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By Qingyun Huang, Wei Lv, Junyi Xiang, Xuewei Lv, Chenguang Bai

The kinetics of iron leaching from ilmenite in hydrochloric acid solutions were investigated. The effects of pre-oxidation roasting, leaching temperature, and holding time on iron extraction rate were determined. The results obtained show that the extraction of iron is significantly enhanced by pre-oxidation roasting and increasing leaching temperature from 75 to 108 °C. The results of the kinetic analysis of the leaching data indicate that the reaction is controlled by diffusion through the product layer. The apparent activation energy for the extraction of iron has been calculated to be 62.5 and 55.1 kJ/mol for untreated and oxidized ilmenite, respectively.

Mar 1, 2018

Calcium sulfate whiskers are considered to be a prosperous reinforced material in application due to their high mechanical properties. But the hydration occurs easily at moist atmosphere or in aqueous solution. The surface topographies of the calcium sulfate hemihydrate whiskers and the hydrates were analyzed by on-line observation and using XRD. The results indicated the transformation of the crystal type and shape of calcium sulfate hemihydrate whiskers and the reduction of whiskers? aspect ratio. The hydration process of the calcium sulfate hemihydrate whiskers and the effective parameters were further discussed based on FT-IR measurements. The conclusions were obtained that the hydration of calcium sulfate hemihydrate whiskers can be divided into the three phases, namely, initial hemihydration phase, dehydration phase, and coarsening, dissolving and the re-formation of calcium sulfate dehydrate crystal phase. In addition, it was found that in the hydration process of calcium sulfate hemihydrate whiskers the calcium sulfate dihydrate whiskers are formed at first and then converted into the calcium sulfate dihydrate with different crystal shapes, but in the hydration of gypsum hemihydrate the gypsum dihydrate is formed without transition products. The surface active site-calcium ion which has strong trend to react with H2O, the surface ?OH and the inner channels are considered to play important roles in the hydration process of calcium sulfate hemihydrate whiskers.

Jan 1, 2014

By Chao Li, Kym Runge, Saeed Farrokhpay, Dee Bradshaw

"It is well known that froth phase has a controlling influence on the overall flotation performance. Froth recovery is expected to be affected by froth transportation behaviour. The latter has been represented by different volume balance and energy balance based models. In froth transportation models based on a volume balance, the froth phase is divided into different zones. The total froth residence time is the sum of the time spent in each zone and is dependent on the cell geometry, bubble burst rate and the position that bubbles enter into the froth phase. Alternatively, the froth transportation model based on an energy balance treats the froth phase as a block. In this model, froth height above the concentrate lip is being predicted by minimising the energy of the system which is dependent on the froth geometry, froth stability and froth rheology. The froth height can be used to calculate the froth efficiency of delivering mineralized bubbles from the pulp to the concentrate lip. This paper critically analyses the current models of froth transportation in flotation, and examines the limitations of these models. The importance of froth rheology, which is the resistance to the froth flow towards the discharging weir, in determining froth transportation, is also highlighted."

Jan 1, 2014

By S. Chander

A series of nonionic and anionic surfactants were tested to enhance the flotation response of a low rank coal. An ethoxylated octyl phenol and several polypropylene polyethylene block copolymers were tested as nonionic surfactants. The anionic surfactant was a dioctyl sulfosuccinate. All the surfactants employed improved the yield significantly but the influence on grade was complex. Separate studies were conducted to determine the emulsification behavior of the surfactants. For the nonionic water soluble reagents tested, a correlation between emulsifying power of the surfactant and flotation was observed. An increase in the number of droplets produced in surfactant containing systems was considered to be the main reason for increase in the yield. Since it increased the number of collisions between dodecane droplets and coal particles. When a surfactant was introduced into the flotation pulp prior to addition of dodecane, it decreased the benefits of the surfactant significantly. The decrease was attributed to an increase in the wettability of coal and a decrease in the surfactant available for emulsification. When a suitable surfactant was added as a solution dissolved in the oily collector, a considerable increase in yield was observed.

