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By K. Saberyan

Zirconium and hafnium are two important elements in nuclear industries. Zirconium is used in fuel rod for its low neutron absorption. Hafnium should be separated from zirconium, because it has higher neutron absorption cross section. In this research, separation process of the mentioned elements from (Zr+Hf)Cl4 mixture produced in the Zirconium production plant (ZPP) of Iran (Esfahan) was studied employing solvent extraction method in the nitric acid medium by using tributylphosphate (TBP) as solvent, and kerosene as diluent. The effects of nitric acid, sodium nitrate and amount of extractant, zirconium concentration in aqueous phase, phase ratio, agitation time, and mixer agitation rate were investigated on the separation process. The process was optimized at 5 M nitric acid, 1 M sodium nitrate, 60% (v/v) TBP. The optimum values for phase ratio, agitation time and agitation rate were 1.5 min and 500 rpm respectively. In this condition, the zirconium extraction efficiency, and separation factor were 65.1% and 205.59, respectively. Finally, we accessed to nuclear grade in this research.

Jan 1, 2014

By P. M. Daling

This report, sponsored by the U.S. Bureau of Mines, presents the results of an examination of available safety assessment methods and their applicability to the mining industry. Standard safety analysis procedures were evaluated for relevance to the mining industry and mine operators' needs. The major safety concerns and needs of mine operators were identified through telephone contacts and a visit to a mine site. Safety assessment methods recommended for use by the mining Industry were also Investigated for potential adaptability to a user-interactive computer system. Several methods were determined to be immediately transferrable to the mining industry; these techniques are described in a user's handbook produced as part of this project. The handbook gives detailed instructions on appropriate application and utilization of these methods. Other techniques will require further development before they can be effectively transferred to the mining industry. These methods, their advantages, disadvantages and resource requirements are described in the final project report. Recommended system safety analysis techniques facilitate an evaluation of total mine system safety and a determination of safety-related interactions among systems within a mine. The application of these methods to the mining industry could result in reductions in both the frequency and the consequences of mine accidents.

Jan 1, 1983

By S. K. Palm

Volatility is a fact of life in the mining industry. Prices of and demand for mineral products are among the most volatile of those for any product. The volatility of these markets wreaks havoc on both corporate management and the personal lives of mining people. Yet, until recently, it has been difficult to assess the impact of volatility on business strategy. This paper discusses how mining firms can profit from market volatility through an operations strategy that stresses operating flexibility. The foundation for our strategy analysis is the observation that a mine is analogous to a stock option. Techniques based on those developed to value stock options have recently been extended to the field of mine valuation. The insights provided by option pricing are very valuable in the development of mine operating strategy.

Jan 1, 1986

By R. H. Zeng

Many subsidence researchers in the U. S. have developed new empirical function methods to predict subsidence, or attempted to validate some empirical functions developed by foreign researchers for use in the U. S. An attempt is made in this paper to develop a new empirical function to predict a surface subsidence basin due to longwall mining. In the U. S., the emphasis of empirical methods for the subsidence prediction over longwall panels has been in large part on determining the profile functions for the major cross-sections of a subsidence basin. In this approach, the surface monuments are usually laid out along the major cross-sections and thus, the subsidence profiles developed are restricted for subsidence prediction along the major cross-sections. However in practice many monuments or surface structures for which subsidence prediction for damage evaluation is required, are not laid out along the major cross-section of the basin. In such cases, it is difficult to get either the empirical profile function for the cross-sections where these structures are located or to predict their subsidence based on the profile function developed for the major cross-sections. Therefore, there exists a strong need to develop a subsidence basin function with a reasonable degree of accuracy, which can be determined or confirmed by the data of scattered monuments on a surface basin. The same subsidence basin function can also be used for prediction of subsidence for any arbitrary points over a longwall panel. In 1982, He (1) proposed the clastic theory, for which he developed the basic differential equations describing the movement and deformation of overburden due to underground mining, and performed the selection of best solution for the equations. He found that the Weibull dietribution is the optimal solution. The Weibull distribution has three parameters that vary to fit the subsidence profile so well that the profile function derived from it provides a high degree of accuracy in subeidence prediction. However the results

