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By Paykan Safe

Computational Fluid Dynamic (CFD) modeling provides a powerful tool to assist with the design of ventilation and fume control systems in smelters and other high temperature metallurgical facilities. For this paper, this tool has been used to analyze the off-gas flow patterns exiting the mouth of a Peirce-Smith converter into a water-cooled hood and drop out box. The effects of various process and physical plant design parameters on process gas and fume capture and potential build up on the converter hoods was examined, and the optimum design and operating parameters were determined.

Jan 1, 2000

By D. A. Huggins

Column flotation is finding increasing use in the flotation of copper, molybdenum and other heavy metals and coal. Columns have proven operational, cost and metallurgical advantages which caused us to investigate their use in the proposed Escondida flowsheet. A comparative pilot plant test with 35 tons of ore showed that one column can replace three stages of cleaning and result in a significantly higher concentrate grade with no loss in recovery.

Jan 1, 1987

By H. J. Thevik, A. K. Dahle

"A mathematical model that calculates the stress development in a coherent and stationary dendritic network due to interdendritic flow is proposed. The fluid flow is assumed to be related to the solidification shrinkage, and under the assumption of no porosity formation and unidirectional solidification, the shrinkage-induced flow within the mushy zone is calculated analytically. The interdendritic melt flow exerts a force on the solid network and an analytical expression for the stress build-up in the network is developed. Parameter studies illustrating the influence of cooling conditions, mushy zone length, dendrite coherency, fraction solid, volume fraction of eutectic, and solidification shrinkage upon the stress development within the solid network are presented. Comparing the magnitude of the calculated stresses to measurements of the strength in equiaxed mushy zones shows that it is possible for the stresses to exceed the strength, thereby resulting in reorientation or collapse of the dendritic network.IntroductionInterdendritic fluid flow is at present regarded as a very important mechanism for feeding of shrinkage during solidification of metal alloys. Solidification of many alloys is often characterised by heterogeneous nucleation of the primary phase on substrates in the melt with subsequent evolution of equiaxed dendrites. These equiaxed dendrites can initially grow freely, but impinge on each other and form a continuous dendritic network, ie. dendrite coherency, quite early in the solidification process. Measurements of the dendrite coherency point have shown that the dendritic network is established at solid fractions ranging between 0.1 and 0.5, and most often around about 0.2 [l]. Depending on the alloy composition this means that as much as 70 to 80% of the volumetric shrinkage has to be compensated by flow of liquid through the interdendritic network. Interdendritic flow occurs with a much larger resistance compared to free flow of the liquid and flow of a liquid with dispersed crystals. The pressure drop associated with the interdendritic flow increases rapidly with decreasing fraction ofliquid."

Jan 1, 1999

By S. Kapusniak

Specialist Machine Developments (SMD) is a design and manufacturing company involved in the design of Remotely Operated Vehicles (ROV?s), ploughs, trenchers and mining machines for use in submerged environments. Established in 1971, the company has made over 500 vehicles for subsea use. These range in size from small remotely operated swimming vehicles with a weight of less than a tonne to heavy duty seabed crawling machines with a weight of up to 310 tonnes (in air). Primarily, these machines have been designed for offshore vessel-based applications, but the machines are equally suited to other submerged mining applications onshore. Many onshore deposits can technically and theoretically be mined using currently available submerged mining ROV technology. Similar equipment to that in use subsea could easily be fast-tracked into use to extend the life of opencast mines facing severe hydrological problems. It could also easily be used to mine vertical ore-bodies where the stripping ratio has become uneconomical due to increasing depth. In some cases mining ROVs could even be suitable for use as the primary extraction method for a new mine. Exploration and extraction techniques used in oil and gas gradually developed and moved from land to offshore in the middle of the last century. Are we about to witness a similar shift with other minerals? This paper describes the design concepts of submerged mining equipment, targetted subsea mineral deposits, the suitability of submerged mining ROVs for onshore deposits, limits to their application and parallel research and development activities which will help to accelerate the use of such equipment in the emerging submerged mining sector.

