Search Documents

By N J Welham

A commercial enargite concentrate was mechanically milled in inert and oxidising atmospheres for 10 hours. No substantial effect was observed in either an inert atmosphere or in air other than a broadening and weakening of the diffraction peaks. Milling dry in oxygen or wet in air was dramatic with a significant reaction occurring which formed arsenolite, As2O3 and CuSO4.5H2O, both of which are readily soluble.A small amount of SO2 was also formed. Dissolution in acid left CuS as the major phase implying incomplete oxidation. The small fraction of tennantite in the sample was comparatively resistant to oxidation.

Jan 1, 2001

By Roger Ferreira da Silva

O método de ensaio não destrutivo baseado na análise do ruído magnético Barkhausen (RMB) possibilita a obtenção de informações a respeito da microestrutura do material examinado e do estado de tensões presente no mesmo. Devido às particularidades do método, as medições devem ser realizadas mantendo-se constante a geometria entre a sonda e o objeto examinado, de forma a assegurar a confiabilidade das mesmas. Quando realizado manualmente, o processo de medição é demorado e sujeito a erros de posicionamento da sonda. Em trabalhos industriais ou em laboratório, esses erros podem resultar em interpretações incorretas, devendo ser reduzidos ao mínimo possível. Visando à redução do tempo de execução das medições e de análise e a eliminação de possíveis erros de posicionamento da sonda de inspeção, este trabalho propõe a automação do processo de medição de RMB em corpos de prova do tipo chapa. Compreende a construção de um dispositivo de movimentação XYZ acionado por motores de passo e do software “Plate Barkhausen”, com uma interface amigável, para controle da movimentação e da medição, além da análise dos dados.

Jul 30, 2018

By A Smith

Rock masses usually exhibit scale dependent mechanical properties primarily due to presence of discontinuities and their inhomogeneous nature. One of the essential preconditions for selection of appropriate strength and deformation parameters of a rock mass in relation to tunnel design is assessment of the scale of the joint network relative to the scale of excavation. In tunnel design practice, scale effects are estimated indirectly using small-scale unconfined compressive strength (UCS) tests and rock mass classification based empirical correlations. Large-scale UCS tests have the benefit of direct assessment of anisotropic and scale dependent properties of a rock mass.This paper presents results of a large-scale UCS test on a jointed siltstone. A 450 mm diameter sample with inclined bedding planes was cored and tested in uniaxial compression until failure with load and displacement measurements. The aim of the test is to determine strength and deformation parameters and correlate them with results of small-scale UCS tests of the same sample. The relationships between the small-scale and large-scale rock mass parameters were validated against published correlations from the literature.

Mar 8, 2011

By G J. I dos Santos

The risk assessment of mining projects is directly related to the possible failure in estimating, and as estimates are made from sampling results, this activity should be done in a judicious and planned manner, to avoid surprises at the start of project operation. Pierre Gy’s (1995) sampling theory addresses the issue of sample representativeness and indicates that only the certainty that the sampling procedure was performed with quality may result in samples being recognised as representative. To validate the representativeness of samples from sampling boreholes selected for studies of mineral processing, the team of geology resource assessment of VALE has proposed a methodology based on the use of statistical analysis tools, which in addition to considering the spatial distribution of these samples in deposit, considers whether they are representative of the populations studied, allowing the geologist to make a quick analysis of sample representativeness.