Jan 1, 1993

By Igor Martins dos Santos

O nitrogênio waste, que é chamado assim por ser mais impuro, devido à existência de uma porcentagem aproximada de 2% mais de oxigênio no mesmo, utilizado exclusivamente no processo de “Slag Splash” na Aciaria, possui um contrato fechado de volume para fornecimento (7.000 Nm³/h, à pressão de 30 bar), o qual estava sendo utilizada aproximadamente a metade do mesmo (3.500 Nm³/h). Como no processo produtivo da CSA, é utilizado o nitrogênio de baixa pressão (16 bar) em grande quantidade (21.600 Nm³/h, sendo aproximadamente 5.600 Nm³/h acima do contrato de fornecimento), foi feito um projeto para interligar as duas linhas de nitrogênio através de aproximadamente 420 metros de tubulação, com sistema de controle integrado e analisador de oxigênio para garantir a concentração mínima de 1% de oxigênio no Nitrogênio de baixa pressão, devido à necessidade de algumas áreas. Nos primeiros seis meses após implantação, foi contabilizado uma economia de aproximadamente R$4.0 milhões (aproximadamente 3.100 Nm³/h de consumo).

Oct 30, 2017

By Bret Boster

Facilities at Amax Gold's Sleeper Mine process some 330 kt of high grade ore and 4100 kt of low grade ore annually to produce 6.8 t of gold and 7.8 t of silver. High grade ore is processed in a conventional milling facility employing gravity concentration, CIC and CIP unit operations for gold and silver recovery. Low grade ore is processed using heap leaching and carbon adsorption methods.. Presented are the evolution and descriptions of the Sleeper processing facilities and discussions of selected' operating results.

Jan 1, 1989

By Ram Song, Yohei Harada, Shinji Kumai, Kazuho Otsuka

"Recently, vertical-type high-speed twin-roll casting (HSTRC) has been developed. The HSTRC shows extremely high cooling rates over 1,000 K/s even at the mid-thickness area. The fabricated strip has many metallurgical characteristics; super-saturation of alloying elements, fine solidified structure, and homogeneous distribution of fine constituent particles. In Al-Mn based alloys, the Mn alloying element can be supersaturated in the a-Al matrix and also form Mn-containing constituent particles during solidification. The Mn supersaturation and the distribution of primary/secondary particles in cast products affect the metallurgical behavior in the down-stream processing and can improve mechanical properties of the final products. In this study, Al-Mn based alloy strips were fabricated by HSTRC with various Mn contents. The solidified microstructure, constituent particles and its distribution, and Mn solubility were investigated in the as-cast condition. Due to the high cooling rate of HSTRC, fine constituent particles were homogeneously distributed, and coarse intermetallics were not observed. Mn solid solubility was estimated by electrical conductivity. The estimated Mn solubility was equivalent between strip surface and mid-thickness area.INTRODUCTION Al-Mn based alloys, as non-heat treatable wrought aluminum alloys, are widely used in packaging and heat exchanger for automobile industry. Besides Mn, Al-Mn based alloys often contain Fe and/or Si as alloying elements or natural impurities. During solidification, Mn can be super-saturated in the Al matrix, and also form Mn-containing constituent particles. Additionally, in the subsequent thermal-mechanical processes such as homogenization, rolling, and intermediate annealing, Mn in solid solution precipitates out of the Al matrix as secondary particles. The size, distribution, type, and the amount of dispersoids including constituent particles affect to texture evolution, recrystallization behavior, and final mechanical properties of wrought Al-Mn based alloys (Huang et al., 2016; Huang & Marthinsen, 2015; Engler et al., 1995; Muggerud et al., 2013). Therefore, controlling the initial level of Mn super-saturation and the distribution of constituent particles are important in the cast Al-Mn based alloys."

Jan 1, 2018

By H. M. Gao

According to the difficulty of dolomite removal from collophanite,normal-reverse floatation process has been adopted in floatation with the use of highly selective collector G-4 and depressant S721. Good indexes of flotation have been obtained with the run-of-mine ore containing 17.96 % P2O5 and 2.31 % MgO being upgraded to a concentrate containing more than 30% P2O5 and less than 1% MgO. The reagent interaction mechanism in low grade collophanite flotation has been stu-died by FTIR analysis and theoretical calculation. The results indicate that the interaction between collector G-4 and collophanite is the result of chemical adsorption in combination with physical ad-sorption with chemical adsorption playing the major role. Depressant S721 adsorbs on dolomite surface to form a water film and effectively depresses the flotation of dolomite and reduces the MgO content in the concentrate.