Aug 1, 2013

By V. N. Kolesnikov

The gold-silver deposits of the northern Primorye region are located in the eastern part of the East Sikhote-Alin volcanic belt, where the belt overlaps the Kema island-arc terrain of the Aptian-Albian age. There have been four deposits and numerous mineralization points found in the NE-trending Kema metallogenic belt that is about 1000 km long and 100 km wide. The known mineralization is of epithermal type, controlled by faults, and concentrated in quartz, quartz-fluorite-adularia, and, less commonly, sulfide-quartz vein systems hosted by the Upper Cretaceous-Lower Tertiary volcanic rocks. The vein systems extend for hundreds meters along strike, varying from tens centimeters to 50-60 meters in width. They are surrounded by wide zones of low-temperature hydrothermal alteration containing some gold-silver mineralization for which the commercial value was not studied during the early exploration. The ore bodies contain from 1 to 50-80 ppm of Au and from 1 to 1000 ppm of Ag. Gold is native, associated with quartz, and represented by particles from tens of microns to 1 mm in size. Silver occurs in native form as a constituent of argentite, pyrargyrite, stephanite, and other sulfosalts. The test work carried out for three vein systems 20 years ago showed that gold might be easily and almost completely recovered from the ore by cyanide treatment. The paper describes the geology and mineralogy of the deposits, Salut and Primorskoye, that are the most studied properties of the Kema belt. It also presents the data available on disseminated gold-silver mineralization in stockworks, altered explosive breccias, and wide zones of low-temperature hydrothermal alteration. This mineralization should be explored for possible exploitation as large open-pit, heap-leach deposits.

Jan 1, 1998

By Guy A. Johnson

To improve productivity and cut costs, modern underground mining operations have become more mechanized. This mechanization has increased the usage of fuels, hydraulics, and electrical equipment associated with diesel-powered vehicles, thereby also increasing the hazards of underground mine fires. The Bureau of Mines evaluated the fire hazard problem and assembled prototype components for a system that would automatically sense and extinguish fires on mobile underground equipment. The prototype system and alternative designs were in-mine-tested and proved effective. This report summarizes this technology, which can cost effectively help solve the problem of fire hazards on underground vehicles.

Jan 1, 1983

By Tsuyoshi Adachi

Photovoltaic (PV) system is especially taken notice as one of important renewable energy resources, because PV has potential to provide a certain amount of energy supply as well as without greenhouse gases emission. Considering recent rapid increasing demand for PV system, more expansion of PV system is expected in the future. However, some precious metals and minor metals such as silver, indium and others are used as component materials of solar cell in PV system. Even if energy supply would become renewable, strict limitation of these metals still remain because amount of natural resources and recycling of metals has restrictions intrinsically. The aim of this study is to reveal the possibility of materials supply restrictions for Photovoltaic system quantitatively and to propose several measurements to assess supply risks for materials. Especially, silver supply potential which is used as wire line in PV system as well as PV demand forecast to estimate material use in the future are focused on. We divide underlying supply risk into 5 measurements and analyze them by time series, i.e. price volatility, resource potential, recycling ratio, production type and supply concentration are investigated. Comparing these factors of silver with other metals, the potential of silver supply for PV is presented. In addition to it, we propose another method to quantify country risk applied an insurance pricing model in finance pricing theory and combine it with the supply concentration measurement. As a result, supply risk of silver will increase gradually in the near future because of its resource constraints and supply-demand balances although silver market is sufficiency competitive one. From the country risk analysis, Peru is not only a significant supply country but also has the highest country risk. Some higher risk countries will increase the level of supply risk even if the concentration ratio of supply indicates moderate level.

Aug 1, 2013

By Grover Wallace

At is important for today?s mining executives and leaders not to underestimate the fact that, while the recent downturn in the economy did take its toll on balance sheets and productivity, factors such as emerging countries, aging workforces, globalization and individual knowledge growth did not lay dormant while the economy was in a lull. It is key for mining leaders to be proactive in their talent strategies. Successful mining companies are developing a clear, concise and communicated strategy and placing a high priority on recruiting the right talent in global markets that parallels their business strategy. They are focused on placing the right people in the right jobs.