Jul 11, 2011

By G. R. Hopkins, A. B. Coons

A survey of the petroleum pipe lines by the Bureau of Mines as of May 1, 1923, shows that on that date there was a total of slightly more than 90,000 miles of pipe lines in the United States, having a capacity of approximately 15,750,000 barrels, which is equivalent to one-fourth of the nation's average production for one month. These lines varied in diameter from 2 to 16 inches, the weighted average being 6 inches. The total pipe-line milenge was about equally divided between trunk lines and gathering lines, though the capacity of the former was about four times that of the latter. This was due, of course, to the difference in average diameter, that for the former being 7.4 inches as compared with 3.7 inches for the latter. The common size for trunk lines was 8 inches, and for gathering lines 2 inches. Oklahora, with 19,180 miles of pipe lines, is the leading State in total mileage, with Texas second and Pennsylvania third. From point of trunk lines alone Texas is considerably ahead of any of the other States, a position which it owes to its size and to the growth in the rovement to its Gulf ports. Cali- fornia, though the leading State from point of production, ranks only seventh in pipe-line mileage. This is due to the fortunate location of the Los Angeles Basin fields, some of which are within sight of the refineries to which their oil is delivered or of the port of San Pedro through which their oil is shipped. The last survey of this nature, made in the spring of 1924 by the U. S. Geological Survey, recorded a total mileage of nearly 83,000 with a capacity of approximately 14,450,000 barrels. This indicates an increase of 9 per cent in both mileage and capacity during the two years.

Jan 1, 1927

By L. D. Tracy

For many yeirs natural gas has been the principal fuel used in the he·1 ting furnaces in those mills located in the. Pi t-c;s. b.urgh district· \7hich manufacture bolts ., nuts, rivets, pick$, mattocks and srr.&11 for6ine;s. For a nUI.1"'.::>er of years the steady supply of this fuel has been more or less interrupted owing to the increased4and f·or d9mes tic use and to the increasing difficulty in securing an ad.eq_ua te c.1mount of natural gas. This condition has led a number of the steel compa.nies to substitute -oulvsrized coal a.s a fuel for the.furnaces. Elaborate irista.llations have been made for pulverizing tne coal ar!d _ coriveyi16 i -c to the fur:waces. • Soon after the furnaces ·-:commenced .. to operate ·,Vi th :pulverized coal, large quanti ties O::f.' fine dust beg.::in to accumulate on the platforms over the fu:rna. ces, the. roof trusses, on the outside of the va.rious· pip·e ·line electric cables a.i.1.d even on the roofs of the buildings. Some of tha comi:,a.n:;.0s, becomin·g alarmed, requested the Bureau of ;Unes to rr.c1ke an investigation to ascertcliin the.· licibili ty of this dust to cause an explosion.· Nhi le conducting this inves ti ga ti on,· an explosion· occurr-2! d in a.nothe:2 nill ·,7hich caused he death of one man and severely burned t;io others. Eleven sc1nrcles of the dust (which for convenience has been termed "mill d.ust 11 ) from various locations in the different mill' buildings were taken and submitted to chemical analyses, microscopic examination and also to flame and explosion tests. From the chu,1ica.l analyses it was found that· the volatile matter in th..:: dusts xanged -from 6.3 per cent to 23,54 per cent, fixed carbon from 50.88 per cent to 67.08 per cent and ash from 32.29 per cent to 32.16 per centw

Dec 1, 1919

By Duclerc Fernandes Parra, Washington Luiz Oliani, Christiano Gianesi Bastos Andrade, Ademar Benevolo Lugão, Danilo Marin Fermino, Francisco R. Valenzuela Diaz

This work concerns the study of the effect of discarded bond paper on the mechanical behavior of polypropylene/organophilic clay nanocomposites. A brown polycationic bentonite from the state of Paraíba, Brazil, was treated with sodium carbonate to transform it into a bentonite that swells in water and then treated with hexadecyltrimethylammonium ammonium chloride to transform it into a bentonite that swells in organic liquids. Polypropylene with 3 % polypropylene graft compatibilizer (PP-g-AM) was mixed with 1 % and 2 % by weight of discarded bond paper and with 1% and 2% by weight of organophilic clay using a twin-screw extruder. The specimens were prepared by the injection process. The clay as received and after organophilization was characterized by XRD, SEM, and capacity of swelling in water and in organic solvents. The nanocomposite specimens were characterized by XRD and thermal analysis. The mechanical behavior of the injected specimens was evaluated by strength, flexural and impact tests. The nanocomposites showed improved mechanical properties compared with the polymer without filler.

