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The term geostatistics was introduced by Matheron (1960) to cover the development and application of mathematical and statistical models which take specific account of the spatial structure of a 'regionalised' variable. In ore valuation the relative positions of available ore values within an ore body or portion thereof, can only be ignored in the unlikely case where there is no significant pattern of association or correlation between them - that is, if they do not disclose any significant spatial structure. A structure might not be evident in the available data, e.g. where the spacing of the available values is relatively wide such as in surface drilling on a new deep gold mine. However, practical selective mining considerations could dictate the need for eventual underground valuation on a scale much smaller than that represented by this spacing and the possibility of a significant structure on such a smaller scale cannot then be ignored. Some spatial structure must be present wherever the average variability among the values of check ore samples from the same, adjacent or nearby grooves or of borehole cores from the deflections in the same borehole, is lower than the overall variability for ore values within the whole ore body. Another practical check on the presence of a spatial structure is where it is evident that there is or will be a significant variation in the ore grades for individual ore blocks. Any correlation between peripheral and follow-up internal ore block values also provides evidence of a spatial structure, and hence the regression techniques covered in §1.16-1.2 1 can be accepted as the first application of the geostatistical procedures. The spatial structure of a regionalised variable can be studied and measured by the pattern, usually a decreasing function, in the level of correlation or of the covariance between pairs of values as the distance or lag between the values increases, that is, by the correlogram or covariogram (Krige, 1968, 1969, 1976; and Fig. 18). In geostatistics, for various practical and theoretical reasons (Matheron, 1960, 1971), the measure most commonly used is the semivario- gram, which increases as the lag increases. The semivariogram and covariance values are interrelated and for the lognormal- de Wijsian pattern used extensively for gold ore valuation both measures as well as their relationship can be defined on a fairly straightforward basis. Provided the underlying as- sumptions are realistic, the choice of measure - correlogram, covariogram or semivariogram - will be dictated mainly by convenience. Paragraph 2.2 will cover some general geostatistical terms and $2.3-2.12 will deal mainly with the theoretical side of the lognormal-de Wijsian model for spatial structures. Wherever the relevant variable lends itself to normalisation via the 3-parameter lognormal distribution (see 51.9) the de Wijsian semivariogram model is also likely to be suitable and will provide substantial advantages in application. Various practical applications will be covered in Section 3. Although confined to the lognormal-de Wijsian model, much of the theory covered and the general approach is applicable to all spatial structures. [ ]

Jan 1, 1981

By S. Tu, Y. Yuan, H. Wei, Z. Chen, M. Jia

"To reduce production costs and increase efficiency in ageing coal mines, a system that utilizes two shearers in a fully mechanized longwall working face is proposed. Using theoretical and engineering experience, three issues pertaining to the system were determined: (a) the two-shearer mining technique; (b) matching and modifying the equipment; (c) and coal-cutting task allocation for each shearer. Two mining processes are proposed, with the two shearers travelling in either the same or opposing directions. To avoid breakage of chains and pan extrusion of the armoured face conveyor (AFC), the length of the AFC ‘snake’ was controlled. To ensure continuous cutting and transporting of coal, the cross-sectional dimensions of the AFC were checked and the shearer closer to the head drive was modified. Based on the assumption of equal cutting times for each shearer, the meeting position of the two shearers was obtained by using a theoretical model of mining task allocation. Application of this technique at No. 2 Jining Mine, China, has shown remarkable benefits: daily production capacity was increased by 54% and personnel efficiency was improved by 33 t/d per person. IntroductionAll coal mines aim to increase the unit output of the working face to reduce mining costs and improve the economic efficiency of the operation. To achieve this goal, a production model known as one mining face of the mining area has been adopted by most Chinese coal mines (Hu, Meng, and Zhu, 2008; Zhang, Zhang, and Wang, 2000). Under these conditions, the main technical approaches to maximize the output are increasing the width of the working face (Qu, Xu, and Xue, 2009) and accelerating the advancing speed (Robbins, 2000). In coalfields with shallow seams, the width of a fully mechanized face exceeds 300 m (Ju and Zhu, 2015; Fu, Song, and Xing, 2010); in coalfields with deep seams, the width of the face is usually greater than 240 m (Liu et al., 2016; Li et al., 2013). The term ‘super-long working face’ was proposed to describe working faces with a width of over 240 m (Zhao and Song, 2016; Xu et al, 2007) in China. To support these long working faces with rapid advancing speeds, high-powered mining equipment is required (Kulshreshtha and Parikh, 2001, 2002; Tu et al., 2009; Mishra, Sugla,and Singha, 2013). This is easily achieved in newly built mines, but is not a good choice for ageing mines because of the low return on a high investment on account of the limited remaining resources. It is therefore difficult for ageing mines to significantly increase their unit output with the existing mining equipment. This study focused on this problem: two shearers were applied to a longwall fully mechanized working face (LFMWF) to achieve increased unit output."

