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By K. E. Waters, M. Mirnezami, R. Gauvin, A. Jordens, K. W. Malas

"There is currently very little information on the physico-chemical properties of rare earth elementbearing minerals, or on their processing. With the increasing demand for rare earths, this is something that needs to be addressed. This paper introduces some surface chemistry analysis of fergusonite (YNbO4), and the bubble-particle attachment. Zeta potential measurements indicate adsorption of sodium oleate and, to a lesser degree, potassium amyl xanthate onto the surface, and an increase in attachment to an air bubble is observed at pH 4.5 and 6.5. At a pH of 10.5, no attachment is observed, whether in the presence of the reagents or not. This analysis, although initial, will be used to initiate flotation tests, in order to facilitate the selective recovery of fergusonite. INTRODUCTIONRare earth elements (REE) are increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. An article in the New Scientist highlighted the importance of a number of REE, many of which most people are be unlikely to have heard mentioned (Crow, 2011). From batteries (lanthanum and cerium) to magnets (dysprosium and neodymium) and lighting (yttrium), the REE are crucial to the advancement of technology and energy saving devices. For example, neodymium is finding most use in the high end magnets that keep the motors turning that power wind turbines and electric cars. In the case of yttrium, the demand outstripped the supply in 2010, emphasising the need to develop deposits containing this and other REE (Crow, 2011). The impact of our dependency on REE has become even more apparent with the reduction in exports by China, which currently controls 97 % of the world’s rare earth production (Pitts, 2011).With the increasing demand for rare earth elements (REE), there is a drive to exploit the known resources around the world. However, the physical beneficiation of the rare earth element bearing minerals is a subject which will require a great deal of investigation to fill the knowledge gaps surrounding these developing rare earth projects. There are numerous articles on REE mineralogy as well as the hydrometallurgical processing of REE concentrates (Alex, Suri, & Gupta, 1998; Peter Gromet & Silver, 1983; Ring et al., 1993; Schnetzler & Philpotts, 1970; Uda, 2000), however a common feature amongst these resources is the lack of detailed descriptions of the physical beneficiation processes required to concentrate REE-bearing minerals. There is work being conducted into reagents and methods for use in recovering some rare earths from their associated ores (Bulatovic, 2010; Ni, Parrent, Cao, & Liu, 2011), but much more in-depth research is required."

Jan 1, 2012

By O. Lopez

"Stringent regulations and increased arsenic presence in ore bodies being exploited have created the need for cost effective and environmentally compliant technologies to remove selenium and arsenic from mine waters and metallurgical waste streams. Existing treatment methods have high life cycle costs and/or produce residues that, due to their unknown stability over the long-term, may represent future liabilities. This results in high compliance costs and uncertainties which negatively impact existing operations and projects in permitting. Selen-IX™ is a new ion exchange based process that selectively removes selenium from mine impacted waters down to 1 ppb while producing a stable inorganic iron-selenium product. Results of piloting completed on streams generated from coal and copper-gold deposits are presented along with preliminary equipment sizing and life cycle costs of full scale treatment. An example of a commercially available system for arsenic removal using sulphide precipitation is presented. The benefit of this treatment method is discussed based on recently completed technical feasibility assessment including laboratory testing and preliminary engineering design. INTRODUCTION Selenium Due to the chemical similarity between selenium and sulfur, selenium substitutes sulfur in many minerals that can be found in a wide range of deposits including coal, base metal, precious metal, phosphate, and uranium. One of the main environmental challenges facing the industry in North America today is related to the removal of hexavalent selenium, e.g. selenate, to ultralow levels, typically between 1 to 10 ppb, from large flows of often cold water containing less than 1,000 ppb of selenium. Recent studies commissioned by the industry identified biological selenium reduction systems as the best available technology. Although the biological selenium reduction process is commercially proven in certain applications to remove selenium to ultralow discharge levels, the technology has been primarily applied to relatively low and constant flows of warm water produced by the Flue Gas Desulfurization (FGD) scrubbers in the power generation industry. The wide spread adoption of this treatment method by the mining industry is hindered by high capital and operating costs associated with treating large flows of cold water, lack of data and knowledge about the long term stability of solid residues produced by this treatment, and limited capacity of biological systems to respond to sudden changes in flow and/or mass load of contaminants. Furthermore, it has been reported that reaching discharge limits less than 3 ppb could be a challenge and that polishing treatment for the removal of BOD and phosphate maybe required to avoid the impact of the biological treatment which requires organics and nutrients, on aquatic environment downstream of treatment plants. Alternate treatment systems are being developed to overcome and/or completely avoid some of the challenges of biological systems. One such treatment system is BioteQ’s Selen-IX™ process which is purely physico-chemical treatment system."