Jan 1, 2015

By Huasheng Chen, Gaifeng Xue, Jing Zhang, Mingsheng He, Bin Liu, Yexian Ouyang, Shoujun Peng

Based on the investigation and study of the topography, microstructure and composition of the buildups which form in the surface of carbon sleeve in continuous annealing furnace for lowand medium-grade non-oriented silicon steel produced by CSP process, combined with production process of silicon steel, the mechanism and major causes for forming buildups of carbon sleeve are discussed from the factors such as CSP process, the quality of carbon sleeve and so forth. Meanwhile, some countermeasures to reduce the formation of the buildups are put forward.

Jan 1, 2015

By Hassan Saalman, Mahmoud Mahmoud, Omneya El Hussaini

The Ferruginous sandstone ore was obtained from Ramlet Hemeyir area, Southwestern Sinai, Egypt, was found to contain 10% rare earth elements (REE). A representative sample has been subjected to sulfuric acid agitation leaching. About 93% of the REE content was released by mixing the ground sample to -100 mesh with concentrated H2SO4 at solid/liquid (S/L) ratio of 1/2 for 5h at a temperature ranged from 250 to 300o C. The REE was precipitated from the prepared sulfate leach liquor of pH 1.0 by adding 35% oxalic acid at 25o C. The precipitation yielded 98% REE. For selective separation of yttrium, the rare earth cake was leached with 31.5% nitric acid. Next, the aqueous solution was contacted with di-(2-ethylhexyl) phosphoric acid (D2EHPA) where 98% yttrium extraction was achieved. Stripping was done with hot H2O (80o C). Finally, a precipitation with oxalic acid was done followed by ignition at 950o C. A yield of 95% yttrium oxide was produced.

Jan 1, 2014

By Grant Wallace, Rod James, Larry Twidwell, Ed Rosenberg, Courtney Young, Sean Dudley, Hsing-Hsin Huang, William Gleason, Jerome Downey

The use of applied chemistry in the production and optimization of leach solutions from Rare Earth Element (REE) ores and concentrates is being investigated. Ore and concentrate samples were characterized using scanning electron microscopy/mineral liberation analysis (SEM/MLA), X-ray diffraction (XRD), and Atomic emission inductively-coupled plasma spectroscopy (ICPAES). Multiple leach tests were performed to analyze the effects of temperature, residence time, and reagent concentration on the leaching of REEs. Analysis of leach solutions was carried out using ICP-AES. Modeling and statistical analysis of extraction behavior was carried out using DesignExpert 9. Modeling data for cerium extraction indicates that extraction is greatly influenced by temperature and reagent concentration, while leaching time plays a much less important role. Experimental design techniques are being utilized to optimize REE recovery. Results, conclusions, and directions for future studies will also be discussed.

Jan 1, 2015

By M Griffiths

This paper outlines an approach to high solids slurry pipeline design with data generated from a closed pipe-loop test system. The pressure and flow rate data generated is used to develop a pseudo-shear diagram for the purposes of system design. Following this approach enables the design of a full pipe flow system maximising system life and reliability. The alternative free fall system is explained and the disadvantages highlighted.Environmental and social considerations are discussed; mainly water and land use, and how designing for high solids slurry pipeline systems can be used improve these aspects of a mining project.Also discussed is how the use of high solids slurry pipeline systems can help to mitigate the risk associated with surface tailings storage facility failure, with the Bulyanhulu project used as a positive example.

Aug 8, 2011

By D Readett

The most critical variable in the successful establishment of the Murrin Murrin Heap Leach plant was the effective agglomeration of the Ni laterite ore. This paper describes the test work undertaken to establish the key agglomeration parameters including state of the art testing and analysis procedures. These parameters were then utilised to establish the key design and operational concepts for the world’s first commercial scale Ni laterite heap leach. Following the technical and economic success of the operation, the actual operational data is compared back to the original test work data.

