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By H. K. Lin

Pyrite oxidation in chloride solutions was investigated with cyclic voltammetry, ac impedance and potential step techniques. The pyrite oxidation in quiescent electrolytes is irreversible and controlled by diffusion. Depression of the semi-circle in the complex plane plot has been explained mathematically based on the concept of the equivalent circuit. When the semi-circle is depressed, the mathematical formula indicates that the reaction resistance should be obtained from the intersection of the semi-circle with Z-axis instead of the semi- circle diameter. The peak charging current densities at 1.10 and 0.90 V vs. SHE obtained from the equivalent circuit coupled with the ac impedance measurements match the peak current densities obtained with the potential step measurements.

Jan 1, 1997

By R. O. Y. Breese

The term "diatomite" implies the nearly pure sedimentary accumulation of diatoms. Sedimentary and chemical purity, low density, inertness, intricate fine structure, high brightness and other properties give the diatom and diatomite unique industrial usefulness and commercial value in high value functional filler and specialty filter aid products. Although diatomite deposits occur commonly throughout the world in Miocene and younger marine and lacustrine sediments, deposits that contain significant reserves of crude suitable for these quality sensitive markets are uncommon. U.S. production is centered on exceptional deposits located in Arizona, Nevada, Oregon, Washington and California. Evaluation of deposits requires understanding of geology, mining, production and end use. As crude quality in deposits varies within and between strata, ore suitable for quality sensitive end uses must be identified through sampling and evaluation programs tailored to permit recognition of critical variations.

Jan 1, 1989

By G. L. Merritt

The implementation of the Surface Mining Control and Reclamation Act of 1977 (SMCRA) has evolved into one of the most complex environmental protection programs to come out of the late 1970's. The level of detail in the statute and the regulations have resulted in a rigid and complex set of requirements for the administration, permit-ting, inspection and enforcement of the program. In addition, the constant change of the federal program caused by regulatory changes, reorganization of the Office of Sur-face Mining Reclamation and Enforcement (OSMRE), ongoing litigation involving OSMRE, and the use of the budget to establish additional mandates on OSMRE and the State Regulatory Authorities have resulted in an unstable program. The instability of the program makes it extremely difficult for the States to implement their programs and to achieve the goals of SMCRA.

Jan 1, 1988

By Y. F. Li

Fengning ilmenite ore is a magnetic deposit in gabbro containing high phosphorus and low titanium, the main minerals in which are ilmenite, magnetite and apatite. The dissemination size of magnetite is so fine that even the percentage of -0.010mm level is up to 36.50%. The fine and vein magnetite are distributed in gangue and ilmenite, so the majority of the magnetite is difficult to be separated from the gangue. Ilmenite is difficult to be recovered by low-intensity magnetic separation even through fine grinding. In high-intensity magnetic separation of ilmenite, the gangue inter-growth with the magnetite and the Fe-containing silicates may be enriched in the concentrate, and the ilmenite of the concentrate will be reduced. Based on the processing mineralogy research, combined gravity-flotation process is suggested to recover the ilmenite. The method is also good to reduce phosphorus in the ilmenite concentrate.

Jan 1, 2014

By J. E. Schiller

The Bureau of Mines is investigating methods to treat waste water that contains cyanide. This report describes a new method that removes heavy metals and all forms of cyanide. In the first step, hydrogen peroxide and sodium thiosulfate are added at pH 7 to 9 in a 1:2 molar ratio to convert free and weakly complexed cyanide to nontoxic thiocyanate. Then steryldimethylbenzylammonium chloride is added to precipitate ferro-cyanide, and finally, ferric sulfate is added as a sweep floc and sequestrant for heavy metals. After the suspended solids settle, the water is polished by filtering. The water initially contained 1 to 5 mg/L Fe, 1 to 5 mg/L Cu, and 10 to 30 mg/L total cyanide; the level of each of these constituents was reduced to less than 0.02 mg/L.

Jan 1, 1983

By T. Zoltai

Asbestos is a generic term for industrially useful fibers recovered from exploitable deposits of the asbestiform varieties of five silicate minerals: chrysotile, anthophyl-lite, actinolite-tremolite, cummingtorute-grunerite, and rie-beekite. Asbestos and asbestiform fibers of some other minerals are known to be carcinogenic. Minerals crystallized in the asbestiform habit-are characterized by unique properties (morphology, strength and flexibility, physical and chemical durability, and defect-free surface structures). The key to the unusual properties, and health effects, of asbestiform fibers appears to be in their unusual surface structure. In contrast, non-asbestiform crystals of the same minerals, including the five so called asbestos minerals, do not have these properties and are not carcinogenic.

