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By R Belissont, C Veloso, L Senez, F Vasconcelos, E Kleiderer, J Mesquita, Y Basselin

Mont-Wright mining complex is an important asset of ArcelorMittal located in the province of Quebec, Canada. It is composed by Mont-Wright and Fire Lake mines, operating 365 days per annum, and producing 25 Mtpa of iron ore concentrate with 66 per cent Fe. Mont-Wright concentration plant is composed by seven lines with a flow sheet encompassing AG/SAG milling, primary and secondary classification stages, spiral concentrators (rougher, cleaner and recleaner stages) and dewatering unit operations. In this context, an equation called ‘Wrec’ was developed in 1971 with the objective of estimating the mass recovery of the different blocks in the beneficiation plant and support the mining planning works of Mont-Wright complex. This equation was based on the correlation between the results of heavy liquid tests performed with drill core samples and spiral concentrators pilot scale tests, returning an estimative of concentrator yield. However, since its first development, no updates have been done in the equation, which lead to some deviations from expected recoveries in the last years. This is probably due to the changes in the process and in the ore fed into the concentrator during the period. In this way, the study presented here corresponds to the execution of heavy liquid/spirals pilot scale tests with 26 composite samples collected at Mont-Wright deposit aiming at revising and updating ‘Wrec’ equation. Based on test work results, an updated formula was established to estimate the plant recovery and a comparison performed using industrial data showed that the old formula overestimated the real yield by 5.40 per cent, on average. At the end of the study the new equation was incorporated into the mining planning process.

Sep 18, 2023

By Verya Nasri, Behrouz Esmaeilkhanian, Mohammad Motallebi

Réseau Express Métropolitain (REM) is the new Light Rail Transit (LRT) network of Montreal, Canada. This new LRT network uses a century-old Mont Royal Tunnel (MRT) to connect Downtown Montreal to the north side of the Island of Montreal by passing through Mount Royal Mountain. This railway double track horseshoe tunnel is approximately 5 km (3.1 mi.) long, 8.8 m (29 ft.) wide and 5.5 m (18 ft.) high, with a constant 0.6% grade. Due to different geological characteristics of the surrounding ground, varied from hard rock to soft soil, different cross sections and excavation methods were adopted for construction of this tunnel. In order to use MRT in the modern transit system, the tunnel needed to be inspected, rehabilitated and be compliant to the recent safety standards. This paper presents a summary of history and characteristics of the existing tunnel plus the implemented steps to upgrade the tunnel. It includes the details of the structural inspection and rehabilitation methods of the tunnel. Further, this paper summarizes the procedures for the space proong, construction of the separation center wall, and the tunnel enlargement. It also describes parts of complications encountered during the construction and solutions implemented to tackle these issues.

Jun 23, 2024

By James Carroll, Lance Heyer

This paper describes the shaft design and construction for a 72-inch microtunnel under 14 active railroad tracks in Avondale, Louisiana. Initial shaft design for a deeper tunnel alignment considered secant piles with a jet grout plug. Final design for a shallower tunnel alignment included contractor input with support consisting of braced sheet piles with a jet grout plug. The authors further elaborate on jet grout implementation in very soft organic clay soils and the practical limitations of jet grouting. This paper emphasizes how all project participants worked together to utilize value engineering and alternative delivery on a unique tunneling project with a focus on temporary shaft support.

Jun 23, 2024

By Ross K. Digby

The Victorian Tunnelling Centre (VTC) has evolved its purpose from purely training workers, to a tunnelling industry education city. The VTC has now focused its activities on the areas of technology; education and training; applied research; and career education. were identied as the hus around which activities would e conducted to create a tunnelling industry education city. The VTC provides ustralias tunnelling industry with an education facility that not only provides laour training, ut enales the industry to come together to meet, participate in product launches, undertake research, work with new technologies and promote tunnelling careers.