Aug 8, 2011

By I. A. Menshikh, S. A. Kotov, N. L. Shinkarkin

All the cycle for conversion of natural and reprocessed uranium of ROSATOM’s “TVEL” Fuel Company is concentrated at the Siberian Chemical Plant. Conversion capacities are located on two sites, i.e. the Radiochemical Plant, which refines feedstock, and the Conversion Plant, which produces uranium oxides and uranium hexafluoride. Liquid radioactive waste arising in the process, after pretreatment, is transferred to a dedicated national operator for underground disposal. Environmental strategies pursued by the Fuel Company involve the introduction of process solutions intended to eliminate liquid radioactive waste and convert it into a solid phase. In the 5–7 years coming, work will be performed to refurbish and upgrade conversion facilities of the Siberian Chemical Plant that will principally change its radioactive waste management scheme. This paper describes the current waste management scheme and sets out planned schemes for management of natural and reprocessed uranium waste, which will be implemented in the refurbishment of conversion facilities of the Siberian Chemical Plant. The new technologies for the management of liquid radioactive waste from uranium conversion described in the present paper have an undeniable advantage over the current technology mainly due to significantly less environmental harm.

Jan 1, 2020

By J Wood

Steady depletion of the world’s primary copper reserves coupled with a meteoric rise in electronic waste (e-waste) generation has led to secondary copper processing assuming an ever-increasing importance within the global copper industry. Treatment of secondary copper feeds at existing smelting operations has traditionally been performed in the Blast furnace, Peirce-Smith converter and/or anode furnace. In the past decade or more, bath smelting technologies have been preferred for the processing of these materials due to their superior environmental performance and flexibility to operate under a wide range of conditions. This paper focuses on the pyrometallurgical processing of copper secondaries in the Outotec Ausmelt TSL Furnace and some of the unique issues facing secondary copper smelters and downstream gas handling/cleaning equipment.

Aug 8, 2011

By Morrison R. S, Doennilan N

Recent mapping (1989-1992) by the Northern Territory Geological Survey in the Tennant Creek 1:250 000 map sheet area has resulted in substantial revision of the lithostratigraphy of the Tennant Creek Block (Donnellan, Hussey, and Morrison, in press). Briefly, the former Warramunga Group (Dunnet and Harding, 1967; Dodson and Gardener, 1978) is divided into the Warramunga Formation, and an overlying less deformed volcano-sedimentary succession, the Flynn Subgroup. The latter is conformably overlain by the Tomkinson Creek Subgroup of the Tomkinson Creek province in the north of the Tennant Creek Inlier. These two Subgroups constitute the Churchills Head Group which is essentially equivalent to the Hatches Creek Group of the Davenport province to the south of the Inlier.

Jan 1, 1994

By E. J. HOFFMAN, J. c. W. FRAZER

The apparatus and methods described in the following pages were devised and used by the writers in connection with certain investiga- tions of the technologic branch of the United States Geological Sur- vey, especially those bearing on the improvement of furnace condi- tions and on efficiency in the use of fuel. The Bureau of Mines, which has charge of such analyses and tests of fuels as were formerly made by the technologic branch of the Sur- vey, is using the same apparatus and methods in connection with similar investigations that are being carried on at the testing plant of the bureau at Pittsburg, Pa. The furnace conditions prevailing both in small plants and in large industrial establishments in this country are frequently far from satisfactory. If such conditions are to be improved, they must be more thoroughly understood, and means must be found to insure complete combustion of the fuel, and yet to permit operation with such an excess of air as will result in the greatest efficiency. In this work the services of the chemist are indispensable. A very important problem is the determination of the small percentage of unburned combustible matter that escapes from the furnace in the flue gases. Under ordinary circumstances so little as 0.1 per cent of unburned combustible matter in a furnace gas is equivalent to about 1 per cent of the fuel used; and for the determination of such small percentages of gas more accurate and refined methods are required than have ordinarily been available heretofore. It is the purpose of this paper to describe some apparatus and methods which have proved satisfactory to those engaged in the chemical work of the investigations mentioned. While these methods and apparatus have been designed more particularly with regard to analysis of furnace gases, their use is by no means limited to that purpose. The reader will readily see their applicability to other uses in which the sampling and analysis of gases are involved.

