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By C. L. Meyers, A. V. Levy, G. Y. Onoda, R. J. Kotfila

This paper presents the hypothesis that solid-solution hardening of regions in the order of tens of angstroms thick along grain boundaries is the most important mechanism controlling the ductile -brittle transition behavior of poly crystalline bcc refractory metals. Further, a physical model is developed and a general equation is derived to describe the dependence of the solute concentration at grain boundaries on temperature, nominal impurity concentration, thermal treatments, vain size, and prior plastic deformation. Analytical curves of the solute concentration at grain boundaries us temperature, calculated by means of the derived equation, are found to have the same general form as curves of ductility us temperature plotted from experimental data. Senziquantitative relationships between the transition temperature and metallurgical variables can he determined by using the physical model. The room-temperature brittleness of the poly-crystalline refractory metals (tungsten, molybdenum, and chromium) is a result of their high ductile-brittle transition temperatures. Recently studies on single crystals have revealed that, when sufficiently pure, these crystals have much lower transition temperatures than polycrystalline specimens of similar purity.'-3 For example, the transition temperature (measured by reduction in area in tensile tests) for very high-purity tungsten crystals has been reported to be as low as -50°F whereas polycrystalline specimens of similar purity had a transition temperature near 400" ~.' These results suggest that the ductile-brittle transition behavior of these polycrystalline metals can be attributed principally to the influence of grain boundaries on plastic flow and fracture. This paper contains a discussion of the manner in which grain boundaries influence the ductility of the poly-.crystalline bcc refractory metals and proposes that the segregation of impurities to grain boundaries is the most important mechanism for controlling the ductile-brittle transition behavior of these metals. Further, this paper contains an analysis of the effect of the compositional and structural variables on the grain boundary-ductility relationship, and introduces a semiquantitative model that can provide a foundation for more theoretical treatment to describe the influence of these variables on ductile-brittle transition behavior. PHYSICAL MODEL FOR PREDICTING DUCTILE-BRITTLE TRANSITION BEHAVIOR Grain Boundary Segregation of Impurities. Based on their own observations and on theoretical grounds, numerous investigators have suggested that impurities segregate to the grain boundaries. Such segregation would be expected because regions exist where both large and small foreign atoms fit with less strain than within the undistorted crystal structure. Therefore, the concentration of impurities should be higher at boundaries than within the grain body. TO estimate the degree (i.e., the ratio of grain boundary to nominal bulk concentration) to which an interstitial solute tends to segregate at boundaries within a solvent metal, the solubility rather than the size misfit could be used as a guide because solubility expresses the joint effect of both elastic and electronic factors.5 The solubilities of interstitial elements such as carbon, hydrogen, nitrogen, and oxygen are low in the group V-A metals and very low in the group VI-A metals.6 These low solubilities suggest that segregation to grain boundaries should occur for each of these solutes in both refractory metal groups. The difference between the ductility of single-crystal and polycrystalline bcc refractory metals can be described in terms of two distinct effects.4 The first of these is the general observation that grain boundaries hinder slip within grains and slip transfer between grains, and the second is that deformation is more complex in each grain of a polycrystalline specimen than it is in a single crystal. Mc Lean has pointed out, furthermore, that strong slip-hindrance effects at grain boundaries should occur in metals having strong segregation of impurities to grain boundaries. Therefore, the effect of grain boundaries on the hindrance of slip is expected to be the dominating influence on the ductile-brittle transition behavior of these polycrystalline refractory metals. cahn5 has suggested that temperature and solute mobility should influence solute equilibrium segregation at grain boundaries, and Fig. 1 illustrates

Jan 1, 1965

By Misra A

After review of the status of research on optirnisation of retreat longwall faces it is argued that an acceptable optimisation model must be based upon realistic cost data that take into account not only the face costs, but the total panel costs. These include the cost of development, face cost, removal and installation cost. The determined optimum length of a retreat longwall face is based upon a realistic model and actual costs.Parameters that influence the optimum face length have been varied over wide limits to allow determination of the sensitivity of the model and the effect of the parameters on the optimum face length. It is concluded that for medium production rates and medium system availability, the optimum face length of a retreat longwall face under Australian conditions lies between 180 and 220 metres.

