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By A. Javadi

"Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Bama concentrator in Iran but with the addition i) Na2S reductant and ii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid.INTRODUCTIONOur recent studies have illustrated the formation of hydrogen peroxide (H2O2) by metal-sulphides during grinding in the presence and absence of oxygen (Javadi Nooshabadi & Hanumantha Rao, 2013a; Javadi Nooshabadi & Hanumantha Rao, 2013b; Javadi Nooshabadi & Hanumantha Rao, 2013c; Javadi Nooshabadi & Hanumantha Rao, 2014). In the absence of oxygen, it was found that pyrite surface is catalytically active and able to breakdown water molecules to form OH• free radical and thereby deriving oxygen in the formation of H2O2 from water molecules. The in-situ formation of H2O2 and its influence on sulphide flotation has not been addressed yet. The presence of strong H2O2 oxidant in the pulp liquid and its selective oxidation of pyrite would be beneficial in depressing pyrite flotation. Therefore, it is important to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp as well as to study possible ways of flexibly controlling the formation of these species through known chemical means for depressing the generation of the oxidant."

Jan 1, 2018

By C. C. Hawes

SILICA is the main impurity in iron ore. It is intimately associated with the iron oxide, sometimes free but more often in the combined state, as a mineral silicate. Its separation and purification sometimes present difficult problems to the analyst. In the absence of any definite knowledge to the contrary, orthosilicic acid. H4SiO4, is supposed to be the only silicic acid made, all other forms, such as metasilicic acid, H2SiO3, representing different degrees of its dehydration. These acids are exceedingly weak but form the most stable compounds found in nature. They are known as the silicate minerals and are formed by the combination of the different metallic oxides

Jan 1, 1936

By B. E. Warren

Jan 1, 1965

By F. Calizaya

This study summarizes the results of various numerical and laboratory experiments per-formed to study the effect of airflow recirculation on gas concentration. The numerical exercises were carried out on a simulated mine ventilation net-work. The laboratory experiments were conducted at the Mackay School of Mines' airflow monitoring system in Reno, Nevada. In both cases, the airflow was recirculated through the system by means of a main fan and a set of booster fans. The booster fans were positioned to produce two types of recirculation: In line and Cross-cut. For each type, various recirculation conditions were generated by changing the booster fan pressure. During each test, the gas emission rate at the simulated working face was kept constant. The study illustrates the conditions under which controlled airflow recirculation may be used to solve a district ventilation problem.

Jan 1, 1991

By W. G. Pfann

A simple method of obtaining multistage batch separations by crystallization was described recently. Known as zone-refining, it comprises passing short molten zones through a long solid charge. This technique can now be used on a continuous basis by means of the zone-void method described in this paper. Feed enters, at an intermediate point, a column down which molten zones travel, and waste and product leave at the ends. Materials move in the column through the agency of voids, which are introduced at the ends and travel toward the feed inlet. The voids and molten zones are moved by external heaters in a simple manner, and the principle of reflux is utilized. ANEW method of obtaining multistage separations by crystallization was described recently.' Named zone-refinina.,-, the method comwrises slowly passing a series of molten zones through a long solid charge. Solute becomes concentrated at one or the other end of the charge, depending on whether it raises or lowers the freezing point of the solvent. The separation increases with the number, P, of zone-passes, approaching a limit as P approaches infinity. Zone-refining has been highly effective in purifying germanium and other substances.2,3 and new applications are steadily increasing. Zone-refining is a batch method and as such it has certain limitations inherent in batch operation. If it could be made continuous, its scope and utility would be greatly broadened. This end has been achieved by the zone-void method described in this paper. In the zone-void method feed is introduced continuously at an intermediate point in a column down which molten zones travel, while impure waste and purified product leave at the ends. Both the flows of feed, waste and product, and also the travels of the zones, are actuated by external moving heaters in a simple manner; and the system utilizes the principle of reflux. The method provides, in the field of crystallization, the counterpart of the continuous fractiona-tion column in the field of distillation. The following will be discussed: apparatus and mode of operation, fundamental nature of the separation, design theory, and practical considerations. The method will be described in terms of a binary solute-solvent system in which the solute is an impurity to be removed and the solvent is the desired product. The distribution coefficient, k, defined as the ratio of solute concentration in the solid freezing out of a molten zone to that in the liquid in the zone, is assumed to be constant and less than one. The process is equally effective for k's greater than one and for ternary or higher order systems. Method and Apparatus The essential features of a continuous zone-refining process are represented in highly generalized form in Fig. 1. A series of molten zones, produced by moving heaters, travels slowly down the column or charge (to the left in Fig. 1). If there were no flows of feed, waste, or product, the process would simply be batch zone-refining, the action of the molten zones being to sweep solute down the column, solvent up the column. For the process to be con- tinuous, with stripping and enriching sections in the column, feed must enter, and waste and product must leave, as indicated. The zone-void process accomplishes both objectives, namely, the indicated movements of zones and the indicated flows of material. Zones are moved by moving heaters, just as in batch zone-refining. Materials are made to flow by creating voids at the waste and product exits and causing these voids to move to the feed inlet. Since there must be a net flow of material from the feed inlet to each of the outlets, the indicated movements of voids are in the desired directions, because movement of a void in a given direction corresponds to flow of material in an opposite direction. In order to produce the desired movements of voids, the column is folded into two vertical sections having the feed inlet in common at their upper ends. Voids are displaced upward by the liquids in the molten zones and their travel is actuated by the motions of the zones. Voids travel with the zones in the enriching section and move continuously. Voids travel opposite to the zones in the stripping section and move intermittently. Creation and travel of voids will now be examined in detail. The enriching section of a column in operation, with its void generator, is shown in Fig. 2. The column section is a vertical tube around which a series of closely fitting, regularly spaced heaters travel slowly upward. Each heater produces a molten region, the temperatures of the heaters and the cooling between heaters being controlled so as to maintain the molten zones approximately constant in size. A void is normally present atop the molten zone in each heater. As the heater rises, it continuously melts solid above it, which drips through the void into the molten zone and continuously freezes out solid below it, of concentration k times that of the liquid in the zone. When a molten zone and void reach the feed inlet, which is kept molten, the void is displaced by an equal volume of feed liquid. Generation of voids of controlled size in the enriching section is shown in Fig. 3. The void generator is a tube of small cross-section, provided with lateral heat-conducting fins which sense the position of the heater. Liquid can escape only when the entire outlet tube is within the heater. If any part of the outlet tube is outside the heater, liquid cannot escape,

