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By R. B. Stein

"Countercurrent decantation circuits(CCD) are often employed in hydrometallurgy to effect solids-liquid separation in combination with a barren solution wash to reduce losses of valuable solution component(s) from the tails. Bechtel Corporation uses its BEMSIM flowsheet-modelling PC computer program to simulate a CCD circuit where the ""dirty"" wash solution contains significant amounts of soluble components. An algorithm successfully models this condition and is simplified to a single expression when the wash solution is a ""clean"" solution containing no solubles. The CCD calculation module is compared to operating data from uranium and nickel-cobalt CCD circuits.IntroductionHydrometallurgical process schemes have often relied on countercurrent washing methods to reduce soluble losses of valuable product in the tails. Commonly used equipment to effect this operation is a CCD circuit of N thickeners in series, where a slurry is fed to thickener I and a wash solution to thickener N; clear pregnant solution overflows thickener I and washed tails exit as underflow from thickener N. CCD circuits of this type are typically employed when the solids tend to slime heavily and where a filter is not economic.A typical CCD circuit usually employs from two to five thickeners and can employ either a ""clean"" washing solution of, say, pure water or else the hydrometallurgical circuit may generate a ""dirty"" barren solution containing an appreciable amount of soluble component which may be advantageously returned to the process as CCD wash solution. Various authors have treated the case for clean washing solutions (Svarkovsky 1977, Merritt 1970). For the case of dirty wash solutions, an algorithm has been developed to enable efficient modelling by the BEMSIM computer program, because the need for an accurate method to calculate soluble losses is required when performing an economic trade-off analysis of the value of product lost in the tails as a function of the number of thickeners."

Jan 1, 1990

By G. Demi, G. Belardi, N. Shehu, S. Cico

The physico-chemical interaction between minerals such as olivine, chromite and serpentine and the ions most commonly present in solution, like Ca and Mg and flotation reagents such as EDTA and oleic acid was investigated. The study was conducted via release tests, electrophoretic measurements and microflotation of selected minerals coming from the Kukes deposit (Albania).

Jan 1, 2003

By W. Shockley

THIS lecture can best begin with a statement of the chief conclusion: The metallurgical industry will find profit in supporting fundamental research on dislocations. This support should be done both in their own laboratories and in universities. My lecture consists of an exposition of the basis for this conclusion. The experience on which I base it is drawn largely from two fields in solid state physics—one field is transistor electronics and the other is dislocation theory. At present the relationship of solid state physics to technology is different in these two fields. In electronics without question, the physics has led the technology. In metallurgy, on the other hand, the technology in the form of metallurgical art is far ahead of the fundamental science. In transistor electronics, physics has suggested and can still suggest previously unachieved combinations of matter that will have new and useful properties; that is, the physicist can make specific predictions. The physicist can also have some confidence that the predicted devices will actually come into existence in a matter of months or years and that they will live up to the predictions. In metallurgy, the physicist cannot to a comparable degree make predictions and have the same hope that they will lead to something new and valuable. There are a number of reasons for this difference. The first is simply historical. Transistor physics is young. It may be regarded as dating from the announcement of the transistor, in which case it is about four years old, or from the first real control of semiconductors as materials (this was accomplished largely by metallurgists, by the way) in which case it is about ten years old. Metallurgical art, on the other hand, is thousands of years old. There is no doubt that the advance of this art has been and will be hastened by a good fundamental understanding of the quantum theory of atomic phenomena. It, is too much to expect, however, that theory will soon catch up with the lead that practice has gained in a thousand years, and that theory will then point out specific pathways to better materials. It seems more probable that modern atomic theory will serve to interpret and organize information much as thermodynamics has done through phase diagrams. In this lecture, I shall emphasize an important feature common to both solid state electronics and to metallurgy. This common feature is the harmonizing principle that justifies discussing electronics and metallurgy as related topics in solid state physics. In both cases the important properties of the materials arise from imperfections. By imper- fections I mean deviations of the materials from perfect single crystals. The imperfections may be of many forms. From the point of view of utility they may be either good or bad, and a given type may be good or bad depending on circumstances. The technical material of my lecture will be divided into two parts. The first will be chiefly concerned with four types of imperfections in germanium crystals. The control of these imperfections makes possible the fabrication of useful electronic devices. A good example of such control is the junction transistor, which I shall discuss from this viewpoint later. The junction transistor, as some of you may have heard, can be used as an amplifier of electrical signals and in a number of respects surpasses what has hitherto been achieved with vacuum tubes. The second part of my technical material will be concerned with dislocations. For about fifteen years the theoretical physicist has had dislocations in mind as the most important kind of imperfection in metals. He has, however, until recently had experimental material of a highly speculative nature to back up his assertions. I am fortunate in the timing of this lecture to be able to describe some recent results that put dislocations on a far more definite basis than has been the case in the past. In fact there are now some experiments which reveal the characteristic properties of dislocations almost as clearly as experiments in transistor physics reveal the properties of holes and electrons, properties that I shall soon describe. It is this advance in the status of dislocations that emboldened me to make my initial assertion that the metallurgical industry will profit from supporting fundamental research on dislocations. Transistor Electronics In order to discuss imperfections in semiconductors, it is necessary to visualize a reference condition that may be regarded as perfect. In the cases of silicon and germanium, which find application in transistor electronics,' the perfect structure is the diamond structure shown in Fig. I. In this structure, each atom is surrounded by four neighbors with which it forms four covalent or electron-pair bonds. These bonds use all of the four valence electrons possessed by each of the silicon or germanium atoms. The electronic structure of the crystal is thus complete and perfect. A crystal of silicon or germanium with a perfect electron-pair bond structure would be an insulator, In order for electrical conduction to occur, it is necessary for imperfections to arise in the electronic structure. In this lecture, I shall discuss four possible imperfections whose symbols and relationships are indicated in Table I. We shall consider first, as an example, a crystal of silicon containing an arsenic atom as an impurity.

