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By Y. De Gao, C. Gang Zhong, X. Yang Qiu, Li Wan

The chelating reagents are used as effective collectors in wolframite flotation, and certain metal cations need to be added using chelating collectors so as to activate valuable minerals and obtain good flotation indexes. Different metal cations will result in different reactivity with collectors, in order to select the effective activator in BHA flotation of wolframite, the activation effectiveness of different metal cations on wolframite ((Fe,Mn)WO4) flotation were studied using pure minerals. The results showed that the wolframite activation by Pb2+was the best among the selected cations. The maximum flotation recovery of wolframite was found to be 95.58 % under conditions of 100mg/LBHA and 1×10-4mol/L of Pb2+at pH 9. The dosage of Pb2+needs to be controlled in an optimum range. Also, the activation mechanism of Pb2+ on BHA flotation of wolframite was investigated by measurements of contact angle, zeta potential, adsorption capacity and IR spectroscopy. It was found that Pb2+ could chemically adsorb onto the wolframite surface improving the flotability of wolframite and enhancing the adsorption of BHA on wolframite. When the dosages of BHA and Pb2+ were 100 mg/L and 1×10-4 mol/L, the adsorption quantity of BHA on wolframite sharply increased up to 0.30 mg/L at pH 9 compared with wolframite treated with only BHA.

Jan 1, 2014

By Deventer Johanna van

Ore bodies around the world are declining in grade, whilst increasing in complexity. The level of impurities relative to the valuable metal is steadily increasing, posing new challenges to existing operations. Ion exchange is widely used in the hydrometallurgical industry for both primary recovery of metals and the removal of impurities. The superior selectivity of ion exchange resins makes them exceptionally suitable for the removal of target impurities to very low levels, thereby saving operating costs, increasing the value of the final product and significantly improving revenue. The ion exchange process in these applications is very simple, using standard ion exchange equipment and acid regeneration. The process can be fully automated, requiring minimal operator interference and supervision Examples of impurities that are successfully removed via ion exchange include iron, antimony and bismuth from copper electrolyte. In the copper electrolysis process, antimony, bismuth and arsenic tend to form slimes which are dispersed in the electrolyte. These slimes contaminate the cathode and/or decrease the quality of the copper deposition. A special chelating resin was developed to remove antimony and bismuth, while at the same time ensuring minimal chloride leakage to the sulphate matrix. The work is described in more detail in this paper. Ion exchange is also used to remove copper, zinc and nickel from cobalt electrolyte. This paper addresses a few of these examples in more detail.

By Mike Adams

Comprehensive pilot testwork has been conducted on BHP Billiton's Ravensthorpe nickel laterite deposit over a fifteen-month period at Lakefield Oretest. Some 228 tonnes of ore were processed in a beneficiation pilot-plant comprising scrubbing, attrition scrubbing, screening and thickening over sixteen pilot runs with an average mass closure of 99.2%. This produced a suitable feed for hydrometallurgical piloting over seven runs covering 1,680 hours of operation. The integrated EPAL® (enhanced pressure acid leach) circuit comprised a limonite pressure acid leach front end discharging into a saprolite atmospheric leach circuit and subsequently to induced jarosite precipitation, counter-current decantation, iron removal, mixed hydroxide precipitation, and manganese removal. The pilot plant met its key objectives in demonstrating the flowsheet's technical viability, and generating raw data inputs for the project feasibility study. Rapid, intensive data capture, collation and reporting helped solve key flowsheet issues. The pilot plant also demonstrated its value as a risk management tool in the resolution of numerous engineering, metallurgical and materials selection issues at a manageable scale. A disciplined approach to experimental planning, operation and management was a significant contributor to the overall success of the campaign. Keywords: Ravensthorpe, Nickel, Piloting, Beneficiation, Pressure, Leach

Jan 1, 2004

By F. A. Baczek

The Electroslurry TM electrowinning concept has been incorporated into a process flowsheet for recovering copper from smelter flue dusts. The process has averaged 96% recovery of the copper as high-grade electrowon while at the same time removing a majority of the impurities that degrade drawn copper as a result of recycling flue dust and liberator cathodes: The dust is processed through several stages consisting of leaching, copper precipitation, Electroslurry TM electrowinning and waste liquor treatment. The process may be integrated into a smelter operation and become an effective and feasible means of maintaining good product purity.