Jan 1, 1986

By D. Havlena, A. S. Odeh

The use of the straight-line method of solving the material balance equation is illustrated by means of six field cases. Also, the application of statistical criteria to arrive at the most probable answer is shown. The theory underlying the straight-line method of solution and the applicability of the statistical criteria was presented in a previous paper.' The field cases include saturated and undersaturated oil reservoirs with and without water drive. The aquifers discussed are: limited radial, infinite radial, very small aquifer and infinite linear. The field cases also include a gas reservoir producing under water drive. INTRODUCTION In a previous paper,' the authors presented the theory underlying the solution of the material balance as an equation of a straight line. The appropriate equations for various material balance cases as well as the methods of analysis and interpretation with comments and discussion were also included. To illustrate the various theoretical cases treated previously, five field cases are analyzed in this paper by employing the straight-line method of solving the material balance equation (MBE) and one example previously published is referred to. The use of statistical criteria to arrive at the most probable answer is also shown. All the field examples presented, except Case 2, are excerpts from complete reservoir studies. To illustrate the method, only sections specifically dealing with the material balance principles are included. Additional geologic information and basic data are reported to better acquire an understanding of the cases and thus to better follow the reasoning that suggested the successful application of the straight-line method of solving the MBE. The six cases are: (1) saturated reservoir, small gas cap, limited aquifer; (2) saturated reservoir, very small gas cap, infinite aquifer; (3) undersaturated-saturated reservoir, very small aquifer; (4) highly undersaturated reservoir, no water drive; (5) high undersaturated one-well reservoir, limited aquifer; and (6) gas reservoir, infinite linear aquifer. THE D4 SAND, GUICO FIELD, VENEZUELA The D, sand, which was discovered in 1943, is presently in a depleted state. Since its discovery it has produced under water drive, gas-cap-gas expansion, and solution gas drive. In Nov., 1947, water injection was initiated to arrest further pressure decline. When discovered, the D, sand was a saturated reservoir with a gas cap /oil zone volume ratio m estimated volu-metrically at 0.0731, an average permeability of 500 md, a porosity value of 25 per cent, and an oil viscosity at reservoir conditions of 0.3 cp. The volumetrically determined stock-tank oil initially in place was 23.1 million bbl. The volumetrically weighted physical data and production data available until Nov., 1953 are reported in Table 1. In Ref. 1, the effects on the straight-line plot of various values of ro/r for a constant ?to, or of various dimen-sionless times for a constant r8/r10 were theorized and were illustrated in Fig. 3A of that reference. In this field case, the previously theoretically predicted effects are established. Thus, the MBE calculations using Eq. 3c of Ref. 1 were performed for various r6/r10 and dimension-less time values. Eq. 3c of Ref. 1 is:

Jan 1, 1965

By Michael Gauna, Christopher Mark

"Coal bursts involve the sudden, violent ejection of coal or rock into the mine workings. They are almost always accompanied by a loud noise, like an explosion, and ground vibration. Bursts are a particular hazard for miners because they typically occur without warning. Despite decades of research, the sources and mechanics of these events are not well understood, and therefore they are difficult to predict and control. Experience has shown, however, that certain geologic and mining factors are associated with an increased likelihood of a coal burst. A coal burst risk assessment consists of evaluating the degree to which these risk factors are present, and then identifying appropriate control measures to mitigate the hazard. This paper summarizes the U.S. and international experience with coal bursts, and describes the known risk factors in detail. It includes a framework that can be used to guide the risk assessment process.BACKGROUNDCoal bursts involve the sudden, violent ejection of coal or rock into the mine workings. They are almost always accompanied by a loud noise, like an explosion, and ground vibration. Bursts are a particular hazard for miners because they typically occur without warning. During the years 2012-2014, serious coal bursts occurred at three different U.S. room and pillar mines. These events resulted in three fatalities and two permanently disabling injuries (MSHA, 2014; MSHA, 2013). In all three instances, the events occurred during pillar recovery at depths exceeding 1,000 feet (300 m). None of these three mines had previously reported a burst to MSHA. Coal bursts also occurred at three longwall mines during this same time period.Despite decades of research, the sources and mechanics of bursts are not well understood, and therefore these events are difficult to predict and control. Experience has shown, however, that certain risk factors are associated with an increased likelihood of a coal burst. A coal burst risk assessment consists of evaluating the degree to which these risk factors are present. In addition, some control techniques are effective in reducing the likelihood of an event or protecting miners from their effects."