Jan 1, 1956

By R. Sellaro

It has long been understood that extended occupational exposures to respirable mine dusts can lead to chronic lung disease. In underground coal mines, coal workers pneumoconiosis (CWP) and silicosis are major concerns. While there have been many studies aimed at understanding total dust concentrations and silica content associated with different mining conditions (e.g., locations/occupations within a mine, cutting methods, geologic strata), little research has been completed to more comprehensively characterize respirable dust (i.e., by distributions of particle composition, size or shape). For such analysis, scanning electron microscopy with energy dispersive X-ray (SEM-EDX) may represent a powerful tool. This article is a preliminary investigation of SEM-EDX to characterize respirable dust from an underground coal mine in Central Appalachia. Samples were collected from various locations in the study mine, and individual dust particles were identified and classified by mineral type. A continuous personal dust monitor was also used to estimate respirable dust concentrations during sampling. This data was compared to particle densities observed under the SEM. Dust is generally defined as small, solid particles with an effective diameter between 1 and 100 µm. In underground coal mines, dust is produced by a variety of activities such as coal and rock cutting, materials handling, haulage and from a variety of materials. While the coal itself is primarily made up of organic carbon, it is estimated that as much as 60 percent of coal mine dust consists of mineral matter, including clays, metal oxides and sulfides, carbonates, quartz, phosphates and heavy minerals (WHO, 1997). Mineral matter may be ingrained in the coal seam or associated with adjacent or interlying strata, and may also be contributed by specific activities such as rock dusting. When dust is generated or made airborne, suspended particles tend to settle slowly with gravitational forces, but can remain airborne for extended periods of time depending on environmental conditions such as air velocity (Courtney et al., 1986) and particle properties such as size (ISO, 1995; WHO, 1999). Thus, miners working underground are routinely subject to occupational dust exposures ? with highly variable characteristics between and even within mines.

By R. W., Ludt

THE use of froth flotation for the separation of minerals has become one of the most important of ore dressing processes. Its particular adaptability to the enrichment of low grade ores has made the process an important factor in the national economy. The methods have been extended to the recovery of a great number of minerals. Among the few minerals which have resisted efforts toward industrial flotation is chrysocolla, a hydrated partly colloidal copper silicate. Chrysocolla, being a product of natural oxidation, has been found to occur in small quantities with many ores which are recovered by flotation methods. In present practice, these small quantities of copper silicate pass off with the tailings and are lost. The advantages to be gained by a satisfactory process for the recovery of chrysocolla is apparent. Any application of principles which points a way toward the satisfactory industrial flotation process for copper silicate would be of advantage. This paper presents an attack on this problem.

