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By R. Trammell, O. Eterigho-Ikelegbe, S. O. Bada

In response to the enormous amounts of coal discard generated during coal mining and preparation, the development of an efficient and sustainable strategic use of this resource is essential. Furthermore, the rising urban population over the next decades is confronted with the depletion of quality raw materials for building components. To this end, this study reports new information on the morphology, water absorption, and flexural strength properties of ceramic composites produced from three different coal discards and polysiloxane pre-ceramic polymer (PCP) resin. In addition, test results relating to the continuous operating temperature, chemical resistance, and efflorescence potential of the composites are presented. The results show that the water absorption and flexural strength of the coal composites, up to 1.94% and 36.46 MPa respectively, exceed the requirements for ceramic and clay roof tiles. The continuous operating temperature of composites is found to be more thermally stable than conventional roofing tiles (concrete and ceramic) between ambient temperature and 600°C. In addition, the excellent chemical resistance of the composites (94.43%−99.98%) compared to conventional roofing tiles (67.82%−99.97%) eliminates the need for additional external coatings. The interesting results documented so far suggest that this technique could be used to produce low-temperature application building products such as bricks, panels, roofing tiles, etc. This new recycling technique offers an excellent opportunity to eliminate enormous volumes of coal discard and to advance the circular economy in the coal industry.

Aug 2, 2022

By J Yamatomi, Y Tamanishi, S Miwa

The four-dimensional (4D) network relaxation method, originally developed by Akaike in 1999, uses Lagrange relaxation and is known for its ability to include the price change and possible better outputs, but the computation time is huge. However, the continuous advancement in computer technologies allows the use of higher-speed computers with more memory capacity. Therefore, in this paper the authors have tried to implement the method with adjustments and improvements in its algorithm to suit the current computing system. As a result, the computation time has been drastically reduced and more constraints can be included, which makes the scheduling a more realistic one. The case study of an open pit gold mine with 129 500 blocks can be solved considering the capacity constraints in 71 seconds. In previous case studies, the mined ore had to be processed or disposed of immediately. Now, stockpiling can be included as another option. Since the details of the algorithm are still being improved, the computation time is a little longer than the previous cases without the stockpiling option. However, it is found that scheduling with the stockpiling option is possible in a reasonable time. In conclusion, the 4D network relaxation method has become more useful with advances in computer technologies and provides better results.

Sep 26, 2011

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By Gerald Verbeek, Erick Baziw

Stone columns are used in geotechnical site remediation to increase load-bearing capacity and reduce settlement of foundations. Stone columns also improve slope stability and increase the shear strength of a soil. A very challenging problem is to characterize the in-situ shear wave velocities from data acquired from Downhole Seismic Testing (DST) after the insertion of stone columns. DST is an important geotechnical testing tool for site characterization that provides low strain (<10-5) in-situ interval compression and shear wave velocity estimates, but the postanalysis of seismic data acquired from DST in the presence of stone columns is very challenging due to the resulting complicated in-situ soil conditions. To obtain the right results it is necessary to use an algorithm that incorporates source wave raypath refraction. Starting with the Normal Moveout Seismic Cone Tomographic Testing (NMO-SCTT) algorithm developed some years ago, this paper outlines the modifications and additions made to this NMO-SCTT algorithm to facilitate stone column site characterization. To dramatically reduce the optimal solution space for the estimated interval velocities the paper also described a priori conditions that are applied based on the unique nature of the stone column site conditions.

By John S. Civetta, Seth Martin, Marc J. Gallagher, Arthur J. Alzamora, Ronald Peralta

The Crown Building, built circa 1921, is a 26-story iconic building located at West 57th Street and Fifth Avenue in the heart of Manhattan. The paper highlights collaboration between the geotechnical engineer and foundation contractor to develop economical and practical solutions to foundation design and construction challenges associated with this complex redevelopment project. The project includes both below-grade and above-grade expansion of the occupied building, and required undermining the existing foundations, and essentially doubling the foundation loads. The below-grade expansion required surgical foundation work including drilling minicaissons, shoring columns, underpinning, and excavating 20 feet of rock.

