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By David R. Sutfin, Joseph Lodde

110 N. Carpenter is new commercial building located in the West Loop neighborhood of Chicago, Illinois. The new home to the McDonalds Corporation work headquarters, accelerated project delivery methods were essential to meet the scheduling demands for this project along with other projects slated to start in the region. As such top-down construction methods were utilized to allow for above and below grade construction to proceed in parallel in lieu of more conventional bottom-up construction methods, thus compressing the project schedule. To achieve this plan, perimeter secant pile walls were constructed in conjunction with interior columns/drilled shafts and a shear wall core constructed from inside a temporary cofferdam. The use of secant pile walls allowed for efficient accommodation of a variety of loading conditions including: exterior curtain walls loads, perimeter column loads, tower crane foundation loads, and in-plane shear loads. Furthermore, this system allowed for efficient and fluid operation of equipment on site in order to accommodate the 90-day window allotted for initial foundation construction. INTRODUCTION 110 N. Carpenter is a recently-constructed 9-story commercial building located on the old Harpo Studios property in the West Loop neighborhood of Chicago, IL. The construction of this 55,750m2 (600,000 ft2) structure is significant to the continued commercial development of Chicago as nearly 46,450m2 (500,000 ft2) of the building houses the new world headquarters for the McDonald’s Corporation, which had moved from Chicago to the suburb of Oak Brook in 1971. McDonald’s recommitment to this urban environment is not only a reinvention of the long-established fast food giant but the anchor for a broader redevelopment of the West Loop neighborhood. Since the opening of this building was seen by the developer, the City of Chicago and others as a key to future local projects, innovative solutions were required to showcase forward-thinking design as well as expedite the construction process. The final result of the design/planning process is a structure consisting of nine levels of above-grade commercial space and two levels of below-grade parking, providing approximately 300 parking spaces. The above-grade structure consists of a reinforced concrete flat plate system, including two-way slabs, columns, and two core/shear wall systems for lateral support. With an average depth of 7m (23ft), the below-grade structure consists of interior components similar to the above-grade structure (structural slabs, columns, shear walls) but includes a perimeter secant pile wall that was designed to support lateral earth pressures; vertical forces from the exterior curtain walls, perimeter columns, and the construction tower cranes; and in-plane lateral forces to reduce the demand on and quantity of interior shear walls. The use of a secant pile wall is a key component to the project because it accommodated the use of top-down construction methods to accelerate the construction schedule.

Jan 1, 2019

By Patrick R. Taylor

Keywords: Thermal Plasma, Electroreduction, Electrolysis, Transition metals, Waste treatment, Molten oxides, Chromium oxide. An innovative process to treat transition metal oxide waste materials from diverse sources is presented. This technology involves using reverse-polarity DC plasma driven electrolysis in molten oxides. The process results in the recovery of the transition metal and other heavy metals from waste. By-products generated throughout the processing was converted to environmentally acceptable slag. The significance of this technology is that the treatment of the waste is accomplished in one step which in turn lowers the cost of remediation. Moreover, this process uses high temperature properties of thermal plasmas, which makes it possible to use molten oxides instead of halides as electrolytes. Chromium was successfully reduced from chromium oxide through the plasma driven electro-reduction process. It was shown that the selection of the appropriate ionic conducting oxides was critical for the formation of a slag that would enhance the reduction of chromium oxide.

Jan 1, 2004

By Y. Tanaka, H. Miki, Y. Aoki, H. Okamoto, G. P. W. Suyantar, T. Hirajima

Due to environmental limitations and the scarcity of freshwater, flotation using seawater or desalinated seawater as process water becomes more common for mining operations. On the other hand, seawater has been reported to affect the flotation behavior of sulfide minerals. Few reports are available on influence of pyrite depression, recycled seawater and lime consumption on flotation by using seawater. In this study, the flotation tests were performed using ore sample to investigate the effect of pH with seawater and process water used in plant on the flotation behavior in a laboratory-scale flotation cell and a pilot plant-scale. The results of laboratory scale flotation indicated that copper and molybdenum flotation kinetics decreased with increasing pH. Furthermore, the iron (mainly pyrite) recovery decreased with increasing pH. The pilot plant-scale flotation test showed that water with a higher concentration of magnesium and calcium (plant processes water) consumed a higher amount of lime. Because of low lime consumption and high copper and molybdenum recovery and grade, pH 8 is suitable compared with pH 8.5 for flotation. Keywords: seawater, process water, copper-molybdenum rougher flotation, pH, pilot test

