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By W. A. Rickelton, A. J. Robertson

The ability of triisobutylphosphine sulfides to selectively recover silver from acidic sulfate solutions containing zinc and copper is described. Selectivity is explained in terms of the concept of hard and son Lewis acids and bases. Silver is stripped from the solvent using a novel strip feed (thiosulfate salt), and the recovery of metallic silver from the strip liquor by electrolysis or cementation is suggested. The high selectivity of extraction for silver and the utility of the stripping reagent are demonstrated in continuous, countercurrent, mini-plant tests. Important reagent properties, such as hydrolytic stability and low aqueous solubility, are discussed.

Jan 1, 1988

By K Inoue

The pressure oxidation of molybdenite concentrates in acidic and alkaline media has been studied. The conditions of the selective oxidation of copper and iron sulphide minerals with a quantitative copper leaching by ferrous-ferric-sulphate solution have been found and explained from the point of view of electrochemical kinetics. The partly oxidised residue consisting of molybdenite and (hydro-) oxide of iron (III) was then decomposed by oxygen in alkaline media. Effects of the main parameters, such us oxygen pressure, leaching temperature, solid-liquid phase ratio, autoclave stirring speed as well as lixiviants nature on the molybdenite oxidation rate have been established.

Jan 1, 2000

By V. I. Lakshmanan, P. D. Tackaberry

The use of activated carbon as an alternative to Merrill Crowe precipitation to recover gold from pregnant leach solutions is recognized. Recovery using activated carbon, however, suffers from the interference, due to organic fouling, clay content and increasingly from the presence of elements such as copper. Ion exchange separation technology is familiar to the mining industry (uranium) and its potential application to the gold mining industry is evaluated with considerable efforts by research workers in South Africa, Australia, and North America. The present paper reviews in detail the status of the research work that identifies potential opportunities.

Jan 1, 1990

By Olice C. Carter, B. J. Scheiner

The Bureau of Mines investigated the removal of two toxic/heavy metals (cadmium (Cd) and lead (Pb)) from brass foundry wastewater. Polymers, copolymers, guars, and gums were used in conjunction with calcium hydroxide (Ca(OH)2) and magnesium oxide (MgO) to remove the metals from solution. Several polymers were successful in removing Cd and Pb from the wastewater. The concentrations of Cd and Pb were lowered from 19 to 0.01 ppm and from 20 to less than 0.01 ppm, respectively. The methods investigated could easily be adapted to many existing wastewater treatment facilities and/or be used independently.

Jan 1, 1991

By M. Arenas

A corrosion study of a bonded NdFeB permanent magnet materials alloyed with titanium carbide additions has been undertaken. The materials were produced by rapid solidification by melt spinning. Commercial epoxy was used as a bonding medium. The corrosion results were compared with those of a near stoichometric unalloyed NdFeB. Anodic polarization and potentiostatic techniques in 0.9 M Na2SO4 solutions were used to characterize corrosion behavior. It was found that the addition of 6 a10 Tic resulted in superior corrosion resistance, as indicated by lower corrosion currents and less iron dissolution at fixed potential.

Jan 1, 1997

By Roshan B. Bhappu, George M. Potter

The chemistry involved in the recovery of gold and silver from natural resources through hydrometallurgical and pyrometallurgical processes is reviewed. Process metallurgy for the cyanidation, activated carbon adsorption, carbon stripping, and electrowinning of gold and silver is discussed. The application of zinc sodium sulfide use for silver recovery from cyanide solutions is covered. Electrooxidation, other oxidation methods and roasting processes for problem ores and concentrates containing organic carbon and impurities such as arsenic, antimony, and tellurides are summarized. The smelting of cathodes, precipitates, and other products, and the various wet and furnace steps in separating dore metal are also reviewed.

Jan 1, 1981

By J. H. Jacobs

The first authorization, in November 1940, was for a plant of only several hundred pounds capacity at Boulder City, Nev. Improvements in the process and subsequent additions to some sections have enabled the plant to produce more than 2,000 pounds of manganese per day for substantial periods. By the time pilot-plant operations were suspended in June 1945, over 1,500,000 pounds of metal had been produced. The future of electrolytic manganese production obviously depends not only on satisfactory development of methods but on availability of raw material and demonstration of valuable uses. Investigations of manganese-ore deposits in this country, made since 1938 by the Bureau of Mines, have revealed large amounts of ore suitable for making electrolytic manganese. At first the pilot plant was operated on ore from the Three Kids mine near Las Vegas, Nev. After practical features of the process had been worked out, other ores from throughout the United States were tested in the pilot plant. The purpose of this paper is to compare the results obtained on the following ores: Three Kids; Ladd mine, Tracy, Calif.; Chamberlain, S. Dak., nodules; and ore from Metals Reserve stockpiles at Deming, N. Mex.; Cushman, Ark.; and Philipsburg, Mont.