Jan 1, 2011

By A. B. Needham

The Great Eastern nickel deposit is located in the western foothills of the Virgin Mountains in the Copper King or Bunkerville district situated in the southeastern part of Clark County, Nev. It is covered by a group of eight claims that can be reached by turning south from U. S. Highway 91 at Riverside, Nev., and driving about 12.6 miles southeast over a winding mountain road, which rises from about 3,000 feet to 4,000 feet in elevation. The climate is dry, with only a small amount of rainfall throughout the year. The temperature ranges from hot during the summer to short periods of freezing weather during the winter months. The vegetation is of the desert variety, and no timber is available for mining. Water for mining purposes would have to be pumped from lower areas. A granitoid gneiss comprises the largest part of the rock outcrops. It has a steeply dipping foliation that strikes about N. 75° E. The gneiss was intruded by basic dikes, which in turn were intruded by pegmatite dikes. The ore occurs as lenticular bodies formed by the convergence of several pegmatite dikes within the main dike. The principal sulfide minerals are pyrite, pyrrhotite, and chalcopyrite, which contain a small amount of nickel. Late in the year of 1939, the Bureau of Mines undertook an exploration project on the Great Eastern property to extend or delimit the known mineralization. Underground work, consisting of 590 feet of drifting and crosscutting, was completed in September 1940, and 1,091 feet of diamond, drilling for downward extension of an ore body in the Lower edit, which was completed in February 1941.

Jan 1, 1950

By R. R. Sayers

"An important, function of the U.S. Bureau of Mines is to instruct miners in first aid, and as a means of promoting interest in it first-aid contests are held under the auspices of the Bureau, usually in coop; ration with other interested organizations, especially the American Red Cross, the National Safety Council and various operators' and Miners' associations. It was early found that the method of judging first-aid meets is one of the most vital factors in determining the degree of success of the meet.It may be safely stated that there is no method for the judging of first-aid contests that has proved ideal. A method that would give the most uniform judging would necessitate the rating of each team by the same judge or committee of judges and, in order that a judge may rate a team satisfactorily, he should see that team perform several events and average the ratings. Such a procedure is not practicable where there are many terms entered in the contest, as it would prolong the meet indefinitely. To overcome this objection the method has been tried of assigning separate judges to each team but this brings in a new factor the individuality of the various judges, some of whom rate closely, others loosely. The next development was to average the judging by having the judges rate different teams for each event. This would seem to solve the problem out it has been found, after using the method over a wide area for a considerable period of time, that the differences in the judging are too marked to be at all satisfactory. The next development was to appoint a committee of chief judges three to five in number especially trained and experienced, to aid the individual judges in rating the teams. This method has proved satisfactory at small meets but, as committee must review the work of each judge on each event, it has not been deemed feasible for a large meet."

Nov 1, 1920

By A T. Bernardes

Using the cellular automata computational technique it was possible to simulate the generation and discharge of an iron ore pellet pile inside a direct iron reduction oven, as well as to calculate the reduction degree of the pellets as they leave the oven. It allows simulation of the variation of operational parameters and verify the results of those variations in the pellet reduction degree. The simulated data was validated in two instances: for the dynamics of the pellet flow inside the oven it was used in an acrylic bi-dimensional silo; and data from direct reduction iron literature was used for validation of the pellet reduction. The simulated results were considered acceptable to describe the movement of the iron pellet inside the direct reduction iron oven and to describe the iron pellet reduction direct in the oven.

Sep 26, 2011

By Feng Xue, Mi Xujun, Peng Lijun, Yin Xiangqian, Liu Dongmei, Xie Haofeng, Huang Guojie, Yang Zhen