Jan 1, 2015

By Lathrop E. Roberts

The opinion is general among smelter operators that magnetite formed in the converter and reverberatory furnace has much to do with the loss of copper in the slag. Its action appears to be due in part to its relatively high infusibility, chemical stability, and specific gravity, as a result of Which it tends to form a layer of highly viscous "magnetite mush" between slag and matte. Particles of matte which might otherwise settle out of the slag are unable to pass through this layer. Maier and Van Arsdele have shown that the inclusion of grills of matte in the slag is also at tires very probably due to chemical reaction between magnetite and the constituents of the matte. In smelter control and in any laboratory study of slats the determination of magnetite is therefore a matter of some importance. The difficulties in the ray of making such a determination with any accuracy are rather obvious. Iron may occur in slag as ferric oxide, magnetite, various intermediate oxides, sulphides, silicates, as free metal, and in solid solution of several of these substances. Even if only the total iron content is to be determined, accuracy can be obtained only by painstaking and time-consuming separations from interfering elements. The determination of ferrous, ferric, and free iron in the presence of each other is a difficult matter under the most favorable conditions, and when present in a slag the difficulties are increased by the refractory nature of the sample, by the presence of sulphides, and by such elements as vanadium and molybdenum.

Jan 1, 1931

By Richard J. Abitz

Thennodynamic geochemical models have been applied to assess the relative effectiveness of a variety of reagents added to aqueous waste streams for the removal of radioactive elements. Two aqueous waste streams were examined: effluent derived from the processing of uranium ore and irradiated uranium fuel rods. Simulations of the treatment train were performed to estimate the mass of reagents needed per kilogram of solution, identify pH regions corresponding to solubility minimums, and predict the identity and quantity of precipitated solids. Results generated by the simulations include figures that chart the chemical evolution of the waste stream as reagents are added and summary tables that list mass balances for all reagents and radioactive elements of concern. Model results were used to set initial reagent levels for the treatment trains, minimizing the number of bench-scale tests required to bring the treatment train up to full-scale operation. Additionally, presentation of modeling results at public meetings helps to establish good faith between the federal government, industry, concerned citizens, and media groups.

Jan 1, 1996

By D. Pienaar, B. McFadzean, T. Jordaan

"Dithiophosphate (DTP) collectors have the lowest affinity for sulfide mineral surfaces compared to other common sulfide mineral collectors, such as xanthates and dithiocarbamates. In some cases it has been found that DTP does not adsorb onto the mineral surface at all and yet increases in recoveries and grades are noticed with the addition of DTP. Many studies have investigated the interactive effects of collector mixtures. However, there have been relatively few studies on the interactive effects between frother molecules and collectors. This study investigates the interactions between different types of frothers and sodium diethyl dithiophosphate.The study found that there were large increases in pyrite and galena microflotation recoveries at both pH4 and pH9 when DTP was mixed with small amounts of frother at a constant bubble size, showing that these increases were neither mineral-specific nor pH-specific. The same effect was not present when xanthate was used as a collector. The increases in recovery when using the DTP-frother mixture were similar irrespective of the type of alcohol or polypropylene glycol frother that was used. In an attempt to distinguish the mechanism of enhanced flotation recovery, various supplementary experiments were performed. It was found through adsorption experiments that no DTP was adsorbing on to the mineral surface. Therefore, interactions at the air-water interface were performed. Surface tension and critical coalescence concentration tests showed that, while DTP is a weak surfactant at the air-water interface, it does not have a synergistic effect in the presence of frother. DTP-frother mixtures do, however, show interactions in the froth phase, indicating an interaction in the thin films. It is proposed that there is a DTP-frother interaction on the bubble surface that enhances the rate of film thinning at the 3-phase bubble-particle contact."