Oct 1, 2018

By W. E. Bearce

The recent concern for the recovery of even the finest fractions of coal preparation plant feeds has created needs for new equipment. Thermal dryers currently available have difficulty reducing the filter cake moisture on down to the desired point. This difficulty involves 1) the physical problem of handling this wet, sticky material and making each particle accessible to the hot gases, and 2) removing the extremely fine dried particles from the cooled gases. The dryer described in this paper handles the first of these problems, and eliminates the second by the substitution of steel balls for air as the heat transfer medium. As a general statement, the cost of preparing coal for market is inversely proportional to the size of the lumps or particles. In the not too distant past the finer sizes were discarded as being uneconomical to treat and this practice might be still continuing if it were not for the insistence of the public that this material be kept out of our streams. This being the only cost-free outlet, the disposal of fine refuse became a significant item of expense in every preparation plant. When this happened it was only reasonable to look to the recovery of the values in this material, not only to defray this expense, but to reduce the tonnage which had to be wasted. There seemed to be no device available suited to reducing the moisture in this material to what the market requires. All of the fine coal dryers commonly employed make use of air to bring the heat of combustion into contact with the coal particles. Any device employing air as a heat transfer medium, has the following two strikes against it in attempting to handle 28 mesh by 0 filter cake: 1) It is practically impossible to bring the hot air into intimate contact with the enormous number of fine particles stuck together in the cake. 2) Even if this can be effected, it is impossible to remove the dried coal from the air. A wet scrubber must be employed, the discharge of which must go back to the filter and dryer as a circulating load of the most objectionable sort, being the extreme fines. Various compromises have been used to cope with the problem of drying this relatively small tonnage of high moisture coal. Often some of the dried coal is mixed back with the feed to the dryer in an attempt to make the mixture more handleable and more available to contact with the hot air than the filter cake alone would be. This may help to some extent with the first problem but it does nothing about the second and a dryer operated in this way has to be oversized. Sometimes the filter cake is mixed with a coarser fraction for the same reason. Here again, while this may make a mixture (the particles of which are more readily brought into contact with the hot air), the problem of getting the fine coal out of the air remains and a larger percentage of the total coal to be dried is handled by the most expensive means. Mechanical dewatering has accounted for more and more of total coal drying lately and in many cases would satisfactorily handle the whole load, down to 28 mesh, if there were a means available for doing a good job on the —28 mesh by itself. The dryer which is the subject of this paper was designed expressly for doing this job — drying fine material by itself regardless of how wet it may be to start with, how fine it may be, or how gummy and sticky these properties in combination may make it. The essential features are depicted in Fig. 1. A rotating cylinder is supported on a frame in such a way that one end may be raised or lowered by hy-