By Ludwig Schmidt

This report, the second of a series, presents the results of laboratory corrosion studies which were made in connection with a one-year test on aluminum lease tanks conducted by the United States Bureau of Mines. Part I of the report contains the results of the field teats.5 The studies were made on an oil lease in a so-called "sour district," near Borger, Tag., where free hydrogen sulphide accompanied the production of oil, gas, and salt water. Steel tanks previously used on the lease had suffered severe corrosion, because steel is inherently susceptible to attack by hydrogen sulphide. Because of the high resistivity of aluminum to the action of hydrogen sulphide, it Was believed that this metal had promising possibilities as a material for the construction of lease tanks in "sour districts." The results of the one-year field teat proved that aluminum lease tanks will withstand corrosion by hydrogen sulphide, but it was found that aluminum was susceptible to attack by salt water, which was invariably present in certain portions of the tanks, and that hydrogen sulphide accelerated this salt-water corrosion in an indirect manner, as will be explained hereinafter. In order to study corrosion conditions encountered in the tanks during the test period, a laboratory was maintained at the site of the aluminum lease tanks.

Jan 1, 1931

In many base metal sulphide concentrators reagents such as collector and cyanide are often added to the grinding mill as well as to the flotation circuit. Whilst good reasons can be cited for splitting the reagent addition in this way, the benefits of such are rarely quantified and the complex reagent-mineral-media interactions occurring during milling are often poorly understood in terms of pulp chemistry. A new laboratory batch grinding mill designed by Magotteaux allows the user to measure, monitor, and control the pulp chemical conditions during grinding when testing different ores and media. Some of these parameters include pulp pH, pulp Eh, temperature, gaseous atmosphere, and dissolved oxygen concentration. In a recent development, the mill has been coupled with a simple on-line reagent monitoring system, designed by CSIRO, which allows the levels of species such as xanthate and cyanide in the grinding pulp to also be measured continuously during milling using a robust UV detection system. In this way the uptake of collector during grinding and the rate and ex-tent of cyanide interaction with the minerals and media can be determined as a function of grinding time. A series of grinding tests using an Australian nickel sulphide ore was conducted with the coupled system in which the cyanide dose, xanthate dose, and media type were systematically varied. The xanthate and cyanide levels were monitored as a function of grinding time and the data collected are discussed in terms of the pulp chemistry of the system and implications for plant reagent dosing strategies.

Jan 1, 2014

By Alessandro Navarra, Joël P. T. Kapusta

"The converting cost modeling software introduced by Ng et al. in 2005 [1] has been extended to consider the reprocessing of reverts and copper scrap. The original model evaluated the operational costs of a Peirce-Smith converter; algebraic relationships had been implemented with arrays (to represent matrices, vectors and scalar ratios). The new software brings flexibility to the underlying thermochemical balances, by using linked-lists instead of arrays. It is now possible to consider the blending of several feeds, including reverts and scrap.The software computes the length of the converting cycle from the Fe and S content of the charge together with the blowing rate; the times required for other operations (charging, skimming and idle time) are also accounted for. The costs of consumables such as flux, fuel, oxygen or compressed air are all evaluated. Downtime, labor, and materials for converter lining repairs are also considered. The software is easily extended to examine the costs of alternative operating strategies or injection technologies such as sonic single pipe injection and sonic shrouded injection. The potential cost benefits of alternative operating procedures and technologies are discussed through example calculations."