The Age-hardening Cu-Cr alloys are extensively used in integrated circuit lead frame, railway contact wire, resistance welding electrode and continuous casting mold copper plate, owing to having an excellent combination of high electrical or thermal conductivity and high strength. High temperature performance is very important during the service process. Effect of Magnesium and Zirconium on softening behavior of Cr-Cr alloy are investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). During the softening process in the Cu-Cr alloy, the recrystallization process, grain growth and Cr precipitates coarsening are observed. The addition of Mg or Zr to the Cu-Cr alloy, the resistance to elevated temperature can be significantly improved, owing to being restrained the growth of the precipitates by segregating along precipitates surface. INTRODUCTION Age-hardening Cu-Cr system alloys can be widely uesed in many fileds such as electrodes for spot welding (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012), intergrated circuit lead frame (Hatakeyama et al., 2008; Cheng, Shen & Yu, 2013; Zhou et al., 2016; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003; Cheng, Yu & Shen, 2014; Zhang et al., 2016; Li et al., 2007) and railway contact wire (Cheng, Shen & Yu, 2013; Zhou et al., 2016; Chbihi, Sauvage & Blavette, 2012; Liu et al., 2006; Pang et al., Xia et al., 2012; Wang et al., 2009; Huang et al., 2003), because it has high strength, good electrical and thermal conductivity. The precipitation behavior of binary or ternary Cu-Cr alloys had been investigated by many researchers (Chbihi, Sauvage & Blavette, 2012; Peng et al., 2017; Batra et al., 2002). In addition, to obtain additional mechanical properties without much deterioration in electrical conductivity, trace addition of alloying elements like Zr, Ag, rare metals (Y and Ce) and Mg are added into Cu-Cr alloy. The addition Mg to Cu-Cr alloy accelerated the process of precipitates nucleation and restrained the growth of the precipitates by segregating along precipitates surface during aging, which enhanced the stability of the deformation microstructure and improved the mechanical properties of the alloy (Zhao et al., 2018). Additional zirconium in Cu-Cr alloy enhances the strength by the decrease in inter-precipitate spacing of Cr precipitates and the formation of Cu5Zr phase (Chihiro, Ryoichi & Kazue, 2008). Owing to the decrease in inter-precipitation spacing of Cr precipitates and to the Ag-atom-drag effect on dislocation motion, the addition of Ag can increase in strength, stress relaxation resistance and without much deterioration in electrical conductivity (Chihiro, Ryoichi & Kazue, 2008). The enhance in strength and electrical conductivity of the Cu-Cr-Zr alloy by adding Ce and Y elements are attributed to removing oxygen and sulfur from as-cast alloy (Li et al., 2006). However, the effect of Mg or Zr element on microstructure and properties of Cu-Cr alloy during the softening process are not clear. Therefore, Microstructure evolution and properties of a Cu-Cr systems alloy were investigated in detail by OM and TEM. The Relationship between microstructure and properties of Cu-Cr systems alloy was also discussed.

Jan 1, 2019

By Richard L. Werner

The petrographic microscope as a tool in determining impurities and grain size of limestones, clays, sand and coal ash for possible use as raw materials is discussed. Its use in the determination of the mineral composition of various size fractions of the raw mix, after fine grinding in ball mills, and of the waste dust from the rotary kiln. A description is given of the typical clinker crystals; alite, belite, tricalcium aluminate and ferrite. The process problems indicated by various changes in the crystal characteristics are listed with possible solutions. Finally the microscope as used in relation to field problems with concrete such as air void volume, percent hydration of the cement, cement aggregate bonding and the determination of solid additives, is presented.

Jan 1, 1982

By Robert R. MacLachlan

New underground mining technology is evolving through the use of large-diameter bore holes containing individually restricted charge weights. This article presents summary observations on cube-root scaling trials using single and rows of charge blasting in sand and in frozen ground. These observations have some bearing on the evolving underground practice, especially where charges of appropriate geometry are used.

Jan 1, 1978

By D. Saramak

"High-pressure grinding technology is considered as one of the most efficient techniques of ore comminution, especially in terms of energy consumption. HPGR devices has been utilized in many mining-related industrial sectors, including iron and non-ferrous metal ores processing (copper, platinum, gold), as well as cement and limestone flour production. Even though the technology well known (introduced into mineral processing circuits in 80’s), there are still examples of ineffective operation of HPGR devices. This is a result of improper application of HPGR into individual crushing circuit. The purpose of the paper was to analyze selected effects achieved in HPGR on the course and effectiveness of beneficiation operations. Investigations were carried out for copper ore, and investigative programme was run for different values of HPGR pressing force, as well as changeable ore characteristics (content of fine size fractions, material moisture). All crushing products were then treated in flotation process, in order to determine useful mineral recovery. Results of investigations show that HPGR operating pressure influences the metal recovery in proportional way, however too extensive pressure values have relatively lower impact on increasing of the metal recovery. Particle size distribution of HPGR feed and its moisture have lower influence on recovery level than HPGR pressure, but too extensive moisture content influences the higher energy consumption of the roller press, together with less effective comminution. The second aspect raised in the paper was a possibility to control and optimize the HPGR-based circuit. There were presented the proposed approach to adjustment of HPGR operating parameters that enables the higher metal recovery.INTRODUCTION The high-pressure grinding technology, invented and developed by Professor Schoenert in 70’s (Schoenert, 1979), is currently regarded as one of the most efficient methods of hard ore comminution. Since then the technology was introduced into raw materials treatment circuits in many mining and mining-related industrial sectors, including iron and non-ferrous metal ores processing (copper, platinum, gold), as well as cement and limestone flour production. Considerable number of works concerning modeling and optimization of HPGR operation were also presented (Daniel & Morell, 2004, Tavares, 2005, Saramak, 2012, Saramak & Kleiv, 2013). Nowadays high-pressure grinding rolls devices are considered as well know technology with over 500 sold machines, according to various sources."