Jan 1, 1989

By G Byrne, A Bowden

There is often a difference in opinion about the allocation of risk in the establishment of mine closure bonds or financial assurances. From the State’s perspective, protection is needed to ensure that the broader community is not left with the liability of properly closing a mine in the event of a default by the mine operator. Such a default might occur where an operator decides to abandon a site, perform incomplete rehabilitation, becomes insolvent or claims limited liability. On the other hand, mine operators who can demonstrate a strong financial position plus a record of social and environmental commitment and performance, argue that there should be some recognition of this in setting a bond that is less than the full cost of early closure. They argue that a mine rehabilitation bond based on the full cost of early closure is overly conservative and ignores the actual risk of the operator being in default. This paper examines an approach that incorporates the risk of default into the establishment of mine closure and rehabilitation bonds. CITATION:Bowden, A and Byrne, G, 2018. Mine closure bonds (financial assurances) – the ‘how much?’ conundrum, in Proceedings Life-of-Mine 2018, pp 32–34 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 25, 2018

By Marcelo A. Martorano, Moyses L. Lima, João B. F. Neto

"Directional solidification is an essential refining step to obtain solar grade silicon from metallurgical silicon. This step can be carried out in a Bridgman furnace, where nearly constant temperature gradients and solidification velocities are imposed on the solid-liquid interface. In the present work, this directional solidification was conducted in a static furnace, in which large temperature gradients and low solidification velocities were enforced to increase macrosegregation. The resulting ingots were analyzed regarding their macrostructures, microstructures and chemical composition. Using measured cooling curves in the ingot as boundary conditions, a mathematical model based on the concept of a stagnant liquid layer at the solid-liquid interface was implemented to predict the macrosegregation profiles. The chemical analyses of the ingots show macrosegregation of several impurities to the ingots top. The mathematical model indicates that liquid convection plays an important role in stabilizing the planar solid-liquid interface, increasing the macrosegregation of impurities.IntroductionMost of silicon used for photovoltaic (PV) energy production is obtained by chemical processes, such as, Siemens and its derivations [1]. However, these chemical processes have drawbacks related to relatively high energy consumption and investment costs, and to safety and environmental problems. In order to overcome these difficulties and to fulfill the silicon demand for PV applications, several metallurgical routes are under development [2] to produce silicon of enough purity to PV applications (SoG-Si) from metallurgical grade silicon (MG-Si).Metallurgical routes involve different steps among which the directional solidification is pointed out as a fundamental one [1]. Directional solidification can cause macrosegregation of impurities to the last part of the ingot to solidify. The impurity segregation during solidification is related to the low solute partition coefficient (k0) between liquid and solid silicon. Most of the impurities in MG-Si have k0 << 1, except for boron, phosphorus and oxygen, which require specific steps of the metallurgical routes to be eliminated. The equilibrium partition coefficient and the solubility limits for the most important impurities in MG-Si are shown in table 1"

Jan 1, 2014

By A. B. Young

T HE smelting industry in Utah is represented by four plants: The Midvale of the United States Smelting, Refining & Mini.ng Co., the Murray of the American Smelting and Refining Co., the Garfield of the same company and the Tooele of the Inter- na.tiona1 Smelting Co. The first two are lead smelters, the Garfield plant is a copper smelter while the last named embraces both a lead and copper smelter. A total daily smelting capacity of over 10,000 tons is represented, of which 4000 tons is lead smelting capacity. With the exception of Tooele, forty miles distant, all of these smelters are within twenty miles of Salt Lake City. Pyrometallurgical operations in this district are con- fined entirely to the production of unrefined bullion, which is shipped east to the various refineries of the respective companies. The smelting industry in this state had its beginning away back in the latter days of the Civil War, many years before the completion of the trans-continental railroad. Ox teams were still bringing their companies of better fixed Mormon emigrants across the plains to the valley of the Great Salt Lake and those in lesser circumstances were still pushing their hand- carts over the same roads to the temporary abode

Jan 1, 1925

By S. S. Peng

A hybrid boundary element-finite element model was formulated to model roof bolt reinforcement of the roof strata with bedding planes. This model was used to analyze the stress distribution around a rectangular opening with variables such as opening width-height ratio, number of bolts installed, number/location of bedding planes, in-situ stresses, etc. The most critical areas are identified and the number and length of roof bolt required are then determined. Two case examples are illustrated.