Jan 1, 2009

By Sergey Komarov, Manuela Diaz, Sano. Masamichi

"Mixing time, bubble behavior and absorption rate of gas injected into a liquid bath through rotary L-shaped lances have been studied by cold models with an effort to improve refining characteristics of metallurgical processes. Two kinds of the rotary lances were tested, namely the single-hole lance and the multi-hole lance. The effects of gas flow rate, bath depth and rotation speed were examined.It is found that when gas is injected through the rotary lances, the mixing intensity and the gas absorption rate are larger than that for the gas injection through stationary lances. The effect of rotation speed decreases as the bath depth and the gas flow rate increase.The multi-hole lance produces much smaller bubbles, which lead to an increase in the volumetric mass transfer coefficient by 3-4 times as compared with the single-hole lance. However, the effect of rotation speed is smaller for the multi-hole lance. The obtained results are explained in terms of the bubble coalescence and fragmentation, the rate of which depends on the departure bubble size and the power supplied to the liquid bath.IntroductionIn recent years, there has been a growing interest in the development of gas injector for metallurgical processes. The majority of the previous work was focused on modification to the injector design to improve mixing and to increase the of chemical reaction rate. These two goals can not be necessarily achieved by the same way. Bottom nozzles and stationary immersed top lances, which have been widely applied to steelmaking processes, are effective for the bath mixing, but have a limit to decrease in the bubble size. This results from a vigorous coalescence occurring between the bubbles when they rise in the molten bath as a bubble swarm.One of the ways to ensure the small bubble size and the effective bath stirring is the gas purging through rotary injectors. A number of studies have been undertaken to improve the refining characteristics by using rotary injectors. All of them are related to aluminum refining. The SNIF equipment (The Spinning Nozzle Inert Flotation) has significantly improved the quality of aluminum products at National Luxemburg Aluminum [1]. Rotary injectors made in the form of a disc have been applied to the Alcoa 622 [2] and the GBF processes [3]. A study of the gas injection by a rotary impeller has been carried out by C. Leroy and G. Pignacelt [4]. All researchers note the significant improvement in removal of sodium, calcium, hydrogen and non-metallic inclusion."

Jan 1, 1996

By A. V. Bogdanovich

In diamond ores processing, final waste tailings size, rejected to dump, is one of the most important parameters. On one side, it is necessary to minimize losses of diamonds, whose size exceeds 1 mm, on the other side ? to provide for the plant high throughput and sufficiently low capital and energy costs, which is in greater part connected with disintegration process. Extensive laboratory, pilot-scale and commercial-scale dressability studies of different types of diamond ores have been performed at JSC ?Mekhanobr Engineering? in recent years. With that, special consideration was given to determination of the required ores? disintegration size that would provide for a high recovery of diamonds. In diamond ores processing, in order to exclude breaking of large diamonds, stage disintegration is used with regrinding of light fractions and heavy fraction X-ray fluorescent separation tailings. On account of rather weak bonds of diamonds with enclosing minerals, in crushing and grinding of diamond ores, selective disintegration takes place, with aggregates? breakup along plane surfaces of least bonding, which facilitates liberation of diamonds and their transition to free state. Heavy components losses with different sizes of final dump tailings were studied in processing of large samples. It was established, that in order to almost completely exclude losses of heavy components over 1 mm size, light fractions had to be ground to 2.5-3 mm size, while X-ray fluorescent separation heavy tailings of -15+3 mm size do not contain diamonds larger 1 mm in aggregates, and their regrinding does not increase total recovery of diamonds. On the basis of the conducted studies, relationships regarding heavy components and diamonds losses with respect to diamond ores final disintegration size were obtained, providing for more rational organization of the ores disintegration and processing flow sheet. Keywords: diamond, waste tailings size, disintegration process, recovery of diamonds

Sep 1, 2012

By Gerald H. Luttrell, Seyed Hassan Amini, Aaron Noble

One of the most important processing engineering tools for designing mineral processing facilities is linear circuit analysis. This technique, originally conceived and developed by Meloy, Williams, and Fuerstenau nearly four decades ago, provides fundamental insights regarding how unit operations interact and respond when arranged in multi-stage processing circuits. Researchers have successfully utilized this tool to improve the operating performance of industrial processing circuits incorporating coal spirals, magnetic separators, mineral spirals, and eddy current separators. More recently, advanced versions of this tool have also been developed to provide a standardized framework for circuit mass balance calculations, to output exact analytical solutions to mass yield and value-based efficiency expressions, and to estimate uncertainty propagation in separation circuits. This article reviews the historical development of linear circuit analysis, describes how the technique has evolved to address more complex circuit design problems, and presents industrial case studies that highlight the importance of this process engineering tool.