Jan 1, 2018

By C R. Crook

A brief outline of production methods and processes is given to show how maintenance fits into the picture at this plant. The work force, and the tools needed to carry out this function, are then described. Preventive maintenance practices, scheduled annual shutdowns and routine check-downs are explained, especially as related to planning and to the materials and labour involved for a mini-mum downtime. A brief explanation of the materials, sup-plies and spare parts program, as well as the part played by the Stores Department in conjunction with the Maintenance Department, is given. Cost control and equipment expenditure indicators are explained. Some specific examples of maintenance jobs are described in order to show the flexibility of the program. S HERRITT GORDON Mines Limited has been in continuous production, except for the planned downtimes needed for expansion tie-ins, or the annual shutdown check-over periods, since the first shipment of nickel on a commercial basis in July of 1954.

Jan 1, 1964

By Perry G. Cotter

The objective of this investigation was to synthesize and investigate the properties of a high-temperature refractory material based on a combination of boron, silica, and magnesium. A magnesium-thermic reaction was used for the synthesis. X-ray examination of the product indicates that the crystalline portion of the composition is a combination of magnesium borides, magnesium silicate, and magnesium orthoborate. Chemical analysis of a representative sample shows, in weight-percent, boron 17.6, silicon 23.9, magnesium 17.8, and chromium 0.5. The balance is largely oxygen. The composition is resistant to high temperatures under oxidizing conditions and is stable in water, hydrochloric acid, and hydrogen. It has a low density (less than 3 grams per cubic centimeter) and a hardness value in the range of quartz. It has a melting point above 1,700° C. and can be hot-pressed to shape in the temperature range between 1,200° and 1,350° C. The properties described in this paper indicate that the material may have some uses as a high-temperature refractory, and because of its boron content it may have some value as a thermal-neutron-absorption material.

Jan 1, 1961

By Xiaohui Li, Lianyun Liu, Hongmin Zhu, Chunfang Zi, Kai Huang, Hongjie Li

"The dissolution kinetics of steelmaking slag in pure water was studied, and the relative influential factors were investigated. The dissolution behavior of slag particles in water was well described by Noyes–Whitney equation, and for this kind of sparingly soluble rigid mineral this simple model was extensively applicable to describe their dissolution process. Experimental data were also obtained to confirm the significant promotion effect on the growth of some algae.1 . IntroductionIt has been found that the population of phytoplankton distributed in the ocean was significantly related to the concentration of some elements [1]. For example, silicon and iron were very low in the high-nitrate low-chlorophyll (HNLC) areas, which was the main factor limiting phytoplankton and other biomass growth in these open ocean surface water [7]. The silicon and iron-rich test also confirmed that the supply of these elements had the direct effect on the growth of phytoplankton processes at HNLC areas [2-8]. So in order to promote the growth of phytoplankton in these ocean areas, providing some of these elements into these ocean areas is a natural idea for choice. Steelmaking slag is a good resource for consideration because it usually contains silicon, iron, phosphorus and other elements that are necessary for the growth of phytoplankton [8-10].Haraguchi has proposed the following idea that [5-6], if steelmaking slag can be spread to the open ocean, the trace components like silicate, iron and phosphate as the indispensable nutrients for the growth of phytoplankton, will be leached into the sea water, not only promoting the growth of phytoplankton, but also making good use of these huge amount of steelmaking slag produced every year. Based on this idea, they have carried out studies in recent years and they found that silicon and iron in the slag could be extracted into seawater effectively and play a positive role in the growth process of many algae. About the dissolution of the steelmaking slag, the Japanese scholars' research work mainly focused on the thermodynamic analysis of its dissolution possibility, and in the process of dissolution they tried to adjust the pH value of the seawater by continuously adding hydrochloric acid, which was deviated from the natural conditions of dissolution, and so the laws drawn under these special conditions can not give the identical guide to the practical application. Therefore, it is quite necessary to investigate the dissolution behavior of the steelmaking slag in the seawater at the normal pH range without adjustment to simulate the dissolution possibility under the natural conditions. In the present study, the silicon extraction behavior from the steelmaking slag was investigated and the dissolution kinetics in this process was also discussed in detail. Further studies were also performed here to evaluate the promotion of steelmaking slag on the growth of algae."

