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By Alejandro Uribe-Salas, Fabiola Nava-Alonso, Gloria Dávila-Pulido

This paper presents results of an experimental study performed on the role of calcium sulfate present in flotation water on sphalerite flotation in the Pb/Cu circuit (non Cu-activated sphalerite) and in the Zn circuit (Cu-activated sphalerite). In the Pb/Cu circuit calcium ions adsorb on the negatively-charged sphalerite favoring xanthate adsorption and therefore making sphalerite floatable; experimental measurements show sphalerite contact angle increases with calcium concentration while xanthate adsorption onto sphalerite increases with the increase of pH and calcium concentration. Gypsum (CaSO4·2H2O) eventually present due to calcium sulfate precipitation is not detrimental to flotation at this stage since it is negatively charged at pH 9 and therefore, does not adhere onto the surface of negatively-charged sphalerite. In the zinc circuit, Cu-activated sphalerite decreases its negative charge (or even becomes positively charged) and develops some hydrophobicity due to the polysulfide produced by Cu-activation. At this stage calcium ions do not interact with the mineral surface and therefore do not favor xanthate adsorption; nevertheless, precipitated gypsum particles do adhere onto the mineral surface, greatly affecting its floatability (e.g., contact angle). Addition of sodium carbonate to dissolve gypsum and to precipitate calcium as calcium carbonate, which disperses in the bulk of the suspension, effectively restores mineral hydrophobicity. SEM observations coupled with EDS analysis clearly illustrate and support the above sequence of events.

Jan 1, 2014

By George P. Demopoulos, Nima Parsi Benehkohal, Marianna Uceda

Lithium-ion batteries (LIBs) find wide range of applications from portable electronics to electric cars and stationary storage or renewable energy. LIB electrode fabrication is done through mixing the active material (Li-ion host) with carbon (conductive component) and polyvinylidene fluoride (PVDF), which acts as a binder. These components are dissolved in N-methyl-2-pyrrolidone (NMP) to form a paste which is then doctor bladed onto the aluminum current collector. NMP is a toxic chemical and the overall fabrication process remains costly. Efforts are made of eliminating NMP by (1) replacing the binder and (2) using a new fabrication method. Of particular interest among these new methods is electrophoretic deposition (EPD). Via the application of DC potential, particles in suspension can be electrophoretically deposited on different conductive substrates in a relatively fast rate rendering EPD feasible for industrial application. A key aspect for successful application of EPD is the formulation of a stable suspension. Within the McGill HydroMET group, we explore the potential of EPD in fabricating LIB electrodes having demonstrated its effectiveness in the case of P25 nanotitania/carbon anodes. The performance of EPD fabricated TiO2/C electrodes is compared to standard PVDF-based electrodes and shown to have comparable charge capacity. This method is now being extended to other electrode materials. In this paper an introduction to the EPD method will be made and subsequently its use in fabricating LIB electrodes will be described. The performance of the fabricated batteries is evaluated via galvanostatic charging/discharging and cycling tests.

Jan 1, 2016

By Nick Vayenas, Ming Cai, Hongbin Zhang Lorrie Fava, Enrique Acuña

"A hybrid methodology is proposed to improve the accuracy of Diesel Particulate Matter (DPM) concentrations simulated in a ventilation network model by using Computational Fluid Dynamics (CFD). DPM, as a primary concern for underground hard-rock mines, has been studied in two dominant numerical models, ventilation network solvers and computational fluid dynamics. Ventilation network solvers are efficient, but they are not able to provide three-dimensional DPM concentration contours and only accept area-average DPM data as input. CFD simulations are time-consuming, but generating DPM concentration results with high accuracy. Besides, both monitoring points and planes can be created in a CFD model, which can take both point data and area-average DPM data as input. The hybrid methodology is intended to combine the advantages of the two by using the CFD results to update the network model results at key locations. A field study was conducted in a dead-end heading in an underground gold mine in the United States. Real-time DPM monitors were used to collect data. A CFD model and a network model were built for the experiment area. The CFD model was calibrated to the experimental data. In the study presented here, results from a calibrated CFD model are converted to equivalent diesel emission rates in the ventilation network model at a shared outlet. The hybrid methodology is used to provide better input for the network model. INTRODUCTION Mine ventilation system is one of the most important parts for an underground mine. It not only provides fresh air to the personnel but also helps clear the contaminants generated from the diesel-powered equipment. For most underground metal and non-metal mines, diesel particulate matter is the main contaminant. It is also the focus of this paper."

