanding of inclusion behavior on a physical basis should provide the solutions to some of these problems.

Jan 1, 1974

By Cuthbert Musingwini, Adeodatus S. Nhleko, Mahlomola I. Mabala

Optimization of a three-dimensional (3D) underground stope layout is complex given the number of variables and constraints to consider, such as the stope size. Determination of the appropriate stope size in stope layout optimization problems is a complex process that must consider several factors including placement of infrastructure and development, production scheduling, and equipment selection. An inappropriate stope layout can result in unrealistic expectations for a production schedule, consequently negatively affecting the derived economic value. Therefore, this paper used a dual interchange algorithm (DIA) to evaluate the effect of stope size on the stope layout economic value (SLEV) for a synthetic Platreef mineral deposit planned for extraction using sublevel open-stoping. The results showed that generally as the stope size increases, the SLEV decreases. This aligns with practical mining because larger stope sizes have a higher chance of incurring more dilution which reduces economic value, while smaller stope sizes enable more flexible extraction where unprofitable blocks can be left unmined as waste, thus increasing the derived SLEV.

Jun 25, 2023

By Anthony Iannacchione

One of the more pressing engineering problems for deep longwall mines in the Southern Appalachian Basin is to design longwall systems that will eliminate catastrophic coal pillar failure from the working environment. The purpose of this study is to quantify the behavior of a particular size abutment pillar prone to burst or bump. Because the 24.4-111 (80-ft) square abutment study pillar is within the pillar size commonly used in this region, understanding the behavior of this pillar should aid in future efforts to design optimum mining strategies. This research has attempted to construct the pillar stress and roof-to-floor convergence profiles in order to evaluate the ultimate strength, deformation modulus, visco-elastic deformation, and violent failure characteristics of the pillar during longwall mining. This information reflects the overriding influence of the local geologic characteristics on bursts, provides the field measurements needed to verify concurrent modeling studies, and suggest some basic mechanisms associated with the coal pillar bursts discussed in this paper.