Jan 1, 2011

By Burden of Occupational Cancer in Canada Project Team, Demers P. A., Kim J., Arrandale V. H., Jardine K.

"In 2012 diesel engine exhaust (DEE) was classified as a human carcinogen by the International Agency for Research on Cancer (IARC) and is one of the most common workplace carcinogens internationally. We estimate that approximately 2.4% of lung cancers (n=560) and a suspected 2.7% of bladder cancers (n=200) are attributable to occupational exposure to DEE annually in Canada. High levels of exposure to DEE in mining results in a disproportionate number of cancers in this sector (approximately 220 lung and 20 suspected bladder cancers annually). These could be prevented by reducing the number of workers exposed and level of exposure. KEYWORDS Bladder cancer, Diesel engine exhaust, Economic burden, Lung cancer, Mining, Occupational cancer, Prevention, Regulation INTRODUCTION Diesel engine exhaust is a complex mixture of gases and particulates containing known and suspected carcinogens such as benzene, polycyclic aromatic hydrocarbons (PAHs), and metals. Approximately 900,000 Canadians are exposed to diesel engine exhaust at work, making it the most prevalent occupational lung carcinogen in Canada (CAREX Canada). Diesel engine exhaust is recognized as one of the most common workplace carcinogens in the world, but its classification as a human carcinogen by the International Agency for Research on Cancer (IARC) was relatively recent. In 2012, after decades of mounting evidence, diesel engine exhaust was upgraded from a probable (IARC Group 2A) to a definite human carcinogen (IARC Group 1) (IARC, 2014). The IARC evaluation was based on strong evidence in humans for an increased risk of lung cancer, as well as strong evidence in animal studies. The key human evidence considered by IARC was from epidemiologic studies of workers in truck transportation, rail transportation, and mining industries, where the use of diesel engines is widespread. These studies provided strong sufficient evidence for an increased risk of lung cancer, as well as limited evidence for bladder cancer. The human studies used particulate matter, generally measured as elemental carbon (EC) or total carbon, as a surrogate for diesel engine exhaust to assess the risk associated with level of exposure. The animal studies reviewed by IARC showed sufficient evidence for cancer with exposure to whole diesel exhaust and the particulate matter fraction of diesel exhaust, but not for the gas phase components."

Jan 1, 2019

By Toshiaki Nakai, Kunihiko Takeda, Kimio Imaizumi, Hiroaki Shirasaka

"The new type of nano-porous silica particle was considered to be constructed by the spinodal decomposition-type process which was found to have narrower pores than those of conventional porous silica prepared from boron silicate or ""Shirasu"" balloon. Nano-porous silica particles were fabricated by the calcination of silica gel mixed with well-dispersed complex salts composed of phosphorous and molybdenum compounds. Both silica and inorganic salts were not perfectly dissolved in the suspension solution. After removing of the water, the silica-inorganic salts complex was volatized and successively calcinated at a temperature ranging from 650 °C to 800 °C. Then, the inorganic salts were removed by dissolving in hot water. Other inorganic salts such as potassium halides were also found to be effective as a pore-size controller.IntroductionControl of structure has an important role in the field of industry as well as in the separation and purification technology for metals and organic syntheses. Many studies on the control of material structures have been reported regarding porous materials with pores ranging from nanometer to micrometer scale. 1 ) One example is zeolite as a naturally yielded porous inorganic material. Various types of synthetic zeolites have been studied as ""molecular sieve"" materials with ordinary pore-size of less than one nanometer. In 1992, crystalline meso-porous material with a large surface area named MCM-41 was synthesized through the use of template synthesis. 2) In direct relation to our study, amorphous borate glass having 4 to 100 nm of fine pores known as Corning glass 3l or SiO2-Al2OrB2O 3-CaO porous glass having large pore dispersity ranging from 4 to 10,000 nm have been reported. 4 ) S) 6 ) Some examples of several reported studies are as follows: phase-separated porous glass consisting of B2OrAl2O3-ZrO2-RO-R2O complex oxide 7 ) glass with finer pore induced from hydrolysis of silane alkoxide, porous material attained by condensation polymerization through the use of sol-gel process 8), alumina meso-porous material 9 ) 10), silica-zirconia material 11), carbon porous material 12), etc.."

Jan 1, 2000