Jan 1, 2015

By Jae-Chun Lee, Sadia Ilyas

We investigate the technical feasibility of bioleaching of metals from low grade sulphidic ore. Experiments were conducted with an adapted consortium of Sulfobacillus thermosulfidooxidans and Thermoplasm acidophilum in batch bioreactors (1.5 L), small columns (10 kg ore load, 8 % S0 sludge) and large columns (80 kg ore load, 12 % S0 sludge). Approximately 83 % Ni, 85 % Cu, 55 % Fe and 81 % Zn was leached out in batch mode while 93 % Ni, 89 % Zn, 81 % Cu and 65 % Fe was leached out in column reactors. Bioleaching potential improved by acid pre-leaching, adaptation of microbial consortium and periodic bleeding of effluents.

Jan 1, 2014

By G J. Harbort, V Lawson, L Reemeyer

The Jameson Cell is a high intensity flotation device, which utilises induced air from the atmosphere. It was developed jointly by Mount Isa Mines and Professor Graeme Jameson of the University of Newcastle in the 1980s. It is proven to generate fine bubbles, in the order of 300 to 500 ¦m, in a high intensity, high shear and compact zone contained in the downcomer. This aerated mixture exits the downcomer into the pulp zone, which is the quiescent mineral and gangue separation zone. A number of Australian base metal flotation circuits feature a reverse flotation stage at the head of the circuit. Testwork and plant operating data has shown that the use of a Jameson Cell in the prefloat cleaner application has further improved prefloat gangue recovery and selectivity. Operation of a Jameson Cell in a carbonaceous/pyrite prefloat cleaner duty at the Mt Isa copper concentrator increased copper recovery and reduced pyrite in the copper concentrate. Testwork at Zinifex Century Zinc Mine showed a decrease in zinc losses by the utilisation of Jameson Cell prefloat cleaner. Appraisal of a Jameson Cell in a scalping role within the Mt Isa Copper Concentrator indicated significant benefits could be achieved.

Jan 1, 2005

By Reinol Compañero, Ivy Gonzales, Herman Mendoza, Brian Buenaventura

"The extraction of gold in the Philippines has been a significant challenge for the past decades. Around 70-75% of gold mined in the country can be accounted from the small-scale mining industry which primarily use the traditional cyanidation and amalgamation; processes which have been advocated due to its adverse affects to health and environment. To address this challenge, an alternative clean and sustainable technology was developed for the small-scale miners to recover gold and other metal/mineral values efficiently from Philippine ores. An initial survey was conducted and followed through with extensive mineralogical investigations ascertain the best method applicable. It was determined that Philippine gold occur in ore as (1) very fine particles in the microns range, (2) free-milling, which is in abundance, and (3) locked particles with sulfides --- it was concluded that enhanced gravity concentration and flotation are viable alternatives. A comprehensive test regime was followed to check the response of the ores obtained from different small-scale mining districts across the country. It was shown conclusively that the gold ores respond positively, with recoveries using gravity concentration and flotation of at least 95% and 88%, respectively; exceeding the nominal recoveries using cyanidation or amalgamation. A specific process flow was designed for each type of ore with customized parameters. It was determined that while capital expenditure of implementing these alternative processes is higher than what is currently being used, the operational aspects show that it is much more economical to apply enhanced gravity and flotation. It should be noted that the process developed addresses the critical issue of environmental costs which should be more than enough to justify the shift from the current to the novel and sustainable technologies."