Jan 1, 1953

By R. A. Hadfield

It seems a specially fitting opportunity to present a paper on the alloys of iron and aluminum at the New York meeting of this Institute, owing to the fact that America has, more than any other country, originated and developed the manufacture of cheap aluminum. The Cowles, Castner, and Hall systems have all originated in the ever-busy brain of our cousin across the water. The problem of cheaply producing this valuable metal has been a difficult one, but to the writer it seems that the more arduous the task the greater the delight with which our American friend attempts to overcome the difficulties surrounding it, and the more vim he throws into the work. Another and equally striking proof of this is to be found in the recent appearance of the already wellknown remarkable work, The Mefallurgy of Steel, by Mr. H. M. Howe, of the Institute of Technology, Boston, Mass. It is to be hopel that this Institute will not be slow to recognize by some special mark its appreciation of this signally valuable and original work. The writer has been led to describe the following experiments, believing that so far no full and exact report has yet been presented to this Institute as to the effect of aluminum alloyed or combined with the metal iron. It has been a special object to make the material as far as possible a true alloy or combination of aluminum and iron, with as small quantities as possible of other disturbing ingredients, such as silicon, manganese, etc. In the material described in these experiments, the total amounts of other elements present (sulphur and phosphorus being disregarded as present in such small quantities) do not exceed about 0.5 per cent. Such material may therefore be probably taken as fairly illustrative of the effect of the metal aluminum upon iron. Since completing the experiments the writer

Jan 1, 1891

By S. M. Narbekova, L. V. Semushkina, Zh. A. Aldybayeva, A. A. Mukhanova, D. K. Turysbekov, N. K. Tussupbayev