Jan 1, 2020

By J. Petersen, K. Shaik

The traditional route utilised for the recovery of Platinum Group Minerals (PGMs) in South Africa involves the concentration of ore by flotation, followed by smelting to produce a PGM rich matte, which is then digested hydrometallurgically to solubilise base metals and Platinum Group Elements (PGE). HCl/Cl2 is conventionally used for PGE dissolution from concentrated material, which is an aggressive reagent associated with high maintenance costs as well as environmental concerns. Of interest is the leaching of PGMs directly from mineral ores, low grade concentrates and tailings in a cyanide-ferricyanide system as a more sustainable alternative. This system has shown favourable Pt recoveries among the Pt minerals, but with sperrylite (PtAs2) displaying highly refractory behaviour. The dissolution of sperrylite is investigated in a cyanide-ferricyanide system in the context of an electrochemical study involving OCP, chrono-amperometry and cyclic voltammetry. This approach allows the assessment of leaching characteristics as well as the investigation of surface passivation, which is believed to contribute to poor Pt recoveries. Some evidence is presented that such passivation is related to the formation of arsenide species on the mineral surface. Keywords: Sperrylite, PGMs, cyanide, ferricyanide, electrochemistry

Jan 1, 2020

By P. M. Solozhenkin, O. I. Solozhenkin

Currently lead nitrate is used as the recommended activator in Au-Sb flotation. However, due to high levels of hazard, the application of lead nitrate constitutes a potential risk for human health and ecosystems. To mitigate the harmful impact of activators on the environment, further research on activation by alternative reagents has been launched to promote the efficiency of antimony ores. In the present study, adsorption of lead, copper and zinc cations has been investigated by nuclear quadrupole resonance (NQR), which has revealed copper and zinc cations penetration into the mineral lattice, although lead cations remain adsorbed on the mineral surface. However, the combination of zinc and copper cations leads to preferential volumetric adsorption of zinc in the mineral lattice and further surface adsorption of copper which positively affects the activation process. It has been established that activation of stibnite can be achieved effectively with the mixture of Cu2+:Zn2+=1:1 as much as with lead cations in antimony ore flotation. As a part of this work, the computational modelling has been used in prognosis of reagent activity evaluation (PRAE) for stibnite and aurostibite flotation by sulfhydryl collectors. The lower PRAE value the stronger the ability of a collector to form a stable complex with a mineral. PRAE has shown a strong negative trend to complex formation on the mineral surface of aurostibite and stibnite. Based on these studies, several collectors have been proposed for effective flotation. To verify the feasibility of proposed collectors tetramethyl (ethyl) thiuram disulfides (TMTD and TETD) have been used for flotation of stibnite, sphalerite, pyrite and arsenopyrite. Flotation performance has been improved significantly with TMTD that allows the avoidance of lead nitrate application and increases the recovery of antimony by 8,16%. Keywords: Stibnite, aurostibite, activation, lead, copper, flotation reagents

Jan 1, 2020

By M. Rudolph, R. Tolosana-Delgado, E. Schach, M. Buchmanna, G. van den Boogaart, U. Peuker

The multidimensional characterisation of processes based on various particle properties is a key requirement for a detailed prediction on certain process streams. To access the relevant particle properties (e.g. particle size, particle density and mineral content) automated mineralogy (i.e. Mineral Liberation Analyser) is applied. The kernel density estimation is used to transfer the received discrete particle data into continuous distributions without the necessity of binning the information and the related loss of information. From these continuous distributions, multidimensional separation curves are estimated. The uncertainty of these representations is tracked via bootstrap resampling. For the evaluation of the separation efficiency of the multidimensional separation curves, the statistical entropy is calculated. The statistical entropy represents a local (for each property combination) as well as a global (for the investigated property range) measure of separation efficiency and can be weighted with various property distributions (e.g. mass or mineral mass distribution) to allow for a comparison of different parameter settings and processes. With the help of a case study of a dry magnetic separation of a cassiterite bearing skarn ore from the Erzgebirge (Germany), the methodology is presented and the results are discussed in detail. Keywords: Multidimensional, magnetic separation, kernel density estimation, mineral liberation, statistical entropy