Jan 1, 2019

By Paul W. Jeran

This Bureau of Mines report has been prepared to provide a means whereby mineworkers without specific geologic training can recognize and record the existence of potentially hazardous geologic features encountered in coal mines. Each geologic feature described in this report has been implicated in roof failure. Through the recording of the observations of mineworkers, based on this report, a geologic map of mine workings and the associated ground control problems can be compiled. From such maps, the trends of changes and features can be determined and projected ahead of mining. The face crew can be alerted to a potential problem and what to look for as the face is advanced.

Jan 1, 1983

Proposed by outstanding electrochemist and electrometallurgist Prof. Raphael Agladze (191 1- 1989), process of copper and manganese co-electrowinning was enhanced to the pre- electrowinning stages: low,temperature co-leaching of copper and manganese containing materials, and to high-temperature co-roasting of the same materials with consecutive leaching. The report presents results of experimental investigations of the processes mentioned above, as well as results of thermodynamic investigations of co-roasting processes, and co- leaching processes computer modeling.

Jan 1, 1997

By E. L. Litchfield

This report of work by the Federal Bureau of Mines has two primary objectives: A survey of the present status and usefulness of the minimum ignition-energy concept, and the presentation of recent data that are believed to bear on the safety problem associated with the ignition of combustible gases by electric discharges. The minimum ignition-energy concept has widespread applicability, especially to safety. The primary obstacle in making theoretical calculations of the requisite ignition energy is the lack of data on chemical kinetics and flame hydrodynamics. The new data on electrical ignition are representative of the great increase in knowledge that can be achieved by proper utilization of geometrical and electrical characteristics associated with the ignition source. CONCEPT OF MINIMUM IGNITION ENERGY The basic concept of a minimum ignition energy (the minimum amount of energy required to cause ignition) follows quite naturally from general physical principles and from the stability (lack of chemical reaction) of the gaseous mixture under the initial conditions. It also follows that if, as a first condition, lossless, instantaneous, and spatially localized energy can be injected and, as a second condition, the relaxation time for conversion of this type of energy to the type required for the reaction is short compared to some characteristic time scale of the ignition phenomenon, the energy requirements will be essentially independent of the type of energy source. Even if condition one cannot be fulfilled, it is sometimes possible to estimate the energy content of the gas required for ignition, and under these circumstances, condition one is fulfilled in effect. There are several instances where results can be interpreted for circumstances that effectively satisfy conditions one and two; these will be discussed later.

Jan 1, 1960

By A. K. Stagg

Toxic substances in On solutions can retard biological leaching of copper sulfide dump ores. On solutions were analyzed for metals, organics, and chloride, and showed inhibitory concentrations of aluminum, manganese, and chloride. Inhibition of bacterial activity by the solid fraction of On solution, with and without the organic constituents, was evaluated. Toxicity to bacterial species was evaluated by monitoring bacterial numbers, pH, Eh, and rates of iron oxidation. The On solution solids were toxic at 50 -60% of their field concentration. Most of the toxicity of the On solution was due to the organic fraction. Different SX reagents show varying degrees of inhibition of T. ferrooxidans. Bacterial inhibitory effects of carriers and lixiviants used in the SX plant should be determined so that entrained SX reagents do not retard biological dump leach systems. The reagents used should be the most cost effective and the least toxic.

