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By Robinson Newcomb

Gypsum is a form of hydrated calcium sulfate (CaS04.2H20) which is widely distributed over the earth's surface. The two varieties worked commercially are rock gypsum and incite. Rock gypsum, the variety commonly mined for commercial purposes, is a relatively soft mineral having a specific gravity of about 2.3 and weighing about 150 pounds per cubic foot. The chief producing States are New York, Michigan, and Iowa. Before being used the crude gypsum is ground and generally calcined. The predominant use of gypsum is for building purposes (the manufacture of plaster), for which calcined gypsum is required. Gypsum is also used as a retarder in Portland cement, as fertilizer, and for other purposes. GYPSUM MINING Crude gypsum is mined by two methods - underground and open-pit. Although the use of the former method predominates, open-pit mining increased in relative importance during the early twenties and contributed about two-fifths of the output during the period 1925-38.

Jan 1, 1940

By B. Currie

Maintenance of quality electrowon copper requires an electrolyte which has suitable chemical and physical characteristics. The proper design and operation of the solvent extraction plant is essential to the quality of the electrolyte sent to electrowinning. An aspect that is not well appreciated is that the return electrolyte can have negative effects on the operation of the solvent extraction plant. Poor SX plant operation creates below optimum electrolyte conditions. High Eh in the return spent electrolyte can degrade the SX reagent with large decreases in copper transfer capacity and increases in internal entrainment. The synergistic interaction of the SX and EW plants needs a single-source design approach to address the interactions. The design elements in the SX and EW plants required to manage the electrolyte conditions are discussed.

Jan 1, 2014

By B. N. Everett

The growing role of Colombia as a major supplier of internationally traded steam coal has been widely discussed in the industry. Although Colombian coal has been produced and exported in small quantities for a number of years, Colombia's position as a major coal exporter began in earnest in 1985 with the first commercial exports from the Cerrejon North Block Project. By way of background: ? The mine is located on the Guajira peninsula in Northeast Colombia, about 90 miles from the coast, as shown in Figure 1. ? In addition to the mine itself, the project involves construction of a dedicated railroad and port, which form a modern, efficient and integrated system. ? The Project is embodied in a 50/50 Association Contract between International Colombia Resources (Intercor), a wholly owned subsidiary of Exxon, and Carbocol, the Colombian state coal company. Intercor and Carbocol share investment and operating expenses equally and Intercor has the additional responsibility of managing operations on behalf of both partners. Each partner is entitled to 50% of the coal produced, and each markets its share separately. ? The project is a multi-seam, truck and shovel operation, based on large reserves (2-3 billion tonnes') of high quality bituminous coal. ? Exports began in the first quarter of 1985 at modest levels through what we call Early Coal Facilities, designed and constructed apart from the permanent coal handling system. ? Production will increase rapidly in each of the next few years, reaching the design capacity of 15 Mt per year in 1939. Based on available resources, however, the resource will support expansion, and continued growth n production into the 1990s appears feasible.

Jan 1, 1986

By Larry A. Haas

The Bureau of Mines is investigating the use of complex gas mixtures, such as would be produced by coal gasification, for reducing iron oxide pellets. A semiempirical model was developed to predict a priori the reduction rate of an iron oxide pellet in a laboratory tube furnace with simulated coal gases at a total pressure of 1 atm. The model uses partial pressures of H2, CO, CO2, CH4 (methane), water vapor, and a temperature-dependent term to predict the rate of reaction. The reduction rate (weight loss per unit of time) was determined with a thermo-gravimetric apparatus (TGA) in the temperature range of 800° to 1,100° C. The ranking of the reductants, in order of decreasing reducing potential, is H2, CO, and CH4 at temperatures between 800° and 1,000° C; however, CH4 became a better reductant than CO at 1,100° C. Water vapor did not decrease the reduction rate as much as did CO2, Carbon deposition was observed at temperatures below 1,000° C with gas mixtures with high CO and low H2 concentrations. With low-Btu gas at 900° C, over 90 pct of the iron oxide was reduced to iron in less than 3 h. This com-pares with a reduction time of 1.5 h with medium-Btu gas and 1 h with reformed natural gases.