Jan 1, 2020

By Mühlböck Marlene

Increasingly stringent global environmental regulations are forcing steel producers to continually improve the efficiency of sinter waste gas treatment. With the Selective Waste Gas Recirculation (SWGR) system from Primetals Technologies, lower production costs can be achieved and the size of downstream waste gas cleaning units can be reduced for investment savings. SWGR features the extraction and reuse of hot sinter off gas from selected wind boxes along the sinter strand, which contributes to improved energy efficiency and off gas treatment in the sintering process. With the next generation of SWGR, Primetals Technologies can provide an energy optimized, emission optimized and environmentally friendly solution that meet customer requirements and country specific regulations. This paper demonstrates the latest developments in selective waste gas recirculation, especially results from pot grate tests and comparison from lab to real plant data. Furthermore theoretical finding and mathematical modelling is presented.

Aug 16, 2017

By R. B. STEWART

A few days ago, while reading a report of the late Dr. Robert Bell in preparation for this afternoon's meeting, I found some impressive figures concerning the magnitude of the Hudson Bay basin. From the waters of the Bay itself, this great territory extends eastward 500 miles, westward l,300 miles to the Rocky mountains, and southward to the source of the Red river. It has a width of 2,100 miles from east to west, and a length of l,500 miles from north to south. Its area is almost three million square miles. It is not, of course, my intention to review the natural resources of this vast territory, but to confine my remarks to that portion of it adjacent to the waters of Hudson bay. A number of erroneous ideas exist in the minds of many concerning this northern country, especially as regards its latitude and climate. Burwell, at the entrance of Hudson strait, is in the latitude of 60 degrees or roughly that of the north of Scotland. The southern end of James bay has about the same latitude as the northern end of Vancouver .island.

Jan 1, 1928

By Susanna G. de Jager, Francis W. Petersen

"The aim of the project was to develop a methodology applicable to different South African coal types to be able to predict with a high degree of certainty what kind of reagent will be suitable for flotation of a certain coal type.The study included 5 coal samples from different collieries and included Highveld seam 3 and 4 coal (as one sample), Waterberg coal (zone 10 -11), Highveld seam 5 upper coal and Witbank seam 2 and seam 4 coal. Seam 3 and 4 (mixture) coal, Waterberg and the seam 5 upper coal were all found to be vitrinite rich coals. The coal characterisation study included petrographic analysis, proximate analysis, float-sink analysis, oxygen-containing functional groups, surface extraction, flotation release analysis and contact angle measurements.The flotation tests showed that the best reagents to float all of the coal samples studied are iso-decanol and dodecene. These reagents produced flotation products that are near to the release curve. Statistical relationship for predicting ash content and yield that can be expected for a certain coal type and selected collector was obtained. From the relationship, the accuracy of the yield is above 95% (p-value below 0.05) with a linear regression of 0.9289. The accuracy of the ash is slightly lower with a linear regression of 0.7841 but also above 95%."

Jan 1, 2003

By Vladimir G. Kochnev

An innovative AG and SAG technology aimed to be applied in grinding of ores and in the production of construction materials is described. A novel design of a cantilever-type mill capable to operate in autogenous, semi-autogenous and ball grinding mode ensures easy delivery and installation even in remote areas, and low capital and operating costs. Results of the tests of the new heel-shaped liners performed by TTD jointly with ALROSA, MINTEK and Anglo-American Corporation are reported. The approach includes also a novel discharge grid design and a technique of treating the material of critical size. These innovations make grinding in AG and SAG mills dramatically more effective, with an increase in the throughput rate and a reduction in power consumption ranging from 1.5 to 2 times.