Jan 1, 1994

By Thomas T., Read

THE education of adolescents to perform the duties and assume the responsibilities of maturity has been a characteristic of human society since the dawn of history. In the beginning the members of the immediate family performed this function, and in modern life they still have an important part in it. Possibly religion was the first field in which education began to be functional; young people were sent for instruction to a teacher who had a broader and deeper knowledge of the subject than was possessed by the family. It does not seem necessary for our purpose to attempt to determine how, when, or where instruction in the practical arts first' began to become functional, and the brief outline which follows must suffice. The discovery and utilization of mineral substances to improve and maintain the conditions of human living is a practical art, which must have had an almost accidental origin and have been developed by empirical experiments. We do not know, nor would it be useful to try to fancy, how men first learned that they could make use .of mineral substances to their benefit, but how- ever that knowledge was initially gained it was certainly trans mitted through instruction in the family. At first such activities must have been merely a .minor part of the making of a-living, but in time those who excelled found it better to devote them-

Jan 1, 1941

By M. Hakan Morcali, Onuralp Yücel, Haldun Gürcan, Serdar Aktas, Semih Özbey, Alper Keskin

"This work presents a method for the precipitation of cobalt sulfate by alcohols, specifically ethanol and methanol. The effect of the initial concentration of cobalt, the volumetric ratio of alcohol to cobalt sulfate solution, the addition of sulfuric acid and ammonia, and the effects of common ions on the precipitation percentage were investigated. The performances of ethanol and methanol were compared in terms of the precipitation percentage of cobalt sulfate, and explanations for different performances are offered. In the sulfate-based solution, the alcohol was shown to displace water ligands from the first coordination sphere of the cobalt(II) cations, which led to the precipitation of the cobalt ions as cobalt sulfate heptahydrate. SEM analysis revealed that the particle sizes of the powders produced by this method are smaller than those of commercially available cobalt sulfate. The scientific literature contains no data on the solubility of cobalt sulfate in ethanol. In this study, the solubility product constant (Ksp) for cobalt sulfate was experimentally calculated to be approximately 1.15 x 10-5.IntroductionCobalt sulfate, which is one of the most important compounds of cobalt, is used in the electroplating and electrochemical industries. The addition of cobalt sulfate to nickel-plating baths makes the treated metals brighter, harder, smoother and more ductile (Armstrong et al., 1988). It is also used as a desiccant for lithographic inks, varnishes, paints and linoleum, as well as in storage batteries, e.g., nickel-cadmium (Ni-Cd) and lithium-ion (Li-ion) rechargeable batteries (Kang et al., 2010). Cobalt sulfate is employed as a coloring agent in ceramics, enamels and glazes to prevent discoloration and as a copigment for the decoration of porcelain. In addition, cobalt sulfate has been used in animal feeds as a mineral supplement (Budavari et al., 1996; Kirk and Othmer, 1999).In the past, brewers used cobalt sulfate to prolong the life of beer foam (Kesteloot et al., 1968). Ranchers have dosed livestock with cobalt sulfate or used fertilizer enriched with this mineral to ensure that their animals obtained sufficient amounts of the trace mineral, which is essential to the production of vitamin B12. Cobalt sulfate has also been used in veterinary medication to prevent and treat cobalt deficiency in ruminants, which causes a reduction in feed intake and body weight, accompanied by emaciation, anemia and debility.Cobalt sulfate is a water-soluble bivalent cobalt salt. Cobalt sulfate heptahydrate dehydrates entirely at 420° C, and the dehydrated salt forms red monoclinic crystals."