Jun 23, 2024

By Suzanne R. Hess-Brittelle, Sharon L. Schulz, Tyler J. Quick, Amy F. Ebnet

"Abiquiu Dam is a rolled earth fill dam with impermeable core located on the Rio Chama in New Mexico. Abiquiu has had a history of excessive seepage through the fractured sandstone abutments since water was first impounded in 1963. The foundation was treated with a single row grout curtain in the cutoff trench prior to placement of the embankment. During the 1960’s and 1970’s, the grout curtain was extended 1,000 ft. into both abutments and sections of the foundation beneath the embankment were regrouted. Grouting of the foundation beneath the embankment required drilling through the embankment. Drilling fluid loss or loss of circulation within the impervious core was observed during multiple phases of supplementary grouting and during verification drilling following the 1970’s grouting program. It is likely that the drilling methods employed for these grouting and drilling programs caused hydraulic fracturing of the impervious core. The fluid losses in the embankment may be related to seasonal shutdown layers in the embankment or benches in the abutment foundations. In addition, it is likely that the impervious core was fractured from grout pressures during installation of grout pipe through the embankment.INTRODUCTIONAbiquiu Dam is located on the Rio Chama in New Mexico and consists of a rolled earth fill dam with impermeable core, controlled outlet works, and an uncontrolled rock-cut spillway. The dam was authorized for flood control and sediment retention and was designed as a dry dam, holding flood pools for relatively short durations. The foundation is comprised of Permian and Triassic age, interbedded mudstones and sandstones that were deposited in an active braided stream system. Sandstones are moderately fractured and have variable aperture and infilling. Generally speaking, joints are near vertical. Abiquiu has had a history of excessive seepage through the fractured sandstone abutments since water was first impounded in 1963. The foundation was treated with a single row grout curtain in the cutoff trench prior to placement of the embankment. In 1966-1968, the grout curtain was extended 500-ft into the left abutment and the foundation beneath a 560 ft. section of the embankment was re-grouted. In 1978-1980, the grout curtain was extended 1,000 ft. into the right abutment, an additional 500 ft into the left abutment and the foundation beneath the right 520-ft section of the embankment was re-grouted. The alignments of these grout programs are shown in Figure 1. Grouting of the foundation beneath the embankment required drilling through the embankment. Drilling fluid loss or loss of circulation within the impervious core was observed during both phases of supplementary grouting and during verification drilling following the 1978-80 grouting program. It is likely that the drilling methods employed for these grouting and drilling programs caused hydraulic fracturing of the impervious core. In addition, it is likely that the impervious core was fractured from grout pressures during installation of grout pipe through the embankment. This paper provides a summary of the drilling and grouting methods used during these programs and the potential for damage to the embankment."

Jan 1, 2016

By D M. Verster, P L. Gillot, A Kone

Randgold ResourcesÆ MorilaÆs gold leach plant is subjected to uncommon æoxygen stressesÆ. Feed ores exhibit very high oxygen demands, primarily caused by iron sulfides. In addition, ore oxygen demand varies significantly over time, as well as between different feed ore sources. The inability of the Morila gold leach plantÆs oxygenation system to cope with these high and fluctuating oxygen stresses manifested itself in variable gold residue grades, and cyanide consumption rates.Management launched a Morila oxygen system review project during September 2009, with the objective of auditing the performance of the then current oxygenation system, against required performance parameters as calculated from oxygen demands of the various feed ore types and targeted dissolved oxygen levels in the leach train.This paper describes the systematic changes made since 2009 to the Morila oxygen system in four main areas: O2-supply plant, O2-volumes, O2-controls and oxygenation equipment. Data are provided on corresponding improvements in leach plant performance. Theoretical, as well as practical aspects of gold leach oxygenation systems are covered.CITATION:Verster, D M, Gillot, P L and Kone, A, 2013. Oxygenation system upgrades and leach plant performance improvements at Morila Gold Mine - 2009 to 2012, in Proceedings World Gold 2013 , pp 215-224 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Chu E. Ho, Paul Napoli