Jan 1, 1968

By J. D. Bateman

At Giant Yellowknife, where high grade gold-bearing orebodies are highly irregular in shape, geology has been applied extensively to the mining of ore. The classical functions of the mine geologist in the fields of exploration and mine development have been extended to guide ore extraction, ensuring "clean" mining and effectively reducing waste dilution. THE property of Giant Yellowknife Gold M.ines Ltd. is situated west of Yellowknife Bay on the north shore of Great Slave Lake, a distance of 600 air miles north of Edmonton, Alberta. The Giant claims were staked in 1935, the company was formed in 1937, and the main orebody system was disclosed by diamond drilling in 1944 following a geological study of the property by A. S. Dadson,* Consulting Geologist for the company. Production began in 1948 at the rate of 200 tons per day and, during 1950, reached a daily rate of 425 tons. During the first 3 years of operation a total of 366,000 tons was milled with an average grade of 0.79 oz of gold per ton. Work is in progress with an expansion to 700 tons per day in view. A descriptive account of the geology and gold-bearing shear zone has appeared previously.* The rock formations in the vicinity of Yellowknife Bay have been subjected to protracted pre-Cambrian tectonic deformation culminating in a series of late faults having a cumulative horizontal displacement exceeding 11 miles. The Giant property is underlain by part of an Archean sequence, several miles thick, consisting of basic volcanic flows and minor intercalated tuffs. The volcanic succession forms the west limb of a major syncline, the flows facing east, but overturned on Giant property to dip west at 65" to 75". Orebodies are confined to shear zones up to 200 ft in width, which were formed along early thrust faults. The shear zones assume fold-like attitudes, the larger of which have an amplitude of several hundred feet. The rock formations beyond the limits of the zone of shearing do not reflect the simulated folds, the axes of which are within a few degrees of the strike of the flows. The schistosity and most of the planar elements in both the shear zones and the orebodies dip west • A. S. Dadson and J. D. Bateman: Structural Geology of Camdian Ore Deposits, Can. Inst. Min. Met. Jubilee Volume (1948), PP 273-283. at angles between 65" and 75", generally corresponding to the dip of the flows. The planar elements within the shear zone system thus dip more or less constantly west whether the shear zone is flat, vertical, or expressed as east or west dipping limbs. The shear zones reflect the deformation and alteration of the basic volcanic flows into chlorite schists which, in most places, have undergone metasomatic replacement to form chlorite-sericite-carbonate schists or sericite schists. The boundaries between the shear zones and country rock, although often gradational, usually can be defined within a few feet or even inches as they are expressed by the limits of metasomatic alteration. Orebodies may occupy a small or large proportion of the shear zone and, although they generally conform to the shape of the zone, their morphology is much more complex. Ore boundaries in some instances are sharp and can be delineated with a chalk line; but more generally, a large proportion of the ore boundaries is not visually obvious and can be determined only by the perception acquired by the geological mapping of ore or study of drill cores. Ore shoots in fold-like attitudes may transect the planar elements of the shear zone at any angle; yet the schistosity within the ore shoot may be coincident with that in the enclosing shear zone. Thus it is clear that problems may arise in the delineation of mining boundaries. Ore generally consists of 20 pct or more quartz with ferruginous carbonates in sericite schist deposited in two dominant stages. The earlier stage limits of quartz with carbonate, pyrite, and very fine-grained arsenopyrite in lenses and bands. The later stage consists of quartz-carbonate lodes, in

Jan 1, 1952

GENERAL GEOLOGICAL DESCRIPTION The uranium mineral appraisal herein described was made for an ore deposit in New Mexico. The uranium mineralization occurs as roughly tabular to lens-shaped deposits of varying thickness within the sandstone of the Jackpile formation of Jurassic age. The mineralization occurs at several horizons within the Jackpile formation, but is not always confined to specific beds. It often transgresses across stratigraphic layers, as demonstrated when attempting correlation of uranium gamma anomalies between adjacent drill holes. Preferred mineral trends have been established in some parts of the deposit, but are not always predictable when attempting to extrapolate beyond the zones defined by drill hole sampling. MANAGEMENT OF DRILL HOLE SAMPLE DATA All of the drill hole sample data used in the appraisal were obtained from interpretation of gamma-ray logs. A brief description of gamma-ray log sampling is given in Chapter 2. Two preliminary steps are involved in preparing gamma-ray logs into sample data normally acceptable for computer manipulation. 1) The gamma analog trace produced by the downhole probe must be digitized, i.e., counts-per-second (CPS) are recorded for each 0.15 m (1/2-ft) interval across the gamma-ray anomaly. The work is usually done on a "digitizer" while following the analog trace with an electronic stylus on a special tablet or table. The other alternative is to do the work manually. Some of the newest downhole logging equipment produces a magnetic tape output which can be read by a computer. 2) The gamma-ray CPS values must then be converted to equivalent U308 assay values, taking into consideration all appropriate correction factors. The US Atomic Energy Commission, now part of the Department of Energy, developed the theory and algorithm for this conversion in the 1960's, and though the work can be done manually, it is best done with the GAMRED (gamma-reduction) computer program. Fig. 14-1 illustrates a typical analog trace produced by the probe instrumentation, including gamma-ray trace (left), self-potential electric log (center), and resistivity log (right). Fig. 14-2 shows a form of the computer output after the analog data has been digitized to 0.15-m (1h-ft) intervals and converted to percentage U308 values for the same hole. The U308 grade bar graph on the right permits rapid visual inspection of anomalous values by depth and elevation. The converted U308 sample data were next processed by the SURVEY program that assigned to each assay interval [0. 15-m (1h-ft)] an X Y Z coordinate, taking into account all deviations indicated from downhole survey information. The output file of the SURVEY program was listed on the line printer for examination by project geologists, and also became the main input file for the URAN/ COMP compositing program, which is designed to group individual 0.15-m (/-ft) U308 sample values into larger intervals representing discrete anomalous zones according to a series of specified parameters entered into the program by the user. Composite U308 intervals were computed by the URAN/COMP computer program, the logic of which may be briefly described as follows: Step 1 The program searches for the highest U308 value in the hole and builds a composite by adding the highest grade interval on either side so long as the added value is greater than a minimum acceptable grade, and the total composite, after addition, meets minimum GT (grade times thickness) constraints. Step 2 The program loops back to find the next highest assay value in the hole not already included into a composite, until all anomalies above minimum cutoff grade are composited. Step 3 Individual composites are combined if they are closer than a specified minimum waste thickness, and the resultant composite grade still meets GT minimums.