Jan 1, 2015

By P F. Hodkiewicz

"Our understanding of mineral resources relies on three basic steps: data capture data interpretation model construction. Until recently, all three of these steps required significant time and manual effort to produce a single resource model for mine planning, typically taking more than a year to progress from drilling to the final block model. Over the past several years, BHP Billiton has been developing innovative workflows in rapid resource modelling projects to significantly reduce these time constraints and make the process more productive by replacing manual activities with automated ones. Rapid resource modelling is the process of combining recently developed off-the-shelf technology with internal technology developments to fundamentally change the way we collect, interpret, model and evaluate geoscience data. Initiatives include automated systems and standardised workflows to make it safer, faster and cheaper to continuously update multidiscipline resource models. Specifically, rapid resource modelling workflows combine: real-time analysis of drill holes and drill samples with downhole tools and hyperspectral scanning systemsautomated interpretation of drill hole intervals based on pattern-recognition algorithmscontinuous modelling workflows using implicit modelling software. This paper outlines technology developments and workflows that provide a more thorough understanding of mineral resources to support faster and more informed strategic, planning and production decisions.CITATION:Hodkiewicz, P F, 2014. Rapid resource modelling – a vision for faster and better mining decisions, in Proceedings Ninth International Mining Geology Conference 2014 , pp 183–188 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 18, 2014

By Ignacy A. Lipiec

The advantage of microorganisms used in bioleach systems to conventional chemical reaction systems is that these apply the available energy more precisely where it is needed, either directly onto the mineral of interest or by efficiently catalyzing the production of a reactant. The literature cover the range from empirical models used in describing macro heat balance in heaps to detailed studies relating the micro heat effects of bacteria adhesion energy to the surface of minerals. In this paper, the heat effects are reviewed in a general way describing bioleaching in two macro systems, heap leaching and slurry bioreactors. The micro scale heat effects is the reactions and conditions at the microorganism scale, including the mechanism of leaching and bacterial behavior.

Jan 1, 1998

By Yotamu Hara, Animesh Jha

"High Curie temperature and large magnetic anisotropy make cobalt an important magnetic material for power engineering applications of magnets operating above ambient. It is also an essential constituent of modem lithium - cobalt oxide batteries, without which modem electronic gadgets will be functionless. Both these applications of cobalt save energy and reduce C02 emission. Ironically, however the production of cobalt from copper and nickel smelting in the world remains one of the least energy efficient process. The paper analyzes the energy balance, material and process chemistry of overall cobalt recovery and the waste generated, which entail the process limitations. We discuss a novel approach for the reduction of sulphide minerals with CaS04, permitting better separation of metals from slag and generating higher concentrations of S02. Such an approach may seem to be an alternative energy efficient option for processing and further purification of cobalt in metallic form. The results are discussed in the context of process thermodynamics and reaction kinetics for Coalloy production.IntroductionCopper sulphides bearing minerals are predominantly associated with iron and cobalt sulphides minerals. Carrollite (CuC02S4) is a mineral that has both copper and cobalt sulphides [1,2], which may also contain FeS, by substituting either Cu2+ or Co2+ ions in mineral lattice. On smelting copper - cobalt - iron sulphide concentrates, some parts of the cobalt often partition to matte at preferentially low oxygen potential by forming eventually an alloy phase with copper, however a significant fraction is often lost into an oxide slag rich in iron and silica. The slag heaps accumulated in the Copperbelt region in Zambia from last 60 years of mineral processing and metal extraction is reported to be 0.3 to 2.6 wt% of cobalt element, which is high [3]. Cobalt is also available in smaller concentrations in the copper smelting and converter slag, as reported in the investigations on the recycling of such slag materials using leaching with ammonium salt [4], iron chloride [5], and sulphuric acid [6], and solvent extraction [7].The recovery of cobalt from slag, irrespective of the techniques researched so far, does not seem energy efficient because the molten slag at 1300°C is quenched by losing thermal and chemical energy. The quenched slag is again reheated to above room temperature for leaching and above liquidus for carbothermic reduction of residual cobalt oxide. For example, in Mintek DC arc smelting [3], 80% of cobalt and 95% nickel are recovered by expending 600 kW per tonne. Assuming that the mineral carrollite is the starting phase, the univariant calculations for the Co-Ca-Si-S-0, Fe-Ca-Si-S-0, and Co-C-Si-S-0 systems are shown in Figure la, lb, and le, respectively at 1573 K."