More complex and heavy-concentrating oxidized and mixed sulphidic oxidized ores are involved in production because of increasing needs for non-ferrous metals. Extraction of the oxidized minerals of non-ferrous metals general in current technologies. The problem is solved to oxidized polymetallic ores the preliminary selective sulphidization is the oxidized surface of the components by means of hydrogen sulphide, sulphide and calcium polysulphide, and also element sulphur, etc. The task was to study details of flotation of the oxidized lead-bearing ore of the Zarechnoe deposit (Kazakhstan) with calcium polysulphide as sulphidation. According to chemical analysis initial samples of the ore contain, %: lead – 4.8; zinc – 0.1; general iron – 0.81. Phase structure lead is characterized by the oxidized form of 57.76-64.5 %; by sulphidic status of 25.5-32.64 %, and by plyumboyarosite of 19.0-23.02 %. Researches on flotation beneficiation of oxidized lead-bearing ore are conducted. Sulfidizator gave to grinding, on flotations there were used the collector (butyl xanthogenate of sodium) and frother (T-80). Experiments were conducted with a new sulphidizator – calcium polysulphide. The latter is obtained by interaction of CaO calcium oxide with sulfur and water at high temperature with component mass the following ratio S:CaO:H2O =10:5:85. Extent of mill initial ore was optimised (88.42 % of - 0.071 mm grade). For the optimum mill mode the studies on matching of an optimized consumption of sulphidizators are performed. On basic technology with application of sulphide of sodium as a sulphidizator at optimum mill, the lead concentrate with the content of lead 64.4 % at extraction of 86.6 % was received. The content of cerussite in a concentrate was about 14.9 % at extraction of 82.1 %. With application of calcium polysulphide as a sulphidizator the lead concentrate with the content of lead 68.0 % at extraction of 88.0 % was received. The content of cerussite has made 16.0 % at extraction of 85.0 %. Application of a new sulphidizator allows to increase extraction of lead in a concentrate from 64.4% to 68% and cerussite extraction – from 82.1 % to 85.0 %. The possibility of application of calcium polysulphide as a sulphidizator instead of conventional sulphurous sodium was established.

Jan 1, 2018

By Warren Smith

IT has been 5 years since the writer left the Philippine Islands and while in that country his chief work did not lie in this field, though he has visited all but one of the localities mentioned in this article. The principal field studies relating to oil were made by his colleague, Mr. Wallace E. Pratt. The writer's investigations dealt with the general stratigraphy and paleontology of the Philippines. With the exception of the investigations made by Mr. Pratt and the writer very little information on this subject is available. A number of geologists in the employ of large oil companies have visited the Islands from time to time but, following the general rule, the public has scarcely ever been permitted to learn anything of the results. The writer is indebted to the Bureau of Insular Affairs, Washington, for late information regarding recent legislation in the Islands relating to petroleum. All the known oil seeps, petroleum residues, such as ozocerite, and natural-gas emanations are associated with Tertiary sediments. The chief seeps and most promising prospects are located as follows: 1. Bondoc Peninsula (lower end), Tayabas Province, Southeast Luzon. 2. The west coast of the island of Cebú from Alegria north to, and perhaps beyond, Toledo. 3. Central Mindanao not far from Lake Lanao. 4. The ozocerite veins on the Island of Leyte in the northwestern part in the vicinity of the town of Villaba. 5. Natural gas from some deep wells in Tertiary shale formations on the eastern flank of the Cordillera and extending out under the plain on the island of Panay.

Jan 2, 1920

By Byron W. Cheever

Of the elements found in iron and steel, none has attracted more attention than phosphorus. It is considered the great enemy of the steel manufacturer-, and the chief aim has been and is to keep it out by using pure crude material, or when once in, to eliminate it or counteract its effect. Its presence is manifested in various ways, but most of all by producing a condition called cold-shortness. The first question, then, which presents itself is, What per cent. of phosphorus produces this condition ? I have searched very carefully for an answer to this question, but have failed to find one. Authors generally agree that wrought-iron may have a larger per

Jan 1, 1887

By E. S. Moore

"The Michipicoten-Goudreau area, bordering on the northeast corner of lake Suferior, has had a tectonic history related to that of the geosyncline occupied by this lake. This basin has been a major structural feature in the Canadian Shield since at least late-Precambrian time. It has been extensively faulted and was the centre of great igneous activity in the Keweenawan feriod . Many of the faults, folds, dykes, and sills in the surrounding regions tend to head directly or indirectly into this basin. Some of the faults in the Michipicoten-Goudreau area appear to run under the eastern part of lake Superior just as the large Keweenaw fault in Michigan extends into the lake on the south side. Some of these faults may even be extensions of or counterparts of the faults on the south side of the lake. Another set of faults in the Michipicoten-Goudreau area runs nearly transverse to some of these major faults, and it is evident that in some places movement has recurred at a later time on faults formed in an early period.STRATIGRAPHYThe rocks of this area, with the exception of Pleistocene and Recent formations, are all Precambrian:"