Jan 1, 1980

By S. C. Lindsay, D. J. I. Evans

With each year that passes hydrometallurgical processes are being more widely used to recover base metals from ores and concentrates. Generally these processes involve liquid-solid separation of metal-bearing liquors from barren residues. This may be done by countercurrent decantation, thickening and filtration, or filtration or centrifuging only. Choice of method is governed by chemical and physical characteristics of the pulps; cost of labor, power, materials, and waste disposal; and even by the amount of capital available when building plans are under way. Since all these controlling factors change with time and location and with technological advances, the separation method must be re-evaluated when new plants or expansion programs are contemplated. At the Sherritt Gordon refinery in Fort Saskatchewan, Alberta, an ammonia pressure leaching process recovers nickel, copper, and cobalt from the nickel concentrate produced at Lynn Lake, Manitoba.' Pregnant liquors are separated from the barren leach residues in a thickener-filter liquid-solids circuit. The decision to use this type of separation was based on a summation of economic factors during the pilot plant and design stages. Although countercurrent decantation was not incorporated in the refinery flowsheet, the problems solved in thickening the leach residues and the experience gained in operating the commercial plant are pertinent to countercurrent decantation, particularly where it is applied to slow-settling leach slurries or slurries having a relatively high vapor pressure of a valuable, obnoxious, or poisonous vapor. The nickel sulfide concentrate is leached under pressure with air and ammonia to dissolve the nickel, copper, and cobalt and most of the sulfur, leaving a residue of iron and siliceous material to be discarded.2,3 During a subsequent distillation stage to recirculate part of the ammonia used for leaching, copper is recovered from the solution as a high-grade sulfide. After further purification to remove traces of copper and undesirable sulfur compounds, the nickel is precipitated by hydrogen under pressure at an elevated temperature. The cobalt, together with unreduced nickel, is precipitated as a mixed metal sulfide by hydrogen sulfide for eventual cobalt recovery. The end solution is then evaporated to produce a crystalline ammonium sulfate byproduct. As shown in Fig. 1, the nickel concentrate is leached in a continuous, two-stage, countercurrent circuit. In the first stage, or adjustment leach, the fresh concentrate is partially leached (60 pct) in the liquor produced in the second stage, or final leach. This system is necessary to produce a solution suitable for treatment in the copper sulfide precipitation step. Both stages are carried out at 170" to 180°F under a total pressure, with air, of 100 to 120 psig in large, horizontal, water-cooled autoclaves. The autoclaves are divided by overflow weirs into four compartments to give a certain amount of staging during leaching. In each compartment a relatively slow-speed (100 to 150 rpm) agitator maintains the nickel concentrate in suspension. Adjustment leaching, carried out in two autoclaves in parallel, is followed by a thickener-filter liquid-solids separation. Final leaching is done in two parallel trains of three autoclaves using aqueous ammonia to extract metal values from the adjustment leach residues. This too is followed by a thickener-filter circuit. Here the residues are repulped once with aqueous ammonia and twice with process water and refiltered after each repulping stage, to insure a maximum recovery of soluble metal, before being discarded to the tailings pond. The adjustment leach is followed by a seven-disk Dorr-Oliver American filter, with an agitator in the filter boot to keep the residues in suspension. Agitators have also been installed beneath the four ten-disk filters following the final leach thickener. Slurry Characteristics: A typical analysis of the Lynn Lake nickel concentrate, produced by differential flotation,' is given in Table I. The concentrate comprises 35 to 49 pct pentlandite, (Fe, Ni)S; 3 to 6 pct chalcopyrite, CuFeS,; 1 to 4 pct pyrite, FeS2; and 24 to 42 pct pyrrhotite, Fe1-2S (where x varies between 0 and 0.2) together with various siliceous minerals such as actinolite, hornblende, and talc. During leaching, the sulfur in the pentlandite, chalcopyrite, and part of the pyrrhotite is successively oxidized through the thiosulfate and poly-thionate radicals to sulfate and sulfamate." Simultaneously the nickel, copper, and cobalt are converted to soluble ammine complexes and the iron in the pentlandite, chalcopyrite, and part of the pyrrhotite is oxidized to a spongy hydrated iron oxide. The hydrated iron oxide is readily broken down by the agitation needed to sustain the concentrate in suspension and to maintain a satisfactory mass transfer of the oxygen from the air to the slurry. Table I shows typical chemical, screen, and