Jan 1, 2014

By G. Soni

A first principle flotation model has been derived from the basic mechanisms involved in flotation. The model consists of a series of analytical equations for bubble generation, bubble-particle collision, attachment, detachment, and froth phase recovery. The model can predict flotation from both hydrodynamic and surface chemistry parameters such as bubble size, particle size, energy dissipation rate, ?-potentials, contact angles (?), etc. The model has been validated in a series of laboratory batch flotation experiments, in which mono-sized glass beads are used as feeds. The experimental results are in good agreement with model predictions both in terms of grade and recovery.

Feb 23, 2014

High-pressure grinding rolls (HPGR) are an accepted, but continuously expanding, comminution technology. The copper industry has a growing need to process harder ores with progressively lower grades, more challenging metallurgy and increasing demand for efficient bacterial leaching applications. This has resulted in a major focus on HPGR use in a crushing circuit. If the industry is to increase leach extraction while lowering energy costs in high-throughput hydrometallurgical operations, HPGR will be of inherent significance. The following paper summarizes test work on copper leach ores utilizing the benefits of HPGR comminution, while increasing several critical metallurgical parameters. Based on the current work and previous investigations, it was found that HPGR comminution within a crushing circuit, in specific instances, can result in 2 - >10% increases in cop-per extraction. The tested variables are crush size, rock type and copper mineralogy dependence. Various other process parameters may also be optimized.

Jan 1, 2011

By Kazem Oraee

Implementing stable final pit walls in open pit mines during the open pit design phase and mine exploitation has become one of the most important concerns of mining engineers in recent years. Failure of mine walls can potentially cause loss of life, roads blocks, and damage to mining machinery, temporarily or permanently halt production at the face and in the worst case scenario, close the mine. Thus, the role of creating stable mine walls is crucial to safety and general operations of mines and any effort to optimize this process has great economic value for mine operators. This paper aims to illustrate the technical aspects of use of the successful presplit blasting method in metal open pit mines. It also shows that using this approach not only increases safety in mines through wall stabilization, but also will boost economic profits by savings in stripping ratio. In this regard, appropriate practical concepts for designing the drilling and blasting patterns and the role of selecting the correct drilling rigs are elaborated in detail through conducting a case study in Chador Malu iron ore mine in Iran.

Aug 1, 2013

By Jim Bruce, Naresh Gurpersaud

"The West Toronto Diamond project, under construction since 2006 and due to be complete in 2015, is a rail-to-rail grade separation project in the heart of urban Toronto. Once complete, a depressed corridor over 1000 metres long will take the CN tracks beneath the CPR tracks. An interlocking steel pile wall serves to retain ground and cut off groundwater. Remedial measures, constructed using jet grouting, were required at several locations within and behind the steel piles.At mechanical interlock joints damaged or suspected of being damaged, jet grouting was used to improve native soils on the retained side of the wall to reduce permeability of the soil mass in intimate contact with the joints to 10-7 cm/s. At a number of steel piles where groundwater and soil type combined to cause basal instability inside the pipes during the interim between excavation and concreting, jet grouting was used to construct temporary bottom seals. At locations near adjacent structures where the steel pile installation process resulted in disturbed ground on the retained side of the wall, jet grouting was used to strengthen and stabilize ground.This paper outlines the details of the various jet grouting applications, the respective testing programs implemented to demonstrate in situ permeability and strength of the soil-grout matrix, and performance of the constructed system.INTRODUCTIONThe West Toronto Diamond (WTD) is a junction of several railway lines, all intersecting at the same grade (Figure 1). A major grade separation project at this site commenced in 2006 and is scheduled to be completed in 2015. The whole of the work is comprised of multiple contracts, completed and/or ongoing, by different constructors. Once completed, a depressed corridor over 1000 metres long with over 23,500 m2 (face area) of retained earth will bring the CN tracks beneath the CPR tracks and eliminate a major bottleneck at the most heavily used rail crossing in Canada."