Jan 1, 1985

By Wayne A. McCurdy

I welcome the opportunity to meet with you and discuss the work and program of the Office of Coal Research. Our programs are oriented to serve the conservation objectives of the Johnson Administration and of the Nation by seeking out the most efficient and best uses for coal. We believe that even if only a portion of our program is successful, the coal industry and the Nation will benefit far out of proportion to our expenditures. Operating with a budget of $7,220,000 in Fiscal Year 1966, OCR sponsors contract research which offers potential for achieving benefits to the coal industry in the form of new production and new markets. This directs us into many areas of research activity: in coal combustion, in advancements in mining methods and coal preparation, in new uses for coal, and in associated economic and marketing research.

Jan 1, 1966

By W. A. Lang

Introduction In this review, which is the fifth of the series on the Progress in Coal Technology, an attempt has been made to outline some of the more important developments that have taken place in coal carbonization during the last decade. Research into both high-and low-temperature carbonization has been active for three principal reasons: (1) the growing shortages in most countries of high-quality coking coals; (2) the demand for smokeless fuels for domestic purposes; (3) the need for metallurgical coke for the increased output of steel in the post-war years. The growing importance of coal tars as a source of chemicals for the preparation of synthetic products and of coal gases for the recovery of sulphur is evident. Many of the researches initiated because of wartime necessity have been continued .and even expanded in the post-war years. High-temperature carbonization with a suitable coal yields a strong coke which is used primarily for metallurgical purposes, a tar with good marketable value, and a large yield of gas of medium calorific value. Low-temperature carbonization gives a more free-burning solid product suitable for a domestic fuel, a high yield of a tar which is generally regarded as superior to high-temperature tar for chemical purposes, and a smaller yield of a higher-heat-value gas.

Jan 1, 1951

By K. Ananthpadmanabhan

Hydrolyzable surfactants such as fatty acids and amines undergo, in addition to micellisation and precipitation, various associative interactions in aqueous solutions to form ion molecular complexes such as acid-soap, dimers etc. depending upon the solution conditions such as pH. The interaction of these collector species with the mineral surface and with other dissolved species in solution will play a significant role in determining the interfacial processes such as adsorption and flotation. Marked differences in the hydrophobicity imparted to the mineral surface depending upon the solution conditions such as Ph can be attributed to possible differences in surface activities of the above complexes. This aspect of solution chemistry of flotation systems is discussed here for two widely used collectors namely, oleic acid and dodecylamine. Equilibrium species distribution diagrams based on the available literature .data and on estimates of energy of interactions between molecules, have been obtained for oleic acid and dodecylamine solutions.

Jan 1, 1978

By Ruddle R. W.

Solid mattes are generally held to be either (a) eutectiferous mixtures of the component sulphides Cu2S and FeS or (b) mixtures of complex sulphides. This chapter shows that liquid mattes consist essentially of a homogeneous phase in which iron, copper and sulphur are present. The amount of sulphur is generally less than that required to account for all the metals as stoichiometric sulphides; mattes cannot therefore be regarded as mixtures of FeS and Cu2S. Some iron oxide may be dissolved in the sulphide phase and magnetite is often present as a second phase. If the sulphur content of the matte is reduced the composition enters the miscibility gap in the ternary system and either an iron- or copper-rich solution (depending upon the composition of the matte) separates as a new phase. On solidification any one of four phases (iron, copper, Cu2S and FeS solid solutions) may crystallize as primaries. The remainder of the matte solidifies as a ternary eutectic. It is possible that iron oxides enter into this eutectic. Knowledge of the ternary Cu-Fe-S system is far from complete and nothing is known of the quaternary system Cu-Fe-S-O

Jan 1, 1953

By G. McIsaac

This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone?s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place. Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. ?Whatif? scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan.