Jan 1, 1989

By NA NA

Listing safety award winners, £I43M has been added to proceeds from coal privatisation in the year to March 1997, bringing total revenues to over £1.3bn, some company news in brief.

Jan 8, 1997

By K. A. McDonald

This paper will describe the experiences of Hibernia Holdings, Inc. in constructing a mineral processing facility in Mexico. It will attempt to set forth a guideline on what companies attempting to operate in Mexico can expect and what actions they can take. Ownership laws, import/export laws, labor laws, security, transportation and operating experiences will be discussed.

Jan 1, 1994

K. W. Turner, Sail Francisco, Cal. (communication to the Secretary*): The recent papers in the Transactions by Vogt,&apos; Lindgren2 and Weed: on ore-deposits that have formed as a direct result of igneous intrusions, show that deposits of this class are widely distributed over the world, and are occasionally of commercial value. This is especially true if we consider under this head all deposits in the zone of contactrnletamorphism, the origin of which may be ascribed to the gases and vapors generated by the heat of the intrusive rock. Mr. Smith&apos;s description of the Chillagoe garnet-formations containing copper, leads one to regard these depoaits as of contactrmetamorphic origin, although he gives certain reaeons for supposing them to be of igneous origin.

Jan 1, 1904

By T. Schmidt, H. Assadi, F. Gartner, H. Kreye

Among all spraying processes, cold spraying has attracted a special attention in recent years, both as a coating - and more recently - as a rapid manufacturing technique. The interest in this process is mainly because of the fact that the deposition of spray material takes place at moderately low temperatures, and thus, oxidation and unfavourable microstructural changes can be alleviated. In this process, a highly compressed gas, flowing through a de Laval nozzle, accelerates the particles of the spray powder to high velocities of up to 1200 m/s. Although there is no melting of particles prior to impact on the substrate, cold-sprayed deposits can be denser and more tightly bonded as compared to the equivalent deposits produced by conventional thermal spraying methods. The present contribution focuses on this unique aspect of cold spraying. Modelling of particle impact, combined with various experimental observations, is employed to illustrate that bonding of particles and hence material deposition occurs through shear instability - associated with severe plastic deformation and localized heat generation - at the interacting surfaces of particles and substrate. The results of modelling also provide an insight to the influence of material and process parameters on the critical velocity and on the microstructural properties of cold-sprayed deposits.

Jan 1, 2006

By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk

In the mineral processing industry, Ni-Cu-Fe-S converter matte is leached to remove base metals from a concentrate containing platinum group metals (PGMs). We investigated the atmospheric leaching process to develop a better understanding of the leaching behaviour of the base metals (Cu, Fe, and Ni) and the PGMs, in particular Ru, Ir, and Rh with respect to key process variables, acid concentration, and Cu concentration under oxidative and non-oxidative conditions. With oxidative leaching, a higher initial acid concentration resulted in higher Cu, Ni, and Fe extractions, as well as faster leaching reaction rates. A higher initial acid concentration also resulted in faster precipitation of Cu, Ru, and Ir under oxidizing conditions. Under non-oxidative conditions, Ni and Fe extraction was much slower, and the effect of initial acid concentration on Cu precipitation was less pronounced. The initial Cu concentration had a slightly smaller effect on the leaching behaviour of Fe and Ni, as well as precipitation of Ru, Ir and Rh. Moreover, a higher initial Cu concentration suppressed both Ni and Fe leaching and had a slight inhibiting effect on the precipitation behaviour of Cu, Ru, and Ir.

Nov 1, 2021

By L. Tartibu, S. Assuli, P. Nkul, A. Kabimba, W. Elongo, N. Makhotla, D. F. Verwey, F. G. Ndiitwani, J. Bilali, T. Mukongo

The presence of colloidal silica negatively impacts various hydrometallurgy processes. This paper details the nature of colloidal silica, operational issues caused by colloidal silica, as well as various mitigation measures. MMG Kinsevere observed severe phase-continuity instability, increased crud formation, and reagent consumption, and reduced current efficiency in electrowinning with a deterioration in copper quality. Historical mitigation measures were initially implemented but failed to solve the problem. MMG Kinsevere successfully achieved efficient silica removal without adverse effect on the solvent extraction with the use of DEHSCOFIX® SC12 coagulant. A week into the coagulant trial, silica concentration had dropped from > 1500 mg/L to within 500 mg/L. The solventextraction plant recovered its stability and again operated at maximum capacity. Additionally, improvement was observed on current efficiency and copper cathodes quality with use of the coagulant.