Jan 1, 2003

By F Soleimani

Coal and gas outburst is a common hazard in coalmines and due to the complexity of its nature, efficaciously predicting the possibility of its occurrence is intricate. The mechanical and gas flow properties of coal, in situ and mining-induced stresses and geological structure are involved in outburst occurrence, whereas suggested thresholds for its prediction do not consider them all. Numerical modelling is known as an effective method that can not only consider couple the effect of different physics but also analyse the effect of associated parameters. In this paper, a coupled fluid flow and geomechanics model has been developed in COMSOL Multiphysics to simulate outbursts by considering the effect of gas pressure and composition, damage mechanics on related coal properties, and progressive excavation and mining-induced stress. For the proposed fully coupled outburst model, the effect of pore pressure and sorption are applied to the stress while the influence of stress changes and damage are considered in updating coal porosity and permeability in each time step. In addition, to study the effect of mining-induced stress, the excavation process is simulated by changing the material properties over time according to the schedule of heading development. Then, outburst initiation is analysed from the energy point of view by using the concept of energy conservation law. The simulation results are used in calculating energy sources of the outburst initiation, also, the effect of particle size and ejection velocity are studied, and the significance of particle size effect on the energy analysis and deformed coal on outburst initiation is discussed.

Oct 12, 2022

By R G. Reddy, Z Zhang

Viscosities of CaO-aluminosilicate ternary melts were estimated using a structure-based model. The model considers depolymerisation effects and related breakdown of the silicate network structure on the addition of metal oxides to the melts. The predicted values are in good agreement with the experimental values over the whole temperature and composition range.

Aug 21, 2024

By J Zhou, L Crompton, K P. Galvin, J L. Sutherland, C P. Lowes, C Bezuidenhout, J Bijzet

Platinum Group Metal (PGM) bearing ores from the Upper Group 2 (UG2) reef often contain significant concentrations of chromite which can potentially be upgraded to produce a saleable product. A common approach is to implement gravity separation on the PGM flotation circuit tailings. However, where the particle size range of interest is broad and the lower size limit ultra-fine, the challenge is how to maximise the recovery at a saleable product grade without compromising throughput. This study was concerned with the performance of a REFLUX™ Classifier for beneficiation of a PGM bearing chromite ore and the benefits of size classification. The sample had a nominal top size of 0.5 mm and was processed over the complete size range and in two discrete size classes following classification at 106 µm. The primary goal was to produce a concentrate exceeding 40 wt. per cent Cr2O3, ideally approaching 42 wt. per cent Cr2O3, with minimal PGM losses above 106 µm. A major challenge was to process at the required solids throughput in a single stage with the feed pulp density constrained to a nominal upper limit of 30 wt. per cent solids. It was found that varying the controller density set point of the REFLUX™ Classifier produced strong control of the product grade. Products as high as 41.1 wt. per cent Cr2O3 were produced at 78.6 per cent recovery for the +106 µm material, while in the −106 µm portion the product grade was as high as 41.4 wt. per cent Cr2O3 at 83.2 per cent recovery. Processing the feed in discrete size classes enabled the volumetric feed and fluidisation rates to be optimised for a given application; hence, superior performance was achieved at the finer sizes. This work has demonstrated the value in considering feed preparation as well as technology selection in developing a robust process solution.

Aug 24, 2022

By G H. Park, Y J. Jun, J H. Park

The carbon solubility of the CaO-Al2O3-FeO-SiO2-MgO slag, the main system formed in the Ruhrstahl-Heraeus (RH) vacuum degasser, was measured at 1873 K to understand the effect of slag compositions on the carbon contamination in the ultra-low carbon (ULC) steels. The stable form of carbon was demonstrated to be carbonate by plotting the log [(wt%C)/aC] ratio against the log p(O2) which ranged -11 < log p(O2,atm) < -9. The carbon solubility of the CaO-Al2O3-FeO-SiO2-MgO slag can be estimated using thermodynamic model. The distribution ratio of carbon increased with increasing concentration of FeO due to the FeO reduction reaction and increased basicity of slag. The carbonate capacity of the CaO-Al2O3-FeO-SiO2-MgO slag can be expressed as a linear function of the activity of lime and the optical basicity.