This paper presents the performance of nineteen open-ended steel pipe piles driven through highly variable overburden soils into glacial till and schist bedrock. The piles were 16 inches in diameter and 0.656 inches thick, with yield strength of 50 ksi. The piles were designed for a service capacity of 250 kips and were driven to achieve an ultimate geotechnical capacity of at least 500 kips. Due to the large variation in the ground conditions, installed pile lengths ranged from 25 to 66 feet. Some piles were driven to refusal on the bedrock while others were terminated at final driving resistance of 2 to 7 blows/in. Two piles were suspected to be plugged during driving while others did not. Each pile was instrumented with strain gages and accelerometers near the pile top, and observed using a Pile Driving Analyzer (PDA) to provide preliminary guidance on pile capacity achieved at end of initial drive (EOID). The influence of plugged and unplugged pile toe conditions on the interpretation of pile capacity was investigated using Case Pile Wave Analysis Program (CAPWAP). Characteristics of driving energy, compressive and tensile stresses developed in the steel pipe piles, and the resulting pile deformation behavior are discussed. INTRODUCTION The Hunters Point South redevelopment in Long Island City, Queens is one of New York City’s major efforts to transform former manufacturing zones into mixed developments for the middle-income community. The site is located along the eastern shoreline of the East River and Newtown Creek. The development included low to high-rise residential buildings, a public school and retail structures. Open spaces were created along the East River and Newtown Creek waterfronts in the form of a continuous park providing for recreational and community related activities. Waterfront structures included small park buildings, walkways and viewing platforms with the shoreline protected by revetments as part of the City’s flood mitigation strategy. The project was implemented in two phases, with completion of construction for Phase 1 in 2013 and Phase 2 in 2019. Based on available historical information, extensive reclamation took place between 1855 and 1898. After 1951, changes to the shoreline were made along the East River, including the removal of reclaimed land along the northern portion of the project site to allow for docking facilities. By 1977, these facilities had been demolished and backfilled to form the current shoreline configuration. The present site was temporarily used as a parking lot with stockpiles of fill mixed with construction demolition rubble, rip-rap and boulders of varying heights across the site. The existing ground surface varied significantly up to approximately 25 feet difference in elevation. The stockpiles were removed and the site was re-graded during final development of the project. This paper discusses the foundation design challenges due to the loose overburden soils and potential obstructions within the fill material, in particular, the issues relating to installation of open-ended steel pipe piles through the ground conditions encountered on site.

Jan 1, 2019

By Abdelmalek Bouazza, Aamir Mahawish, Will P. Gates

Bio-grouting by means of microbial induced calcite (calcium carbonate) precipitation (MICP) to improve mechanical properties of granular soils has gained much attention in recent years. The biogrouting process offers an alternative and environmentally friendly approach to conventional soil improvement techniques, such as cement. Bio-grouting by urea hydrolysis has been extensively applied to tackle various geotechnical problems. However, it has yet to be applied to improve engineering properties (compressive strength) of a coarse cohesionless material with the aim using it as sand/stone columns within soft and very soft soils. This paper investigates the effect of using light, moderate and heavy biochemical treatments on the unconfined compressive strength (UCS) of coarse sand columns. In addition, the microstructure of the bio-cemented coarse material has been analysed by X-ray computed tomography (XRCT). The experimental results revealed that the UCS could reach up to 200kPa, 1000kPa and 5500kPa for light, moderate and heavy bio-cemented coarse sand columns, respectively. The microstructure investigations showed that the deposited calcium carbonate can be identified using XRCT imaging and can be associated with the gain in UCS values. Various microstructure properties, such as void ratio, dry density and porosity were also identified and compared with the laboratory data.

Jan 1, 1900

By David B. Reger

New discoveries of gas in the southern counties featured the petroleum industry in West Virginia during 194;. Drilling for oil increased slightly over 1944 and a small increase of initial production resulted. Out of 28 wildcats drilled, there were 16 gas discoveries and 12 dry holes. No commercial oil was found in the 28 wells.