Jan 1, 1949

By Fernando Rodríguez

El artículo busca responder a esta interrogante: ¿cómo hacer para reactivar la minería y, a la vez, elevar nuestras prácticas de responsabilidad en el marco de los Objetivos de Desarrollo Sostenible (ODS) de las Naciones Unidas al 2030? El escenario de “nueva normalidad” post pandemia COVID-19 implica, para el sector de la gran minería, implementar formas innovadoras de explorar, diseñar, construir, operar y cerrar minas. Si bien el desafío es grande, esta situación constituye una oportunidad única para liderar la reactivación económica del país, de la mano de prácticas de responsabilidad social y ambiental ejemplares, que apunten a una mayor contribución al desarrollo sostenible.

Jun 30, 2020

By Franklin M. Grynkewicz

As part of the Boston Harbor clean up project, the new 1,000 mgd Deer Island Sewerage treatment plant includes ten 240 feet high egg-shaped "residuals" tanks. Contract documents called for these structures to be supported on 2,600 sixteen inch concrete filled pipe piles. The project site is underlain by highly variable glacial and marine deposits. Subsurface conditions vary from one extreme where firm glacial deposits exist at subgrade to the other extreme where 70 feet of medium stiff clays overlying weathered bedrock must be dealt with. The most common profile consisted of 15-20 feet of sands, 20-40 feet of marine clays, and 20-60 feet of stratified glacial deposits (commonly called tills) overlying Argillitic bedrock. Post bid redesign work, initiated as a cooperative effort between the owner and the general contractor, demonstrated that an $8 million savings could be realized if high capacity 48 inch diameter caissons replaced the specified pipe piles. A highly unusual arrangement of having the general contractor and specialty subcontractor providing input to the owner's engineering team allowed the redesign work to proceed on a "fast-track" schedule.

Jan 1, 1992

By Arne Landsberg

The Bureau of Mines has undertaken research to elucidate the chemistry involved in the efficient recovery and control of minor elements in base metal smelting operations. These elements should be effectively recovered not only because they have commercial value, but also because of their potential hazard to workers' health and the environment, if they are not controlled during processing. Cadmium, a minor metal in zinc ores, is the subject of this report. The roasting step of the complex zinc-smelting process was chosen for investigation because of the high potential for removing cadmium by volatilization during this primary stage. Commercial roaster feed materials were used to determine the sequence of reactions and the effect of these reactions on the volatilization of cadmium. Electron microprobe examination of both the commercial roaster product and oxidized sulfide solid solutions prepared in the laboratory showed that oxidized iron was of prime importance in preventing cadmium volatilization. The mechanism by which iron prevents cadmium volatilization is proposed, and a preheating technique is recommended for more effectively recovering cadmium prior to roasting.

Jan 1, 1981

By B. Zeifert, C. Martínez-Morales, A. Romero-Serrano, A. Pineda-Rivera, H. Martínez-Gutiérrez, G. Diaz-Sandi

In this work, the effects of CaO/SiO2 ratio and the FeSO4 and FeS2 contents on the stability of the mineralogical species in chromium-based slags were studied. The chemical stability was evaluated by leaching with an acid solution. The main Cr-compounds in slags with FeSO4 and CaO/SiO2=1 were FeCr2O4 and Ca3Cr2Si3O12, while Cr3S4 predominated in slags with FeS2. The slags with CaO/SiO2=2 mainly contained CaCr2O4. The highest Cr concentration levels in the leaching liquors corresponded to slags with CaO/SiO2= 2, and the lowest Cr concentration corresponded to slags with high FeSO4 or FeS2, owing to the stable binding of chromium in the compounds FeCr2O4, Cr3S4 and FeS•Cr2O3.