Jan 1, 2014

By T. Shumba

The solvent extraction section of an old Uranium Plant in the Vaal River region produced a sub-stance called Crud (Chalk River Unidentified Deposit) that formed within the aqueous/organic interface of the settler of the solvent extraction circuit. The crud was deposited together with gold tailings to the tailings dam many years ago. Previous research done on the crud confirmed that ex-posed crud leaches Mn and Ni at concentrations that are well above their acceptable risk limits as well as Zn that leaches at concentrations that are slightly lower than its acceptable risk limit. Soil washing and bioremediation technologies were employed to treat the contaminated soil. Various laboratory test work and the pilot scale studies were conducted in parallel with each other and the results of the laboratory studies were used to determine critical parameters. Four lixiviants, i.e. sulphuric acid, acetic acid, oxalic acid and ethylene diamine acetic acid were tested at three concentration levels i.e. 0.001M, 0.0001M and 0.00001M, respectively. Column tests showed that the leaching of the heavy metals increases as the soil porosity increases. Silica sand was added to increase porosity of the contaminated soil. Highest Mn removal was achieved mainly by sulphuric and oxalic acid at 0.001M at all soil levels. EDTA was significantly efficient in the removal of Ni and Zn. The recovery of heavy metals, particularly Mn, decreased as the depth of sampling in-creased. Heterogeneous bacteria and filamentous organism plate counts were conducted to evaluate the growth of the bacteria and filamentous organisms in the soil. Results showed that more organism growth took place in the bioremediated soil with a fertilizer added to it. The leaching of metals from the soil that was bioremediated in the pilot study was generally higher than the extraction of the metals from the soil that was leached with no bioremediation carried out. The results from this study suggest that the leaching of heavy metals from the contaminated soil is to a large extent dependant on the pH of the leaching solution. By increasing the soil?s porosity and bioremediating the soil, higher extractions of metals were achieved.

Jan 1, 2014

By Ernest A. Hodgson

A SERIOUS hazard which must be faced in some mines, though quite absent in others, is that of rockbursts. Bursts cannot be wholly avoided in such mines, but the hazard would largely disappear if they could be predicted. The problem of prediction resolves itself into that of measuring pressure in the mine and determining when that pressure nears a critical value. The geophysical approach to the problem lies in discovering some physical property of the rock, which varies with pressure, which can be measured for rock in place, and for which the indication of critical conditions is sufficiently definite and open scale. A physical property, suggested first in connection with earthquake pre-diction, is that of sub-audible snapping. It was argued that, as the pressure grows, the rock probably yields microscopically and that minute snapping occurs which is so faint as to be inaudible to the unaided ear. Experience has proved this to be the case. Following other earlier work begun early in 1939, experiments with this method were initiated at Lake Shore Mines in 1941, and equipment was slowly being developed in practice when, fortunately, it was found possible to by-pass this tedious development programme. Experiments with sub-audible snapping in mine rocks had been carried out by Dr. L. A. Obert of the U.S. Bureau of Mines and his associates over a period of about four years. An amplifier and a recorder were developed, each reasonably satisfactory in practice. Lake Shore Mines offers a tempting field for rockburst research. Dr. Obert was invited to test his equipment in this and other mines in Ontario and did so. As a result, he and the administrative personnel of the Bureau became interested in the Lake Shore experiments co the extent of most generously arranging for the manufacture of sets of their own designed equipment for use in this programme. The first three sets of recorders were ordered at once and were delivered in May, 1942. A second group of three sets, incorporating various improvements indicated by experience both in the United States and in Canada, reached Kirkland Lake in April, 1943. The pick-up devices, known as geophones, were made in the electronics laboratory at Lake Shore by Mr. Zack Gibbs, who has had charge of all the instrument development in this re-search.