Jan 1, 1946

By Arash Khosravifar, Nason McCullough, Stephen, Milad Souri, Scott Schlechter, E. Dickenson

The results of five centrifuge models were used to evaluate the response of pile-supported wharves subjected to inertial and liquefaction-induced lateral spreading loads. The centrifuge models contained pile groups that were embedded in rockfill dikes over layers of loose to dense sand and were shaken by a series of ground motions. The p-y curves were back-calculated for both dynamic and static loading from centrifuge data and were compared against commonly used API p-y relationships. It was found that a significant reduction in ultimate soil resistance occurred in dynamic p-y curves in partially/fully liquefied soils as compared to static p-y curves. It was also found that incorporating p-multipliers that are proportional to the pore water pressure ratio in granular materials is adequate for estimating pile demands in pseudo static analysis. 1. INTRODUCTION Liquefaction-induced ground deformations can cause severe damage to pile-supported wharves and other waterfront structures. A common approach in analyzing the lateral behavior of piles against seismic loads is using the beam on nonlinear Winkler foundation (BNWF) or p-y spring analysis. One common p-y relationship for sand is the one proposed by the American Petroleum Institute, also known as the API sand model (API 1993). While the API sand model was originally developed for the static loading conditions, it is common to modify the API sand curves for the effects of cyclic loading. However, there is no consensus on how to modify the static p-y curves for the effects of liquefaction and pore water pressure generation in loose granular soils. In previous studies, p-y springs of piles in liquefying soils were back-calculated from case histories, centrifuge model studies (e.g., Wilson et al. 2000; Brandenberg et al. 2005; Abdoun et al. 2003), full-scale tests (e.g., Rollins et al. 2005; Chang and Hutchinson 2013), and numerical analyses (e.g., McGann et al. 2011). In general, these studies found the softening effects of soil liquefaction on p-y curves, as well as a hardening behavior attributed to the dilative response of the liquefied soil around the pile. However, these studies provide varying recommendations on how to modify the static p-y curves to capture this complex behavior. Some design guidelines propose softening the static p-y curves using p-multipliers (e.g., Caltrans 2012). Other studies propose an upward concave shape for p-y curves in liquefied soils (e.g., Franke and Rollins 2013; Chang and Hutchinson 2013).

Jan 1, 2019

By A. C. Galvis-Castro, R. Salgado, M. Prezzi, E. Ganju, R. D. Tovar-Valencia

It is generally accepted that the unit shaft resistance of piles in sands is lower for tensile loading than for compressive loading. So far, very little attention has been paid to the influence of the installation method on the tensile-to-compressive unit shaft resistance ratio. The objective of this paper is to analyze the effect of installation method on the ratio of unit shaft resistance in tension to that in compression for a model pile installed in a dense silica sand. To study installation effects, load tests on model piles were carried out in a half-cylindrical calibration chamber with digital image correlation (DIC) capability. The model piles were either jacked in one stroke using a constant rate of advance, or pre-installed into the dense sand samples. Digital images of the model pile and sand were taken during the load test and processed using DIC to obtain the displacement field in the sand. It was found that unit shaft resistance was essentially the same in tension and compression for the pre-installed pile, however for the jacked pile, the unit shaft resistance in tension was approximately half of that in compression. DIC analysis revealed that: (1) during the load test, more displacement occurs in the soil domain for the pre-installed pile compared to the jacked pile, (2) for the jacked pile, the magnitude of displacement in the soil domain is greater in tension than in compression and (3) for the pre-installed pile, the magnitudes of displacement in tension and compression are similar. INTRODUCTION Pile foundations can be categorized into two main types depending on the method of installation: displacement piles (e.g., jacked or driven piles) and non-displacement piles (e.g., bored piles or drilled shafts) (Basu et al. 2010; Salgado 2008). The response of these piles to loading can be studied in the laboratory by means of calibration chamber experiments on model piles that are either jacked into the samples, representing displacement piles (Jardine et al. 2005; Lee et al. 2011; Tovar-Valencia et al. 2018), or pre-installed in the sand sample, representing non-displacement piles(Galvis-Castro et al. 2019a; Le Kouby et al. 2013; Tehrani et al. 2016)