Jan 1, 2017

By R. P. King

The central idea presented in this paper is straight forward. Some fairly obscure mathematical techniques are presented from the fields of integral geometry and stereology and these techniques are shown to provide workable quantitative relationships from which the liberation spectrum of an ore after comminution can be determined. The experimental data that is required can be obtained very accurately and conveniently by image analysis of polished sections of the original ore. This quantitative mineralogical analysis provides a bridge that can link the worlds of the mineralogist and the mineral process engineer. This paper has been written to introduce this quantitative approach to a wider audience in the hope that the approach will be used more widely and that the basic linear intercept analysis data will be measured for a wider range of mineralogical textures. This could lead to a more comprehensive characterization of typical mineral ores that will be of considerable use in practical mineral processing.

Jan 1, 1991

By L. A. Harris

In the present study the open gradient magnetic separation' (OGMS) method has been used to beneficiate the -30 + 100 mesh fraction of two high volatile bituminous coals. The evaluation of the effectiveness of the magnetic separation for cleaning these coals is the subject of this paper. Coal petrography in combination with scanning electron microscopy (SEM) and x-ray diffractometry (XRD) were used to characterize the magnetically separated coal fractions. These analyses revealed that the majority of the pyrite and non-pyrite minerals were concentrated in the positive magnetic susceptibility fractions. The bulk of the starting samples (-80 weight percent) were located in the negative magnetic susceptibility fractions and showed significant reductions in pyrite and non-pyritic minerals. The magnetic separation appears to effectively split the samples into relatively clean coal and refuse.

Jan 1, 1981

By H E. S Moorcroft, D Scott

The increasing mining depths of South African gold mine deposits are resulting in ever-increasing heat loads associated with depth and the geothermal gradient. Together with changes in the mining horizons brought about by the depletion of older, shallower, high-grade reserves, this leads to the need for the continuous review and redesign of cooling requirements. Traditionally, cooling requirements were met by using a combination of cooling strategies, including bulk air cooling on surface and underground. If this proved to be insufficient, chilled service water and secondary remote air-cooling systems were introduced. This paper reviews these practices in order to provide a cost-effective means of catering for the introduction of hydropower at the Gold Fields Ltd South African operations. Some of the equipment that has been developed to meet the requirements of both hydropower and refrigeration includes hydropower fans, cooling coils and in-stope venturis. These are individually described and discussed, together with their roles within the greater strategy. The planned change in the cooling strategy and the employment of these technologies have effectively doubled the cooling available, from 10 MW to more than 20 MW, extracted from the hydropower water used to drive the mining equipment. In conclusion, the cooling strategy described allows a total heat load of approximately 52 MW to be successfully ventilated and cooled through the use of combined surface and underground refrigeration installations, and through the use of hydropower-chilled water.

Jan 1, 2005

The Cannington silver lead zinc deposit is located near Mt Isa in North West Queensland. This world class orebody is owned by BHP World Minerals (BHP) and is estimated to contain 45 million tonnes of ore at an average grade of 11 per cent lead, four per cent zinc and 500 grams/tonne silver. At BHPÆs planned 1.5 Mtpa extraction rate, the mine life will exceed 20 years. Construction of the underground mine, which commenced in August 1993, was carried out by Peabody Resources Ltd (Mining Services Division) (PRL) for BHP Minerals Pty Limited (BHP) under contract packages totalling approximately $100 M using several innovative techniques to deliver safety, quality and time related project goals. Client/Contractor Partnering, resulting in harmonious working relationships, a combined commitment to the achievement of an excellent safety record, and a seamless transition from the construction phase to operation of the mine, has been a feature of the project.

Jan 1, 1998

By V. Yahorava

Mintek has developed a non-destructive Resin-in-Leach method for the recovery of Rare Earth Elements (REE) from phosphogypsum (PG) waste dumps. However, PG from different sources was found to be highly variable in terms of REE recovery and physical properties. Development of a pre-treatment process was initiated to improve the robustness of the current REE recovery process in order to render it effective for any type of PG. Extensive research into the mineralogy of REE associations with PG revealed that the majority of REE are trapped inside phosphogypsum clusters which inhibits their recovery. Hydrothermal treatment of PG-containing slurry was found to result in re-crystallisation of gypsum with the release of REE phases encapsulated in it. This process was tested on various PG samples and subsequent REE recoveries improved from 5 to 80%. This approach carries a large potential for unlocking value associated with gypsum dumps worldwide.