Dec 1, 1947

By Secis R

Northparkes Mines is located 27 km northwest of Parkes in central west New South Wales. The E26 deposit is the largest of all defined to-date in the area, containing over 50 per cent of Northparkes' resources and reserves. The combination of orebody geometry and geotechnical characteristics provide ideal conditions for the block cave method of mining of the first lift of the E26 deposit. Although this method of underground mining has been used for decades in other countries, E26 is the first example of its use in Australia. Copper-gold mineralisation at Northparkes is related to quartz monzonite porphyries that have intruded coeval Ordovician volcanics. Sulphide mineralisation (dominantly bornite and chalcopyrite) occurs principally within quartz veins associated with the porphyry intrusions. Veining and mineralisation occurs within both the porphyries and volcanics. To optimise the recovery of a resource within a block cave mine, a good understanding of the rock mass and ore flow characteristics is essential. These have a significant effect on the fragmentation size and range and on parameters such as the drawzone spacing, height of interaction zone and dilution entry. As ore within a cave column moves and mixes when material is extracted from below and beside it, the total reserve extracted is unique for a particular draw strategy/production history. Until recently, reserve estimates and production schedules were based on the application of a uniform dilution factor to the tabulated resource. However, given the complicated flow and mixing within the cave column, such a simplistic approach can produce erroneous results. Northparkes Mines purchased and sponsored the upgrading of a commercially available software package specifically developed for modelling removal of resource blocks under caving conditions. This Gemcom software package, PC-BC, has been used for mine planning, reserve reporting and production scheduling. Blocks within it resource block model are converted into a mineable reserve taking into account mixing and dilution during depletion of drawcolumns (by horizontal and vertical redistribution of insitu tonnage and metal). As PC-BC gives individual drawpoint reserves, it can be used during the planning stage to determine whether or not a drawpoint is economic. For E26 Lift I an optimal layout containing 130 drawpoints has been developed based on a nominal 14 m x 14 m drawpoint spacing and a 0.8 per cent equivalent copper (eCu) cut-off grade. Annual production schedules for the depletion of material above this layout are based on: I higher tonnage removal from higher grade drawpoints in the early years of production; and 2 drawpoint production rates proportional to the total tonnage of orr remaining in the drawcolumn up to the optimal height of draw tier subsequent years. The reserve is tabulated from the combined annual production schedules over the life of the lift. The pre-mining reserve for Lift I of E26 is 26.6 Mt at 1.43 per cent copper and 0.39 g/t gold, of which approximately 23.4 Mt will be extracted under caving conditions. By scaling down the annual production schedule, weekly drawpoint tonnage calls can be given for short-tern production scheduling.

Jan 1, 1997

By R. Barany

This paper reports determinations of heats of formation (from the oxides and elements) of crystalline cadmium metasilicate and crystalline lead meta-silicate by hydrofluoric acid solution calorimetry. The results, in conjunction with known entropy values, yield free energies of formation. There are no earlier data of this type for cadmium metasilicate. The results of this investigation for lead metasilicate deviate from the literature values (which are less reliable) in the direction of increased thermodynamic stability. Both cadmium and lead metasilicate are much less thermodynamically stable with respect to their constituent oxides than are the corresponding compounds of the alkaline earth metals.

Jan 1, 1959

By Daniel R. Stewart, Ralph R. Sacrison

The function of the geological engineer is to assist in mine planning and operations by collecting, interpreting, and applying geologic data to the solution of engineering problems. The geologist supports this effort by collecting additional geologic information specifically useful to the engineer. This use of geologic information reinforces the value of mine geology to the mining process beyond the traditional role of orebody definition. Work discussed includes: evaluation of caving strategies at the Climax and Henderson mines, support definition and slope stability at the Climax mine, and some uses of geology in cavability estimation for the Mount Emmons project.