Jan 1, 1980

Certainly, one of the core processes for the recovery of fine magnetic susceptible iron ore particles, mainly hematite iron ores, is the wet high intensity magnetic separation or WHIMS. This paper outlines a variety of recent developments and innovative process designs in the JONES® type WHIMS. It highlights the latest examples of flow sheets in terms of the diversity of combined rougher, scavenger, cleaner stages and adds to this the new more advanced JONES® type WHIMS equipment technologies like the HIGH FLOW ? HF, the QUATTRO ? Q and the SPLITT OPERATION ? SP. As a result of the increase of the capacity and magnetic intensity, the specific production cost could be decreased. The high worldwide acceptance for this continuous development testifies for the success and state of the art technology.

Sep 1, 2012

By Bent Babel, Martin Rudolph

"The characterization of reagent-mineral interactions in flotation systems of finely intergrown ores holds difficult challenges for the applicability of standard techniques like Hallimond tube tests and contact angle experiments or renders them impossible due to a lack of sufficient samples in terms of quality and quantity. This disadvantage may not apply to more sophisticated techniques, but these often do not work in an aqueous environment. We present the utilization of an atomic force microscope with a hydrophobic colloidal probe to characterize the wettabilities of individual mineral domains of an ore sample, while additional spectral information is gathered by Raman spectroscopy. The exemplary ore sample investigated is mainly containing cassiterite and quartz, therefore the reference measurements like Hallimond tube tests and contact angle experiments were carried out with this binary system as a comparison. The focus of the study lies in the correlation of data gathered by the atomic force microscope and the Raman spectrometer with data from standard techniques. Finally, the applicability of the colloidal probe atomic force microcopy technique for reagent-mineral investigations is critically evaluated.INTRODUCTIONThe focus of this paper is the application of colloidal probe atomic force microscopy (CP-AFM) for theinvestigation of reagent-mineral interactions on a binary system of cassiterite and quartz. This and similar concepts using hydrophobic AFM probes have been applied by multiple authors (Rudolph and Peuker, 2014a; Rudolph and Peuker, 2014b; Wada et al., 2017; Xie et al., 2017). The hydrophobic interaction is the main interacting mechanism for the hydrophobic colloidal probe with hydrophobic sample surfaces and the long range attractive component has been accounted to nanobubbles on the interacting surfaces (Yakubov et al., 2000). More detailed information on nanobubbles are available in two reviews compiled by Attard and Hampton (Attard, 2003; Hampton and Nguyen, 2010). This paper is based on the work by Rudolph and Peuker comparing different AFM based measuring concepts, additionally gathering data with Raman spectroscopy and correlating results of microflotation and CPAFM measurements (Rudolph and Peuker, 2014a; Rudolph and Peuker, 2014b)."

Jan 1, 2018

By Ye Chen, Jianhua Chen, Meng Liu, Yuqiong Li, Xiao Mu, Cuihua Zhao

"Sulfidization-amine is the most effective method for the recovery of smithsonite (ZnCO3), however the interface interaction details remain unclear. The sulfidization-amine flotation mechanism of smithsonite has been studied by Density Functional based Tight Binding (DFTB+) method in this paper. The slab model of ZnCO3 (101) surface was built and the adsorptions of a monolayer of HS- and S2- ions were conducted to model the sulfidization effect on the ZnCO3 (101) surface adsorption. DDA hardly interacts with the hydrated ZnCO3 (101) surface. Under the low concentration of Na2S, HS- ions form a Zn-SH-SH structure on the ZnCO3 (101) surface, which hinders the interaction between DDA and surface Zn atoms. Under the high concentration of Na2S, a layer of ZnS is formed on ZnCO3 (101) surface, which is favorable for the adsorption of DDA on the surface. This is consistent with the flotation practice where smithsonite flotation requires a large amount of sodium sulfide. The results could provide a microscopic investigation into the sulfidization-amine flotation mechanism of smithsonite.INTRODUCTIONSmithsonite (ZnCO3) is an important and typical oxide mineral of zinc. It is a semi-soluble salt mineral with a solubility product constant of 1.46 × 10-10 (Weast, 1973). The most common and effective method to recover oxidized zinc ores is froth flotation (Caproni et al., 1979; Pereia and Peres, 2005; Kashani and Rashchi, 2008). It is well known that the flotation of oxidized zinc minerals is much more difficult than the flotation of zinc sulphide minerals (Hosseini and Forssberg, 2007).The recovery of zinc oxide ores with poor floatability attracts more and more attention due to the depletion of easy-recovered of zinc sulfide ores.Sulfidization-amine flotation, which using Na2S as sufidizing agent and amine as collector (Mckenna et al., 1949; Rey, 1954; Abramov, 1961; Rey, 1979; Hosseini and Forssberg, 2007). This method is the most successful technology used for zinc oxide minerals flotation in large-scale industrial applications since it was invented in the 1950s (Önal et al., 2005; Pereira and Peres, 2005). There have been numerous experimental researches on the sulfidization-amine flotation of smithsonite. Shi et al., (2013) studied solution chemistry of smithsonite flotation system. Feng and Wen (2017) studied the formation of zinc sulfide species on smithsonite surfaces and its response to flotation performance. Wu et al., (2017) investigated the sulfidization behavior of smithsonite with the use of zeta potential, inductively coupled plasma (ICP), scanning electron microscope (SEM), and X-ray photoelectron spectroscopic (XPS). Their measurement results confirms the chemisorption of sulfur ions and the formation of ZnS film on the smithsonite surface after Na2S treatment, however the influence of HS- ions on the surface and the influence of sulfidization on the amine adsorption have not been discussed."