Jan 1, 2012

By Masahiko Yamaki, Takahiro Yamanashi, Hijiri Hashimoto, Hirochika Hayashi

"In this study, the authors used heat conduction analysis with the aim of quantitatively evaluating whether treating improved ground with cover soil is an effective measure for maintaining strength development in the surface layer of improved ground after constructing cement treated soil for the winter season. This report describes a simple procedure to evaluate covering soil thickness, which is necessary for the strength of the surface of cement treated soil, by using the freeze index and both the water content ratio and dry density.INTRODUCTIONIt was reported that when ground improvement using cement is performed in winter in a snowy cold region (Fig. 1 photo, Fig. 2), the uppermost 1 m of the improved ground (i.e., the cement-treated soil) tends to become prone to solidification failure from exposure to the cold air during curing (Hashimoto et al. 2006). In light of this, our research laboratory conducted unconfined compression tests using curing temperature as a parameter of analysis on improved ground toward understanding the influence of curing temperature (ambient air temperature) on the strength improvement afforded by ground improvement.The authors found that if the curing temperature is maintained at 0°C for the first 28 days after improvement and then at 5°C for the next 337 days after improvement, the improved ground is expected to have 90% of the unconfined compressive strength of improved ground whose temperature was maintained at 20°C for the first 365 days after improvement (Hashimoto et al. 2011)."

Jan 1, 2015

By Valeri Mitkov

Studena Quarry is one of the main suppliers of inert materials for concretes production in Sofia. It is characterized by massif heterogeneity in density and fissuration. Failure to take into consideration this fact during the planning of the blasting works recently had unsatisfying results in their carrying out – obtaining of materials with too small dimensions or high percentage of outsize material. Series of test blasting were carried out to find the relations for calculation of the main parameters of the drilling and blasting works. The blasting network was enlarged to 6 x 6 m, the diameter of the shot-boreholes was changed from 110 to 152 mm, the stem of the boreholes was significantly reduced and the relative consumption of blasting agents as a whole was reduced to 0,37 ?g/m3.

Jan 1, 2010

By M. Pfeifer, M. N. Brodie, D. J. Barratt

"This paper reviews design trends related to the various SAG mill configuration and drive options available today. The impact of these options on capital and operating costs is assessed, and key technical issues reviewed. The discussion is based on the conventional North American ’pancake’ mill configuration. IntroductionDuring the past decade mill technology has evolved significantly in the following key areas:• improvements in variable speed motors continue with on-going advances in electronics;• ring motors, or gearless drives, are becoming more common in mill sizes 32 ft and larger, with ratings of 10 000 HP and greater;• geared drives have become available up to ratings of 9500 HP per pinion, compared to the earlier 6000 HP guideline;• improvements in speed reducer technology due to the use of carburized and ground precision gearing, make the high speed motor-speed reducer drive more competitive with the direct coupled low speed motor drive;• a unique speed reducer drive is being introduced to this industry which combines ring gear drive pinions with speed reduction. mprovement in gear alignment is claimed, and the overall drive arrangement is more compact than is possible with a conventional speed reducer drive;• the first 38 ft and 40 ft diameter mills have been designed and manufactured; and • application of large multi-shoe bearings have made shell supported mill configurations available for all, including the largest sizes. These designs have flat instead of conical mill shell ends, and have the potential for technical and cost advantages compared to conventional trunnion supported designs.This proliferation of mill design features provides several options to those involved in planning and design of milling plants, and requires more extensive evaluation to optimize mill design features to best suit specific project requirements."

Jan 1, 1999

By John E. Pahlman

The Bureau of Mines has conducted research on a dual leaching method that offers the potential for the economic recovery of the silver, as well as of the manganese, contained in some domestic manganiferous silver deposits. The method consists of an initial leach of manganese with aqueous sulfur dioxide (S02) followed first by a neutralization rinse, and then by a second leach with cyanide solution for the extraction of silver. Refractory silver in these ores was either (1) intimately associated with the manganese, (2) chemically resistant to cyanide leaching, or (3) rendered inaccessible to cyanide leach solution by the surrounding manganese mineralization. Less than 10 pct of the silver was extracted when minus 2.5-plus 1.3-cm ore pieces were leached directly with cyanide. However, extractions of 25 to 82 pct of the silver and 65 to 96 pet of the manganese were attained in laboratory column-leach tests using the dual leaching method on equivalent-sized ore pieces from seven domestic deposits.