Sep 1, 2005

By Rob Thomas

"In Australia, a wide roadway is commonly defined as any roadway that is driven to a width greater than 5.5 m (18 ft). These roadways are typically required to enable the installation of longwall equipment (termed installation roads); however, other applications include the need to house conveyor driveheads and pre-driven recovery roads.As a result of the increasing size of longwall equipment and mine infrastructure, in some mines, roadway widths of between 9 and 12 m (30 and 39 ft) and are being developed.Accepting that these almost always constitute strategically important and often long-term roadways, this paper considers the use of: (i) an empirical roof support design model, which is based on over one hundred case histories, (ii) various roof support design principles, and (iii) commonly accepted strata management techniques.The paper demonstrates that wide roadways can be driven and supported to an acceptable standard providing due consideration is given to the prevailing ground conditions (including the quality of the immediate and upper roof strata, the Depth of Cover and the horizontal stressfield), the final width of the roadway and the required use of the roadway.INTRODUCTIONRoof behaviour and the associated roof support requirements in wide roadways, which are roadways typically driven to a width that is greater than 5.5 m (18 ft), are controlled by a number of key geotechnical and operational factors. The recognition of these factors is an important first step in the design process and it is imperative that each is considered in conjunction with local mine site information.The main points of note in this regard can be summarised as follows:• The greater the final width of the roadway, the greater the resulting surge in roof displacement on widening - note: a) see Figure 1 for a schematic illustration of the roof displacement trends typically measured during the development of the first pass and roadway widening, b) since displacement increases with roadway width, it is always recommended that the roadway width is kept to the minimum required and c) general buckling beam theory indicates that the capacity of any beams present in the roof will reduce in inverse proportion to any increase in roadway width squared (i.e., [final width2 -first pass width2] I final width2)."

Jan 1, 2010

By Leoncio Méndez, Jesús Arguijo, Juan José Frausto, Daniel Castruita, Daniel Aguilar

Minera Sabinas (Grupo Peñoles), localizada en Sombrerete, Zacatecas, México, produce concentrados de cobre y zinc. Su proceso es un circuito de conminución de quebradoras y dos molinos de bolas en circuito cerrado con hidrociclones seguido de un circuito de flotación, a partir de mineral polimetálico extraído de una mina subterránea. Su problemática consiste en que la recuperación por flotación disminuye significativamente cuando minerales con contenido de pirrotita son procesados. La flotabilidad natural de la pirrotita supera la cinética de flotación de las especies de cobre y zinc y limita la capacidad de la concentradora para generar concentrados vendibles. Este artículo presenta un diagnosticó de los problemas que se tienen cuando se procesan minerales con alto contenido de pirrotita, así como resultados de un programa experimental a escala laboratorio realizado en el CIDT de Peñoles y en sitio. La investigación se enfocó en definir un esquema de reactivos para poder procesar minerales con pirrotita en su composición. Compósitos de alta y baja ley de cobre fueron usados en la investigación. Se identificó el agua de proceso como una fuente de iones calcio y sulfato. Se desarrolló un esquema de reactivos orientado a promover la selectividad de las especies de valor respecto a la pirrotita, incluyendo tratamiento del agua de proceso.

Sep 20, 2019

By R. P. Aldis

A wide range of mineral-derived products are required by the electronics industry for it to function. In one form or another, almost all the known elements have been experimented with and tested for various electrical applications. The two major areas for which minerals are used in electronics are as conductors and semiconductors. Conductors provide the means to transport and distribute electricity, while the main application of semiconductors has been to manipulate electricity. Silicon is the most widely recognized semiconductor material, but gallium, indium, and germanium are rated as the most important metals to the semiconductor industry for future and near future technologies.

Jan 1, 1991

By Edwarde R. May

The Flambeau volcanogenic massive sulfide deposit located in northwestern Wisconsin occurs within the southern lobe of the Canadian Precambrian Shield. The steeply dipping tabular body occurs in a complex pile of cyclic schistose intermediate to felsic fragmental volcanics. No chloritic alteration pipe is recognized but adjacent rocks have undergone magnesia metasomatism and subsequently were metamorphosed to the upper greenschist and lower amphibolite facies. Although modest in size the deposit is of special interest in that it has an extensive and well preserved supergene enrichment blanket. Economic minerals found within a pyritized quartz-sericite schist are chalcocite and bornite overlying primary chalcopyrite.

