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By B. R. Broekman, D. W. Penman

Discussion by P.J Lloydt Broekman and Penman describe (J.S. Afr. Inst. Min. Metal., vol. 91, Aug. 1991, p. 261) the addition of sodium cyanide and zinc sulphate to the flotation feed at Prieska. They note that for 'safety sake, lime was added to the rod mil to raise the pH to 9,5', and that 'personnel working in the vicinity of the rod mil were required to wear gas masks'. Author reply to P.J. Lloyd We thank Dr Lloyd for his interesting contribution. As he correctly points out, the Prieska float had run with cyanide solutions at pH values of 6,4. In fact, it ran safely for extended period with the pH slightly below 6.

Jan 1, 1991

By Yosuke Ota, Makoto Tawara, Tetsuya Kojima

"Dry-lube has been used in Europe to enhance formability of aluminum sheet for automotive applications, but it is difficult to ensure degreasing performance with lower degreasing bath temperature. However, newly developed, highly lubricating pre-coats utilizing a urethane resin, which is soluble in water, have been found to show excellent degreasing performance. Furthermore, a richer pre-coat weight coincides with a lower friction coefficient and better formability. Combined use of anti-rust liquid oil showed different friction coefficient depending on applied surface pressure.INTRODUCTION The global demand for aluminum alloy products, especially for automotive application, has been increasing because aluminum alloys can offer excellent corrosion resistance with good strength and low density compared with steel. Aluminum alloys can contribute to saving much more energy and greenhouse gas emissions over the lifetime of the product. On the other hand, the amount of aluminum alloys in vehicle architectures is still somewhat limited due to relatively low formability. As a consequence of this low formability, it is necessary to set a certain limit to the shape of an aluminum alloy panel for automotive applications. So far hot melt wax dry lubricants have been in use especially in Europe as they have been recognized to provide better lubrication than conventional rust protection oils (Meiler & Jaschke, 2005). The benefit of hot-melt wax for automotive manufacturing is associated with a more stable forming process and the possibility to avoid extra lubrication in the press shop. But because of the low poorer solubility of hot-melt wax in degreasing aqueous bath solution, a higher degreasing temperature is required so that no remnant of hot melt wax can be carried over to the next manufacturing process. This temperature control is difficult to impress upon a manufacturing degreasing bath originally designed for liquid oil, especially in Japan. The typical temperature of degreasing bath in Europe is around 60°C, while it is only around 40°C. in Japan. Various types of pre-coats other than hot-melt with high lubricity have been reported (Tawara, 1993; Ueda, Hatsuno & Totani, 2013), but a balance between sufficient degreasing performance and high lubricity has not yet been achieved for an actual production process line."

Jan 1, 2018

By V. Yahorava

Mintek has developed a non-destructive Resin-in-Leach method for the recovery of Rare Earth Elements (REE) from phosphogypsum (PG) waste dumps. However, PG from different sources was found to be highly variable in terms of REE recovery and physical properties. Development of a pre-treatment process was initiated to improve the robustness of the current REE recovery process in order to render it effective for any type of PG. Extensive research into the mineralogy of REE associations with PG revealed that the majority of REE are trapped inside phosphogypsum clusters which inhibits their recovery. Hydrothermal treatment of PG-containing slurry was found to result in re-crystallisation of gypsum with the release of REE phases encapsulated in it. This process was tested on various PG samples and subsequent REE recoveries improved from 5 to 80%. This approach carries a large potential for unlocking value associated with gypsum dumps worldwide.

By J Heyes

Historically mining engineers haven't spent enough time planning waste dumps, but waste movement costs often outweigh ore haulage costs. There is a real incentive to plan waste dumps right the first time to minimise rehandle and final closure costs. At BHP Billiton Iron Ore there has been an increasing sophistication in waste dump design and they are becoming as important as the pit design. Closure landforms are now included in mining studies. Closure is embedded in the business planning cycle. The results from the recent life of mine study at Whaleback is a case in point where a base case of the shortest hauls with no closure constraints was compared against a closure case. A properly planned and executed waste plan revealed that no rehandle was required and haulage costs were eight per cent less if closure design implementation was carried out concurrent with mining. At cessation of mining the landforms were such that decommissioning of critical acid rock drainage dams and coverage of exposed pyrite areas could occur straight away, without the need for additional rehandle.  The paper also covers design and scheduling elements of waste design both in-pit and ex-pit, management of potentially acid forming material (PAF) and trends in PAF management and designing for final landform closure. This paper illustrates that there is value in terms of costs savings, sustainable outcomes and reputation if the mine planners are involved in the closure planning process.