Jan 1, 1943

By MATTHEW HART, THOMAS BAMFORD, Kamran Esmaeili, MICHAL KOWALCZYK, FILIP MEDINAC

Improved haul road conditions can positively impact mine operations resulting in increased safety, productivity gains, increased tire life, and lower maintenance costs. For these reasons, a monitoring program is required to ensure the operational efficiency of the haul roads. Currently, at Bald Mountain mine, monthly site severity studies, ad hoc inspections by frontline supervisors, or operator feedback reporting is used to assess road conditions. These methods are subjective and provide low temporal resolution data. This case study presents novel unmanned aerial vehicle (UAV) technologies, applied on a critical section of haul road at Bald Mountain, to showcase the potential for monitoring haul roads. The results show that orthophotos and digital elevation models can be used to assess the road smoothness condition and to check the road design compliance. Moreover, the aerial mapping allows detection of surface water, rock spillage, and potholes on the road that can be quickly repaired/removed by the dedicated road maintenance team.

Sep 15, 2020

By John M. Devine

Hydrogen sulphide associated with natural gas was noted as early as at Point Albino, Canada. The presence of this impurity was recognized also in other of the earlier oil and gas fields, although the occurrence was by no means common. However, in recent years, with the development of the producing zones of test Texas and the Texas Panhandle, the Production of "sour" crude has increased greatly and hydrogen sulphide has proved a generally troublesome factor--frequently a major problem--in the drilling and operation of many wells in those areas. The problems arising from the drilling and producing of oil or gas wells in hydrogen-sulphide areas, fall under two general divisions: safety problems and corrosion problems. Mention is made of a third division which is closely related to the other two, that of treating--or the development of processes for the removal of hydrogen iron the standpoint of safety and health hazards, hydrogen sulphide in the petroleum industry has been discussed in a number of publications. Likewise, the problem of hydrogen-sulphide corrosion of production equipment has been given considerable attention in the literature.

Jan 1, 1931

By P. M. Daling

The objectives of this study were to examine a representative cross section of formal safety analysis techniques developed for the nuclear and aerospace industries, to recommend those methods that would be suitable for application to the mining industry, and to include those methods in a user's manual. Volume II of this report, the user's manual, describes several methods that were determined to be immediately transferrable to the mining industry. The handbook gives detailed instructions on appropriate application and utilization of the methods. Other techniques will require further development before they can be effectively transferred to the mining industry.

Jan 1, 2006

By L. C. DeCory

"Concrete is a common denominator to the building process and portland cement is an integral and necessary component of concrete. The cost of portland cement is nominal and its cost comprises, in most instances, a small portion of the total cost of ""put-in-place"" concrete.The domestic demand for portland cement in Canada is projected to be slightly less than 11 million short tons in 1980. In order to achieve this projected goal, stabilization or lowering of the cost of put-in-place construction is necessary. This enhancement of the cost of building can be achieved by:(1) improving the building process;(2) refining and improving design techniques; and(3) developing improved and economical concrete products.Some of the techniques and materials that will lead to building cost stabilization include systems building in its broadest sense, slipforming, precasting, prestressing, computer design, lightweight aggregates, fibrous concrete and integration of building components."

Jan 1, 1973

By Thomas O. Llewellyn

This U.S. Bureau of Mines (US8M) report presents a concise review on sources, processes, supply, and historical use patterns of domestic cadmium. It also covers a preliminary estimated cadmium material balance for the year 1989.

Jan 1, 1992

By P. Hr?enjak

Two groups of methods are usually used in design procedures of underground excavation of dimension stone: the analytical and numerical methods of analysis. In all of these methods the in situ rock mass strength represents the main problem. This is due to massive rocks in dimension stone deposits, consisting of large blocks of rock separated with particular discontinuities, for which the Hoek-Brown empirical criterion, developed for jointed rock masses, cannot be realistically used to estimate rock mass strength, especially for a particular block of rock mass or a particular pillar. On the basis of the regular underground excavation process of dimension stone by separating blocks with the flat jack application, we developed the in situ flexural strength testing method. We carried out numerical analyses and evaluation of uncertainty of measurement in order to validate the in situ flexural strength testing method. On the basis of very good validation results, as well as results of the in situ flexural strength testing of exploitable layers on the ?Kanfanar? quarry, we introduced a new coefficient of reduction, which can be used for correction of other strength parameters determined by laboratory testing for obtaining a realistic value of rock mass strength.

Aug 1, 2013

By W Newns

This paper describes laboratory and in situ tests and determines a set of parameters for stiffness and strength properties for a weak sedimentary rock mass, the East Coast Bays Formation of Auckland. The parameters derived are discussed in relation to peak strength and in respect of deformation limits associated with sequential excavate and support (SEM) or conventional tunnelling.