Jun 19, 2024

By S Serp, M Duchateau, P Chevreux

Molten salt reactor (MSR) is a promising advanced reactor system aiming to the transmutation of minor actinides such as americium in order to reduce the inventory of ultimate nuclear waste. The fuel is a molten salt in which actinides are homogeneously dissolved in the liquid phase. A chloride salt may be retained for this concept, as it provides low melting point, high solubility of actinides, harder neutron spectrum. To avoid corrosion and precipitation issues, molten salt composition has to be carefully controlled with impurity content as low as possible. Obtaining pure actinide chlorides without contaminants such as oxide, oxychloride, hydroxide and water is still a challenge. To prepare actinide-bearing salt, the chlorination of actinides oxides was investigated in an unstirred reactor under flowing gas as solid-gas reaction. The carbochlorination of PuO2 were performed in the temperature range of 600 to 800°C with chlorine gas as a chlorinating agent and the presence of solid carbon. PuCl3 was successfully synthesised by this method and characterised by X-ray diffraction measurements but some impurities such as oxide phase remain inside the formed product. Refinements of anhydrous and hydrated PuCl3 phases by Le Bail method were also performed for crystalline materials definition. Conversion mainly depends on the chlorinating temperature and the contact between the oxide and the chlorinating agent. A conversion value of 70–80 per cent was achieved at 700°C from PuO2 with quite high specific surface area. The conversion rate was not improved with increasing the chlorination time. The volatilisation of Pu was observed during the carbochlorination experiments. To avoid a loss of Pu caused by sublimation, the chlorination temperature should be limited to 650°C despite that the conversion of PuO2 to PuCl3 was enhanced by increasing temperature. Both carbochlorination and hydrochlorination of AmO2 were also carried out leading to the formation of AmCl3. These first results suggest that americium oxide was chlorinated more readily than plutonium oxide. The purity of produced PuCl3 and AmCl3 still deserves further investigations.

Jun 19, 2024

By D. J. Buchanan

British Coal's mining research programme is directed towards the strategic objectives of reducing production costs, improving product quality and resolving health, safety and environmental issues. The strategy for R&D is described and selected parts of the programme are reviewed. Two major initiatives are directed towards reducing production costs: geotechnics and automation. Integrated exploration techniques are used to delineate geological structures as an aid to mine planning. Rockbolting is being rapidly introduced and the in situ stress field has been found to be of significant influence. Automation is the subject of a major programme. A strategy for coal quality has been devised. The health, safety and environmental programme concentrates on the traditional hazards together with surface environmental problems.

Jan 12, 1992

By N Pranoto, E Lawell, T Dean, M Grant

The Goonyella Riverside Mine is located 30 km north of Moranbah in Central Queensland, Australia. Recent mining activities have exposed the north–south striking Kenya and Zimbabwe thrust Faults. These faults vertically offset coal seams by up to 25 m and locally thicken coal packages through imbrication of coal seams. The presence of back-thrusts add to the geotechnical complexity of maintaining highwall stability. The Kenya and Zimbabwe Faults have provided multiple challenges to the mining operation, with an unplanned additional 240 kt of coal tonnes being mined from imbrication of coals seams or from the refinement to local scale geological models. These additional coal tonnes have been either identified during the mining of the coal seam or just prior to overburden removal above the coal seam. These faults can also negatively impacted highwall stability with highwall failures, lowering the overall slope angle for pit designs and increasing stand-off distances for hazardous highwall conditions. Unmanned Aerial Vehicles are used to scan exposed highwalls and enable geological mapping via high-quality 3D images. Measure while drill data from drill and blast rigs can provide local-scale intersections of the faults and coal seams. Mine Geologists utilise these and other data sets to create localised geological models refined position of the fault planes and coal seams. These models are utilised by relevant mine site teams to ensure the safe and efficient mining of coal around these faults.

Mar 22, 2022

By R. L. Grayson, W. E. Wallace, J. W. Stephens, M. D. Attfield, P. S. Brower, V. Vallyathan, M. J. Keane, J. C. Harrison