Jan 1, 2009

By K. E. Waters, M. Mirnezami, R. Gauvin, A. Jordens, K. W. Malas

"There is currently very little information on the physico-chemical properties of rare earth elementbearing minerals, or on their processing. With the increasing demand for rare earths, this is something that needs to be addressed. This paper introduces some surface chemistry analysis of fergusonite (YNbO4), and the bubble-particle attachment. Zeta potential measurements indicate adsorption of sodium oleate and, to a lesser degree, potassium amyl xanthate onto the surface, and an increase in attachment to an air bubble is observed at pH 4.5 and 6.5. At a pH of 10.5, no attachment is observed, whether in the presence of the reagents or not. This analysis, although initial, will be used to initiate flotation tests, in order to facilitate the selective recovery of fergusonite. INTRODUCTIONRare earth elements (REE) are increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. An article in the New Scientist highlighted the importance of a number of REE, many of which most people are be unlikely to have heard mentioned (Crow, 2011). From batteries (lanthanum and cerium) to magnets (dysprosium and neodymium) and lighting (yttrium), the REE are crucial to the advancement of technology and energy saving devices. For example, neodymium is finding most use in the high end magnets that keep the motors turning that power wind turbines and electric cars. In the case of yttrium, the demand outstripped the supply in 2010, emphasising the need to develop deposits containing this and other REE (Crow, 2011). The impact of our dependency on REE has become even more apparent with the reduction in exports by China, which currently controls 97 % of the world’s rare earth production (Pitts, 2011).With the increasing demand for rare earth elements (REE), there is a drive to exploit the known resources around the world. However, the physical beneficiation of the rare earth element bearing minerals is a subject which will require a great deal of investigation to fill the knowledge gaps surrounding these developing rare earth projects. There are numerous articles on REE mineralogy as well as the hydrometallurgical processing of REE concentrates (Alex, Suri, & Gupta, 1998; Peter Gromet & Silver, 1983; Ring et al., 1993; Schnetzler & Philpotts, 1970; Uda, 2000), however a common feature amongst these resources is the lack of detailed descriptions of the physical beneficiation processes required to concentrate REE-bearing minerals. There is work being conducted into reagents and methods for use in recovering some rare earths from their associated ores (Bulatovic, 2010; Ni, Parrent, Cao, & Liu, 2011), but much more in-depth research is required."

Jan 1, 2012

By G. L. Oldright

The data in this paper were collected at the Trail smelter of the Consolidated Mining & Smelting Co. of Canada, Limited, through the courtesy of S. G. Blaylock, vice president and general manager; James Buchanan, smelter superintendent; George Murray, assistant smelter superintendent; and the staff members given in Paper XI, Report of Investigations 3243. INTRODUCTION This paper is the thirteenth of the series on Smelting in the Lead Blast Furnace, and the third of the series on Handling Zinciferous Charges. Tyro other papers have been written on the Rate of Descent of the Stock Column, and Formation of Accretions. These are Reports of Investigations 2963 and 3094, for the Tooele plant and the Bunker Hill plant, respectively.

Jan 1, 1934

By W. C. Hirt

Selective flocculation was used to produce superclean zinc concentrate with minimized silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, Tennessee. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but has never been used for processing zinc. The feed material assayed 0.45% Si02. Use of 0.56 kg/tonne (1.13 lb/st) of sodium silicate and 0.070 kg/tonne (0.141 lb/st) of causticized tapioca starch resulted in 98.2% zinc recovery in a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The present target level for silica contamination in JMZ zinc concentrates is 0.3% Si02. This work has shown that selective flocculation offers a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1993

THE Michipicoten area, one of numerous iron-bearing "Archean" segments in the Shield, contains two main types of iron formation, a normal Keewatin-type, consisting of interbanded chert, siliceous magnetite and jasper, and, gradational to this, a carbonate-sulphide type which contains large de-posits of siderite and pyrite. The carbonate-sulphide type of iron formation bears a direct and intimate relationship to the volcanic development of the area; it there-by affords some insight into genetic problems of Archeanron formation in general. The purpose of this pa-per is to summarize the geological setting of Michipicoten iron formations and to briefly review genetic aspects of recent work in the area. GENERAL GEOLOGY in largely by assorted volcanics and sediments of the Michipicoten series and younger, regional granite masses. (Fig. 1). The Michipicoten series comprises a thick assemblage of mixed flows and pyroclastics together with elastic sediments and banded iron formations. The volcanics belong to the Andesite-Rhyolite Association, and characters-