Jan 1, 2018

By Stanley M. Moos

In reviewing available vacuum filtration equipment in this paper, several types of filters have been included which are probably not familiar to operators in the mining industry. However, it was felt that these units might be of interest in the event that an application should arise for the filtration of a product in the future that does not exist today. In addition, exposure of our industry to equipment used in other industries might have a tendency to be thought provoking and perhaps lead to the development of equipment and/or applications in our industry which do not necessarily exist at this time. Most innovations in filtration equipment have been confined to the improvement or design change of components and accessories, particularly reflecting the availability of materials of construction that have been developed. Recent developments in the application of horizontal belt filters have been innovative. The application of this unit as a substitute for or an adjunct to thickeners in a CO circuit can certainly be innovative and perhaps provide a basis for reduction in capital and operating costs in this area. For example, mill tails are generally pumped at the highest possible density that will adequately flow. Tailings ponds and dams with their attendant design requirements are based upon this estimated water volume. Availability of a much dryer, non-flowing filter cake opens up several new options for disposal. Considerable cost savings could result in the design and planning of disposal areas for containing dryer material. . No attempt has been made in this paper to provide a manual for the operation of all of the many types of equipment that are available. Rather, the paper tries to present an overview.

Jan 1, 1978

Ok Tedi Mining Limited has recently completed the first phase of a trial to compare the performance of D26B Krebs cyclones in different configurations to the new Warman 650 mm CAVEX cyclones. From 1992, rougher flotation feed size has increased from the target d80 grind size of 150 ¦m with increasing SAG mill throughput. At high SAG mill throughput, operators have difficulty maintaining the target cyclone feed pressure and must increase the cyclone feed density, thus resulting in a coarsening of the cyclone split. Warman International have developed the CAVEX high capacity cyclone. The new CAVEX cyclones, when compared to the Krebs units appear to:produce a measurable increase in volumetric flow for the same pressure drop; maintain or decrease the proportion of coarse particles reporting to overflow; and lower the overflow density. In all plant trials to-date, the CAVEX cyclones appear to be superior to the standard Ok Tedi Krebs cyclones. Further testwork is planned to evaluate modified Krebs cyclones (with recent design improvements) against the CAVEX cyclones.

Jan 1, 2000

Power plants that utilize conventional wet flue-gas desulfurization methods produce enormous amounts of flue-gas scrubber sludge. A typical 400 MW power station that burns a high sulfur coal produces 170,000 tons of wet flue-gas scrubber sludge per year. This scrubber sludge is currently landfilled at an enormous cost to utility companies. This material could be used as a raw material for industries that use gypsum, such as the wallboard and plaster industries. However, before it can be used as feedstock for these industries, some of the impurities such as unreacted limestone and silicates must be removed from the scrubber sludge. Froth flotation has tremendous potential for separating these impurities from scrubber sludge. In order to select an optimum flotation process, it is necessary to characterize the surface properties of the major components in the scrubber sludge, which consist of calcium sulfite, calcium sulfate, calcium carbonate (limestone), and silica. In this study zeta potential measurements were used to determine the surface charge of the components in scrubber sludge, with the goal of optimizing a froth flotation process to produce a marketable gypsum product for the wallboard and plaster industries.

Jan 1, 1996

By Khiva Haidar Shauma Tassno, Zulham Ahmad, Farhan Harist Maharesi, Abdullah Badawi Batubara

Blasting operations can use a bulk emulsion explosive (EE) with a formulation based on used oil as a replacement for refined fuel oil. The most commonly employed used oil for making EE is a mineral based used engine oil that passes an impurity content standard. It is known that not all types of used oil are easily incorporated into EE formulations. Impurities in used oil can disturb EE stability resulting in crystallization and phase separation and consequently led to poor detonation quality. In 2024, a poor blast result occurred at an Indonesian mine due to utilization of used oil that was not within specification. A research project conducted from February to April 2025 found that used transmission oil differs from used engine oil in hydrocarbon composition. Transmission oil contains more additives that affect EE stability due to polarity differences and the disruption of colloidal state stability. Lab tests including stress testing and crystal growth observation aided the development of a stable EE formulation based on used oil and used transmission oil. In mid-April 2025, blast evaluations were conducted using the EE that was formulated using used engine oil and used transmission oil. Measurements of velocity of detonation, fragmentation, and digging time, demonstrated high quality EE was produced. Application of used oil in EE revolutionized the capability of mining operations to improve blast sustainability and cleanliness. Through comprehensive research, robust testing, and effective supply chain management, it is possible to replace some portion of refined fuel oil with used oil without compromising blasting performance. The inclusion of used transmission oil broadens the overall used oil specification and increases the volume of recycled used oil available for blasting. The increased volume of used oil available can reduce the amount of waste generated by mining projects while maintaining operational efficiency.