Jan 1, 1992

By Daniel R. Stewart, Ralph R. Sacrison

The function of the geological engineer is to assist in mine planning and operations by collecting, interpreting, and applying geologic data to the solution of engineering problems. The geologist supports this effort by collecting additional geologic information specifically useful to the engineer. This use of geologic information reinforces the value of mine geology to the mining process beyond the traditional role of orebody definition. Work discussed includes: evaluation of caving strategies at the Climax and Henderson mines, support definition and slope stability at the Climax mine, and some uses of geology in cavability estimation for the Mount Emmons project.

Jan 1, 1984

By Hodges D. A

The manufacture of steel from raw materials which have to be mined, transported and processed must affect the environment. Steelmaking, like almost every other stage of manufacture involves the unwanted production of dust and fume; thus a major part of the steel industry's effort to minimize changes to the environment is the collection, treatment and recycling of dust and fume to avoid pollution of the atmosphere and waterways. The paper describes how this achieved in the various steelmaking processes and shows the diversity of problems-and their solutions in this context. Particular emphasis is, given to basic oxygen steelmaking.

Jan 1, 1976

By Y. Chunhua, L. Chunsheng, W. Sheng

"Countercurrent solvent extraction is the dominant industrial rare earth separation method. For the rare earth separation, with low separation factors and multiple components, designing and optimization plays an important role in reaching product quality and reducing separation plant costs. Based on the theory of countercurrent extraction, cost-efficient methods, such as third-outlet separation and hyperlinked extraction processing, have been introduced following computer simulation. The consumption and fixed investment of industrial practice are compared, by which advantages of the optimized rare earth separation process are indicated. INTRODUCTIONThe rare earths (RE) have outstanding optical, magnetic and electric properties in advanced material applications and have therefore received much international attention in recent years. Liquid-liquid extraction is the major industrial RE separation method and is widely used in the industry. Supported by the government and with collaboration from the institutions and enterprises, China has made great progress in RE separation, and has become the dominant supplier of separated RE products. Complicated by multiple elements and low separation factors, careful design of RE separation processes is vital for the quality and cost of production. The theory of separation is the key to basic of flowsheet design and industrial applications.BASIC SEPARATION PROCESS AND THEORYGeneral ProcessAcidic extractants such as P507, P204 and naphthenic acid, are the most popular extractants in modern RE separation industry. In the general separating process, the extractant is saponified with a base, then ion-exchanged with RE solutions, thereby to provide stable and high RE loading in the extractant to fulfill the requirement of production quantity and quality. The RE-loaded extractant is then countercurrently extracted and scrubbed with RE solutions and the RE element thereby is purified. After the countercurrent extraction process, the RE-loaded extractant is stripped with acid to obtain an aqueous RE product, and prepare the extractant for recycling (Xu, 1995)."

Jan 1, 2012

By G. Gu, B. Fang, R. W. Revie, M. Elboujdaini

Electrochemical behavior of an X-80 pipeline steel, including frequency-sweep electrochemical-impedance spectroscopy (EIS), time-sweep EIS at a constant frequency and open-circuit potential (OCP) monitor, was investigated using four-point bending specimens subjected to a stress-corrosion cracking (SCC) test in a near-neutral pH environment. The capacitive loop became smaller with test duration, revealing an increase in the corrosion rate. The resistance obtained in the constant-frequency EIS test showed two regions, of which the region with a remarkable decrease in resistance transformed into a region of slow decrease, whereas the capacitance increased with test time indicating that iron dissolution was fast at first, and then a corrosion product or film formed and covered the surface, leading to the pitting formation.

Jan 1, 2005

By Ellen Amoako Afful, Michael Moats, Guang Xu, Ashish Kakoria

Electrowinning and solvent extraction are crucial steps in the production of high-purity copper. However, safety concerns have been raised regarding the acid mist generated from the electrowinning process. The mist generated results in health risks to workers and damage to machinery and infrastructure. Currently, chemicals and pellets are used to control acid mist. However, the effectiveness of these controls may vary depending on the type of organic solvent used in the solvent extraction process, which can influence the generation of acid mist. This study aims to evaluate the impacts of organic solvents and surfactants on acid mist suppression. In this study, an electrolyte is contacted with organic solvents to simulate the solvent extraction. The electrolyte is dosed with 20 mg/L of surfactant at each contact. Acid mist testing is performed on the electrolyte separated from the organic phase at the end of the solvent extraction step. The mist collected is analyzed to determine the level of acid mist generated. The results of this study indicate that organic solvents and surfactants showed significant acid mist suppression, but with somewhat different suppression efficiencies. After first contact, Licorice and the organic, for instance, showed a suppression efficiency of up to 69.7% but its efficiency gradually decreased as the number of contacts increased.