Jan 1, 1961

By F. B. WEEKS

I HAVE chosen for my subject a mining district which in an article published four years ago I referred to in the following words: "One of the un- usual anomalies of mining development and history is that a district having added thirty or more millions of wealth to a principal mining state, situated within four to six miles of two transcontinental railways and two auto highways, and within 150 miles of the most widely advertised part of the United States, should have been so completely lost sight of that probably not one mining man in ten can tell offhand where it is situated." But this district never was a dead one: it was only slumbering. During the past four months, day by day, it has been emerging from that state of slumber.

Jan 1, 1929

By N. Syna

The selection and preparation of activated carbon suitable for specific application can often involve exhaustive adsorbent preparation and testing. This work examined an emerging technique based on modelling the correlation of observed adsorption capacity to the carbon characteristics as a means of decoupling the roles of carbon textural and surface chemical properties. The insights to these specific roles are then used in tailor-making adsorbents and in establishing the optimal carbon properties for specific application. In this study, a series of activated carbons prepared from bagasse by physical and chemical techniques and commercially available carbons were used in developing the models. These carbons were tested for the adsorption of thiourea-gold (I) chloride complexes. Thiourea is an important alternative gold lixiviant with the potential to address current ecological and safety concerns in the extraction of gold. A four-component model, which correlated the adsorption gold capacity to carbon textural and surface chemical properties, was proposed. The model fit was assessed using multi-linear regression and a partial F-test. This was followed by goodness of fit test achieved through r2, adjusted?r2 and mean square error (MSE) values. The results suggest the adsorption of the gold-thiourea complex is strongly influenced by the internal surface area and pH of the carbon. Tailor-made activated carbon from bagasse showed adsorption gold capacities of up to 198 mgAu/g adsorbent, demonstrating the potential of bagasse as a precursor for gold adsorbents and of this empirical modelling approach in developing adsorbents for metal recovery.

Jan 1, 2014

By Thang V. Nguyen, Lisheng Shao, Gary E. Taylor

"The Community Memorial Hospital of Ventura, California, proposed to build a new state-of-the-art Cancer Treatment Center with radiation shielding walls and roof. The loose silty soils at the site had the potential to liquefy during an earthquake, which would result in significant settlement under the heavy footing loads. Treatment options included various deep foundation alternatives, as well as several ground improvement methods. The choice of wet soil mixing minimized the disturbance to the adjacent hospital during construction and potential settlement. Wet soil mixing allowed the structure to be supported on a raft foundation, meeting the stringent building total and differential settlement criteria. The authors also performed unit cell 3-D finite element analyses to evaluate the behavior of the wet soil mixing system in seismic loading conditions. This paper highlights the ground improvement design, construction, QA/QC, and the research related to evaluating the effectiveness of soil mixing for liquefaction mitigation.INTRODUCTIONThe Ventura Community Memorial Hospital proposed the construction of a new Cancer Treatment Center to replace the existing structure, which was built in 1901. The hospital complex is located in a wellestablished residential neighborhood. The soil conditions at the site of the proposed structure required ground modification to support the very heavy radiation treatment section of the building and limit settlement. Originally, 90-foot-long precast piles were considered for foundation support. Based on supplemental Cone Penetration Tests (CPTs) performed, the deepest CPT did not encounter competent pile bearing strata at a depth exceeding 30.5 m (100 ft). This could result in failure of the piles under long-term conditions, especially if hydro-consolidation occurs. The more realistic pile penetration depth would have been 36.6 to 45.7 m (120 to 150 ft). In addition, the excessive noise in association with pile driving would have been unacceptable to the community, patients, and staff of the hospital, so an alternative ground improvement solution was required.The specialty geotechnical contractor recommended wet soil mixing, an economical solution of creating a soil-cement product known as soilcrete that would significantly reduce the construction related noise and provide a more complete deep foundation for the structure.SOIL CONDITIONS AND SETTLEMENT CONCERNSThe subsurface soils were interbedded (Fig. 1) consisting of loose to medium dense silty sands, and soft to medium stiff silty clays to a depth of 30.5 m (100 ft). Groundwater was encountered at depths of 9.1 m (30 ft) and historical high groundwater was at 8.5 m (28 ft) below the ground surface."