Jan 26, 2026

By Gabriel Pessoa Vilas Boas

O presente artigo apresenta um estudo sobre a mistura do nióbio em chapas de alumínio pelo processo Friction Stir Welding (FSW), levando em consideração o efeito de forjamento envolvido na soldagem. O processo FSW, consiste em utilizar uma ferramenta rotativa que em contato com o material a ser soldado gera atrito, provocando aumento de temperatura e deformação plástica. O aquecimento gerado é abaixo do ponto de fusão dos materiais envolvidos, por isso é considerado como solda em estado sólido. Para alcançar os objetivos desta pesquisa, conta-se com a colaboração da Companhia Brasileira de Metalurgia e Mineração (CBMM), que forneceu amostras de Nióbio Metálico em cavaco para proceder aos experimentos deste artigo. A amostra adquirida foi triturada manualmente, em seguida, cominuido em moinho de bola para obtê-lo em forma de pó, viabilizando, assim, a inserção na junta a ser soldada. O nióbio foi colocado entre dois metais de base de Al-Mg 5052F que foi soldado pelo processo FSW, em uma máquina adaptada para esse processo. Após a soldagem foi feito a metalografia na seção transversal onde observou-se uma boa mistura do nióbio no metal soldado. Além disso, foi analisado a microestrutura formada e a composição química através do microscópio eletrônico de varredura (MEV).

Oct 30, 2017

By Edelink Efrain Tinoco Falero

Na indústria siderúrgica integrada, geram-se vários tipos de coprodutos, dentre estes escoria granulada de alto forno, os pós de aciaria extraídos nos sistemas de despoeiramento a úmido e a seco do conversor LD e o pó de coletor de alto forno. Em relação aos pós, são principalmente portadores de unidades de ferro e carbono, podendo conter também zinco, o que os tornam alvos de estudos e inovações que buscam recuperar ou reciclar estes elementos. No presente estudo foram concebidos briquetes autorredutores usando os pós finos-F e grossos -G, oriundos de um sistema de despoeiramento a seco de aciaria LD, nas proporções percentuais, F – G, de 50-50 e 70-30, misturados com pó de coletor de alto forno. Utilizando como aglomerante o cimento ARI, foram avaliadas as resistências à compressão dos briquetes em diferentes tempos de cura e determinadas suas metalizações nas temperaturas de 1100°C e 1150°C, em tempos que se estenderam até 45 minutos. Adicionalmente, as capacidades dos briquetes de alterarem a temperatura do aço liquido quando adicionados ao banho, foram avaliadas utilizando-se o balanço térmico do sistema briquete-aço liquido, bem como considerados os potenciais de oxidação do processo e o estabelecimento de um sequenciamento termodinâmico para as reações. Os resultados mostraram que os aglomerados autorredutores possuem alta capacidade refrigerante quando adicionados ao aço liquido, o que os enquadra como possíveis materiais alternativos à sucata e pelotas no controle da temperatura do aço nos convertedores LD. Além disso, a alta cinética de metalização do Fe mostrou ser também viável o uso dos briquetes autorredutores na recuperação do metal contido nos resíduos.