Jan 1, 1995

By M. Ploc

The grinding process in the mining industry has seen an increased throughput to accomplish greater production and lower overall production costs. Up to 8-9 MW, a single motor can be connected to drive the mill through a pinion and ring gear. Above the single-pinion drive limit, the dual pinion approach was developed to allow two drive motors to be used. This allowed the mill input power to be increased to 16-18 MW. Recent developments in clutch and ring gear materials and design are allowing greater input powers of up to 20 MW to be considered. To avoid damage to the ring gear by uneven load sharing between the two motors, it is critical that the two machines accurately share load. This is typically achieved by either drives capable of controlling load torque between motors or using a GE proprietary control system that accurately controls the load torque from each motor.

Jan 1, 2010

By J. H. Schubert

Mintek has developed a level-control system, FloatStar, for use in flotation circuits. Instead of controlling levels separately in each unit, the controller monitors levels throughout the circuit. It can thus take account of the global effects of any control actions. A collaborative project between Mintek and Karee Platinum Mine has begun, looking at aspects of flotation control. Karee plant was chosen as the site for this work because of its good existing control infrastructure. As a first stage of the joint project FloatStar was installed. Analysis during installation and running of the FloatStar has illustrated how circuit design and measurement technology can affect process control. Severe interactions have been observed in the levels of adjacent banks. The effect of FloatStar on flotation performance was tested and an improvement in level control was observed. Similarly, a faster settling of the plant after start-ups was observed. Both the improved level control and faster start-ups lead to higher platinum recovery.

Jan 1, 1999

By Robert L. Montgomery

Heats of solution of samarium (III) oxide and chloride in hydrochloric acid and of samarium (III) oxide, sulfate, and hydrated sulfate in sulfuric acid were measured. The heats of solution of this hygroscopic oxide are larger than those from the literature, probably because of more complete removal of water in the present study. From the literature value for the heat of combustion of samarium, the heats of formation of samarium (III) chloride and sulfate are -244.18 ± 0.41 and -928.5 ± 1.6 kcal./mole, respectively. The heat of hydration of the sulfate is -34.7 ± 1.0 kcal./mole. The heats of formation of other samarium com-pounds have been recalculated, using the new data.

Jan 1, 1959

By C. H. Wright

Introduction The rapidly expanding and increasingly complex Canadian industrial structure, with the mining, metallurgical, and chemical industries as a large integral part, has, in recent years, brought greatly increased importance and value to our industrial minerals. In the modern economy of our mineral industry the importance which is due the non-metallics has been somewhat overshadowed by the great value of our large metal production and, in addition, by the glamour and fascination usually associated with the mining and treatment of gold ores. The term 'Industrial Mineral' is used in this paper in its usual sense and refers to non-metallics other than fuels. Coal and petroleum products, including natural gas, are considered as industrial minerals in those applications in which they are used for strictly chemical process purposes. Certain reduction metallurgical industries are so closely allied to chemical industries that for purposes been of this discussion no attempt has made to differentiate between them. Chemical industry in Canada today is a fairly large factor in our national economy, whereas in 1898, when the Canadian Mining Institute was born, it was very small indeed. Chemical concerns are largely dependent on industrial minerals for raw materials and process supplies and, as the country has developed industrially, so have the demands for non-metallics increased, not only by chemical industry but also by other large consumers, such as the construction and metallurgical industries. At the present time there is a greater than normal incentive prevailing for new discoveries, due to the serious lack of balance that exists in our import and export trade. This fact has resulted in intensive efforts to rectify the situation by locating new deposits and re-assessing those already known in an effort to enlarge and improve our home production of raw materials and also to extend their processing in Canada for our own needs and for export. The rapid advances in science and technology that have taken place since 1900 have also resulted in many cases of beneficiation and utilization of otherwise too low grade materials in order to satisfy current demands. The purpose of this paper is to indicate the history and the trends of the utilization of industrial minerals in established industry and to indicate the important part played by non-metallics in connection with the opening up of new industries. Some consideration has been given to the continual competition between natural and 'synthetic products and to the general tendency towards more rigid specifications.