Jan 1, 2019

By Frank Rausche, Scott D. Webster, Rozbeh B. Moghaddam

"Pile foundation driveability is a function of several variables such as subsurface characteristics, hammer type, hammer efficiency, pile type, and plugging conditions. One important phenomenon occurring during pile driving, and yet not well documented and published, is the friction fatigue, where a reduction of shaft resistance is observed as the pile is driven to greater embedment. This paper introduces current soil models developed for the assessment of friction fatigue, and further presents a comparison between predicted driveability obtained from Wave Equation Analysis Program (GRLWEAP) and field driving records. From a literature survey, and review of technical articles, a widely-used soil model known as AH-01 has been selected to analyze the friction fatigue concept. Using a WEAP software, two driveability analysis were completed using the standard approach with setup factors, and adapting the AH-01 model into the WEAP input file. Driveability predictions were compared to the driving records corresponding to a 1676-mm x 44- mm open-ended pipe pile with a total and embedment lengths of 180-m and 119-m, respectively. Results from analyses and the comparison presented in this paper provide further information regarding existing methods for the incorporation of the friction fatigue concept to the driveability analyses, and contributes to a better prediction of driveability of open-ended pipe piles. IntroductionDynamic measurements during pile installation provide more dependable information as compared to results obtained from predictive models used for design. Despite uncertainties associated with a specific project site and foundation type, measured data provides a reliable understanding of the soil resistance and its distribution throughout the length of the pile. Back-calculations or back-analyses based on a series of measured data from a pile driving process could help to obtain reliable models to better predict events related to pile installation process in spite of all variability related to fitted models. One of the widely-used analysis regarding pile driving during the design phase is the “driveability analysis” where capacity, blowcounts, maximum stresses in the pile element, and transferred energy from the hammer to the pile element are predicted using mathematical models along with a software. Such analysis requires relevant information regarding soil, pile, and hammer properties combined with a deep understanding of the level of impact each one of these properties could have on the analysis."

Jan 1, 2017

By Nihal Bohra

A temporary bridge, supported on steel pipe piles, was built to expedite the construction of a breakwater structure off the western coast of Peru. The bridge provided access for dump trucks to the breakwater across a 342 m (1122 ft.) wide navigation channel from a liquefied natural gas (LNG) loading facility, at the end of a 1.3 km (0.82 miles) long permanent trestle, in 15 m (50 ft.) water depth. After the completion of the breakwater, the temporary bridge was removed, and the piles were extracted approximately one year after the initial driving. The bridge deck was typically supported on pairs of 914.4 mm (3 ft.) diameter, 18 mm (0.708 inch) wall steel pipe piles spaced at 7.5 m (24.6 ft.) across the bridge width and 18 m (60 ft.) along the bridge length. In an attempt to reduce the driven pile embedment, an inner closure plate was installed at 2.7 to 7 m (9 to 23 ft.) from the pile toe to force closed-end behavior. The piles were designed to carry 3400 kN (383 tons) axial compression load, and a minimum of 8 m (26 ft.) embedment was specified to provide sufficient resistance to the lateral loads. The subsurface conditions consisted of cemented conglomerate of sand, gravel, pebbles and some boulders, locally known as the Cañete Formation. The driven pile embedment varied widely, between 8 to 24 m (26 to 79 ft.). A significant portion of each pile was above the seabed, passing through seawater and up to the bridge deck, and was therefore unsupported. The extraction of the piles was challenging due to the subsurface conditions, presence of significant water column, pile weight, and the inner closure plate. Several different approaches were attempted before the piles could be successfully extracted. This paper summarizes the difficulties encountered and observations made during the driving and extraction of these piles.