Oct 30, 2017

By Samuel Rigert, Marco Bettelini

"INTRODUCTION AND OBJECTIVES Long rail tunnels require in most cases powerful mechanical ventilations. Besides requirements related to normal operation and maintenance, operational safety always requires a high level of smoke management. Identifying the optimum ventilation concept is essential for achieving proper performance and safety while keeping investment and operational cost at a reasonable level. For the purpose of the present paper, long tunnels have a length of typically 20 km or more. This is related to the European classification of trains (TSI 1303/2014), where the maximum distance from the portals to a firefighting point and between firefighting points is limited to 20 km (only category B passenger rolling stock allowed) or 5 km (general case). From TSI 1303/2014 it can be concluded, that tunnels over 20 km require in any case emergency stations with complex mechanical ventilations. Based on the experience arising from a number of recent projects in the European area, including in particular Gotthard (GBT), Lötschberg, Lyon-Tourin (LTF), Brenner (BBT) and Gibraltar, safety-relevant issues related to the ventilation of long railways tunnels are reviewed in this paper. Amberg Engineering is directly involved in these challenging design tasks and can provide first-hand experience and know-how. As a particular highlight, special attention is devoted to the longest tunnel worldwide, the 57 km long Gotthard Base Tunnel, which will be commissioned in 2016. THE GOTTHARD BASE TUNNEL Overview The Gotthard Base Tunnel will be commissioned in 2016 (official inauguration on the 1st of June and beginning of regular operation on the 11th of December) and will be the worldwide longest tunnel. Its complex and powerful ventilation system is very representative for many other long tunnels and is used as reference in this paper. Therefore, a few key characteristics of the Gotthard Base Tunnel and its ventilation system will be described in some detail in this initial chapter. The Gotthard Base Tunnel (GBT) consists of two single-track tunnel tubes with connecting galleries every 312 meters. Two so-called multi-functional stations (MFS), located at roughly 1/3 and 2/3 of the tunnel length, host the key equipment for normal and for emergency operation. At these locations, double crossovers allow trains to switch from one tunnel tube to the other. An emergency station is located in each multifunctional station, allowing trains to stop in case of emergency. The general layout of the GBT is presented in Figure 1."

Jan 1, 2016

By Chi Zhang, Junyi Wu

"With the increasing popularity of lithium cobalt oxide in lithium ion battery industry, which is driven by new energy vehicle and mobile device applications, the demand of cobalt is also growing rapidly in recent years. There is a significant trend of increasing investment on cobalt capacity in China, and the automation renovation is considered as an option of improving production efficiency. This study aimed at evaluating the practicability of stainless permanent cathode blank and automatic stripping process in cobalt electrowinning process. The purpose is to replace the old starter sheet process in cobalt electrowinning, which so far was used by most of cobalt refineries in China, but very labor intensive and exposed operators to serious aerosols that contained both cobalt and acid. In the old starter sheet process, the initial cobalt starter sheet is produced onto a plate made of titanium, while the titanium cathode blank and hanger bar fit the critical corrosive environment but is lack of mechanical strength for automatic production which has been mature in copper electrowinning process. To evaluate the proper materials instead of titanium, the coupon corrosion tests with different raw materials including 316L and other stainless steel grades were held for several months in production environment at a cobalt tank house in China. Following the comparison between titanium and other tested materials, a pilot production test in a cobalt tank house is also on-going.INTRODUCTION Cobalt has been known in early China and used in pottery glazes, and the ancient Greeks and Romans used its compounds to make colored glass since long time ago. The blue on the colored porcelain from the Tang Dynasty in China was also due to the presence of cobalt compounds. The word cobalt is known being derived from the German kobalt, from kobold meaning ""goblin"", because the cobalt-bearing blue ore, CoAsS, was called kobaltin in Europe in the Middle Ages, it may have been thought to be harmful to the health of the miners because of arsenic in the ores."

Jan 1, 2018

By Yvette Heritage

"The risk of fatalities from rib failure is still prevalent in the coal mining industry. This risk has prompted further research to be conducted on rib deformation in order to understand the mechanisms of rib failure, with the long-term objective being to improve rib support design. This paper presents the results of ACARP research project C25057, which investigated the mechanics and drivers of rib failure. The results of rib deformation monitoring at three different mines in Australia provides rib deformation characteristics for overburden depths ranging from 160 m to 530 m. Monitoring includes deformation during development drivage conditions and during the longwall retreat abutment stress environment. The rib deformation monitoring covered three different seams: the Goonyella Middle Seam, Ulan Seam, and Bulli Seam in the Bowen Basin, Western Coalfield, and Southern Coalfield, respectively. The observed mechanisms driving the rib deformation ranged from bedding shear failure along weak claystone bands to vertical shear fractures to kinematic failures driven by shear failure dilation. The variation in mechanisms of rib failure, together with the seemingly consistent method of rib support design, prompts the question: What exactly is the role of rib support?INTRODUCTIONThe current risk of rib fatalities in the coal mining industry has prompted further research into understanding the mechanisms of rib failure. Three Australian mines assisted further research by providing sites for rib deformation studies as part of the Australian Coal Association Research Program (ACARP) project C25057. The mines included in this study were Moranbah North Mine, Ulan West Mine, and Appin Mine. This paper provides key results of the rib deformation monitoring relevant to assessing the mechanisms of rib deformation.The approach of monitoring rib deformation and rib support loads was used to measure and characterise the dynamic rib deformation present in both development and longwall retreat stress environments. The characterisation of rib deformation, together with rock failure modelling, was used to determine the mechanisms for failure within the rib and to assess the interaction of rib support with the failure process. The mechanisms of rock failure are considered an important factor in understanding the drivers for the failure. Consideration of the site-specific failure mechanisms can provide for a more tailored support design."