By P. Mpofu

In this work, the modification of interfacial chemistry of colloidally stable kaolinite clay dispersion has been carried out to improve its flocculation performance and dewatering behaviour. Synergistic action between dispersion pH, hydrolyzable metal ion and high molecular weight polymeric flocculant structure type (anionic polyacrylamide-acrylate copolymer (PAM) and non-ionic polyethylene oxide (PEO)) was found to play a pivotal role in inter-particle bridging, the enhancement of the settling rate and extent of consolidation of the pulps. Flocculation with PEO led to higher settlings rates in acidic than alkaline pH, whilst for PAM, the maximum dewatering rate was achieved in the neutral pH range 6 - 7.5. Upon shear, the PEO flocculated pulps showed dramatic improvement in consolidation to 40 wt%, the extent of which was greater at lower than high pH values. For PAM-based pulps were however, not shear-responsive, lower sediment solid contents of 15 - 23 wt% was observed between pH 3 and 11. Hydrolysable metal ions, Mn(II) and Ca(II), used respectively at pH 7.5 and 10.5 in conjunction with PAM and PEO, significantly enhanced the settling rates and consolidation of the pulps. The findings exemplify the strong links existing between pH-mediated particle surface chemistry. polymer structure-conformation, inter-particle bridging and dewaterability of kaolinite dispersions.

Jan 1, 2004

By Jon G. Bredeson

A survey of electromagnetic noise reports was performed and a summary of the results are given. Industrial concerns were surveyed for techniques to minimize the effects of electromagnetic noise and are presented. The common types of communication links used in mines today are presented. A mathematical development was presented which determines the probability of bit errors versus distance for various types of communication links designed for in mine use. The probability of undetected errors for the protocols of the communication links is given together with burst error detection.

Jan 1, 1981

By R. T. Jones

"SynopsisScientific progress relies on the publication of ideas and experimental results that can be replicated, tested, and improved over time. The first printed book on metallurgy to have been published in Europe is considered to be De la Pirotechnia, written in Italian by Vannoccio Biringuccio, and published in Venice in 1540. Together with De Re Metallica, written by Georgius Agricola and published in Latin in 1556, this can be considered to mark the start of scientific and technical literature in this field. Scientific publishing of journal papers has been in existence for 350 years, since the world&apos;s oldest and longest-running scientific journal, the Philosophical Transactions of the Royal Society, was first published in London in 1665.The nature of scientific societies has changed significantly since the early days when regular meetings were held to discuss science and conduct experiments, and the reading of scientific papers took place, and publication of papers was undertaken to record the proceedings of meetings, often including rather robust debate. In today’s world, there is a plethora of publications, and it is close to impossible for anyone to keep up with the vast flow of information. International conferences with hundreds of presentations have taken the place of the local meetings that used to discuss a single paper or experiment. In this frenetic environment, it is essential that researchers are able to trust the material they read.The system of peer review is used to maintain standards and to improve the quality of papers. This vital system is, however, significantly flawed. There is little incentive for reviewers to invest sufficient time in picking up all errors in publications, and any ineptitude on their part is usually protected by anonymity. It has reached the point where some reviewers have mistakenly permitted the publication of hoax papers deliberately presented with a complicated scientific facade. In light of such astounding inadequacies, perhaps a more open review process would be an improvement. Electronic publishing allows errata to be linked to the original papers.There is an increasing trend towards open access for papers in scientific journals and conference proceedings, which helps to reach as wide an audience as possible. This also supports the statement in the Universal Declaration of Human Rights, which says ‘everyone has the right freely to … share in scientific advancement and its benefits’."

Jan 1, 2015

By C. O. Stee

IN the October, 1936, issue of the Canadian Mining Journal there was published a series of very comprehensive and exccellently illustrated papers by Mr. C. O. Stee and members of his staff dealing with Siscoe operations and ore-bodies. These were, in the order in which they appeared: Geology of Siscoe Gold Mine, by O. L. BACKMAN Diesel Power at Siscoe Gold Mines, Ltd., by C. O. STEE andE. A. BLOMQUIST Mining at Siscoe, by L. T. POSTLE and W. F. Engineering and Surveying, Siscoe Milling Practice, Research and Testing Laboratory, Assaying of Mill Tails and Solutions, BROWN(6) by P. A. TEEPLE (7) by L. E. DJINGHEUZTAN by L. RIVETT (8) by G. IRWIN (9) The Editor of the Canadian Mining Journal cordially assented to our suggestion that these papers be reviewed at the 1937 Annual General Meeting of the Institute, and the authors very kindly accepted our invitation to present such reviews . Of these courtesies, full acknowledgment is here accorded. To our readers, we commend the original papers in the Canadian Mining Journal. The summaries presented at the meeting follow. EDITOR. THE GEOGLY OF THE SISCOE MINE The Siscoe gold deposits lie in and near a stock of granodiorite, related to the Bourlamaque batholith, which has intruded highly folded Keewatin volcanic rocks .. The volcanic rocks lie to the north of a belt of Timiskaming sediments.