Jan 1, 2015

By R. D. Haynes

Coal, gas, and oil in many geological formations of the Eastern United States are intimately associated but have traditionally been recovered independently of each other. Oil and gas wells, however, are often spaced sufficiently close to cause the subsequent loss of up to 50 percent of the recoverable coal in the form of pillars or barriers left for mine safety purposes. A long-range planning technique was devised for exploiting oil and gas wells simultaneously with the mining of coal to recover the maximum fuel potential of the formations. Planned plugging of oil and gas wells, determined partly from production predictions via decline curve analysis, is coordinated with a mine development plan to achieve maximum coal recovery and reduce overall production losses of gas and oil due to plugging of the wells.

Jan 1, 1973

By Irena Grigorova, Tashka Ignatova, Ivan Nishkov, Andrian Valchev

"Feldspars used by ceramic and glass industries as fluxing agents are mainly obtained from high quality feldspar deposits. The demand for feldspar as raw material for industrial applications especially in ceramic manufactures is continuously increasing. However, due to the depletion of those deposits, the research activities related to the recovery of feldspar from the lower grade feldspar deposits and feldspar bearing rocks such as pegmatite, granite, arkosic sandstone and syenite have been intensified in the last two decade. In Bulgaria, the main deposit of arkosic sandstone is located in the area of Shumen town, NE Bulgaria. In Srednya deposit arkosic sandstones are found in Upper Cretaceous sediments (Santonian). In this formation, there are two major industrial minerals - feldspar and quartz. They may be of economic value and possibly suitable for commercial uses. The main purpose of the present study was to investigate the beneficiation and upgrading processes of Srednya deposit arkosic sandstones. In a laboratory scale it was studied the possibility to obtain the feldspar concentrate and quartz sand from arkosic sandstones. Particle size distribution, chemical and mineralogical compositions of quartz-feldspar sands were determined. The bench-scale tests using the KOALIN AD laboratory experimental facilities were conducted. Many processing techniques were tested: disintegration, washing, sizing, carbonate flotation and feldspar flotation. The experimental results show that there are possibilities to obtain the silica sand with low content of Fe2O3 - below 0.02 % and potassium feldspar with content of K2O > 14 %. A new technology for recovery of feldspar and silica sand from arkosic sandstone was developed."

Jan 1, 2014

By P Bourke, S Ronkainen

Since the early days of flotation, process technicians have known that the speed at which the froth is recovered over the lip of the cell has a very direct and consistent influence on the grade and recovery of the circuit. No plant would deny that, even to this day, one of the most important aspects of a process technicianÆs job is ensuring that the froth is moving at a desired and controlled speed over the lip. Unfortunately, process technicians cannot watch the froth throughout the entire shift, as there are always other problems to attend to. A considerable amount of work has thus been done to develop a æsystemÆ that automatically measures the speed of the froth. This measurement would then be used in simple controllers to emulate the steps taken by the process technician in correcting deviations of the froth speed from its desired level. Many of the earlier attempts to measure speed were ineffective, as they were unable to cope with turbulence on the froth surface. The FrothMasterÖ instrument makes use of machine vision technologies to measure the speed of the froth over the lip of a cell at a very high sampling rate. This instrument produces an extremely reliable and accurate measurement of the froth speed (as well as other parameters such as bubble size and froth stability). As we will show, the effectiveness of the speed measurement in controlling the performance of the plant is a testimony to its reliability. Three FrothMasterÖ units have recently been installed on the Cadia Hills Gold Mine in New South Wales (Australia). The objectives of this installation were:to control the mass-recovery of two Tank Cells in series on the same level where differences in the hydrostatic head between the two cells result in the cells pulling inconsistently with respect to each other; control of the concentrate grade (per cent copper) from the first rougher; reduction in the frother consumption in the rougher circuit by monitoring the froth speed. A simple controller was designed to react to disturbances in the same way that human operators react. This was done after consultation with the metallurgists and the process technicians at Cadia. The controller had two functions: Stabilisation: The stabilising controller made use of three manipulated variables (level, frother addition rate and aeration rate) to control the froth speed to a setpoint. Optimisation: The optimising controller adjusted the froth speed setpoint based on deviations of the grade (measured in real-time by the OSA) from a setpoint. The plant metallurgist adjusted the grade setpoint based on information about the ore. The results from a 21-day trial have shown the following:The ratio of concentrate mass-recovery between two cells in series on the same level has been successfully balanced, thereby overcoming problems due to differences in hydrostatic heads. It is possible to control the speed of the froth, in mm/s, to within five per cent of its setpoint using the aforementioned manipulated variables. It has also been shown that, for reliable control, it is necessary to control more than just one variable (eg level or air). The grade of the first rougher concentrate has been controlled to within 0.3 per cent of the grade setpoint for long periods of time, which has important implications for the circuit recovery. The frother consumption has been reduced significantly. This paper will thus show that substantial progress has been made to demonstrate the value of using on-line froth speed measurements in flotation plant control to obtain real financial benefits.