Jan 1, 2018

By M Jones

The past 100 years the mining industry can be characterised by a focus on increasing financial returns often to the detriment of social, human, manufactured and environmental capitals. Despite the sustainable development principles promoted by the International Council on Mining and Metals (ICMM), the Equator Principles and the African Mining Vision, which should have enhanced project promoters’ ‘licence to operate’ within a host community or nation, the industry has often failed to integrate proven innovations and best practices that enhance sustainability outcomes for mineral resource projects. This failure has led to delays, the abandonment of projects, with value destroyed for promoters, governments, host community and investors.The paper will outline the application of proven innovations, Enterprise Optimisation (EO), and Sustainable Operations (SUSOP®), during the pre-feasibility phase of a project. By determining the value of each capital before and after the application of proven innovations, the presentation will outline how and where value can be created across all five capitals over the life of a project or operation.The paper will demonstrate how the application of proven innovations significantly transforms the value-proposition of a mineral resource project or operation by generating additional value across all of the five capitals, reducing project risk, thus generating value for all stakeholders.CITATION:Jones, M, 2015. Fundamentally transforming the economic and sustainability signature of mining assets, in Proceedings Third International Future Mining Conference, pp 169–180 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By T. McCallum, C. Cooper, C. Lewis

"Following a successful solvent extraction (SX) pilot plant demonstration in 2016, CYANEX® 600 has been used commercially to recover molybdenum from concentrate leach liquor since March 2017. Consistent with the piloting results, the commercial plant has achieved expected molybdenum recovery, a significant reduction in base consumption, and a step-change improvement in physical performance. This paper highlights the optimization activities and plant performance from startup through normal operation. INTRODUCTION Historically, tertiary amines have been the most commonly used extractant for molybdenum and rhenium recovery. Tertiary amines utilize a protonation of the ligand combined with an anion exchange mechanism as proposed in equations (1-2). R3N + H+ ???R3NH + (1) 4R3NH+ + Mo8O264- ???(R3NH+)4Mo8O264- (2) In addition to the transfer of Mo and Re, the amine transfers acid and other anions to the strip liquor. The undesirable transfer of other species increases base consumption during stripping, impacting operating costs. Additionally, lower solubility of molybdenum-amine complexes create operational challenges, resulting in diminished physical performance. The presence of colloidal Si in concentrate leach liquors and the formation of Pickering Emulsions adds to the physical plant performance challenges with the amine extractant. CYANEX® 600, a phosphinic acid-based extractant, uses a cation exchange mechanism proposed by equation (3). 2(H2R2) + MoO22+ ??(HR2)2MoO2 + 2H+ (3) The cationic exchange mechanism eliminates chemical transfer of acid and other anionic impurities and avoids some of the physical challenges of the amine extractant (emulsion and 3rd phase formation). In addition, the reagent offers high selectivity for Mo over Re, which may be desirable in certain moly pressure oxidation (POX) flowsheets. Alkali base (ammonium hydroxide, sodium hydroxide, sodium carbonate, etc.) is used for molybdenum stripping. Therefore, reduction or elimination of chemical acid transfer from extract can significantly reduce base consumption in strip. Extensive laboratory and pilot plant testing was completed to evaluate the use of CYANEX® 600 for molybdenum recovery at Freeport-McMoRan’s Bagdad operation. The test work and pilot demonstration confirmed a reduction in base consumption along with improved selectivity. In addition, the evaluation highlighted a step-change improvement in physical performance over the incumbent amine extractant. The decision was made to convert the commercial operation to CYANEX® 600 in March 2017."

Jan 1, 2018