Jan 1, 2011

By Madan Kumar Annam, Hari Krishna Y, I. V. Anirudhan

"For completion of projects in time with positive results, improvements of productivity and effective project management procedures have become extremely important. This paper discusses a milestone project comprising 198 residential units of stilt plus 4 levels that highlighted the benefits of these key aspects. Success of ground modification procedure benefitting the entire cycle involving End Users, Suppliers, Bankers and Developer is discussed.Soil profile for a considerable depth comprises weak layers of silty clay and sandy clay with varying consistency. Deep foundations have been an automatic choice of foundation for major buildings constructed in similar environment. After serious geotechnical appraisal, reconsideration of the foundation system with an alternative solution of Ground Improvement was found to be optimal in terms of Cost and Time. Full raft foundation on the improved ground by installation of Vibro Stone Columns (dry bottom feed method) was considered as an alternative foundation system. The ground improvement works were completed within 6 weeks (as against 6 months to that of pile foundations) that was made possible through effective project management. Full size plate load tests were conducted to ascertain effectiveness of the ground improvement works. Success of the foundation system was proved by full scale monitoring of foundation settlement during and after completion of the project over a span of 2 years. This paper describes design considerations, quality control in the construction of Vibro Stone Columns (dry bottom feed method) and performance monitoring of the project thereafter.INTRODUCTIONGenerally in weak deposits, deep foundations like bored cast-in-situ piles and driven piles have historically been the foundation choice for major buildings and other structures. Construction of pile foundations is becoming a challenge due to their high cost, large construction time and due to severe environmental issues (noise pollution, ground vibrations and carbon footprint). Since the proposed building complex is located within the proximity of a well-developed residential locality, objections raised by neighborhoods to pile driving activities called for a rethinking on the foundation system.The top 6m to 8m of soil profile comprises of silty clay / sandy clay having highly varying consistency. GWT was encountered at 3.0m below the existing ground level. Under this situation, the reconsideration of the type of foundation system with respect to the geotechnical analysis gave a thought to assess feasibility of ground improvement system."

Jan 1, 2015

By J. H. Walsh

IN THE DEVELOPMENT of procedures for the separation of minerals, the choice of reagents for flotation is frequently determined by the extent to which a given mineral is wettable by water. Measurements of the contact angle of an air bubble on wet mineral surfaces are often used in the laboratory to estimate the wettability of the surface. For the results of these measurements to be reproducible, the surface of the mineral must be polished to a mirror-like smoothness and must be free from oily contamination. Elaborate procedures for preparing mineral surfaces have been developed by Wark ( 1) and Taggart (2), and these procedures have been generally accepted as adequate for their purpose. The polishing techniques, how-ever, have certain inherent disadvantages which make it impossible to assess the effects of polishing, entrained abrasive, and adsorbed gases on the wettability of the mineral surface.

Jan 1, 1957

By Richard S. Dennis

Acid recovery employs ion exchange (I-X) resin as separation media for inorganic acids from dissolved metallic salts by physical adsorption and without the use of chemicals. This technology has been used for years on spent etching and plating liquors to recover acid for reuse in the bath and to reduce waste acid neutralization costs. It is also used for electrolyte treatment to facilitate valuable metal recovery via acidity reduction. TETRA's ccrxr'" I-X contactor has been used successfully for acid separation from its metallic salt counterpart in a simple, continuous operating mode using strong base anion resins. Efficient separation is enhanced by acid reconcentration to nearly its original strength or as high as 14-20%. Continuous treatment also recovers heat to the tankhouse or bath and improves metal quality due to consistent acid quality. Conventional fixed bed ion exchange (I-X) systems are impractical for acid recovery because of complex control design and large resin inventories needed to process very low liquid-to-resin treatment ratios associated with strong acid concentrations.

Jan 1, 1996

By Charles "Chick" Rodgers, Anthony Sarion

"With declining feed grade and increased production targets, it became necessary to upgrade Key Lake's eight stage counter current decantation (CCD) circuit. Following laboratory trials, mill operations recognized that dilution of the feed slurry and buffering of the feed density variations would improve thickener throughput. Plant testing resulted in the installation of Outokumpu's Supaflo ""Floe-Miser"" system. The circuit's flowsheet, instrumentation and control strategy were also upgraded along with the thickener feedwell modifications. The paper will also discuss these modifications and the implementation of the current control strategy.IntroductionCameco Corporation's Key Lake operation is the largest single uranium producer in the world. Current production is fourteen million pounds of uranium oxide (U 308) per year. It is owned 2/3 by Cameco and 1/3 by Uranerz Exploration and Mining with Cameco as the operator.The mine is 570 kilometres north of Saskatoon on the southern edge of the Athabasca basin. Access to the mine is by an all-weather road and a private airstrip.Process DescriptionThe Key Lake milling process consists of five individual plants: crushing and grinding; leaching and counter current decantation (CCD); solvent extraction; yellowcake precipitation and ammonium sulphate crystallization; and bulk neutralization (Figure 1 -Simplified Mill Flowsheet). A detailed mill flowsheet can be found in the appendix."

Jan 1, 1998

By Paul S. Korinko, Simona E. Hunyadi Murph

To address a radiological contamination event, a materials and process project was initiated. During the course of this project, processes and materials were developed that successfully captured zinc vapors physically and chemically, respectively. However, the physical traps were placed in an undesirable area and it was determined that the chemically captured zinc reactions was reversible. Consequently, advanced nanomaterials are being developed to capture zinc vapors. The current state of the art of the science and engineering of these materials and their efficacy for zinc capture and retention is discussed in this paper.