Jan 1, 1948

By Greg Sanders, Michael Gilbert, James G. Shaughnessy

"A new raw water intake from the South Holston River to the Kingsport water treatment plant is under construction. The exploration for the 335 meter long horseshoe shaped tunnel design took advantage of the site topography along the alignment to better define the complex geology consisting of Knox Limestone and Sevier Shale formations separated by a fault zone. To assess the geological conditions and to determine the extent of the fault zone, a 183 meter long horizontal boring and geophysical investigation was performed along a portion of the tunnel’s horizontal alignment. Explorations defined the fault zone width at approximately 5 meters and packer testing along the alignment provided a means of estimating groundwater inflows. As the tunnel excavation advances, comparisons of exploratory data versus encountered conditions will be made. This paper provides details on the geotechnical investigation, lessons learned, and the influence of the geology on the tunnel design. PROJECT OVERVIEW The Kingsport WTP is supplied with raw water via the South Holston River. The City of Kingsport (City) owns and operates the Kingsport Water Treatment Plant (WTP). The existing raw water intake system, consisting of pumps, power supply, raw water piping and appurtenant facilities has been determined to be vulnerable to failure. The original Raw Water Pump Station (RWPS) was constructed in 1928 as part of the original Kingsport WTP project. The 1928 RWPS operated until 1970 when it was replaced by the existing RWPS. This existing system still utilizes the 1928 piping and piping tunnel. Improvements to the RWPS hydraulics and capacity are required to meet the City’s future water treatment needs. The system extracts water from the South Fork of the Holsten River and coveys it via three pressure pipelines to the WTP. The conveyance piping exits the RWPS, ascends approximately 23 m up a near vertical rock outcropping then enters a 120 m long tunnel. Upon exiting the tunnel the piping continues underground to the WTP. The drill and blast tunnel is horseshoe shaped and nominally 3.3 m high by 3.3 m wide. The easternmost 62.3 m of the tunnel is without any type of support. The remainder is lined with concrete. According to the City of Kingsport, the concrete lining was installed in the 1970’s as part of upgrades to the facility. An evaluation of the current facilities concluded that the conveyance piping was in poor condition and required replacement."

Jan 1, 2016

By W. L. Falke

Research was conducted to develop methods on a laboratory scale for recovering manganese from manganiferous slimes and limestones . The procedure is a low- temperature modification of the carbamate process , in which manganese is dissolved and the valence reduced by treating slimes and limestones with controlled amounts of sulfurous acid . Manganese ( II) hydroxide is precipitated and leached with ammonium carbamate solution , and manganese carbonate is separated by warming the leach solution . A major portion of the reagents is regenerated and recirculated . About 75 percent of the total manganese in manganiferous slimes , and from 50 to 75 percent of the total manganese in manganiferous limestones , are recovered as manganese carbonate containing 45 percent manganese .

Jan 1, 1964

The U.S. Bureau of Mines investigated CaF2-assisted H2SO4 leaching to extract Mn from domestic silicate manganese resources. A pyroxmangite ((Mn,Fe)Sio3) ore containing, in pct, 34 Mn, 23 Si, 3 Ca, and 1 Fe was leached at 90° C for 3 h in a solution containing, in g/L, 12 Mn, 140 H2SO4, 130 (NH4)2SO4, and 5 CaFz. Manganese extraction of 92 pct was achieved. Manganese of greater than 99 pct purity was prepared by electrolyzing the purified pregnant solution at a current density of 50 mA/cm2. The current efficiency was 65 pct.

Jan 1, 1991

By D. Ackerman, S. Cole, G. Langefeld, I. Parker

The removal of gravel from the seabed using a hydraulic mining tool is a complex multi-phase problem that cannot be analysed using traditional continuum based simulation techniques. One potential approach is to simulate the behaviours of the solid phase via the discrete element method and the liquid phase via finite volume based computational fluid dynamics. The interaction between the phases is accounted for by Eulerian coupling. The feasibility of using the combined computational fluid dynamics-discrete element method to simulate gravel entrainment from an idealized seabed is evaluated. The simulation results are validated using experimental data. It is concluded that while the current approach appears feasible, further work needs to be done to improve the accuracy of the simulation and to evaluate the approach?s ability to model more complex behaviours.

Jan 1, 2007

By Erich U. Petersen

Recognition of mineralogical and chemical zoning patterns associated with mineralization is an integral part of mineral exploration. Even though the origin of zoning may not always be known, zoning patterns as expressed by the systematic distribution of ore and gangue minerals, alteration or elemental assays (soil and rock geochemistry) have received much attention and are extremely useful in guiding exploration efforts toward locating economic mineralization. By contrast, the potential of using zoning information recorded in solid-solution minerals to address practical geological-engineering problems has received less attention. Solid-solution minerals can provide critical information for common problems faced in exploration, mine development and valuation. Mineral zoning information from solid-solution minerals can now be easily obtained because advances in electron microprobe instrumentation have made these instruments a most efficient, accurate, economical and practical tool for analysis of large numbers of samples. Now entire mines and districts can be studied in a timely and cost-effective manner as required by modern mineral exploration and mining practice. This article shows how knowledge of the composition of fahlore minerals can be used in addressing important problems in exploration, development and valuation. Situations are described in which drilling intersected "low grade zones" (Case one: Orcopampa, Peru, precious metal system) and where there was a need to determine the "lateral correlation of multiple ore intercepts" (Case two: Sheep Creek, Montana, sediment-hosted sulfide deposit).