Jan 1, 1961

By S. Gallagher

If we consider ergonomics to be an exercise in matching job demands to worker capabilities, one of the principal capabilities we must be concerned with is that of human strength. Our ability to evaluate different characteristics of muscular strength has increased dramatically over the past couple of decades with the development of new and increasingly sophisticated instrumentation. One would think that armed with such advanced techniques, we might be able to develop methods to conclusively identify workers at risk of injury in physically demanding jobs. Unfortunately, this has not yet proven to be the case. Instead, what these instruments have continued to point out is how intricate a function muscular strength really is, and how complicated and ambiguous its relationship is to musculoskeletal injury. While we cannot just use isolated tests of strength to specify precisely who may be at risk of injury, studies have indicated that strength testing can be a useful tool for job design and, under certain circumstances, selection of workers for demanding jobs. However, because strength is such a complex phenomenon, there has often been some confusion regarding the proper application and interpretation of strength tests in ergonomics, especially among persons not thoroughly familiar with the limitations and caveats associated with the available procedures. The purpose of this chapter is to discuss some of the fundamental principles of strength assessment in ergonomics, so that these procedures can be better applied to control the risk of musculoskeletal disorders in the workplace 1.1. What is Strength? (And what are we Measuring?) Many of the complications associated with strength assessment arise from the simple fact that even our most sophisticated machinery does not directly measure the force or tension developed by a muscle in a living person. Instead, we can only observe the consequences of force development by a contracting muscle, or more likely, by a combination of muscles There are many ways in which we can measure the effects of muscular contraction, and the techniques we use can have a dramatic impact on the strength readings we will obtain. Consider the situation illustrated in Figure 1. In this example, the muscle exerts a constant force of 1000 Newtons (N). However, the forces we measure can vary quite dramatically depending on where we place the force cuff - from 167 N if we place it near the wrist to 500 N if we place it near the elbow. Which value should we select as properly representing the muscular strength for this elbow flexion exertion? The preceding example illustrates some important points with regard to strength assessment. Perhaps the most important is that "muscular strength is what is measured by an instrument" (Kroemer et al. 1999). It should also be clear from this example [ ] that two researchers could perform an elbow flexion strength experiqent on the same group of subjects, but if each selected different force cuff positions, they might end up with wildly differing estimates of strength. Differences in the strengths of various muscle groups in the published literature may be the results of differences in the procedures and measurement methods used by the experimenters Thus, it is critical that any strength data presented be accompanied by a detailed account of the manner in which the data were obtained. A few additional points need to be made with regard to the testing of human strength. We must be clear that what we are obtaining in such tests are not a person's maximal strength capability, but their maximal voluntary strength. The voluntary nature of the exertion introduces an unknown, but surely substantial, amount of variability in our measurements of strength. One can imagine two subjects with identical muscular strength capabilities, but with varying levels of motivation or discomfort tolerance, for example. We are likely to observe considerable differences in the voluntary force exerted by the two, but it should be understood that such results may be largely the result of psychological factors, and not differences m muscular strength per se. The important point to be made here is that not only are we unable to directly measure muscular force, what we are able to measure is modified by an invisible filter - a filter subject to a wide variety of influences and which will differ considerably for every person we test To make matters worse, this filter would be expected to change even within a given individual on a given day. From the foregoing discussion, one can perhaps better appreciate some of the difficulties with establishing a definitive relationship between an individual's measured strength and that individual's risk of injury.

