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By Gökhan Hardal, Berat Yüksel Price

Negative temperature coefficient (NTC) thermistors are required to have good electrical stability for many domestic and industrial applications. The aging phenomenon of NTC thermistors can be described as the change in electrical resistance due to thermal stress with time. In this study, Ni0.5CoxMn2.5−xO4 (x = 0.5, 0.8 and 1.1) ceramics were fabricated by the conventional solid-state reaction method. The powder mixtures of manganese, cobalt and nickel oxides were ball-milled for 5 h. The powders were calcinated at 900 °C for 2 h. The samples were sintered at 1100 °C for 5 h. To investigate the aging behaviour, the samples were held at 150 °C for 400 h. Aging in the samples were calculated by the following equation; ΔR/R0 = (R − R0)/R0 in which R0 is the resistance at 25 °C before the aging test, and R is the resistance at 25 °C after the aging test.

Mar 1, 2017

By Prakash Venkatesan, Yongxiang Yang, Seshadri Seetharaman, Aida Abbasalizadeh, Jilt Sietsma

Electrolytic production of metallic neodymium is carried out in fused fluoride salts containing neodymium oxide. Two major challenges pertaining to neodymium production are (a) low oxide solubility and (b) possible fluorine gas evolution. A novel iron-based reactive anode is proposed and tested to overcome fluorine gas evolution during electrolysis of neodymium oxide in molten fluoride salts.

Mar 1, 2017

By Mingming Zhang, Udaya Bhaskar Kodukula, Marcelo Andrade

The physical and chemical properties of sinter feed are important factors that determine the productivity and quality of sinter product. In this study the feasibility of treating sinter feed by high pressure grinding rolls (HPGR) is investigated for selective cracks generation exploiting weak zones along grain boundaries of poor quality iron ores without generating much fines. The pre-treated sinter feed was characterized for size distribution, surface area, contact angle, and SEM analyses. The characterization results indicated that surface area of the pre-treated sinter feed sample increased about 20%. Pot-grate sintering tests results also indicated improvement on cold permeability, sintering yield and productivity, sinter Tumbler index, and low temperature degradation index (LTD) after HPGR pre-treatment.

Mar 1, 2018

By Neale R. Neelameggham, Brian R. Davis

Organic agriculture is using natural materials such as degrading plant matter to replenish soils. This includes use of naturally degraded plant components such as peat, humus and weathered brown coals. Another important natural organic matter which has not been applied in agriculture thus far has been the black coal, Here we show that reversing the coal formation reaction by combined hydro-oxidation principles of biochemical engineering in natural conversion methods in an accelerated fashion. The modified coal soil additive can convert arid lands into farm lands for the future to sustain the population growth. In addition, the development of this new use of black coal will revive economically deprived areas from phasing out coal in the USA and Europe. This will show how the Stored energy in coal can be made renewable in helping plant growth under the soil to facilitate above ground photosynthesis.

Mar 1, 2018

By G. S. S. Raman, M. S. Klima

The effects of pressure and cake thickness were studied using a split-plot design for pressure filtration of a fine refuse slurry obtained from a bituminous coal preparation facility. Pressure filtration offers the potential to significantly reduce the moisture content of the fine refuse stream with the addition of little to no flocculants, thereby minimizing the volume of refuse stored in impoundments and providing a recycle water stream for use within the plant. Experimental results showed that the final cake moisture decreased with increase in pressure and decrease in cake thickness. In addition, specific cake resistances calculated for the various tests indicated an increasing trend with increasing pressure and decreasing cake thickness. With increase in cake thickness, an increase in cake moisture and the weight of solids deposited in the cake was observed. An ANOVA analysis indicated that both cake thickness and pressure significantly affected the cake moisture, while only cake thickness statistically influenced the weight of solids in the cake. A regression model was developed with an R2 value of about 0.99 to relate cake thickness, the single largest statistically significant factor, with the weight of solids in the cake. Filter capacities were calculated in terms of the solids deposited per unit time based on a product specification of 25 percent cake moisture, and it was observed that the thinnest cake had the highest filter capacity.