By Jeffrey C. Schuh, Logan Bloemer, Daniel P. Dietzler

Over the past 30 years, the authors have encountered numerous projects where recognizing the geology, soil properties and groundwater conditions, and considering alternative construction techniques have promoted efficient and cost-saving construction. The construction documents for these projects, produced by various engineering firms, provided basic information on geotechnical conditions. The authors became involved in each project either because there was a problem during design or construction or, as a contractor, won the project because they saw a value engineering opportunity to take advantage of the geologic setting of the project to design and build alternatives to what the designer depicted. Understanding the geologic setting is critical before planning and designing begins. Being able to work with the geology and the materials on site is preferred before specifying more costly and complex solutions, which often require the importing of materials and adherence to unnecessary and/or inappropriate specifications. Failing to understand the geology or not knowing all the techniques available for construction can lead designers to develop solutions that could be inappropriate. This paper presents several examples of value engineering and project performance enhancements developed through knowledge of basic soil mechanics and implementing innovative solutions. History and Background Most people attend DFI meetings, present their experiences, listen to others, and read articles and papers with the hope they can learn from others. Geotechnical engineers and contractors often interface with others in the execution of projects who have, at best, a rudimentary knowledge of geology and soil mechanics. Of course, there is a need for architects, bankers, and regulators, etc., but they typically do not have much interest in the nuances of geotechnical engineering, which relies on both art and science. Thus, significant time is spent educating counterparts in the need for comprehensive subsurface investigation programs and the intricacies of construction in the “dirt,” as they typically refer to soil and rock.

Jan 1, 2019

By Giulia M. B., Ferruccio Cribari, Alessandro Bertero, Eliano Romani, Roberto Sorge, Francesca Casini

"The use of Artificial Ground Freezing (AGF) to form earth support and seepage control barrier systems has had applications worldwide. These cover a variety of construction problems, including the formation of frozen earth walls to support deep excavations, structural underpinning for foundation improvement, and temporary control of ground water in construction processes. An application of AGF during construction of Line C of Rome underground is described in detail.The new line “C” of San Giovanni metro station was constructed adjacent to the existing line “A” of San Giovanni station; the new metro line “C” is deeper than line “A” and runs below the existing station. The underpass project envisages an Artificial Ground Freezing in order to create a structural and waterproof temporary cut-off suitable to the two new tunnels excavation, while keeping trains running in the safest possible condition. The excavation of tunnels under the water table, with a hydraulic head of over 10 m in not homogeneous soils having different mechanical properties and permeability and below existing sensitive structures, involves special ground freezing sequences and methods, as well as peculiar drilling systems and operations, such as TDDT (Trevi Directional Drilling Technology).Artifical Ground Freezing IntroductionNatural freezing occurs seasonally in many areas of the globe and can affect negatively the engineering performance of geotechnical structures; on the other hand, man-made freezing is a controllable process that can be used by civil engineers to stabilise temporarily the ground in order to support and/or exclude groundwater from an excavation until the final retaining and lining structures are constructed. Freezing and thawing of the pore fluid within soils involve complex thermal, hydraulic and mechanical processes that have significant mutual interactions. For example, phase changes of the pore fluid caused by temperature variations can modify the pore water pressure in the soil, which, in turn, can induce mechanical deformation. At the same time, any changes in the hydraulic and mechanical conditions affect the thermal processes by advection and changes of ice and water contents.An application of AGF which will be presented in the paper, refers to the construction works of Line C of Rome underground. In this case AGF was carried out to provide temporary support during excavation of the two Line C running tunnels directly underneath the existing S. Giovanni station of Line A, in the safest possible condition. In order to keep the trains of Line A operational during excavation, a temporary structure was installed and a real-time monitoring system was conceived in order to control the temperatures of the soil during freezing and the response of the structures of the existing station."

Jan 1, 2016

By Ernesto Furtado de Mello Neto, Eliezer Thuler, Claudio Vano Nunes, Carlos Alberto Cristofari

The Brazilian steel industry is dealing an adverse scenario with direct competition from global emerging markets. In this scenario, the need to improve asset operational performance, makes complex studies involving technical knowledge and asset life behavior, become important tools to support companies strategic accomplish. These studies allow consider performance, costs and operational risks relationship in the decision make process. The Asset Management approach support these studies in order to observe the whole asset life cycle, understand value chain through all company process and optimize the asset economic life. In this context, the present technical work has the purpose to support asset management decision making regarding ArcelorMittal Vega cold rolling drive motors, through the motors fail behavior modelling and estimated the risks involved in asset management decision. Through the Reliability, Availability and Mantenability (RAM) analysis, simulations were performed considering the failure, repair cost data and investments to build options to mitigate the operational risks.