Jan 1, 1911

Production of oic at BHP Minerals Pty Ltd's Cannington Mine commenced in May 1997. The initial sloping blocks at the [nine are located in the upper part of the Footwall Lead lode, and the Hangingwall Lead and Glenholme Breccia lodes. This paper discusses the geological investigations, interpretation and modelling that was undertaken for the Footwall Lead lode production block at Cannington Mine, as well as providing a basic geological introduction to the Cannington deposit.

Jan 1, 1997

By H Benzer, N A. Aydogan

It is well known that the high pressure grinding rolls (HPGR) can only be operated efficiently under choke feeding conditions in which a material bed is built up between the rollers to ensure interparticle breakage. By increasing the fines amount in the material bed up to a specific level with the recycling load, a uniform material bed is created and higher pressure gradient along the roller width is obtained which results in compact flakes including more fines. Extensive test work has been carried out with an industrial HPGR unit grinding cement clinker in a cement plant in Turkey. During the test work the recycling load of the circuit was changed to achieve different ratios to the fresh feed rate in order to identify the effect of the recycling load on the circuit performance. Six different tests were performed with the circuit at steady state. For each test, samples were collected from HPGR fresh feed and discharge, and total feed, then the particle size distributions of the samples were determined and mass balances around the circuit were calculated. The conclusion was that the reduction ratio of the HPGR increased with increase in recycling load. The flake densities showed the same trend with more compacted flakes being produced for higher recycling loads.

Jan 1, 2009

By Tianzu Yang, Xunbo Deng, Weifeng Liu, Lin Chen, Shuai Rao, DUCHAO ZHANG

To overcome the shortcomings of traditional cyanidation process for refractory gold ores, the smelting processes have been proposed. These smelting processes could be divided into two kinds, namely, indirect smelting and direct smelting. In the indirect smelting process, the calcine of refractory gold ores are added in the copper or lead smelting processes during which gold can be enriched into copper matte or crude lead. Then gold is extracted from the anode slimes. In the direct smelting process, refractory gold ores are smelted directly with gold enriched into ferrous matte. Then gold is extracted from ferrous matte. Based on the direct smelting process, the metallurgy-beneficiation united process for refractory gold ores has been proposed. In this process, gold is firstly enriched into ferrous matte by direct smelting, then the grinding-flotation process is used to obtain gold-rich sulfurous iron ore, and finally gold is extracted via hydrometallurgical method.The metallurgy-beneficiation united process has advantages of high gold recovery ratio, environment-friendly and low cost, which provides a new idea for the extraction of gold from refractory gold ores.

Mar 1, 2017

By Sheng-ping He, Zhuo Chen, Qian Wang, Kun-peng Xu

During the continuous casting (CC) process of Ti-Stabilized Stainless Steel, the nozzle clogging or even the crusts composed of TiN, Al2O3, TixOy and the complex inclusions MgOAl2O3, Al2O3 is often occurred. The main objective of the present study is to research the reaction between refining slag or mold flux and Ti-Stabilized Stainless Steel by thermodynamic calculation. A suitable refining slag composition was sought to absorb Al2O3, Tix Oy inclusions, and the reactions between different mold flux and steel was calculated and compared. It was found that a suitable refining slag was difficult to adjust aluminum and titanium to meet requirement simultaneously. The target refined slag is composited of 3–8.7% SiO2, 56–59% CaO, 33–38% Al2O3 and 4% MgO with low melting point and high absorption capacity of inclusions for in the refining of the 321 stainless steel. SiO2, Fe2O3, Na2O and B2O3 of mold flux would react with titanium in the steel. The CaO–SiO2 based mold flux had a strong reactivity than CaO–SiO2–Al2O3 and CaO–Al2O3 based mold flux.

Mar 1, 2017