By A. G. Yapo, T. W. Camm

"Mining plays a key role in the development of modern civilization as a source of essential raw materials and provider of essential fuels, producer of jobs and a factor in support of the international balance of monetary payment (Camm, 2014). Professionals in mining locate, develop, design and manage ore deposits in an environmentally safe and profitable manner. As mineral deposits become increasingly scarce, new challenges face the industry. A current trend is to an increased emphasis on underground mining techniques for deeper deposits. Operations are safer now than before as companies understand better their work environment and the importance of mining responsibly.A continual challenge for the industry is accurately reflecting the costs and selling price of ore. An enduring characteristic of mining is the situation where the market typically determines the price of a commodity; the main control a company has on the bottom line is to control the cost of production.An attempt to bring light and clarity to the cost of their business will give a better idea to investors on the true profitability of the mining business. Gold producers face this struggle to accurately reflect the cost of production while also seeking to attract the interest of the investment community (Hill, 2013). In order to have a consistent format to report on their production costs, leading gold producers, through their alliance inside the World Gold Council (WGC), worked on the adoption of a new cost framework: the all-in sustaining cost (AISC) and all-in cost (AIC).Since 1996, the traditional cash cost reporting has focused only on the mining and processing costs incurred in mining an ounce of gold, which included the costs of goods sold (labor, energy, and consumables costs) and royalties (Table 1). But cash cost reporting ignores many important aspects, like sustaining capital, general and administrative expenses and site rehabilitation at the end of the mine life (Whelan, 2013). The cash cost was used to attract many investors into the business. In fact, the high gross margin (sales minus cash costs) has been promoted in past decades by the industry instead of the net or operating margin. As a result, even when the gold price was high, nearly $61/g ($1,900/oz) in August 2011, gold producers were not reporting excessive profits in their cash flow/income statements, to the disappointment and incomprehension of investors (Milstead, 2014). The truth was simply that the other costs omitted in the traditional cash cost were reducing the apparent profits.The disconnect led to a need for more accurate cost reporting in order to win back investor confidence and provide better understanding of gold mining economics. In 2012, the senior gold mining companies, including Gold Fields, Barrick Gold Corp. and Newmont Mining Corp., worked with the WGC to develop a new measure. This resulted in the June 2013 publication of the new framework AISC and AIC, which has been widely embraced by the sector since Jan. 1, 2014 (WGC, 2013).The adoption of the new cost template would have the dilemma of showing the real profitability of gold mine properties, which might alleviate taxes from governments and legislators, but it might also scare off investors toward more lucrative industries if not winning back their confidence."

Jan 9, 2017

By Mark P. Meyer

This U.S. Bureau of Mines publication presents salient information in abstract form on 247 coal deposits in Alaska. Coverage includes currently producing deposits and deposits that appear to have commercial production potential. Data arc taken from coal properties identified by the U.S. Bureau of Mines minerals availability program and by a literature search. Infrastructural and institutional factors affecting coal development in Alaska are also discussed.

Jan 1, 1987

By John L. Lamont, Walter Crafts

SECONDARY hardening in tempering has long been recognized as a typical characteristic of steels containing large amounts of carbide-forming alloys. These steels, when quenched and tempered, tend to soften somewhat after tempering at low temperatures, and to reharden at intermediate tempering temperatures before finally softening to low hardness. This behavior in tempering has been studied by many investigators, chiefly with respect to the secondary hardening of high-speed steels. The initial softening has usually been ascribed to decomposition of martensite and growth of iron carbide particles. The secondary hardening has been explained by formation of fresh martensite from residual austenite, formation of very fine alloy carbide particles and by precipitation hardening of metallic compounds in the ferritic matrix. However, factors derived for the calculation of tempered hardness in low-alloy steels1 indicated only a tendency toward retarded softening rather than a discontinuous rehardening. A study was, therefore, made to determine whether fresh martensite from residual austenite and precipitation hardening are essential to rehardening and the degree to which tempered martensite could be rehardened by precipitation of alloy carbides. The mechanism of carbide rehardening was also investigated to determine the nature of the process. The causes of secondary hardening in high-speed steel have received serious consideration for about thirty years. Among the earlier workers Bain and Jeffries2 in 1923 recognized residual austenite as a significant factor, but in addition, emphasized the effect of the formation of alloy carbide particles of "critical" size. They conceived that freshly quenched martensite forms low-alloy iron carbide at low tempering temperatures; with further tempering the iron carbide is then modified by alloying elements that can diffuse most readily at intermediate temperatures (850°F); and that the iron carbides grow in size by coalescence so that the steel tends to lose hardness. At higher tempering temperatures carbide stability rather than alloy availability becomes the controlling influence and in high-speed steel "iron-tungsten carbide is the most stable one and forms to the elimination of the earlier formed carbides. . . . The iron-tungsten carbide particles reach approximately the size for critical dispersion after a short reheat at 1100°F." This concept, the formation of alloy carbide nuclei, redissolving of the iron carbide, and diffusion of carbon to the alloy carbide, was restated for vanadium steel in 1932 by Houdremont, Bennek, and Schrader.3 Subsequent studies have confirmed that iron carbide changes to alloy carbide at 1000 to 1100°F, but the mechanism of the process has received little consideration .