Feb 1, 2025

By Jack E. Thompson

Thank you Tom and JM for that nice introduction. The remarks I am about to make rely on a large way on comments made by Barrick's Chief Counsel, Patrick Garver, to an internal meeting of Barrick's senior staff. I plagiarized so much from his notes that I thought that I should provide attribution. I did get his consent to borrow so freely. What I have done is take his general comments and used my conversations with CEO's and other participants in the industry to enhance the message with concrete examples that underscore the points I wish to make. What you are about to hear is my personal view – I am not speaking as a representative of any company. With that introduction, now would be a good time to give you the main theme of my talk: The SEC should change its rule making to a more public cooperative approach. If that were to happen the SEC would avoid some of the harm it has been doing to the companies in this sector and the very shareholders it seeks to protect.

Jan 1, 2003

By C. G. Anderson

As the global demand for copper and gold steadily increases and the need for environmentally sound processing also grows, successful hydrometallurgical treatment of enargite (Cu3AsS4) concentrates has come to the forefront. This type of concentrate contains considerable arsenic so that successful arsenic fixation, for example as scorodite, is of the essence. This paper outlines the successful application of low temperature and low pressure nitrogen species catalyzed (NSC) hydrometallurgical pressure oxidation of enargite concentrates. The successful stabilization of the arsenic as an iron arsenate compound is discussed. Also, the use of experimental design software is highlighted as a process application and optimization tool.

Jan 1, 2006

By TUIJA MONONEN, LUDGER BENIGHAUS, VIRGINIA DEL RIO, CHRISTINA BENIGHAUS, SARI KAUPPI, JUHA M. KOTILAINEN, JAVIER GÓMEZ, JARI LYYTIMÄKI

This article presents results from a comparative case study focusing on newspaper coverage of mineral exploration and mining in three European countries representing different geological and socioeconomic contexts. The results show that regional newspapers in Finland, Germany and Spain report about mining issues relatively intensively even in the absence of major accidents or other media events causing peaks of attention. The tone of the articles is generally neutral to positive toward mining activities. Common themes include mining revival, mining events and social interaction, history of mining, and damages related to mining. Past, present and future employment opportunities related directly or indirectly to the mining sector are key storylines. Contrary to some expectations, the regional-level debate was not dominated by a long-lasting confrontation between the mining industry and its adversaries spearheaded by environmental nongovernmental organizations.

By Murat Erdemoğlu, Turan Uysal, Thierno Saidou Barry, Mustafa Birinci

The rapid development of the global alumina and aluminum industry is straight coupled with the demands and the needs of these materials. Nowadays, the only well-known accessible resources to produce alumina and aluminum are bauxite ores. But bauxite ores are limited, and the remaining exploitable reserves do not have high contents in alumina. In countries where there is little or no bauxite reserves or where the recovery of existing bauxite ores to produce alumina with the Bayer process are not economic, alternative resources for alumina have been explored. The most attractive resources for replacing bauxites are aluminosilicate clay minerals and coal fly ash. The important processes developed for the recovery of alumina from these sources are acid leaching and alkaline leaching processes. The acid leaching is known as the most efficient in which thermal and mechanical activation are included for improving the performance of the process. The objective of this review is to give a comprehensive insight on the production of the alumina from thermally or mechanically activated clays and coal fly ash by hydrochloric, sulfuric, and nitric acid leaching processes.

By John D. Sullivan

The recovery of copper by leaching from relatively low grade ores containing both oxidized and sulphide minerals is rapidly gaining in commercial importance. There is an economic limit below which certain ores can not be treated by concentration methods, and material with values below this limit must be discarded, possibly to be treated later, or the copper must be extracted by wet processes. Heap leaching has been carried out by the Phelps Dodge Corporation, Copper Queen Branch, for several years, and to-day its plant is a large producing unit. The Ohio Copper Coy at Bingham, Utah; has been leaching in place since 1919. Many other leaching operations are also being; carried out in various parts of the United States and in foreign countries. The plant at Rio Tinto, Spain, may be considered the father of heap leaching.

Jan 1, 1931