Jan 1, 1937

By Simon Lekakh, Von Richards, C. Hank Rawlins, Kent Peaslee

"Batch aqueous leaching and carbonation tests were conducted using industrial steelmaking slags to determine the effect of carbonic anhydrase enzyme as a catalyst. Calcium leaching is a strong function of particle surface area, and the extent can be expressed as a function of time and particle size. Carbonic anhydrase did not affect the calcium-leaching rate, however, it did catalyze calcium carbonate formation to achieve a neutralization time near the theoretical rate. Additionally, carbonic anhydrase modified the precipitate morphology due to accelerated particle nucleation. Time controlled tests in which the pH dropped to ~6 decreased the amount of carbonate produced, and this effect was exaggerated by carbonic anhydrase, while pH controlled tests (>8.5) exhibited the highest rate of carbonation. Because the leaching rate was ~50% faster than the carbonation rate, a further increase in the amount of carbonation may be realized by using carbonic anhydrase however pH must be >10.3.IntroductionSteelmaking slag contains high fractions of alkaline earth oxide based phases (i.e., CaO and MgO) that exothermically form carbonates. Thus, it is being considered as a means of permanent carbon dioxide sequestration. At current U.S. steel production rates, approximately 13-17 million tons/year of slag are generated from basic oxygen furnace (BOF), electric arc furnace (EAF), and ladle metallurgy furnace (LMF) processes [1]. BOF and EAF slag is used as high quality mineral aggregate or cement clinker, while LMF slag, produced at ~15% the rate of BOF and EAF slags, has limited use as blast furnace flux or acid mine neutralization with the majority going to landfill [2]. Based on slag’s chemical nature and immediate availability as a co-product from steel production, the steel industry initiated a project to investigate hydrous carbonate formation in steelmaking slag as a method of sequestering carbon dioxide emitted in steelmaking offgas [3]. The goal of this project is to determine the reactor parameters suitable for the design of an industrial system for treating steelmaking offgas with raw or minimally processed slag."

Jan 1, 2009

By R. N. Orava

TO the author&apos;s knowledge, only one satisfactory high-resolution technique for etch-pitting dislocations in Cu-Zn alloys has been published.&apos; In that account, pits in 70/30 brass single crystals were produced by etching electrolytic ally in a 30 pct orthophosphoric acid bath. Thereafter, observations were made from surface replicas by electron microscopy. The method of pitting and observation permitted the high resolution necessary for the distinction of individual dislocations in arrays of pile-ups. However, no comment was offered concerning the possibility of obtaining pits which are amenable to optical resolution. Moreover, for adequate results, the electrolytic pitting process is invariably preceded by a polishing stage which could obscure the surface features of interest. Consequently, it would be desirable to be able to delineate, by solely chemical means, dislocations which could be detected by both optical and electron metallo-graphic techniques. This was achieved by the simple expedient of modifying two etchants reported by young2 to reveal dislocations on the (100) planes of pure copper. Single crystals of 70/30 a brass, described previously,3 were sectioned to provide a surface parallel to a set of {100) planes, mechanically polished, and subsequently electropolished at 2.4 v in a solution comprised of 2 parts H3PO4, 4 parts ethanol, and 3 parts water. The inclusion of ethanol tended to inhibit nonuniform surface attack. Etch-pitting was effected by a 2 to 3 sec immersion in a 70 pct aqueous solution of HNO3. The samples were then washed in a fast-flowing stream of water, and rinsed further in distilled water, and ethanol, before drying. It is important to note that this reagent should be either used immediately after mixing, or, if allowed to cool, reheated to about 35°C prior to use. No pitting was obtained at room temperature. Typical results are shown in Fig. 1 where (a) is an optical view of the pitted surface and (b) is an electron micrograph of a silicon monoxide replica shadowed with tungsten oxide. The former is characteristic of a somewhat longer etching time (-6 to 8 sec) which varied with bath temperature. Similar pits accrued from a 1/10 aqueous dilution of another of Young&apos;s solutions2—2 M FeC1,6H20 and 7.8 M HBr.