Jan 1, 1948

I N the introductory chapter to "Man and Metals," T. A. Rickard wrote "Five hundred thousand years ago the first footfalls of man's oncoming echoed down the corridors of time." This phrase has always appealed to me, not only for its resonance but because it seems to place in some perspective man's place in the cosmos. As we go about our daily occupations and as we meet here tonight, we must agree that we have come a long way slowly at first through the ages of change but with a quickening pace that has brought to man's know-ledge and use, within the last hundred years, more ideas, more material advantages, more opportunities and more comforts than were ever imagined or dreamed of in those long corridors of time. Looking back to the dawn of his-tory, a mere five thousand years ago, there is one aspect of the birth and growth of civilization that has particular significance for the miner and the metallurgist.

Jan 1, 1965

By William P. Shinn

Jan 1, 1881

By P. T. Velu

Solubility of metal oxides in the molten salt electrblytes is an important parameter in the electrochemical processing of metals and alloys. The efficiency of an electrochemical process primarily depends on the quantity of metal oxide present in the electrolyte in the dissolved form and its thermodynamic properties. The activity of CeO2 was calculated using the free energy of fusion of CeO2,{ AG°m, CeO2. The AGOm,CeO2 }was deduced from the values of enthalpy, heat of fusion and melting point of Ce02. The activity coefficients of CeO2 as a function of temperature and melt composition were calculated. The thermodynamic data such as integral molar enthalpy, entropy and Gibbs energy of formation were calculated as a function of composition and temperature.

Jan 1, 1994

By R. H. Derammelaere

With renewed interest in coal slurry pipelines in China, Indonesia, Australia and Canada for electric generation, it appears worthwhile to update the relative economics of transporting coal by slurry pipeline. Three slurry pipeline technologies are evaluated for the commercial transportation of 3.0, 6.0, and 9.0 million tonnes per year (MMT A) example cases, over distances of 250 km, 500 km and 1000 km.

Jan 1, 1998

By H. Castillo

This paper describes the computer simulation of thermal stress fields generated in the quenching of the ns 415 H Steel automotive parts (Valve Lifters), running the ANSYS Multiphysics software of finite element (FEM). Simulation was performed introducing residual stress measurements on specific values areas, like internal pressure condition in the material. The stress condition effect in the material and the properties as temperature function data, were introduced to the FEM software. The thermal stress simulation was made on the 2D system. The parts were austenized to 850 900 °C and then oil quenched, tempered at 150 -200°C, and air cooled. The X-Ray diffraction technique was made to take measurements from residual stresses on valve lifters surfaces. The results analysis showed the ideal stress condition necessary in raw material to reduce the scrap percent in grind operations after hardening heat treating process. Keywords: Thermal Stresses, Temperature profile, Computer Simulation, Finite element analysis, Quenching of steel, Residual Stresses

Jan 1, 2003

By M. H. Stanczyk

Bench-scale laboratory tests were made by the Bureau of Mines of a segregation-flotation concentrate, assaying 20.43 percent copper, to investigate the influence of various ratios and concentrations of ammonia and carbon dioxide on copper extraction. Leaching the concentrate with a solution containing 900 pounds of ammonia and 360 pounds of carbon dioxide per ton of feed, followed by washing the leach residue with 1.75 tons of a 10-percent solution of ammonium carbonate and about 1 ton of water (as steam) per ton of solids, resulted in a copper recovery of 96.3 percent. Resegregation and flotation tests of the washed residues revealed that 85 percent of the copper in the residue could be recovered. Steam distillation tests of a typical ammoniacal leach liquor, assaying 39 grams copper, 105 grams ammonia, and 77 grams carbon dioxide per liter, recovered over 99 percent of the copper as a mixed oxide-carbonate precipitate. The ammonia losses in leaching, filtering, washing, and distillation were 0.12 pound per pound of copper recovered in the precipitate. Calcination and subsequent hydrogen reduction of the precipitate yielded a metallic copper powder assaying 98 percent Cu, 0.87 percent Si02, 0.10 percent MgO, 0.54 percent CaO, and 0.41 percent R203.