Jan 1, 1954

By V. de la Garza

The La Cienega Gold District is located at latitude 25°01'01"N and longitude 106°19'00"W, in the NW part of the State of Durango, Mexico. Ore deposits at The La Cienega District consist of a series of sub-parallel, NE-trending veins which cut andesitic and rhyolitic rocks that belong to both upper and lower tertiary volcanic sequences. The veins are vertical to steeply-depping structures which consist of quartz, generally containing gold-silver and less than ten percent lead, zinc and copper sulfide and sulfosalt minerals. Supergene enrichment is present on the upper parts of known oreshoots. Tertiary volcanic rocks of rhyolitic composition are the main host rocks of the gold-bearing quartz veins in the District. Gold productionc from the La Cienega orebody is scheduled to reach 100,000 ounces per year, becoming the largest gold-producing District in the Sierra Madre Occidental Province.

Jan 1, 1994

By H. G. Doll

An earlier paper on the general subject of the SP log has analyzed the limitations of that log, in particular when dealing with thin permeable beds enclosed in thick highly resistive ones. Under such conditions, the SP log does not give a good definition of the permeable beds. Selective SP logging is a new method which gives an accurate determination of the permeable beds; even in highly resistive formations, except when the salinity of the mud is extremely high. It also permits a close approxi. mation of the static SP to be obtained. The method consists generally in controlling the potential of auxiliary electrodes located in the drill holes in the vicinity of the measuring electrode. In this manner. the flow of SP current along the drill hole is modified to counterbalance the effect of highly resistive strata. Several procedure; and arrangements used to record selective SP curves and static SP curves are explained. Field examples illustrating these methods are given and discussed. INTRODUCTION In an earlier paper,' the shape of the SP curves and the amplitude of the SP peaks were analyzed, considering how the circulation of the SP current is influenced by the subsurface media as a function of their geometrical configuration and their resistivities. It was shown, in particular. that the permeable beds situated between highly resistive formations are sometimes indistinctly indicated by the deflections of the SP log. It is the purpose of this paper to dircuss a new method now being developed, namely selective SP logging, whose principal feature is to enable a more accurate determination of the depths of the permeable beds present in highly resistive formations, such as occur in limestone fields. It will be shown also how an addi-tional curve called the static SP log can be derived from the selective SP log, or recorded directly, to facilitate the interpretation. Another purpose of the static SP log is to provide an approach toward the determination of the value of the static SP, where this value is not readily given by the SP log. This application. although less important at the present time than that mentioned above, nevertheless is of interest, inasmuch as, according to laboratory and field experiments conducted by several investigators, the determination of oil saturation of reservoirs from the data of the electric log implies the knowledge of the resistivity of the connate water,2,3 to which the static SP seems to be related.4,5,6,7 PRINCIPLE OF SELECTIVE SP LOGGING The method of selective SP logging of the formations traversed by a bore hole consists in recording two curves under the following conditions: The measuring device comprises one measuring electrode M and two additional electrodes G-G', connected to each other. located above and below

Jan 1, 1950

By G. T. Lineberry, L. Adler

Due to safety-imposed constraints on clearances for mobile bulk handling equipment, it is necessary to optimally select a unit based on speed and size. The unit cannot be both large and fast. Since output is proportional to both size (or capacity) and speed, the combination must be carefully examined to maximize output. A simple graphical procedure and a calculus-based solution are presented to accomplish this. While the procedure applies to all mobile bulk handlers, as an example of the solution technique, attention is focused on shuttle cars. Background Major variables To fully define a bulk handling problem, the conditions, equipment, and activities must be characterized. The conditions and activities, when lumped together, are termed "encumbered space," since they "act to impede motion, as with a burden" (Lineberry, 1979). The insertion of mobile bulk handling equipment into what is already a difficult set of conditions and activities compounds the state of encumbrance, as limited space is competed for by many normal and life support systems. Long (1972) recognized the effects of design criteria, including road width, on haulage vehicle speed and, therefore, on production. Velocity-clearance curves Velocity-clearance curves are either available or can be constructed in the field. A preliminary set of curves for average conditions and activities is shown in Fig. 1, where clearances are only for the side of the vehicle (Lineberry and Adler, 1984). These curves set the safe speed limits for a vehicle operating at given clearances, under given conditions and activities. When feasible, velocity-clearance curves should be constructed through field measurement and observation. Curve construction should also consider haulway roughness, distances, and operator skill, as well as loading and dumping characteristics. It should be noted that haulage capacity determination is a total systems problem, not one just dependent on velocity and clearances. Production requirements and company capabilities also influence capacity determination.