Jan 1, 2000

By M. Westendorf, T. Banerjee, S. Kaushik, D. Tinney

"The Copper Mountain Mine is located in Princeton British Columbia, Canada and produces 80 – 90 million pounds of copper annually, as well as gold and silver by-products. The ore processing plant has a conventional SAG/ball mill circuit with inline pebble crushing, followed by flotation. At most plants, much time is spent evaluating and optimizing the comminution and flotation circuits. The cyclones are a key contributor to the effective operation of the plant: They define the circulating load in the comminution circuit and provide the classification that ensures liberated material is passed through to flotation. If the cyclones are not performing as they should, the results are often a combination of lost recovery, grade, capacity and reduced throughput in flotation. For such an impactful unit operation, cyclones have historically been under-instrumented. Consider as well that the cyclones are typically located at the highest elevation in a plant, and it becomes clear why they often underperform. Copper Mountain Mine recognized the critical role that cyclones filled in their plant and worked to optimize their operation through the implementation of a Portage Cyclone Detection (PCD) system to identify plugging and roping incidents, Portage Pumpbox Control (PPC) to manage the flow to the cyclones, and AwaRE to control the grinding circuit. As a result, cyclones overflow stability has increased, switching out a roped or plugged cyclone now happens within seconds rather than many minutes, and both the grinding and flotation circuits perform better. INTRODUCTION Cyclones are one of the most extensively used pieces of equipment within the mineral processing industry because of their simplistic operating and maintenance philosophies. The cyclones are commonly used as classifiers within the comminution circuit to control the grinding product particle size for satisfactory performance of downstream operations. The cyclones are a key contributor to the effective operation of the plant and have a significant impact on the mineral processing plant operations. If the cyclones are not performing as they should, the results are often a combination of lost recovery, grade, capacity and reduced throughput. Similarly, an inefficient cyclone operation may also lead to low or high recirculating loads that impact the efficiency of the comminution circuit. This highlights the importance to have proper stability in cyclone operation while implementing any plant-wide optimisation strategy."

Jan 1, 2015

By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By QinGuo, Shenghui Guo, Jinhui Peng, Linqing Dai, Libo Zhang

This paper adopts a simple and novel preparation. Taking cellulose as a template, a tubular morphology structure of micro/nano ZnO crystals was obtained by microwave roasting at high temperature. The higher the microwave roasting temperature, the larger the degree of crystallization. The experiments indicate that the best photo catalytic effect can be obtained at 850 : At this temperature, the oxidation of cellulose is complete. Large quantities of hexagonal shaped ZnO crystal can be observed, specifically the (0001) crystal face. Under ultraviolet-visible irradiation, taking long arc mercury lamp as light source, the material had good photocatalytic activity. The decomposing efficiency of methylene blue reaches 97% in 60min, which is superior to that of preparations without templates at the same temperature.

Jan 1, 2016

By KENNETH W. GREENAWALT, William Greenawalt

THE patent system, through which an inventor is given exclusive right to his invention for a limited period as a reward for his industry and in reimbursement of his expenditures, originated in England in the famous "Statute of Monopolies," enacted in 1623. The first patent granted in America was to Samuel Winslow, in Massachusetts, in 1641. The basis of the patent system of the United States is a provision in the Constitution giving Congress the power to secure to inventors for a limited time the exclusive use of their discoveries. The first legislative enactment was the law of 1790, which was placed on the statute book after Washington had addressed Congress in its favor. Under this law, the Secretary of State, the Secretary of War, and the Attorney General constituted the board for the examination of patent applications and the granting of patents. The first Secretary of State, Thomas Jefferson, became the first administrator of the patent sys- tem in this country. He personally examined every application filed during his term of office.