By Charles O. Thomson

When a wire rod of iron or of steel is immersed in a hot solution of common salt, allowed to remain long enough to bring the metal to the temperature of the brine, and withdrawn, the surface of the rod is irregularly covered with a deposit of crystals of salt. These crystals adhere to the cod with great firmnes, in consequence, doubtless, of a thin film of ferric hydrate, which is formed between them and the rod as the water dries off. The rod can now be reduced, by successive passes through a dic or draw-plate, without any

Jan 1, 1881

By A. Demers, M. Chapman, N. Reynier, R. Lastra, M. Courchesne, C. Laviolette

Historic medical isotope production at Canadian Nuclear Laboratories (CNL) in Chalk River involved the dissolution of irradiated isotope targets prior to extraction of Mo-99. This process generated liquid waste that was cemented in 5-gallon containers and transferred to an outdoor waste-management facility for intermediate storage. Research was undertaken to develop an innovative method for uranium, mercury and cesium recovery from the radioactive cemented waste (RCW). Regulations prohibit the removal of active radioactive waste from the Chalk River facility. Thus, CanmetMINING produced surrogate material following the same procedures and conditions to those used at CNL. The selective recovery of the uranium from the surrogate radioactive cemented waste (SRCW) could offer CNL more disposition options for the resulting wastes. Leaching tests were performed using four different SRCW at 1 kg scale. Different conditions, operating parameters, and the presence of plastic and corrosion products were evaluated on solubilization. The research investigated the use of potassium iodide with the sulphuric acid leach to increase metals recovery. Iodine improves the solubilisation of metals and the U dissolution reached 99%. The increase of leaching time reduces the U solubilization due to silica gel formation. Therefore, it will be important to control leaching time to avoid the loss of U during the pilot scale experiments. For Hg, the solubilization ranged from 60 to 80% due to the presence of metallic mercury and mercury sulphide found in SRCW cured at 60°C and/or aged for 30 months. Ion exchange (IX) was found the best method to separate the uranium from the impurities and produce a purified and concentrated uranium solution suitable for yielding a uranium product (yellow cake).

Jan 1, 2020

By E. J. Peterson

Oil shale retorting induces mineral and chemical reactions to occur on the macroscopic and microscopic levels in the kerogen-bearing marlstone. The nature and extent of the reactions is dependent upon process variables such as maximum temperature, time at temperature, atmosphere, and raw shale composition. This report describes the investigation of the mineral, chemical, and trace element release properties of spent shales retrieved from an experimental in situ retort at Occidental Oil Shale, Inc. 's Logan Wash site in Garfield County, Colorado. Correlation between mineralogy of the spent materials and the mobility of major, minor, and trace elements are indicated, and relationships with important process parameters are discussed. The progress .of carbonate decomposition reactions and silicat ion reactions is indicative of the processing conditions experienced by the shale materials and influences the mobility of major, minor, and trace elements when the solids are contacted by water. Shale minerals that are exposed to the extreme conditions reached in underground retorting form high temperature product phases including akermanite-gehlenite and diopside-augite solid solutions, kalsilite, monticellite, and forsterite. The persistence of relatively thermally stable phases, such as quartz, orthoclase, and albite provide insight into the extremes of processing conditions experienced by the spent shales. Leachate compositions suggest that several trace elements, including vanadium, boron, fluoride, and arsenic are not rendered immobile by the formation of the high-temperature silicate produce phase akermanite-gehlenite.

Jan 1, 1981

By T. D. Yensen

IN the investigation of the magnetic properties of iron-nickel alloys,1 it was found necessary in order to make the alloys forgeable, or malleable, to add small quantities of some other element. Iron-nickel alloys have been known for nearly a century, but have been made in commercial quantities only since 1885. Their remarkable mechanical properties were disclosed by Riley in 1889 and from that time on a large amount of research work has been done both to discover new properties and to correlate the results obtained.2 Lately the Bureau of Standards has collected the published data in a special circular3 giving in compact form an account of the properties of the iron-nickel alloys. It also contains a clear historical sketch of the development as well as a selected bibliography. The chief difficulty with the development of iron-nickel alloys was that the "pure" alloys do not forge readily. The addition of small amounts of manganese, however, made the alloys forgeable, and manganese has therefore come to be regarded as a necessary constituent of nickel steels. The present paper shows to what extent manganese is needed for various nickel contents and also what is the effect of other alloying elements on the forgeability. It also touches upon the cause of forgeability but refers to other sources for more exhaustive treatises, on the subject. The alloys were prepared by melting electrolytic iron and electrolytic nickel with of without other alloying elements in the desired proportions in a magnesia crucible in a vacuum furnace under a. pressure of 1 mm. mercury. The ingots weighing about 2 kg. were allowed to cool in vacuo. If pipes or blowholes were present, the ingots were cut in such

Jan 1, 1920

By D. F. Williams

The modelling, simulation, and design of processes for the recovery of gold from solution by absorption on carbon require the combination of a suitable rate expression with a description of the flow conflguration of the system. By the use of a suitable rate expression from the literature, methods are presented for the design of multi-stage countercurrent absorption systems corresponding to the commonly used carbon-in-pulp and carbon-in-column contacting systems. The sensitivity of the recovery to various design parameters is illustrated. These results have important implications in the choice and design of equipment.