Jan 1, 2018

By D. L. Lampshire

Biological leaching using native heterotrophic bacteria was studied by the U.S. Bureau of Mines as a means of extracting manganese from a domestic low-grade wad ore. Column heap leaching simulation techniques were employed using molasses as the nutrient source for the bacteria. These column studies were designed to investigate the effects of molasses medium flow rate, concentration, and replacement interval on the extent and rate of manganese extraction. .Results showed that flow rates between 0.41 and 8.1 L/min/m2 had little impact on manganese extraction. The total amount of molasses used did have a direct effect on the extent and rate of manganese extraction. Manganese extractions over 90-pct were obtained in 12 weeks of bioleaching with 2-week medium replacement cycles.

Jan 1, 1993

By C E. Gordon Brown

Aircraft utilization, weather and cost data are given for three separate projects north of the sixtieth parallel in the Northwest Territories and the Yukon Territory. These operations, carried out by helicopter-equipped geological and prospecting parties, have cost $24 to $30 per square mile, depending principally on the distance from the base. They provide adequate surface exploration of areas with 40 to 50 per cent rock outcrop. A good one-inch-to-one-mile geological map can be made. T HE exploration of the Canadian northland has been given increasing attention by the mining industry during recent years. In many cases, the initial problem is to make an adequate reconnaissance of a large area where existing geological information is meagre. The Geological Survey of Canada pioneered the use of helicopter-equipped geological parties for mapping at a scale of eight miles to the inch.

Jan 1, 1964

By G. B. Gait

This report is the fifth in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region. A catalog of the microfilmed maps of 47 of 49 major mines and 18 independent mines in the Southern field is presented. Previous reports included catalogs of microfilmed maps of mines in the Eastern Middle field, the Wyoming and Lackawanna Basins of the Northern field, and the Western Middle anthracite field.

Jan 1, 1978

By Jiongtian Liu, Guixia Fan, Caom Yijun

A cyclonic-static micro bubble flotation column (FCSMC) is an effective separation device for fine grain treatment. The separation of fine ilmenite by FCSMC was explored in this work. The influence of reagents dosage (regulator, collector and auxiliary collector), pulp density, circulation pressure and aeration quantity on TiO2grade and recovery wasinvestigated.The optimal conditions of a rougher are follows: pulp density 45%, pH 5.0, MOH collector dosage 2800 g/t, diesel oil dosage 700 g/t, circulationpressure 0.19 MPa, aeration quantity 0.8 m3/(m2•min). The optimal conditions of a cleaner are follows: pH 4.0, circulation pressures 0.16 MPa, and aeration quantity 0.5 m3/(m2•min).A pilot plant continuous test with a rougher-cleaner by FCSMC for 72 hours was proceeded under the optimum conditions. Compared with industrial flotation machines, the concentrate grade of FCSMC is 48.11% with an improvement of 1.08 percentagepoints, while the recovery is 82.36% with 13.64 percentagepoints increment. Moreover, the flowsheet is simplified from six parts (a rougher-two scavenger-three cleaner) in flotation machines to two parts (a rougher-cleaner) in FCSMC. Proofs were also provided by the analysis of the by-size grade and recovery of concentrate.Results show the FCSMC is an effective separation device to recover -74 µm size fraction.