Jan 1, 1930

By Pierre-Yves Declercq, Andre Vervoort

"After the mass closures of entire coal mine districts in Europe at the end of the last century, a new phenomenon of surface movement was observed—an upward movement. Although most surface movement (i.e., subsidence) occurs in the months and years after mining by the longwall method, surface movement still occurs many decades after mining is terminated. After the closure and flooding of underground excavations and surrounding rock, this movement is reversed. This paper focuses on quantifying the upward movement in two neighboring coal mines (Winterslag and Zwartberg, Belgium). The study is based on data from a remote sensing technique: interferometry with synthetic aperture radar (INSAR). The results of the study show that the rate of upward movement in the decade after closure is about 10 mm/year on average. The upward movements are not linked directly to the past exploitation directly underneath a location. The amounts of subsidence at specific locations are linked mainly to their positions relative to an inverse trough shape situated over the entire mined-out areas and their immediate surroundings. Local features, such as geological faults, can have a secondary effect on the local variation of the uplift. The processes of subsidence and uplift are based on completely different mechanisms. Subsidence is initiated by a caving process, while the process of uplift is clearly linked to flooding. INTRODUCTION After the mass closures of entire coal mine districts in Europe at the end of the last century, a new phenomenon of surface movement was observed—upward movement in the area above the past exploitation and in the immediate surroundings. Of course, most surface movement (i.e., subsidence) occurs in the months and years after mining by the longwall method (Peng, 1986). This downward movement continues to occur at a smaller rate many decades after mining has been terminated when the water in the underground excavations is pumped to the surface. This is the case as long as a mine is in operation. However, after the closure and flooding of the underground excavations and the surrounding rock, this movement is reversed, and the surface is uplifted. A total uplift of about half a meter has been recorded to date. This phenomenon has been described in several different coal basins in Europe, for example, in Belgium (Devleeschouwer et al., 2008), France (Samsonov, d’Oreye, and Smets, 2013), Germany (Baglikow, 2011), the Netherlands (Caro Cuenca, Hooper, and Hanssen, 2013), and Poland (Preusse, Kateloe, and Sroka, 2013). To date, research has focused mainly on understanding the phenomenon (e.g., Herrero et al., 2012) and identifying general trends, whereby the link with the rise in water levels is an important issue (Caro Cuenca, Hooper, and Hanssen, 2013). The most accepted explanation is linked to the swelling of clay minerals in the argillaceous rocks in the coal strata (Herrero et al., 2012). Without doubt, the full explanation is complex, and swelling is probably not the only cause of the residual movement. Most coal strata rock is weakened upon contact with water. The increase in water pressure also results in a decrease in the effective stress. Both aspects facilitate the fracturing of rock, which normally would result in further subsidence. However, decreases in the effective stresses also result in the relaxation or expansion of the rock, which induces an upward movement (Fjar et al., 2008). All of these aspects, including the long-term residual subsidence due to compaction under dry conditions, result in a net upward movement. The phenomenon discussed here is clearly different from the upsidence, sometimes observed on other continents (e.g., in Australia, Galvin, 2016). When upsidence occurs, the rock near the surface bends and buckles upwards due to the overstressing of the floors of the valleys."

Jan 1, 2017

Hazardous waste has often very complicated chemical compositions in a variety of physical forms and is normally processed in rotary kiln incinerators. Due to large variations in waste types and difficulties in feed characterization, the complex transport processes within the incinerator are not well understood, and the incineration process meets challenges in a smooth operation, and expects various uncertainties in the process chemistry and emission control. For better understanding of the incineration process, simulation was carried out by using Computational Fluid-dynamics (CFD) to characterize temperature and species distribution in the incinerator. In order to catch certain aspects of thermal and chemical behavior, a novel approach is proposed to represent approximately the waste streams and the subsequent combustion process. Hazardous waste in various forms from an industrial-rotary-kiln waste incinerator is firstly converted to a hydrocarbon-based virtual fuel mixture with approximately the same HIC molar ratio and calorific value. The simulation of the combustion process of the simplified hazardous waste was proceeded with a combustion model. The distribution of temperature and chemical species especially the remaining CO in the system is preliminarily investigated. Distribution of CO concentration, as a good indicator of emission level for the incineration process, could be used to evaluate the emission control. The predicted temperature distribution has been compared with available measurement data from an operating rotary kiln waste incinerator at AVR-Chieme, in the Netherlands. Reasonable agreement has been reached between the measured and predicted temperature data. In the next step, measurement of species distribution in the system is planned to further validate the combustion model.

Jan 1, 2003