Jan 1, 1985

By C. Romero, R. Mendoza

The SX-EW plant consists of three parallel trains with two extraction and two stripping stages, with the mixing chambers situated on the same side of the settlers, using a coalescing launder to direct the solution flow to the outlet weirs in the side as the mixers. In the tankfarm the loaded organic tanks will include a coalescing packed column to separate the aqueous entrainment. Organic from gunk will be recovered in a packed column, instead of a centrifuge. The EW plant utilize polymer concrete cells with permanent stainless steel cathodes with edge strips on side and bottom, without wax.

Jan 1, 1996

By Michael A. Arkoosh, E. A. Peretti

ANALYTICAL results have previously been presented for the diffusion-controlled solution of a second phase in a finite medium for planar, cylindrical, and spherical geometries.' These results were obtained by numerical methods using digital computer techniques and are applicable not only to the stage of the problem where the unstable phase shrinks to zero size, but also the subsequent stage where the concentration gradients in the matrix phase become negligible (essentially complete homogenization). It is anticipated that the results of such an analysis may be of use to those workers who are interested in the processes

Jan 1, 1970

By J. C. McLaughlin, Bill A. Hancock, David J. Meacham

Great Salt Lake Minerals (GSLM) uses flotation to utilize low grade harvest evaporites in the leaching/ crystallization process. A final potash product coloration problems was encountered that was attributed to AERO• 801s promoter - magnesium ion precipitation in flotation which carried into the dissolution/crystallization circuit. Bench studies resulted in changing 801s to 845 which provided acceptable product brightnesses and higher flotation potassium recoveries. This is a case history reviewing the unique GSLM processing scheme, the bench and plant work identifying the potash quality problem, the bench work and solution, and subsequent process study and circuit optimization efforts.

Jan 1, 1993

By B. R. Eichbaum, J. E. Murphy, J. A. Eisele

The US Bureau of Mines demonstrated ferric chloride leaching of galena concentrate on a continuous bench scale basis. Leaching was performed at 95°C (200°F) and with a contact time of 15 minutes. The ferric chloride leaching solution was continuously fed to a leaching tank at a constant rate for periods up to 45 hours. In each test, a constant redox potential was maintained in the slurry exiting the leaching tank by controlling the concentrate feed rate. In the 45 hour test, lead extraction exceeded 99.5%, and the lead chloride produced was 99.97% pure.