Jan 1, 1987

By Adam J. Gesing

Eddy current separators are increasingly used by the auto shredder operators to produce higher grade of nonferrous metal concentrate for recycling. While this increases the unit price of the concentrate, metal losses through inefficient metal recovery quickly offset the price differential. We show how to optimize the eddy current separation system at the shredder to maximize mate- rial throughput, nonferrous metal recovery and grade of the nonferrous metal concentrate.

Jan 1, 1998

By G. W. McCaa

Plans for a large industrial development in the Upper Ohio Valley between Moundsville and New Martinsville, West Virginia, were announced in the Fall of 1955. This development consisted of a large aluminum plant to be .built by Olin-Mathieson; a 675,000 KW power plant to be constructed by the American Electric Power Service; and a large coal mine adjacent to the power plant to be developed by the Hanna Coal Company Division of Consolidation Coal Company. The Ireland Mine was designed to efficiently supply fuel for the power plant, and this was the first consideration in the location of facilities, design, and development of plant and the selection of the equipment. The first problem was to find a suitable area for the surface facilities. A level bottom area south of the power plant was reserved for future industrial plants and this area was also blocked off from the coal reserves by an old abandoned and flooded mine. The coal storage facilities of the power plant were on the north side of the plant and it was decided to locate the coal mine preparation plant on-the shoulder of a hill above the power plant. This location required the excavation of 70,000 yards of rock but permitted the driving of a belt slope from the plant at an angle so that the haulage roads underground would miss the abandoned Cresap Mine. This location also permitted the plant to be located at an elevation so that the conveyors leaving the plant were horizontal and had sufficient clearance above the highway and railroad tracks. The other surface facilities consisting of air shafts, supply slope, supply yard, office, bathhouse, shop and warehouse were located in the valley some distance north of the preparation plant. This location placed these facilities one mile nearer to the working area. Plans for design and development of the mine were started in November 1955; grading and clearing of surface area was started in January 1956; the air shafts and slopes were started in the Spring and Summer of 1956; and the first coal was produced from the supply slope in October 1956. The preparation plant was put in operation in March 1958, and by July 1959 was producing 8,000 tons per day.

Jan 1, 1959

By J. Smuts

The mixed-valence iron silicate ISCORITE (Fe7Si010) was identified recently in a number of ironmakingmater1als, some of which were first produced more than a century ago. Although the existence of iscorite was not reported before 1967 and published phase diagrams do not make provision for it, the morphology of the phase in all the materials that were examined suggests that it is stable under a variety of conditions. It is shown that is-corite can accommodate various foreign cations in its lattice where they can replace Fe and/or Si. The morphology of is-corite in a number of materials of different origin is shown in relation to iron oxides and silicates in optical and SEM/BSE images.

Jan 1, 1991

By M. D. Martin

Low metal prices and increasingly stringent environmental regulations, coupled with the threat of higher governmental royalties are adversely affecting both existing and new operations. Existing operations must therefore be run at maximum operating efficiencies to enable mining companies to survive and grow. Well planned and executed "outsider" reviews can help achieve this goal. Many mine managers and those who direct them resist the idea of "outsider" reviews for a variety of reasons, some valid and some not. Those managers who do bring in the "outsiders" are nearly unanimous in reporting that the exercise in self-discipline was well worth the pain and effort and repaid the cost many times over. This paper makes a strong case for "outsider" reviews and gives recommendations on the kinds of reviews to undertake. The authors draw upon their nearly 70 years combined experience, much of which has been in operations.

Jan 1, 1994