Jan 1, 1976

By Stanley W. Ivosevic

The South-Central area of the Osa Peninsula, Puntarenas Province, on the Pacific coast of southern Costa Rica, may have produced on the order of 30,000 kg (100,000 troy oz) of gold since prehistoric times. The Peninsula lies along an 800- to 900-km-long belt of late Mesozoic eugeosynclinal rock deposition, hydrothermal activity, and deformation (Campanian). The oldest rocks exposed in the area are basalt and tuffaceous mudstone of the Late Jurassic or Cretaceous Nicoya ophiolite complex. The Nicoya Complex is overlain by weakly lithified Pleistocene Older Sediments, predominantly conglomeratic sandstone and derived from erosion of the Nicoya Complex. Erosion reduced the Complex to a surface of high relief, so that the detrital source was in the area originally; the source retreated with subsidence. Stratigraphically, the Older Sediments are followed by surficial deposits of intermediate age, consolidated Younger Sediments reworked from Older Sediments, and unconsolidated Holocene surficial deposits reworked from Younger Sediments. The most prominent structures are a northeast-trending anticline and northeast and northwest fault sets. Some deformation was Cretaceous, but folding and much faulting occurred after deposition of the Older Sediments. Remnants of plainlike features and destructional terraces on the Older Sediments attest to stepwise downcutting of the terrain during successive stages of uplift. Near the end of this process, the present valley floors and coastal headlands developed. During a probable epeirogenic rise in sea level, Younger Sediments filled the valley bottoms and an aggradational coastal plain developed. Sea level dropped by stages and with some reversals to its present position; this caused stepwise incision of the valley fill, stepwise beveling of the coastal plain, and development of the present wave-cut platform. Spilitization around the time of the Campanian orogeny caused some parts of the Nicoya complex to be calcitized and others to be silicified. Gold, pyrite, and probably additional silica were introduced during subsequent hydrothermal activity. Native gold was eroded from Nicoya Complex lodes and reconcentrated through three generations of placer gold deposits. First, the gold was deposited as a detrital.

Jan 1, 1977

By Arthur V. Petty

The Bureau of Mines has investigated the effect of refractory oxide additions, introduced in soluble form, on the refractory properties of 42-, 58-, and 70-pct-A1203 brick. Brick having porosities ranging from 12 to 16 pct were impregnated with solutions containing chrome, chrome-iron, zirconium, calcium, magnesium, cobalt, nickel, tin, and manganese ions. Additions of some of these ions provided dramatic improvements to such properties as hot modulus of rupture, hot load, and particularly slag resistance. These improvements can be related to reduction of porosity, amorphous grain boundary phases, formation of more refractory bond phases, and reduction of the wettability of Al203-containing refractories by metallurgical slags. Fifty-eight-percent-AI203 brick, impregnated with chrome, showed hot modulus of rupture, hot load, and slag resistance two to five times better than those of untreated 70-pct-AI203 brick. This could result in reducing the Nation's dependence on imported refractory-grade bauxite generally required for high-A1203 brick, as domestic alumina resouces could be used to produce the improved refractories.

Jan 1, 1984

By J. Gao, H. O. Gekonde, S. V. Subramanian

"The functional role of inclusions at low cutting speeds is to promote ductile fracture in chip formation process, whereas the role of inclusions at high cutting speeds is to prevent tool crater wear by suppressing the tribological phenomenon of seizure at the tool-chip interface. Glassy oxide inclusions are engineered into the workpiece to form a viscous layer in-situ at the tool-chip interface at high cutting speeds. The viscous layer lubricates the tool-chip interface to prevent the seizure. In comparison with the large volume fraction of inclusions needed for promoting ductile fracture at low cutting speeds, the amount of inclusions required for lubricating the toolchip interface at high cutting speeds is very small and is in the range that is typical of clean steels. The chip fracture process at high cutting speeds is aided by strain rate hardening of the matrix, which facilitates chip disposal of relatively clean steel.Inclusion engineering for high speed machining involves the control of the rheology and composition of inclusions to meet target viscosity at the tool-chip interface. The application of thermodynamic models in controlled production of inclusions in steels designed for high speed machining is discussed."

Jan 1, 1998

By Dennis R. Twining

Recently a mining analyst for a major bank called me to say that during his travels he had encountered an electric utility interested in a new uranium supply. Since we produce uranium as a by-product of phosphate operations rather than as a primary product, he assumed we simply sold our output in the spot market and that a new prospective purchaser would be of interest to us. This assumption was incorrect; the uranium had already been sold on a long term basis at terms more favorable than the currently depressed spot market. From the outset our approach to the marketing of uranium was based on the principle that by-product marketing is not unlike primary product marketing. This was particularly appropriate in the case of uranium, as we were planning a considerable technical and capital commitment to a new business. This illustrates: that the fundamental principle in by-product marketing is to follow a primary product strategy; that the terms "by-product" or "co-product" are creations of accountants; that they have no place in marketing decisions! Traditionally, the term "by-product" has implied that only a secondary marketing effort is required. Recent history has contradicted that view by demonstrating that by-product values can have marked impact on a mine's revenues and costs. In fact, by-product values can spell the difference between success and failure.