Jan 1, 1961

By Rick Frechette, Greg Nelson

"The 2018 Elko Roundtable was held at the Red Lion in Elko, NV on March 15, 2018. The gracious host was once again Knight Piésold. Attendance was robust with representatives from more than 14 mining properties across Nevada representing nine corporations. Total attendance was at its highest in almost a decade. A high level of interest was also gauged by the number of companies with multiple attendees.The topic of water in mining was clearly a factor in creating the large show of interest. In terms of industry trends that are tracked annually, this topic had been absent from the list for more than 10 years (Deloitte, 2018) but was squarely planted there this year. And deservedly so. Three attending companies are signatories of the International Council on Mining and Metals (ICMM) which espouses a firm stance on water stewardship (ICMM, 2017).How’s the water?It is reported that water scarcity affects more than 40 percent of the world’s population (Deloitte, 2018). Consumption of water in the United States, based on the last detailed census, entails only 1.5 percent usage by the mining industry. The largest users are reportedly thermoelectric power and irrigation, combining for more than 75 percent of the U.S. consumption. During the prior census period, water usage at mines was up dramatically (USGS, 2014).Mine water source usage is primarily a mix of ground water and saline or fresh surface water resources. Over the previous period, saline sources experienced the greatest percentage in growth as a mine water source, nearly doubling in use. Nevada ranks second as a state nationally in mine water consumption. California is the leader, and Nevada is immediately followed by Utah and Alaska (USGS, 2014).Water rights in Nevada and the ongoing litigation at the state level, particularly over the Humboldt River basin, have elevated the concern over the supply of water and have raised the interest regarding the topic of water across the mining industry as well as within other industries.The Elko Roundtable meeting began with a safety share and introductions, and included each attendee mentioned a water problem or solution that he or she would like to discuss during the day. An interesting list of subtopics was developed from this round robin and yielded the following most common themes:• Mine pit dewatering during operation and pit wall stability.• Draindown from tailings dams and heap leach pads and dealing with this at closure.• Post closure pit lakes, pit lake water quality and associated water rights."

Dec 1, 2018

By C. Cho

One problem with the application of neural networks to the multivariable control of mineral and extractive processing is deciding whether and how best to use them. The objective was to compare neural network control to more conventional strategies and find any advantages in terms of set point tracking, rise time, settling time, disturbance rejection, and other criteria. The procedure was to develop neural network controllers using both historic plant data and simulation models. We tried various neural network control patterns including both inverse and direct neural network plant models. These were compared to state space controllers that were, by nature, linear. For grinding and leaching circuits, a nonlinear neural network-based model predictive control strategy was superior to a state space-based linear quadratic Gaussian controller. We also learned the importance of incorporating state space into neural networks by making them recurrent--feeding certain output state variables into input nodes in the neural network. We concluded that neural network controllers can have better disturbance rejection, set point tracking, rise time, settling time, lower set point overshoot, and can be more foolproof and easy to implement in complex, multivariable plants.

Jan 1, 1996

By N. S. Dalal, X. Shi

"This study reports a new property of the important NAD(P)H-dependent flavoenzymes, glutathione reductase, lipoyl dehydrogenase and ferredoxin- NADP oxidoreductase, that can catalyze a one electron reduction of metal ions such as chromium(VI) and vanadium(V). During the enzymatic reduction process, molecular oxygen is reduced to H2O 2 , which reacts with the reduced metal complexes to generate hydroxyl radicals. Since the hydroxyl radicals have been suggested to play an important role in Cr(VI) toxicity, this study provides a basis for a recent observation that Cr(VI) mutagenesis is strongly oxygen dependent. These results also point to an enzymatic pathway for the metabolism of some metal ions and concomitant generation of hydroxyl radicals. l. INTRODUCTIONThe purpose of this communication is to report that some important NAD(P)H-dependent flavoenzymes (glutathione reductase, lipoyl dehydrogenase and ferredoxin-NADP+ oxidoreductase) can catalyze one electron reduction of metal ions such as chromium(VI) and vanadium(V) and simultaneously reduce molecular oxygen to generate Hi02 and, eventually, the ""OH radical. This finding is significant because (i) the known substrates for the flavoenzymes are organic species and not metal ions, and (ii) the report on the enzymatic formation of the ""OH radical provides a new pathway for understanding the mechanism of genotoxicity of some non-ferrous metal ions. For example, it has been suggested that OH radical is likely to be the major species responsible for Cr(VI) genotoxicity [1-5). The 'OH radical is generated through the reaction of Cr(V) complexes with cellular Hi02 [4,5]. Cr(V) itself is known to be generated from Cr(VI) in various biological systems, in particular, microsomes [ 6), mitochondria [7] and mitochondrial electron transfer chain complexes [8]. However, no specific enzyme responsible for the Cr(V) generation has been identified except possibly glutathione reductase [4]. In this study we have used ESR and spin trapping techniques to show that the flavoenzymes can generate Cr(V) and provide a catalytic redox cycle for 'OH formation in such reactions. Herein we present our results on Cr(VI) and summarize those on other systems. Correspondence address: N.S."