Jan 1, 1992

By M Chiquito, R Castedo, P Segarra, L M. López, J A. Sanchidrián, J Navarro

The aim of this work is to assess the performance of different constructive solutions against explosions on the strength of masonry walls. The solutions tested, namely an external metal mesh, a glass fibre film on the external face of the wall and a basalt fibre film located on the inner face of the wall, have low to medium cost and are originally designed for other purposes, like seismic protection. Four cubic boxes 3 × 3 × 3 m were built using each of the solutions and typical masonry blocks. In the tests, a spherical plastic explosive initiated in the centre was placed at scaled distance of 2.9 m/kg1/3, so that moderate damage would be caused on the wall. In order to assess the performance of the explosive, pressure gauges were placed at the wall and at different distances from the explosion. Additionally, vibrations were monitored with seismographs in the far field and a high-speed camera was used to estimate the shock wave velocity during the tests. The resulting damage has been evaluated on 13 points of the external wall of each box using a rebound hammer. Damage maps have been drawn for each wall based on these measurements and damage has been assessed inside the box considering the fragments mass launched during the test. The use of external metal mess leads to a decrease of 34 per cent on damage of the external wall and 38 per cent reduction of spalling. The use of a film in the inner wall provides a strong reduction on spalling.CITATION:López, L M, Segarra, P, Castedo, R, Sanchidrián, J A, Navarro, J, Santos, A P and Chiquito, M, 2015. Performance of different constructive solutions against explosions in full-scale masonry walls, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 819–824 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By William Ewing

Copper is rapidly being adopted by the semiconductor industry as the interconnect material of choice. The aqueous processing techniques used generate wastes such as spent electrolyte from electroplating, electroplating rinse water, copper solutions from removing copper from the back of the wafer and CMP waste streams. We are examining the use of chelating resins as a means of recovering copper from these streams within the processing plant, thereby allowing recycling of process water and minimizing hazardous waste disposal costs. We have examined the effect of model plating additives (and other organic complexing agents) on the efficacy of Dowex M4195. Although these might have had a significant effect, commonly used electroplating additives polyethylene glycol (PEG), benzotriazole (BTA), thiourea, glycine, and 3-mercapto-1-propanesulfonate (MPSA) each had little or no effect on the ability of the resin to chelate copper and remove it from solution. This suggests that Dowex M4195 could be useful for treating waste solutions of rather variable compositions.

Jan 1, 2003

By Cornelis Van Der Veen

Foundation piles, partly passing through unconsolidated compressible layers, suffer a downward drag that is called negative skin friction. The negative skin friction depends on the movement of the surrounding unconsolidated soil relative to the pile and on the friction between pile and soil as a function of that movement. The negative skin friction adds to the load on the pile. However as it is a function of the pile movement relative to the soil, the amount of negative skin friction to be taken into account to determine the allowable bearing capacity depends on the allowable pile settlement. In this paper this property is indicated by the factor µ. As under the conditions of ultimate pile bearing capacity negative skin friction does not occur, a factor of safety is introduced, which is lower than normal. Eventually a formula for the bearing capacity is given in which µ and both figure. The exact values for given circumstances have to be determined empirically. A few examples are given.

Jan 1, 2010

By BHAMIDIPATI S. SASTRY, SRIVATSAN J. SRIDHARAN

Pressure losses in mine ventilation systems are estimated using friction factors and shock loss factors. The efficient planning and designing ofmine ventilation systems depend on the accuracy of the friction factors as well as the shock loss factors that are taken into consideration. While there is a much more acceptable knowledge of what constitutes friction loss in mine roadways, the shock loss factors are in general readily not available for all possible contexts of flow separation phenomena in mines. One such special case of shock loss in mines is the train of mine cars in the airway. Mine cars are widely used for the transportation of material, and the information on shock loss factor for mine cars is limited. This paper examines the pressure loss occurring due to a train of mine cars in an airway using scale model studies and numerical investigations. Computational fluid dynamic (CFD) studies are conducted using four different turbulence models. The performance of different turbulence models is analyzed by comparing it with the experimental results. The study suggests that the boundary layer resolution method is significant in the simulation of shock loss. From the study, it is found that the shock loss factors from presently available model overestimate the pressure loss by 7 to 15 times. A better prediction model for the shock loss factor of a train of mine cars in the airway is proposed using the experimental results.