Jan 1, 1983

By A. M. Alfantazi, M. Boissoneault, D. B. Dreisinger, J. Synnott

"The effects of five commercially available foaming reagents (range of 0 to 25 ppm) namely Dowfroth 250, Saponin, Yucca, Licorice and Meta-Para Cresol on acid mist control, current efficiency, polarization behavior, and deposit morphology and orientation were investigated. The deposition was carried out using a bench scale electrolysis apparatus (cell volume 3L) at 500 Nm-2 and 38°C for 3 hours from Kidd Creek zinc electrolyte. The acid mist control capability of the various reagents was studied and compared by characterizing the foam layer generated during actual electrowinning conditions and by direct quantitative measurements of acid mist levels on top of the electrowinning cells. Within the range considered, the addition of these reagents reduced the current efficiency, refined the grain size of the deposit, and changed to preferred orientation of most of the deposits. Among the reagents tested, acid mist measurements indicated that Licorice and Dowfroth 250 were the best acid mist suppressant at emissions of 0.30 mglm3 and 031 mg/m3 respectively while Yucca and MPC produced the most mist at 3.0 mg/m3 and 33 mg/m3 emission rates, respectively.IntroductionMost of the world's primary zinc is produced via a combined roast-Ieach-purificationelectrowinning process. Depending on the electrolysis conditions, several additives may be added to the electrolyte. Some (e.g. glue, antimony, sodium carbonate) are added to mainly counteract the detrimental effects caused by impurities while others (e.g. licorice, Saponin) are used as foaming reagents to prevent excessive acid mist formation. Acid mist emission is a problem in many electrolysis operations because it corrodes the equipment and is a health hazard to the workers in the tankhouse as well as it pollutes the environment. Due to recent trends towards more environmental protection and more stringent in-plant hygiene, there is an increasing need to minimize these aerosols. In order to eliminate or minimize these aerosols foaming agents are usually added to the electrolyte to produce a foam layer on top of the electrolyte, thus trapping most of the mist. The ideal foaming agent would trap all of the mist and would not interfere with the electrowinning process. It is also evident that the reagent toxicology, cost and availability are important factors that need to be considered.Review of the available literature clearly indicated that very little work has been done in the past on the subject of acid mist control in electrowinning operations particularly in the area of foaming and anti-misting properties of surfactants. Two papers [1,2] have reviewed briefly the existing technologies for acid mist control. Recently, most of the work in this area has focused on the development of special mechanical devices that could be attached to the electrodes and control the mist generation at the source before it is emitted to the cellhouse [2-5]. On the other hand, extensive body of literature exists that deals with the effects of anti-misting reagents on the electrowinning aspects [6-7]."

Jan 1, 1997

By J. Bruce Clemmer

[Gypsum is one of the mo .. t iJf.l)ortant nonmp.tal1.ic T!1inerals, as is indicat-? ed by the fact that tlle Uni ted states cO!1sUl:Ied p, roximn..tely 3,500,000 tons of natura.l and calcinecl e::,j;-psum in 1937. The b\.'.ilr:.in.; traces \"fe.ro the largest users and required 2,520,000 tons of calcine for the r-roductiop. of plaster,]

Jan 1, 1941

By R. L. Crosby

Microscopical and X-ray diffraction techniques were used to identify two intermediate phases in that part of the solid region of the magnesium-cerium system between and Mg3Ce. Previous literature had reported only one intermediate phase for this region, 1)12t chemical analysis determined the approximate composition of the two compounds to be Mg23Ce2 and Mg17Ce2. The range in composition of the two intermediate phases was found to be limited to less than 0.3 atomic percent cerium. The study did not determine the crystal structure of Mg17Ce2, but that of Mg23Ce2 is tetragonal with a = 10.33 A and c = 19.51 A.

Jan 1, 1966