Jan 1, 1986

By A. H. Larson, R. J. McClincy

The activity of Sb,03 in PbO-Sb,03 slags containing less than 50 mol pct Sb,03 was determined by the inert-gas saturation method at 700°C. In this composition range, the activity gf SbzO3 shows a strong negative deviation from ideality. The activity of PbO in these slags was calculated by application of the Gibbs-Duhem iniegration to the Sb203 activity data. The calculated activity of PbO in slags containing more than 63 mol pct PbO was found to deviate in a positive direction from ideality uthile a negative deviation was found for slags containing less PbO. The standard Gibbs free energies of formation of Sb,03 and PbO. Sb203 have been calculated and compared with existing data in the literature. The activity of Sb203 in PbO-Si0,-Sb203 (PbO/SiO, = 2) slags containing less than 25 mol pct Sb,03 was also determined by the inert-gas saturation method at 700°C. In this composition range, the activity of Sbz03 shows a very large negative deviation from ideality. VERY little experimental work has been published in the past to determine equilibrium data in the oxide systems connected with the refining of lead. These data are of value since impurities such as antimony, arsenic, and tin must be removed from lead and recovered for further treatment. Equilibrium studies on antimony and arsenic systems are also of interest for the design of new processes for lead refining and lead dross treatment. Maier and ~incke' first determined the liquidus curves for the PbO-Sb203 system and identified the compound PbO . Sb203. They found the phase diagram for this system to be two simple eutectics located on either side of the congruent melting compound. They also determined a very limited amount of vapor pressure data for Sb406 abbve PbO-Sba3 melts at 697"~. A second phase diagram investigation on this system was reported by Hennig and Kohlmeyer' who confirmed the existence of the compound PbO . Sb203 as well as the form of the diagram. A disagreement was noticed, however, in that their liquidus temperatures over nearly the entire composition range were higher than those reported by Maier and Hincke. Barthel~ and pelze14 redetermined the liquidus curve at the PbO-rich end of the PbO-Sb@, system and agreed very closely with the results of Maier and Hincke. None of the investigators mentioned above reported any mutual solid solubility in the PbO-SbD3 system. Zunkel and Larson5 have determined the phase diagram for the PbO-rich end of the PbO-Sb203 system by slag-metal equilibrium studies in the Pb-PbO-Sb203 system and by thermal analysis studies in the PbO-Sbz03 system. A maximum solid solubility of 5.6 mol pct Sb203 in PbO was observed at the eutectic temperature of 604°C. Their results for the phase diagram agree favorably with those of Maier and Hincke. The vapor pressure of Sb2O3 in the temperature range from 470" to 800°C has been determined by Hincke, using a modification of the transportation meth~d.~ His results for temperatures below the melting point of Sba3 are the only data reported in the published literature. The predominant vapor species has been shown to be Sb,06 by Norman and staley.? Myzenkov and Klushin,8 using the boiling-point method, have determined the pressure of Sb406 above liquid SbD3 in the temperature range from 715" to 1025°C. The agreement between these two studies is not very close. A portion of the discrepancy lies in the fact that Hincke used silica crucibles, which were attacked by the liquid Sbz03 at high temperatures. This fact does not account, however. for the large difference observed at the melting point. ~aier' gives a brief summary of vapor pressure data for Sb,O, above pure liquid Sbz03 which agree quite well with the data of Myzenkov and Klushin at temperatures near the melting point. This paper describes the determination of Sb2O3 activity data in the PbO-Sb203 and Pb0-Si02-Sb203 (PbO/SiOz = 2) systems by the inert-gas saturation method. These activity data are compared with the data calculated by Zunkel and arson. EXPERIMENTAL Materials. The materials used in this investigation were analytical reagent-grade PbO (99.8 pct PbO, 0.14 pct insoluble in CHsCOOH, 0.02 pct not precipitated by HB, 0.1 pct CaO, and 0.08 pct SiOz), Sbf13 (99.6 pct Sb203, 0.004 PC~ C1-, 0.005 PC~ SO;-, 0.15 p~t AS, 0.001 pct Fe, and 0.03 pct other heavy metals such as Pb), and SiOz (chromatographic grade). Apparatus for Vapor Pressure Determinations. The apparatus used in this investigation consisted of a transportation reaction system with two separate gas trains. The argon transporting gas was first mixed with a small amount of hydrogen, metered, and dried by passage through silica gel and anhydrone drying tubes arranged in series. After this preliminary drying, the argon was passed through copper wool at 500°C to convert the residual oxygen to water vapor which was removed by three anhydrone drying tubes. A second stream of argon was metered and dried and then passed around the outside of the alumina reaction tube to flush away the volatile species to pre-

Jan 1, 1970

By Linge H. G

The effect of the presence of ore pulp on the adsorption rate of gold on activated carbon has been studied. A substantial reduction in the rate occurs when the pulp is present. The reduction in rate appears to be caused by two effects: permanent carbon pore blocking by ore particles and temporary shielding of the carbon particle surface, slowing gold access to the carbon due to the physical presence of the fine pulp. There is no significant effect arising from the presence of a pulp viscosity modifier even for conditions when mass transport dictates the loading rate of carbon in clear Solution.

Jan 1, 1987

By H. M. Garrett

The basic cement making process is outlined relative to the fuel but chemically sensitive suspension preheater (SP) kiln which made its debut in the early 50s. The SP history is trailed through the process disasters of the late 50s; identification of chemical sensitivities in the 60s; and resurgence of the SP together with development of its stepchild process, the precalciner (PC) kiln, in the 70s. The current energy problem and related conversions to coal re-emphasize the process chemical sensitivity. Attention is focused on the basic problem of coal sulfur and ash variations and several solutions are presented.

Jan 1, 1981

By D. A. Sangrey, D. Marcus, S. A. Miller

A methodology was developed wherein the increase in compressive strength, mineralogical changes, and pore water composition were studied simultaneously as a function of moisturized spent shale curing time. From these results the relationship between the nature of cementation process and the composition of pore water was established. Heavy metals were entrapped in the cementing constituents and the pore water became mainly a solution of alkaline sulfates. The specific data are applicable only to the material studied. But the methodology and general conclusions are useful for evaluating the environmental factors in spent shale disposal and expected leachates composition.

Jan 1, 1986