Mar 8, 2011

By Y. Luo

Based on the concept of slope stability analysis, a formula for determining an important parameter required in the mathematical model for the prediction of mining subsidence in hilly terrain has been proposed. The slope geometry and soil physical and mechanical properties of the surface natural slope can all be considered in the formula. Incorporation of this new formula into an existing mathematical model provides an integrated approach in studying ground movement in hilly regions.

Jan 1, 1998

By W. G. Worcester

IN the presentation of this paper to the Institute, three objects are in the mind of the writer: first, to set forth the close relation which, of necessity, exists between ceramics and the industrial minerals; second, to clarify the apparently hazy understanding which many have of ceramics in general; and lastly, of equal or even more importance, to stimulate a greater interest in the industrial minerals, especially in those used and required by the ceramic industries. While Canada is now producing in large quantities a fairly wide variety of the ceramic industrial minerals, there are some which are not known to occur in the Dominion. Hence it is to be desired that our geologists, prospectors, and others, while on field work, should be on the look out for commercial deposits of such minerals as diaspore, bauxite, ucts of a value in excess of $600,000,000, a figure which places ceramics as kyanite, massive topaz, and sillimanite. A find of any of these in quantity would prove of very great importance and value to the country as a whole. At this point it seems desirable to introduce formally the word ceramic or the plural of it, ceramics. In doing so it may be stated that the origin of the word dates far back in history in that it was derived in part from the Greek word Keramos, 'a potter' or 'pottery', which in turn has been traced back to an older Sanskrit root meaning 'to burn' or 'burned stuff', having reference, no doubt, to burned pottery or other clay wares; and the word was so used until near the close of the last century, when the world's first schools of ceramic engineering were established in the United States. The use of the term ceramics was then expanded to cover a much larger field the entire field of the silicate industries and products. At one time it was suggested by a limited number of ceramists that the term 'ceramic engineering' be changed to 'silicate engineering'. This proposal, however, gained little support and was soon abandoned.

Jan 1, 1945

By Åke C. Rasmuson, Mahmood Alemrajabi, Kerstin M. Forsberg, Kivanc Korkmaz

"In the present study the recovery of a Panasonic Prismatic Module 6.5 Ah NiMH 7.2 V plastic casing hybrid electric vehicle (HEV) battery was investigated, separately processing the anode and cathode electrodes. The composition of the electrode materials was determined by total dissolution and analysis using ICP-OES. Nickel is the dominant metal in the active materials (65% by mass in the anode and 70% by mass in the cathode). Most of the rare earth elements (La, Ce, Nd, Pr and Y) are located in the anode active material, whereas only a small amount of Y is found in the cathode material. The electrode materials were further characterized by SEM-EDS and powder XRD. The electrodes were leached in sulfuric acid and in hydrochloric acid under different conditions. The dissolution was followed by taking out samples and analyzing the concentration of REE, Co, and Ni using ICP-OES. The results indicate that the dissolution of nickel could be limited by slow dissolution kinetics of nickel oxide. Further, it was found that light rare earths are lost through precipitation during sulfuric acid leaching with increasing extent as the temperature and sulfuric acid concentration increases. The separation of REE from the sulfuric acid leach liquor by precipitation as NaREE(SO4)2.H2O and from the hydrochloric acid leach solution as REE2(C2O4)3.xH2O have been studied by performing experiments using battery leach liquors. INTRODUCTIONIt is well known that the Hybrid Electric Vehicle (HEV) is becoming more common due to economic and environmental reasons. Batteries are widely used in HEVs’ such as automobiles or larger trucks for transportation purposes. The most common type of battery in these vehicles is nickel metal hydride (NiMH), largely due to Toyota's decision to use them in their popular Prius. More than two million hybrid cars worldwide are running with NiMH batteries, such as the Prius, Lexus (Toyota), Civic, Insight (Honda), and Fusion (Ford). Panasonic manufactures HEV prismatic NiMH batteries that have been used by Toyota and GM (among others), while Sanyo manufactures HEV cylindrical cell NiMH batteries, which have been used by Honda and Ford."

Jan 1, 2016