Jan 1, 2023

By W. E. Armstrong

Gypsum was first exploited as ?a commercial proposition in this province by the Union Mining Company which, in 1900 opened quarries on the east shore of Lake Manitoba, near the present site of Gypsumville. This company established a mill at the head of Portage Bay on the lake, and the manufactured plaster was carried by the companies boats to McArthur&apos;s siding on the Whitemouth river near Westbourne, Man., from which point it was distributed. In 1904 a reorganization took place and the Manitoba Gypsum Company Limited bought out the original company, and operated the original mill for about one year when it was destroyed by fire. There were many factors which rendered the operation of a mill at the quarries very difficult; lack of rail transportation for bringing in supplies, and the impossibility of local power development made manufacturing costs very high. Satisfactory distribution could not be affected because of water transportation and poor terminal facilities at McArthur&apos;s siding. For these reasons the new mill was built at Winnipeg, where cheaper power and better distributing facilities permitted the industry being placed in a better position. The company continued to bring the gypsum rock by steamer to Totogan, from which point it was transported by rail to Winnipeg. This period was one of steady expansion as the product became better known and more universally accepted as a wall finishing material. Unfortunately, in 1909, this new mill was destroyed by fire, causing a serious set-back to the company, at a time when the steady growth of the western market gave every promise of the industry being placed on a profitable basis.

Jan 1, 1925

By Everett P. Partridge, J. E. Conley

Available statistics show that the demands of the American chemical industry for sodium sulphate have been increasing slightly in recent years. The supply from domestic sources, particularly in the form of byproduct salt cake from the acid manufacturers, has been tending to decrease this to the growing manufacture of synthetic acid. Both hydrochloric and nitric acids are being synthesized from their elements. The natural result has been that a smaller amount of salt cake is available. Simultaneously, the expansion of the kraft-paper industry, especially in the South, has brought about greater demand for sodium sulphate in that section. This demand is being met by domestic byproduct salt cake, by imported German sodium sulphate made from potash waste liquors, and by favorably situated domestic deposits of Glauber salts and the anhydrous salt, thenardite. No shortage of natural sodium sulphate exists in the United States, but usually such deposits occur in semiarid regions far removed from transportation facilities and from markets. Moreover, the major portion of the natural deposits is Glauber salt or mirabilite (Na2 504 • 10H20), which must be dried or dehydrated in order to meet consumer requirements. The water of hydration represents, roughly, 55 percent of the total weight of the crude salts and therefore has a very important influence on transportation costs, in many instances the cost of getting even the dehydrated product to market is the deciding economic factor. Therefore, the recovery of production of anhydrous sodium sulphate from plant-waste liquors or from natural brines of suitable composition might be economically feasible.

Mar 1, 1936

By Sam Tour

OF the new alloys achieving commercial prominence during the year, an aluminum-silicon magnesium casting alloy, which is similar in many respects to the 4 per cent copper alloy, developed about 1921, which has attained such a wide field of service, may be mentioned. The new alloy, like the old, is a heat-treatable type and develops about the same physical properties. The alloy casts easily and is relatively insensitive to high pouring temperatures. Its ability to produce substantially leak- proof castings is noteworthy. A second casting alloy development is the new Aluminum Co. of America No. 132, "Lo-Ex" piston alloy, a result of nearly eight years of research. The alloy contains about 14 per cent silicon and varying amounts of nickel, copper, and magnesium. It exhibits a low coefficient of expansion and thus permits small piston clearances. Its lower specific gravity is a further advantage.

Jan 1, 1932

By Kamran Esmaieli

Open Pit Mining Through Underground Voids: Challenges Main Challenges/Hazards: Unexpected collapse of the pit floor and/or pit walls; The loss of equipment and/or people into underground voids; Loss of explosives from blast holes that broken through into the underground voids. How to address these challenges? An important step that must be integrated into mine planning and design is the accurate detection and delineation of underground voids. (i.e. probe drilling, Geophysical techniques, laser scanning,?); Leaving a pillar of adequate thickness between the working bench and the underground voids; Backfilling the underground voids from surface using vertical or inclined raises; Monitoring the working locations (pit floor and pit slopes) to detect movements.

May 1, 2013