Jul 24, 2020

By T. -W. Hong, Y. Son, S. -J. Hong, D. Choi

The characteristics of indium-tin-oxide (ITO) nanoparticles recovered from TFT-LCD panel scraps were investigated. The ITO was separated from TFT-LCD panel scraps by dissolving the color filter layer located between the ITO layer and the glass substrate. The solution was filtered to separate the ITO from the color filter component, and the filtered ITO was dissolved in the acid solution. ITO nanoparticles were then precipitated with ammonium hydroxide and organic dispersing agent, followed by heat-treatment at 600 °C. HRTEM, EDX and XRD analyses revealed that the 20 nm sized particle were composed of 90 % In and 10 % Sn, and were well crystallized to in the (222) preferred orientation.

Jan 1, 2014

By Michael Kukay, Paul Conrad, Cosmas Opoku-Ware

This project is exploring the potential for developing trees tolerable to degraded un-reclaimed mine site soils and tailings as a solution to re-establishing long-term tree growth on those sites. The project incorporates growing tree seedlings in an underground greenhouse grown from seeds planted in the degraded mine soils in which they will eventually be planted. The outcome of the project is expected to lead to a successful solution for re-establishing tree growth in soils and tailings containing high metal concentrations with minimal post-planting human intervention. The research is being conducted in an underground greenhouse located 100 ft below the surface in the old Orphan Boy Mine Underground Mine Education Center (UMEC) located on Montana Tech’s campus in Butte, Montana.

By W. M. Weigel

LESS advances in the technology of non-metallic minerals than for several years past mark 1931, and the cause is easily found. The universal depression and decreased markets for non-metallic as well as other mineral commodities has forced the producers to cut out all unnecessary expense and reduce operating costs to a minimum in order to keep going, even on a reduced output, and to prevent insolvency. The result. has been that but 'little research has been carried on, and such as has been completed has in but few cases been put into commercial practice on account of the expense involved in new equipment and plant changes. The trend in the industry has been more economic than technologic, and the greatest effort put on market studies and sales attempts to expand markets and scrutiny of present operating 'practice leading to reduction of cost of production. This tendency has been increased by highly competitive conditions and the buyer's market which has prevailed and to the fact that price has been a greater factor than quality in placing orders. Only in cases where improvements in technology would immediately and effectively reduce costs or where in special cases there was but little competition with almost a monopoly control has actual technical development taken place.

Jan 1, 1932

By K. Esmaieli

This paper addresses issues associated with ore pass degradation caused by material impact. A series of numerical experiments, using the particle flow code, were undertaken to investigate the influence of various finger raise configuration. This has allowed the identification of favorable configurations. The results of this analysis, when coupled with field observations, can contribute to the design of ore pass systems that can prolong the useful operating life of ore pass systems.

May 1, 2009

By Waleska Campos Guaglianoni

With the growth of nanoscience and nanotechnology, the synthesis of nanostructured oxides has received a special attention. Metal oxides are widely used in the manufacture of microelectronic circuits, piezoelectric devices, fuel cells, catalysts, filters and bactericides systems. These metal oxides represent a large class of semiconductor materials suitable for photocatalytic processes. In recent years, new materials of this class such as TiO2 and ZnO have been developed due to their photo-catalytic abilities to degrade various environmental pollutants. This work aimed to evaluate the photocatalytic activity of zinc oxide previously synthesized by combustion synthesis in solution using citric acid as fuel and different reasons fuel/oxidant. After synthesis, the powders were subjected to heat treatments at different temperatures and photo-catalysis. The photocatalytic activity was evaluated by the degradation of a solution of methyl orange in a photochemical reactor of UV illumination, after which the transmittance of the samples measured with the assistance of a spectrophotometer. To analyze the results, a commercial zinc oxide was used as standard. The products of combustion synthesis in solution showed that photocatalytic activity varied according to the ratio fuel/oxidant and as a function of heat treatment. The results showed a higher photocatalytic activity for the products obtained with disabilities fuel in the reaction and heat treated.

Aug 8, 2018