Jan 1, 2014

By H. S. Chiang, S. S. Peng

"SummaryAir velocity distribution surveys on four mechanized longwall faces are presented and discussed. Although there are discernible patterns in the velocity distribution, there are wide differences in distribution in the cases examined. This can be attributed to differences in mining and face geometry. An important factor is air leakage into the goaf.IntroductionOver the past two years several intensive air velocity surveys have been carried out in West Virginia coal mines as part of a programme aimed at understanding dust transport mechanisms on mechanized longwall faces. These are presented here and some of the patterns of velocity distribution are discussed.Ventilation survey methodologyThe air velocity vector consists of three mutually perpendicular subvectors; the vertical subvector is directed toward the roof, one of the horizontal subvectors is parallel to the coal face and the other pointing to the gob. The air velocity which was measured in this paper is the horizontal subvector parallel to the coal face.To record the velocity distributions at the longwall faces, the surveying stations and the surveying points were established as follows.(1) The first station usually was set at the third support from the headentry T-junction. Within the first few supports, the air coming from the intake airway encounters a sharp right-angle turn at the T-junction, and forms a turbulent region close to the coal face. The intake air in this region is also influenced by the motors that drive the face conveyer. But when the air reaches the different. But for the same face the number was the same. The main air-travelling area was divided into six to 12 equally sized sub-areas, and each surveying point was situated approximately at the centre of the sub-area.The velocity survey was carried out by two persons, one reading the meter and the other taking down the readings. A complete survey at one station took about 5-8 min. Usually, the dimension of the cross-sectional area was measured during that time.A third person used the smoke tubes to observe the following: (I) the air movement patterns at different locations; (2) the extent and the direction of the air leakage; and (3) the machines' influence on the main airflow. At the same time he observed and recorded the roof conditions and the compactness of the roof-caving in the gob."

Mar 1, 1989

By V. I. Lakshmanan

Wastes when produced can be reused or recycled prior to disposal. Industries that cause environmental concerns during manufacturing include primary materials and primary metals. Pollution prevention mechanisms to achieve waste reduction require new separation, reclamation, control and process simulation technologies. Substituting recyclables for virgin resources will reduce energy use, water pollution, air pollution, water use and mining wastes. Shrinking landfill space will spur new technologies for waste treatment and recycling. These situations hence offer opportunities for innovative flowsheets with appropriate separation technologies. Development of innovative flowsheets to treat recyclables offer unique opportunities for process/product development, obtain green products and hence market advantage. The paper will illustrate with selected innovative flowsheets to treat recyclables.

Jan 1, 1996

By Ivan V. Klumpar

If components of a gas-liquid stream react with each other and with stationary solids, involving parallel and sequential, reversible and irreversible, and slow and instantaneous reactions, the process can be defined by a set of simultaneous differential rate equations and simulated as multistage semibatch re¬actors. Each stage is divided into finite time increments. Within each increment, even the simultaneous reactions are treated as sequential. The proposed method follows process evolution from non-steady state startup to normal operating conditions. It allows computing byproduct buildup in recycles, tracer response curves and, in case of underground processes, expansion to adjacent parts of the deposit.

Jan 1, 1979

By Fathi Habashi

Nitric Acid has been used for over 50 years in the uranium industry and in phosphate fertilizer manufacture. Its application in the treatment of sulfide concentrates is relatively recent. A review of recent developments is given.

Jan 1, 1999

By H. J. Heinen

The Bureau of Mines, investigated a cyanidation-carbon adsorption technique for extracting gold from arsenopyrite concentrates. Agitation leach experiments were conducted on 85-pct-minus-35-mesh gravity concentrates containing 21.8 oz gold and 6.4 oz silver per ton. Results obtained in leaching the concentrates showed that 96.9 pct gold and 90.7 pct silver extraction could be achieved in 96 hours of agitation. Gold and silver were recovered from the resulting pregnant solution by exposure to granular activated carbon in a countercurrent system. Carbon loadings of 2,556 oz of gold and 502 oz of silver per ton were achieved. These loadings are significantly higher than heretofore thought practical.

Jan 1, 1980

By Hsing Kuang Lin

Ferric chloride leaching w.as applied to a complex sulfide ore from Tok, Alaska to dissolve zinc, lead, silver and copper. Gold in the leaching residue, as well as in the ore, is found to be refractory to the conventional cyanidation process. Roasting, pressure oxidation and elemental sulfur removal followed by cyanidation were tested to improve gold dissolution. Also tested were thiourea leaching and high-pressure cyanidation. The readsorption of dissolved gold by carbonaceous matter in the chloride leaching residue was analyzed. Based on the experimental results, factors causing difficulty of gold dissolution from the leaching residue are discussed.