By Ian F. Hughes

"Concepts of an integrated steel plant for sheet products to be built and operating in the year 2000 will be described. The design and operating methodology of this market driven facility will integrate process uniqueness, standardization, manufacturing automation, artificial intelligence and information flow.An integrated steel plant for the year 2000 is defined for this article as one that will be built on a greenfield site and ""started up"" in the year 2000 with a capacity of three million tons per year of flat rolled products ranging from cold rolled and electrical steels to high strength formable steels and a full range of coated products.It may seem that the 21st century and the steel plant we're discussing are far into the future. The startling truth, however, is quite the opposite. As shown in Figure 1, even with accelerated development, a new process on which laboratory development work is begun today might just barely pass through the laboratory phase, pilot plant, and commercial feasibility stages such that it can be considered viable for construction and start up in the year 2000.On that basis, it is very unlikely that this 21st century steel plant will utilize any technology that isn't at least under investigation in the laboratory in 1988. As a result, we recognize that planning and selecting the facilities for this plant is, in fact, a pragmatic rather than futuristic process, and that its main value is in providing a bridge to longer-term predictions."

Jan 1, 1988

By B. A. Slaker, T. Miller

"An underground limestone mine in eastern Ohio was experiencing significant floor heave and roof falls, attributed to high horizontal stresses. Areas of the mine showing floor heave were monitored with roof-to-floor extensometers and photogrammetry surveys, to determine the rate and magnitude of heave. Extensometer data were recorded hourly at four locations across adjacent entries while photogrammetry surveys of the floor were performed at the same locations every two to five weeks. A final survey was performed using an I-Site 8200 laser scanner. Following instrumentation, floor heave up to 10.1 cm (4 in) was measured by the extensometers, photogrammetric reconstructions, and laser scanner over a 6-month period. The extensometers were biased by the location where they were placed, failing to consistently capture the location and extent of floor heave and cracking. The photogrammetry surveys were not precise enough to capture small magnitude movements. Mining in the area was halted and within several months the floor movement and incidence of roof falls was significantly lessened. INTRODUCTION Limestone formations in the United States can be subject to relatively high horizontal stresses due to the presence of tectonic loading of the strata. Horizontal stresses have a documented history of causing stability issues in underground limestone mines. Kuhnhein and Ramer (2004) discussed the influence of horizontal stress on complex ground control interactions associated with limestone pillar design and mine layouts. Esterhuizen et al. (2008) documented roof damage observations associated with high horizontal stresses such has roof guttering, beam instability, oval-shaped falls, and failure propagations. There have also been a number of documented case histories of horizontal stress causing unexpected roof and pillar failures at shallow depths (Stacey and Yathavan, 2003). To the knowledge of the authors, there has only been one well-documented case of floor failure causing stability issues in an underground limestone mine. Murphy et al. (2015) documented the role that a weak, moisture-sensitive floor had in the development of a massive roof collapse. For this paper, the study site neighbored, and was in the same general geology of, the site in Murphy et al. (2015). However, the weak, moisture-sensitive floor was not present for the current study. The current study site has experienced significant floor instabilities caused by high horizontal stresses. The instability area was monitored using two different methods to determine if the floor failure would eventually propagate into roof or pillar failure. The objective of this paper is to analyze displacement monitoring measurements from string potentiometers and remote sensing techniques in an area experiencing active movement. Based on the measurement trends and observed damage from inside of the mine, the presumed failure process will be discussed."

Jan 1, 2017

By Dale S. Preece, Ruilin Yang

"Air-decks are often employed for presplitting along the final highwall of a blast and are sometimes also included at the bottom or in the middle of explosive columns in the production portion of a blast. Shock wave physics is an important part of air-deck behavior since the bulk explosives in the column impart a shock into the air-deck where the air shock then passes through the air-deck at a rapidlyattenuating velocity. Through both high-fidelity modeling and shock physics theory it is shown that theresulting pressure in the air-deck is two orders of magnitude less than the detonation pressure of theexplosive."