Pure respirable quartz is a known pathogenic agent for lung disease. However, for mixed dusts, neither mineralogical nor in vitro cytotoxicity assays unequivocally predict the contribution of quartz to their pathogenic potential.First, although Coal Workers' Pneumoconiosis (CWP) and Progressive Massive Fibrosis (PMF) prevalence have been found to correlate with total respirable coal mine dust exposure, and with coal rank (Attfield and Morring, 1992), epidemiological studies generally have not found the quartz component of coal mine dust as measured by X-ray diffraction or infrared spectroscopy (each of which essentially measures the mass-percent quartz in a bulk sample) to be clear predictors of CWP prevalence or incidence (Walton et al., 1971). Second, the properties which distinguish the extreme fibrogenic potential of quartz are not revealed by conventional in vitro bioassay comparison with other silicate mineral dusts. As an example, quartz and kaolin (aluminosilicate) clay in vitro cytotoxicities are comparable for lavaged primary pulmonary macrophages.The studies discussed here address these two anomalies from a general hypothesis that the pathogenic activity of respired quartz particles is associated with properties of, and interactions with, the particle surfaces. One factor in the expression of toxic activity by a particle surface is the biological availability of that surface. Anomalous lack of correlation of disease prevalence with mass percent quartz in exposures to some mixed composition respirable-sized dusts suggests that individual particle surface features, invisible by bulk sample mass analysis, may alter the biological availability of a fraction of quartz particles in a dust. For pure-surfaced mineral particles, the comparably strong prompt membranolytic activities of quartz and kaolin in vitro suggest that upon deposition of such particles in the lung there must be other interactions with particle surfaces which distinguish quartz. This might be due to toxic surface-associated sites specific to silica, or to interactions of other sites on other mineral particles which affect the biological availability of their toxic functional groups. For example, alurninol groups on clays affect the availability or activity of adjacent silanol groups. Surface activities which distinguish quartz pathogenici ty might be manifest in one or more of the sequential interactions upon deposition in the lung; first with the pulmonary surfactant system, then with extracellular and phagolysosomal enzymatic digestive processes, or with subsequent cytotoxic processes.

Dec 1, 1995

By G. Gomathi, K. Asokan, K. Subramanian

An electrochemical reactor with anode and cathode chambers separated by a composite perfluoro polymer cation exchange membrane was designed, fabricated and used for the reduction of dissolved carbon dioxide under ambient conditions to formate. The flow reactor enhanced the mass transfer of carbon dioxide compared to the batch reactor. Experiments were conducted using two different perfluoro polymer membranes - Nafion 961. Efficacy of CO2 reduction on various cathode materials (Cd, Pb, Sn and Zn plated stainless steel woven mesh) were determined. Optimum values of flow rate and current density were evaluated for the energy efficient formation of formate in aqueous KHCO3 (pH 7.5-8.5) buffer solutions.

Jan 1, 2008

By Martin B. Hudson, Kenneth S. Hudson, Gwendolyn Arreguin

A twin high-rise project site in Century City posed several foundation engineering challenges for the design team. One portion of the twin high-rise project site was required to utilize top-down construction in order to allow a driveway to remain open during construction of the project’s 40-foot deep excavation. The challenge was compounded by the need to utilize a mat foundation to support the high-rise construction and yet have temporary drilled shafts through the mat foundation area that would not create excessive differential settlement. This was accomplished by constructing a deck supported by eight drilled end- bearing drilled shafts with Osterberg load cells and five 7-foot-diameter end-bearing drilled shafts. The Osterberg load cells served to verify the capacity of each of the drilled shafts and preload the soils at the drilled shaft tips. The 7-foot-diameter shafts were constructed with bond breakers to prevent skin friction but instead mobilize end bearing (for settlement compatibility with the surrounding mat foundation). After the drilled shafts were placed, then top-down construction began beneath the driveway, leaving the driveway supported on the drilled shafts. Construction challenges included drilling of the shafts through previously abandoned tieback anchors from an adjacent parking structure basement, as well as cemented layers within the rock materials. The paper describes the use of the various analytical methods used to calculate capacities and check settlement compatibility, the construction and testing methods utilized, and the construction challenges encountered. INTRODUCTION Wood Environment and Infrastructure Solutions, Inc. (hereafter referred to as Wood) performed a geotechnical investigation for the New Century Plaza currently being constructed in the Century City District of Los Angeles, California. The New Century Plaza project consists of the construction of two new towers (designated as North and South Buildings) and the rehabilitation of the existing Hyatt Regency Century Plaza Hotel. The existing hotel tower is 15 stories in height above the existing grade and is underlain by four subterranean basement parking levels. The new North and South Buildings will stand approximately 46 stories in height above the existing grade to accommodate residential use. The new towers are planned west of the existing hotel. The site was previously occupied by the existing hotel subterranean parking structure and overlying podium structure, and a loading dock in the southwest portion of the site. The former western portion of the podium and subterranean parking structure west of the existing hotel building western edge were demolished to allow for new subterranean levels, a new podium structure, and the new towers. The lowest floor of the proposed subterranean level required excavation on the order of 35 to 80 feet.

Jan 1, 2019