Jan 1, 1986

By Pascal P. Percy

Dado el elevado costo de transporte que implica el traslado de mineral aurífero en la compañía minera La Poderosa, se ha elaborado un proyecto denominado "Proyecto de transporte sobre rieles" donde se garantiza el acarreo de 550 t/d a partir de 1994 y se reduce los costos del transporte a 56%. En este sentido, el presente trabajo describe la ejecución del proyecto a través del uso de túneles, chimeneas y trocha en superficie, reemplazando la os volquetes y camiones. Asimismo, el proyecto desarrolla la ejecución del túnel en forma convencional a través del metraje, logrando un control estricto de los tiempos empleados en cada operación unitaria, la utilización adecuada de los recursos, coordinación de los trabajos a realizarse y los servicios requeridos.

Nov 24, 1993

By R. P. King

The ideas leading to the formulation and utilization of a flotation model are developed. The main theoretical and experimental work that has been carried out by the National Institute for Metallurgy Research Group at the University of Natal is presented. The two experimental flotation plants available to this Group are described.

By Philip D. Pearson

CALAND Ore Co.'s dredging program has reached the halfway mark. The goal is to remove more than 160 million cu yd of lake bottom material overlying the iron orebody in Falls Bay of Steep Rock Lake, Ont. Two large dredges were constructed to remove this overburden, a layer of soil about 90 pct varved clay some 400 ft thick. Moisture content of the clay is high-approximately at the liquid limit of the soil. A few years ago, searching for additional reserves of ore, Inland Steel Co. looked toward Canada and the newly developed Steep Rock iron range. To this end an option agreement was signed Dec. 30, 1949, between Steep Rock Mines Ltd. and Caland Ore Co. Ltd., a wholly owned subsidiary of Inland Steel. Several drilling programs were conducted between this date and Jan. 1, 1953, when a 99-year lease was signed covering an area of 1249 acres. This lease calls for ore production to begin in 1960, with full production of 3 million tons per year by 1969.

Jan 8, 1957

By Francisco Alberto Marreiros da Rocha Filho

O uso de vanádio na produção de vergalhões microligados data do início do século XX, sendo amplamente utilizado na construção civil voltada para regiões susceptíveis a abalos sísmicos. Desse modo, este trabalho visa revisar os efeitos promovidos pelo uso do vanádio na fabricação de vergalhões antissísmicos, levando em conta a utilização de dois processos distintos de laminação – Forno de reaquecimento a Gás Natural (FGN) e Laminação Direta (LD) – como forma de conferir ganhos em resistência, mantendo-se níveis satisfatórios de tenacidade. Foram realizados ensaios microestruturais e de propriedades mecânicas entre lotes provenientes dos dois processos, avaliando-se propriedades como tamanho de grão médio, limite de escoamento e limite de resistência, correlacionando-as com o efeito provocado pelo uso do vanádio, concluindo-se que seu impacto no refino de grão austenítico/ferrítico e endurecimento via precipitação de carbonitretos de vanádio é de fundamental importância para a obtenção de propriedades mecânicas satisfatórias em vergalhões antissísmicos.

Oct 30, 2017

By K. A. Lewandowski

Agglomeration of ore used in heap leaching allows for the immobilization of fine particles that would otherwise migrate and cause permeability problems in the heaps. For copper ore, binders are needed in order to make stable agglomerates. However, the majority of binders break down when introduced to an acidic environment, allowing fine particles to be released from the agglomerate surfaces. These particles migrate through the heap impeding solution flow, leading to a decrease in metal recovery rates. The authors have developed a series of testing procedures to determine the acid resistance of several binders. Only five binders were shown to be acid resistant in soak tests, decreasing fines migration by up to 93%, compared to tests which were agglomerated with leach solution, raffinate, as a binder. Flooded percolation column testing also showed that these binders were able to reduce the "slump" of the ore by up to 82% and increased the hydraulic conductivity by up to 90%, when compared to agglomerating with leach solution alone. The use of binders in the agglomeration of copper ore also showed no negative effects on the bacterial populations throughout a leach cycle.