Jan 1, 2017

By P. Knüpfer, B. Babel, M. Rudolph, F. Perez Maldonado, U. A. Peuker, L. Ditscherlein

"In heterocoagulation processes for the separation of mineral particles, the most famous being froth flotation, the main characteristic of separation is a differing wettability of the constituents to be separated. This most crucial property in the economically important process of flotation is often only and incompletely, quantitatively described in terms of contact angles against water. A water contact angle larger than 90° is referred to as hydrophobic and hydrophilic vice versa. Looking at Young’s equation shows that it is actually the surface energy of the solid in interaction with the surrounding phases and their surface energies (or surface tensions for liquids) which describes whether there will be hydrophobic/hydrophilic hydration interactions leading to attraction or repulsion. This, we have previously published for various more or less hydrophobic minerals in correlation to their flotation response, i.e. flotability (c.f. Rudolph & Hartmann, Coll.Surf.A 513, 380-388). In the same paper we also discussed the heterogeneity of wettabilities as assessed with the novel method of inverse gas chromatography. Furthermore we have also reported on hydrophobic force distributions as assessed with atomic force microscopy which are as well due to wettability heterogeneities (c.f. Fritzsche et al., Coll.Surf.A 459, 166-171).In this paper we present wettability distributions of different substrates and particles with various surface roughnesses/shapes and degrees of hydrophobization as assessed with iGC, AFM and dynamic sessile drop analyses. We are putting the results in context in unifying models and present methodologies helpful to make use of the fundamental information and their impact on the actual industrial separation process in fundamental process models. Besides froth flotation we also emphasize the impact on selective hydrophobic flocculation process."

Jan 1, 2018

By Frank G. Horino

This report describes an instrument designed by the Bureau of Mines for quantitatively identifying texture of rock surfaces produced by grinding or extremely rough surfaces beyond the range of commercial surface measuring instruments. The transducer for the instrument is a linear variable differential transformer that converts mechanical motion caused by surface roughness, waviness, and lay to an electrical output. The electrical output is recorded graphically as an X-Y plot of the line traversed on the rock surface. Details of the synthesized device and its calibration are given. The sensitivity of the unit is 2 percent of the scale setting of the amplifier. The horizontal scale is adaptable from ¼ inch to 15 inches of specimen length with a sensitivity of 0.01 inch if a 10 to 1 magnification is used and 0.1 inch if a 1 to 1 magnification is used.

Jan 1, 1968

By Tony Rorke, Sydney Thabethe

A large overburden blast was carried out at Douglas Colliery, Middelburg Mine Services, close to a national road in South Africa. The road is a busy route between Witbank and Bethal and damage to the road could not be risked. The section of road next to the blast was particularly prone to damage, because it had been mined out on its eastern flank, and the large blast was to take place on its western flank. There were thus three potential damage risks: 1. Fly rock damage to the road surface 2. Vibration damage to the road substrate 3. Damage caused by bulk displacement of the block supporting the road into the void on the mined out side. This paper presents the design and blasting methods used to control the blast and avoid these three risks. Electronic delay detonators were used in multi-decked holes. Signature data were used to determine the blast timing to make sure that delays were used that would provide destructive interference. The timing direction and sequence was decided using wave interference patterns to direct repeated shocks away from the road. The precise detonators and the odelling capability allowed effective control of the blast vibration result. Each hole was charged with two explosive decks separated by a deck of aggregate to limit the charge mass fired per delay and thus limit the reaction forces acting towards the unsupported road. The vibration and blast results are presented in the paper, together with the design that was applied. Details are provided on how the blast was charged and primed. The detonators that were used are described and the timing design is presented.Copyright © 2004 International Society of Explosives Engineers 2004G Volume 1 - Blasting Next to an Unsupported Road Using Electronic Detonators 1 of 13 It is concluded that damage risk to nearby structures can be effectively controlled using electronic delay detonators, provided the appropriate modelling is applied to obtain the most effective delay periods.

Jan 1, 2004