Jan 1, 1990

By Hiroshi Nakajima, Kotobu Nagai, Toshihiro Hanamura

"Low carbon ferritic steel bars with ultra-fine grain structure was developed through a warm rolling for the first time by the present authors. They show better low temperature toughness than conventionally hot-rolled plates. Hence, the brittle fracture surfaces in Charpy tests were examined in terms of the effective grain size of fracture, compared with those of conventional QT steels. The ductile-to-brittle transition temperatures were in good accordance with those for the QT steels if referred to the effective grain size of fracture: · However, the size was a few times that of the ferrite grain. This means the grain refining is not yet fully utilized from the viewpoint of low temperature toughness. The anisotropy of· the impact properties and the annealing effect of highly dislocated structure on the toughness are also discussed in the present paper.IntroductionFor structural materials, both high strength and good toughness are required. Well-known approaches for obtaining better toughness for steels are as follows:1) Grain refining2) Addition of Ni3) Thin plate effect by cracking parallel to the rolling direction prior to crack propagation4) Contribution of metastable austenite.Among them, only the grain refining can raise the strength and improve the toughness. And it is well known that the finer the ferrite grain size, the lower the ductile-to-brittle transition temperature. For example, in the case of 0.11 carbon steel, the transition temperature decreases linearly to in d 1/2 [1 ]. However, these have been told in the regime of coarse grain size that is larger than 10 µm in diameter. There ~as .been no study dealing with the low temperature toughness in the regime of ultra-fine grain size with a diameter in the order of 1 µm."

Jan 1, 2000

By William G. Wilson

In the U.S. today a number of tentative synthetic fuel plants have been sited by a number of major corporations. Each of these for a number of reasons have deferred construction. The only synthetic fuel plants under active development are those being built with the Energy Research and Development Administration (ERDA) under the authority of the Non-nuclear Energy Research and Development Act of 1974 (Public Law 93-577). Under this Act in joint sponsorship with industry, a series of coal conversion pilot and demonstration plants are being built to produce environmentally acceptable fuels from high sulfur coals. Before entering into a discussion of the factors associated with the siting of the ERDA coal conversion program, the difference between a pilot plant and a demonstration plant should be explained. The terms pilot plant and demonstration plant iridicate a size of plant rahter than technology. A pilot plant will vary from an "add-on" to an existing facility to an independent unit. Demonstration plants are a wholly independent, self contained plants, capable of independent operation to demonstrate the environmenta1, economic, and technica1 feasibility of a technology. These plants are from one-third to one-tenth the scale of a commercial operation and often described as plus 1000 tons per day of coal consumption. Their purpose is stated in the Act (Section 6, (3)(E),) "to accelerate the commercial demonstration of technologies for producing syncrude and liquid petroleum products from coal: Provided. That the Administrator shall invite and consider proposals from potential participants based upon Federal assistants and participation through guaranteed prices or purchase of the products .... " In site selection and plant design it has been suggested that special interest groups should be allowed to dictate the site and specify the design. Under the present program the industrial partner who is contributing 50 percent

Jan 1, 1977

By G J. Showers, P Botman, A G. Hunt

Iron Road Limited (Iron Road) is currently evaluating the feasibility of producing 21.5 Mt/a of high-grade (>66 per cent Fe) magnetite concentrate from a 3.7 Bt resource (JORC) located at Warramboo on the central Eyre Peninsula in South Australia. Bulk concentrate can be produced via a conventional grind and low-intensity magnetic separation flow sheet. Due to the comparatively coarse magnetite liberation size (106 µm), consideration was given to enhancing both the grind economics and coarser product sizing via gravity separation.This paper outlines the test work, flow sheet design and engineering design of a gravity beneficiation circuit (GBC) conducted by Mineral Technologies for Iron Road. The resulting circuit optimisation necessitated mass balance simulation by Iron Road’s SysCAD model to quantify the resulting changes in mill recirculation load. This included the determination of project-critical grinding power and energy requirements with and without the GBC installed into the primary ball mill classification circuit. The outcome of this work was the design of a GBC, including spirals and up-current classification, which led to a substantial reduction (33 per cent) in ball mill recirculating load and power requirements, together with a favourable coarsening of final product size due to the relatively coarser gravity concentrate. This has led to a significant reduction in project design capital and operating costs. A further benefit of this approach is increased recovery of (paramagnetic) hematite and lesser titano-hematite via gravity separation compared to an all-magnetic separation approach.CITATION:Hunt, A G, Showers, G J and Botman, P, 2015. Test work and design of a gravity circuit for Iron Road’s Central Eyre Iron Project, in Proceedings Iron Ore 2015, pp 139–142 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015