Jan 1, 2015

By Chuanfu Zhang

Based on Thermogravimetric and Differential thermal analysis (TGA-DTA), porous copper powder is prepared by thermal decomposition of complicated copper oxalate. The effects of various conditions on the morphology, crystalline grain size and specific surface area of copper powder were investigated, including temperature, duration, mixing ratio of nitrogen and hydrogen. Furthermore, composition and morphologies of the products were characterized by X-ray diffraction (XRD), Scanning electron microscope (SEM) and BET adsorption isotherm. It is found that porous copper powder was produced under optimum conditions. The specific surface area is over 6.74 m2?g-1, and average pore size in particles is about 30.3 nm. After comparison of SEM images, the final product Cu well inherits the morphology of the precursor, thus a mechanism of in-situ decomposition is proposed.

Jan 1, 2009

By K McSweeney, A Marton

This paper discusses the development of a strategy for ensuring long-term geotechnical stability of final pit walls at AngloGold AustraliaÆs Sunrise Dam Gold Mine. The strategy makes use of improved blasting techniques, changes to the mining sequence and other geotechnical techniques. Only the blasting techniques will be discussed in this paper. These were developed from numerous trials over a period of several months from May 2003 through to November 2003. The focus was to reduce crest loss damage and thereby improve final wall integrity, maintain designed safe berm widths, and ensure long-term stability. Crest loss mechanisms are now understood and are explained in this paper. The preferred solution is outlined; which is a combination of improved blasting and changes in the mining sequence to cater for pre-existing ground conditions. These ground conditions include dynamic hyper saline water with sometimes intersecting steeply dipping discrete structures. Project requirements were defined as mitigating or eliminating crest loss using 127 mm diameter pre-splitting and targeting minimal production blasting vibration levels against the walls. Blast results were measured by post blast visual inspections and video. Blast design input utilised the predictive algorithms built into simulation software when attempting to minimise vibration levels against the walls. Protection of the already fired pre-split line is now achieved using small charges against the wall and timing sequences which form a mask for the later firing main charges. The pre-split spacing is now modified to suit the geology. There eight blast domains identified around the perimeter of the pit, each having varying joint orientation. In addition, blasting the bench adjacent to the berm crest has particular considerations not required by the middle and lower benches. The preferred solution was to purposefully translate this damaged top section of the pre-split bench into a planned subsequent dig zone. The design of this top æweightÆ is a direct response to the nature of the crest loss mechanism.

Jan 1, 2004

By G. F. Weaton

1.1 The purpose of this paper is to show the way by which estimates are made of the tonnage and grade of iron ore and taconite reserves of Minnesota. 1.2 The procedures include those of estimating the open pit reserves of: (a) Natural iron ore, and (b) Taconite 1.3 The methods of estimation which will be discussed are primarily based on the information from exploring iron ore deposits. They consider the geology of the deposit as well as the contained mineral of potential value. 2.0 Some geologic, engineering, and economic principles. 2.1 Ore 2.11 "In the broad economic sense, and from a legal standpoint as well, ore is mineralized rock, which under appropriate conditions of time, space, technology, economics, and politics, can be mined, processed, and made to yield a saleable metal , or other mineral products at a profit."(Parks, 1957) Stated differently, metallic ore is rock material from which presently known methods of beneficiation, a merchantable concentrate, suitable for use in the manufacture of metals at a profit, can be produced. Crude ores as low as 0.38% metal, as in the case of copper and even lower in the case of the precious metals.

Jan 1, 1985

By Hamed Layssi, Farid Moradi, Thomas Tingson

This paper describes the feasibility and pilot study of of using existing non-destructive testing solutions for evaluating structural integrity and mechanical performance of mass concrete foundations. This paper includes two pilot studies using well-known NDT methods (i.e., Crosshole Sonic Logging and seismic tomography) for new applications (i.e., NDT inspection of mass concrete foundations). In the first case, we will examine an existing mass concrete foundation block with internal cracking, which has negatively impacted the strength and stiffness of the foundation block. A combination of pulse velocity and 2D tomography was used to evaluate the structural integrity in the foundation block. In the second case, the quality and integrity of newly built mass foundations were evaluated using Crosshole Sonic Logging (CSL). The methods are combined to locate potential sub-surface defects such as large voids and discontinuities. This paper aims to study the effectiveness of the NDT methods of Deep Foundations to assess the quality and structural integrity of new and existing mass foundations and explore the opportunity to extend the capabilities of these tests beyond their conventional use.

Sep 8, 2021