Oct 9, 2019

By A E. Petts

Record iron ore prices and a renaissance of infrastructure in the Pilbara have Flinders Mines poised to move from explorer/developer to an iron ore producer. The potential of the company’s Pilbara Iron Ore Project was first highlighted by the announcement of Rio Tinto’s Caliwingina North deposit to the north and the Fortescue Metals group’s Serenity deposit in the southeast. The success of Flinders Mines’ exploration has been based on incorporating landscape studies into an existing geological framework, and using this to understand the iron-rich materials that were emplaced during the Tertiary. The development of the Delta and Eagle deposit resource models highlights this process. There are three main mineralisation styles at the project; detrital iron, channel iron and bedded iron deposits. They have textural and mineralogical similarities with comparative deposits in the region. Gaining an insight into the geological processes unique to detrital iron deposits and more distal channel iron deposits has been important to understanding the geometallurgy of the mineralisation. The model sits comfortably with other regional oregenesis models and allows a contextual framework to be developed around the timing of deposition of the Fe-rich detritus and pisolitic nodules that dominate the deposits. The exploration model also allows Flinders to explore more effectively for bedded iron mineralisation developed prior to, and since the development of the Tertiary weathering landscape.

Jul 11, 2011

By L. J. Su, J. Y. Zhang, P. W. Gu, J. F. Xu

Surface tension of mold flux is a key factor affecting optimum casting conditions. A thermodynamic model was developed to determine the surface tension of mold flux containing fluoride based on the ion and molecule coexistence theory of slag structure and Butler’s equation. The relationship between composition and surface tension was investigated by this model. Results indicated that the calculated values showed good agreement with literature data, and the average error was 8.19%. The surface tension value of the CaO–Al2O3-based mold flux was larger than that of the CaO– SiO2-based mold flux. The surface tension in a multi-component system decreased with increasing contents of SiO2, CaF2, and Na2O, which are considered surface-active components. This trend was more significant in the CaO–Al2O3-based mold flux.

Dec 11, 2024

By R. E. Lindstrom, D. J. Bauer

Studies were conducted to assess the potential of naphthenic acid as a fractional extractant for rare- earth mixtures and yttrium in sulfate solution . Naphthenic acid was an effective extractant , and separation factors were favorable in the presence of aqueous phase chelating agents . Addition of EDTA to the naphthenic acid extraction system resulted in average separation factors of 2.2 between adjacent yttrium- group elements , whereas DTPA resulted in average separation factors of 3.5 between adjacent cerium- group elements . EDTA was of value in separating yttrium from the rare- earth elements . Thorium and uranium were preferentially extracted over the trivalent rare- earth elements by naphthenic acid .

Jan 1, 1964

By F. E. Brantley, D. A. Martin

Synthetic zeolites were tried as selective adsorbents for recovering sulfur dioxide from synthetic gases and gases produced from gypsum decomposition . Initial adsorption tests , using the synthetic gases , indicated that three of these compounds , having sulfur dioxide capacities of up to 29 grams per 100 grams of adsorbent , were satisfactory . Regeneration studies showed that over 90 pct of the sulfur dioxide desorbed from the loaded beds was of sufficient purity for direct liquefaction . However , all zeolites tested lost adsorptive capacity with repeated use . The zeolite determined to be the most promising in the preliminary synthetic gas tests was also evaluated for capability in adsorbing sulfur dioxide from gases produced by the thermal decomposition of gypsum . Despite small amounts of hydrogen sulfide in the gypsum decomposition offgas , good adsorption of sulfur dioxide was attained . The economic practicality of utilizing zeolites for sulfur dioxide removal from industrial gases was not evaluated , but the technical feasibility was demonstrated .

Jan 1, 1963