Jan 1, 2007

By Wilfred M. Kenan

The relationship of various genetic classifications of graphite, their properties and general applications are reviewed. The classifications being amorphous, flake, high crystalline (vein) primary synthetic graphite and secondary graphite. The properties discussed are size, carbon, sulfur, ash content, general chemical analysis and degree of graphitization of each type. The major sources for natural and synthetic graphite powders are discussed in addition to factors which govern the cost as well as the supply. The economics of graphite are basically determined by the consumer and the end application. Graphite is a strategic mineral and is on the government stockpile list.

Jan 1, 1984

By K. F. Jakob

Sustainable development is a principle for the way we should act in the present. It ensures also options for the future to achieve a balance between social, economic and ecology development. The efficiency of raw material utilisation is being enhanced through technological developments, starting from extraction through all the following stages of the value creation chain. The use of domestically produced resources helps to assure the technological know-how. Additional indicators being collected and published by individual companies are questionable in countries with a tightly regulated legal framework such as in Germany, but make sense in developing and threshold countries. Sustainability in terms of efficient use of raw materials will manifest itself at the next stages of the value creation chain. Examples for efficiency improvement can be found in the steel, the power generation and agriculture industries. The approval procedures for German mining operations entail an internationally extremely strict assessment of the potential impact on the environment. All the mining activities include remediation and recultivation where the practise in Germany has become model character by international levels.

Jan 1, 2005

By Paul K. Sims

The Central City district is one of several adjacent mining areas in the Front Range, Colorado, that contain precious metal-bearing sulfide veins of Laramide (Late Cretaceous and early Tertiary) age. The districts are in the Front Range segment of the Colorado mineral belt, and are characterized by porphyritic igneous rocks of intermediate composition that have intruded Precambrian crystalline rocks in the core of the Front Range. The veins and minor stockworks that constitute the ore deposits in the district were formed largely as fracture fillings. The veins range from simple fissures to complex, branching lodes, and commonly range from less than 0.5 to about 1 m in width. The principal values are in gold and silver. The common metallic minerals are pyrite, sphalerite, chalcopyrite, tennantite, and galena; minor minerals are enargite, pitchblende, and gold tellurides. Quartz, cryptocrystalline silica, carbonates, fluorite, and barite compose the gangue. The ore deposits have a well-defined concentric zonal arrangement. A core of pyrite veins (central zone) is surrounded by a peripheral zone of galena-sphalerite vein with gold and silver. An intermediate zone contains transitional veins that have minerals characteristic of both the central and peripheral zones. The minerals were deposited in three stages during a single period of mineralization: uranium; pyrite; base metals, gold and silver. The wall rocks were altered primarily during pyrite-stage mineralization. Sericite envelopes developed adjacent to fractures, and were succeeded outward by zones of argillized rock. The valuable ore minerals were deposited in ore shoots localized by several types of structural controls, principally vein intersections, the physical nature and structure of the wall rocks, and irregularities along the fractures themselves. During supergene alteration, gold was concentrated in the upper, oxidized parts of the veins, commonly to depths of 50 m. The precious metal-bearing sulfide ore deposits are closely associated in space and time with the Laramide porphyritic igneous rocks and are believed to have been derived from hydrothermal fluids related to the magmatic activity. The ore deposits have mesothermal aspects and apparently formed in the temperature range 200°-320°C.

Jan 1, 2013

The restructuring of the minerals industry has created new challenges for the design and delivery of professional development, and difficult decisions for potential participants. New technologies offer some new methods of delivery, but fall short in providing all of the benefits of face-to-face participation. This paper is intended to be a catalyst for discussion of the issues involved in delivery and participation in cost-effective, relevant and timely professional development.

Jan 1, 2000