Jan 1, 1968

By D Oliveira

The use of an equivalent continuum for a rock mass is not always suitable for situations where the failure is structurally controlled by discontinuities as in the case of wedges in the tunnel roof. In these instances, discontinuum approaches are usually preferred. Rock joints that are filled with soft infill are likely to be the weakest planes in a rock mass, having a dominant influence on its overall shear behaviour. In this case, the joint material model adopted for the discontinuities should be able to describe important mechanisms, such as asperity sliding and shearing, post-peak behaviour, asperity deformation, and the effect of the soft infilling. The latest version of a soil-infilled joint model is discussed here. It describes more comprehensively than previous models the occurrence of dilation and compression with lateral displacements, and also represents the hardening mechanism related to asperity interference as observed in the laboratory that cannot be readily captured by the existing joint models. An analytical approach for the analysis of rock wedges structurally controlled by soil infilled joints is presented.The analytical approach presented in this paper for assessment of symmetric rock wedges in the roof of a tunnel demonstrates, that the peak shear strength of the joint may not be fully mobilised before detachment of the wedge. The analysis verifi ed that an overestimation of the factor of safety may be observed when an elastic-perfectly-plastic joint model was assumed, whereas the computed maximum factor of safety was considerably less when adopting an appropriate soil-infilled joint model.

Mar 8, 2011

By D. Harrington

Part III-B, presented in this circular, completes the series reviewing the literature on effects of breathing dusts with special reference to silicosis; it includes data on the status and cost of compensation for silicosis in the United States and several foreign countries and a summary and general conclusions covering the whole series. Parts I, II, and III-A of the series have been issued as Information Circulars 6935, 6840, 6948 , and 6957; Part I defines and classifies dusts, indicates sources of exposure, and describes the physiological effects of breathing dusts; Part II-A discusses the principal dust factors producing pulmonary pathology and methods of determination of dust in air; Part II-B presents data on the engineering and medical control in the prevention of dust diseases and general recommendations for their control in industry; and Part III-A deals with the economic and legal aspects of dust diseases in industry.

Jan 1, 1936

By Rongjie Kong, Shiwei Wang, Dongjiao Gui

Metal cations have significant effects on the flotation of coal and minerals. In this study, the effects of monovalent cations ( Na+ and K+) on the flotation of low-rank coal (LRC) were investigated using flotation and particle–bubble attachment experiments and through X-ray photoelectron spectroscopy (XPS) and molecular dynamics simulations. Oleic acid (OA), methyl linoleate (ML), hexadecyltrimethylammonium chloride (CTAC), ricinoleic acid (RA), and kerosene were used as flotation collectors. The flotation experiments revealed that the flotation yields of LRC improved when OA, ML, RA, CTAC, and kerosene were used in pure deionized water. However, flotation was suppressed for these collectors in the presence of K+ and Na+ ions. In contrast, when using CTAC, the flotation yield increased in the presence of these ions. Specifically, the flotation yield increased from 41.24 to 87.03% when 2.0 kg/t CTAC was used in 10 mmol/L NaCl solution. Particle–bubble adhesion experiments and XPS revealed that the hydrophilic groups of CTAC were adsorbed on the LRC surfaces by electrostatic forces, whereas the oxygen-containing functional groups of OA, ML, and RA formed hydrogen bonds with the LRC surface in pure water. Finally, the simulating result revealed that the hydrophobic ends of the OA, ML, and RA collectors hinder the flotation of LRC by adsorbing monovalent cations, whereas the adsorption of monovalent cations on the hydrophobic end of the cationic surfactant (CTAC) promotes flotation via strong electrostatic interactions.

Jan 31, 2024