Jan 1, 1989

By L. H. Lange, F. F. Hintze

"Mineralogical Composition of Cyanite RockIn the group of minerals used in making this study, the cyanite is associated with quartz, mica, and feldspar in the schist. The amount of quartz is variable, but it is always an abundant mineral. Both large and small crystals of quartz occur in irregular masses, rarely ever showing crystal outline. Mica is of the clear and dark varieties the larger crystals being dark as a rule, and the finer crystals of light color, The present mineralogical composition of the mica is rather variable as most of the original biotite and muscovite have suffered alteration, and much secondary mica is present as a result of alteration of the original mica and other minerals present, especially the larger cyanite crystals. A large part of the mica now found in the ore is chlorite, with varying amounts of Jefferisite and others, especially sericite. These are in the form of aggregates, or felt-like intergrowths filling the spaces between the quartz, cyanile, and feldspar.The feldspar is plagioclase probably mostly albite. It is white, possesses good cleavage, and is one of the hard brittle minerals of the rock. It alters to kaolin, and sericite, and more or less of these alteration minerals are present within the feldspar crystals but not separated from them.The cyanite is of two varieties, distinguished by their colors as blue and white cyanite. The blue color varies in intensity, being a pronounced blue in some crystals and paler in shade in others. Some crystals have been seen which possess the blue color in one-half of their mass and are pure white or clear in the other half. The purity of the cyanite is probably not affected by the color, but it is difficult to detect the white cyanite in the ore by macroscopic examination, so that great care has to be exercised in the selection of the ore in the field."

Apr 1, 1931

By Jun Ho Lee, Dae Young Kim, Ebrahim Farrokh, Ki Chang Hyun

"The Jinhae Geoje gas pipeline tunnel project is the largest (7.8 km) and the deepest (90 m) subsea tunnel in South Korea. This tunnel will house a pipeline to carry natural gas from the mainland to Geoje Island southeast of the country to alleviate the increased demands for natural gas, especially in the winter season. Tunneling is currently underway using two slurry shield TBMs of 3.5 m diameter. This paper describes the major design elements of the tunneling machines and their performance evaluation. For this purpose, a thorough analysis of geotechnical information was performed to evaluate the tunnel elevation to reduce the risk of tunneling under high water pressure in unstable and permeable rock mass under 9 bar water pressure. TBM specification and TBM performance were also analyzed using different methods, including well-known models as well as a rotary cutting machine test developed in house in Hyundai Engineering and Construction Company. INTRODUCTION High demand for natural gas, especially in winter season was the primary driving factor for the design of the Jinhae Geoje gas pipeline project. This project is located southeast of South Korea between Jinhae district and Geoje Island and runs for over 50 km length. The mid part of this project includes a 3.5 m diameter subsea tunnel consisting of two sections of Geoje to Jiri Island (4.3 km) and Jinhae to Jiri Island (3.5 km). Figure 1 shows the tunnel project location and its layout. Figure 2 shows the geological profile along the tunnel. As can be seen, the tunnel passes mainly through three rock types: granite, tuff breccia, and andesite tuff. This tunnel was planned to be constructed by two face pressurized shielded TBMs and to be lined with a segmental lining of 2.8 m internal diameter. The major challenge for this tunnel is its maximum expected water pressure at the tunnel invert (8.83 bar). At such a high water pressure, the TBMs required special design to ensure they can handle unexpected water pressure and to ensure the risks for the TBM maintenance intervention are minimal. In this regard, a thorough analysis was conducted on the TBM design parameters and geotechnical information to define required TBMs’ design parameters and to identify the safest tunnel elevation. This paper provides a brief overview of the project geotechnical information, TBM selection and its design specification, tunnel elevation selection, and TBM penetration rate evaluation. In this regard, a rotary cutting machine testing equipment was used to perform trial tests on a similar rock type encountered along the tunnel for performance evaluation and optimization."

Jan 1, 2016

By Karsten Hagenah, Tor Jensen, Jens Laugesen, Øyvind Fjukmoen, Lucy Brooks

This paper discusses operational environmental threshold levels for exploitation of mineral resources in the deep sea. Such criteria are needed to be able to monitor and control deep sea mining with respect to the stringent environmental requirements that are needed. It is recommended to use existing environmental threshold levels for comparable underwater activities. Fields of application are mainly but not exclusively seabed mining operation activities under the governance of the International Seabed Authority (ISA). The threshold levels and limits mentioned in this paper are proposed recommendations based on other activities than seabed mining but are a proven and accepted approach in other maritime industry activities. An example of such other activities with proven and accepted environmental threshold levels are Oil & Gas exploitation activities in the sea. Background The first exploitation of mineral resources in international waters is coming closer. Presently regulations for exploitation for mineral resources in the Area are being developed by the International Seabed Authority (ISA). The ISA regulations will contain the framework related to environmental monitoring of exploitation. However, the regulations will not contain operational environmental threshold levels for the Contractor.

Jan 1, 2018