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By Braam Blom

PK2 Ventilation shaft is part of Paardekraal No 2 twin shaft system that is being developed to replace depleting Merensky reef production at Paardekraal shaft complex. The sinking team at this shaft faced considerable challenge of improving the total sinking cycle in order to be able to deliver the fully equipped shaft on time and on schedule. The cladding support cycle was identified as the tedious and time consuming activity in the overall shaft sinking operation. Reduction in the time required for handling and setting up the support installation equipment, and the time required for subsequent installation of the necessary support has a direct impact on the overall cycle time, and consequently the overall productivity and efficiency of the sinking operation. This reduction in support cycle was achieved by making use of machine carousel. The objective of this paper is to describe the support methodology that was used during the ventilation shaft sinking and the use of the machine carousel to reduce the cladding support cycle. The machine carousel replaces the traditional use of machine kibble in conventional vertical shaft sinking and has been designed specifically for installation of sidewall support at the shaft bottom during the sinking process.

Jan 1, 2009

By R. T. Tshikhudo

Nanotechnology can provide solutions to many of the world?s socio-economic challenges. The application of nanomaterials for water treatment and analysis, point-of-care diagnostics and targeted drug delivery systems or devices could improve the quality of life for people in developing countries. Gold colloids have a long history (dating back to the 4th century AD) and are particularly well known for their aesthetic appeal and their therapeutic properties. Since Faraday published a report on the synthesis and properties of colloidal gold in 1857, a reasonable insight into the nature of gold sols (nucleation, growth and kinetics of coagulation) has been developed. Considerable attention has been drawn during the past few decades to the development and optimization of methods for the preparation of gold nanoparticles. In nanoscience and nanotechnology today, gold nanomaterials appear to be the most widely used material by both academics and industrialists. This is due to the extraordinary properties of gold nanoparticles (e.g. optical, catalytic, and magnetic?they are also known to act as strong Raman enhancers and may also amplify fluorescence under certain circumstances). Mintek, through Project AuTEK and the DST/Mintek Nanotechnology Innovation Centre (NIC), has been at the forefront of the development of new industrial uses for gold. Mintek?s gold nanotechnology programme focuses on the development of gold-based nanostructured materials and their applications in health, water and other related areas. While few projects use gold nanoparticles for water treatment and analysis, Mintek?s gold nanoparticles are widely used in the health sector. For example, gold nanoparticles are engineered and produced in large quantities as systems for targeted drug delivery. They are also used as tools for advanced rapid diagnostic tests. Both optical and electrochemical rapid diagnostic methods are developed for the human and animal health sectors for point-of-care testing. This paper gives a brief introduction and overview of gold nanotechnology, and desrcibes the development of some of Mintek?s gold nanoparticle targeted drug delivery systems and lateral flow point of care prototype devices.

Jan 1, 2009

By G Davies, D Dunn, C Mawdesley, O Bertoli

The coal industry in Australia has been actively working in recent years towards the (re)integration of geostatistical techniques to the process of coal resource estimation. The benefits of using geostatistical techniques, over the current interpolation algorithms in use in coal modelling packages used to generate the grid estimates, need to be illustrated for the methodology to gain a broader acceptance in the coal industry. This paper focuses on the benefits gained at BHP Billiton Mitsubishi AllianceÆs Saraji mine for the estimation of the total product yield value at a 9.7 per cent product ash cut-off of a particular seam of the Saraji deposit. In order to perform this comparison, the results of the alternative estimation methodologies need to be benchmarked, which in most situations is achieved through the reconciliation of the estimates against production and/or process plant reconciliation data. Unfortunately, this benchmarking was not possible as no reconciliation data for the area of interest in the chosen seam was available, as it has not been mined at the time of the study. Where no reconciliation data is available, an alternative method is to use conditional simulations as the benchmark for comparison. The simulated values can be regarded as ærealityÆ, and the alternative estimation methodologies, based on a sampling of the underlying ærealityÆ, can then be compared using the simulated ærealityÆ as the benchmark for comparison.

Jan 1, 2009

By Naj Aziz

Both bolt profile shape and spacing (rib spacing) have been found to influence the bonding capacity of the grouted rock bolt. The bolt surface profile configuration has greater importance to rock bolting in strata reinforcement in mining than the steel rebar used in civil engineering construction. This is because a rock bolt in mining usually is subjected to greater dynamic loading than the steel rebar in civil engineering construction. The increased bonding capacity of a bolt is important when supported ground is either heavily fractured, faulted or the supported ground is of soft formation, typically that of coal measure rocks. Past laboratory studies have identified the bolt profile spacing as of significant relevance to bolt resin rock bonding increase, however, no attempt has been made to determine the optimum spacing between the bolt profiles spacing. Accordingly, a series of laboratory tests were carried out on 22 mm core diameter bolts, commonly used in Australian mines, installed in cylindrical steel sleeve. The study was carried out using both push and pull testing methods. The push test was carried out in 150 mm long sleeves while the pull testing was conducted in 115 mm long sleeves. Profile spacing tested include, 12.5, 25.0, 37.5, and 50 mm lengths. Additional studies undertaken include modelling the profile of the load-displacement data of pull testing. Bolts with a profile spacing of 37.5 mm were found to provide optimum load bearing capacity as compared to other tested profile spacings.

Jan 1, 2009

In this study, a 3D model of the shovel motion based multi-body system dynamics in the Automatic Dynamic Analysis of Mechanical Systems (ADAMS) environment was developed. The kinematics model of the shovel was modeled as a multi-body system, which comprises the lower, upper, and the attachment mechanisms. The Euler-Lagrangian equations were employed as the computational framework to describe the dynamic behavior of the model. A virtual prototype of the shovel was built in the ADAMS software environment. This environment allows the visualization of a 3D motion of the general mechanical system and the prediction of interference of the moving components of the shovel. The numerical analysis and animation of digging, swinging and dumping motions for the shovel were performed. The superimposed display of the deployment for the shovel in three phases allows a detailed examination of the dynamic interference among assembly components. This research provides a solid foundation for further shovel dynamics performance studies. Keywords: Shovel, Spatial Kinematics, Virtual Prototype, Visualization

Jan 1, 2009

By Jonisha P. Pollard

In restricted vertical working heights such as low-seam coal mines, workers are forced to assume kneeling or squatting postures to perform work. These postures are associated with increased risks for the development of significant knee pathologies such as meniscal tears and osteoarthritis [1,2]. Previous research has shown an increased applied knee flexion moment when kneeling in high flexion [3]. However, these models have been applied to flexion up to 140° which neglects contact between the thigh and calf which occurs beyond 140°. In addition to thigh-calf contact, when kneeling near full flexion there may be additional contact between the heel and gluteal muscles. To the author?s knowledge, heel-gluteus contact has not been previously investigated, but thigh-calf contact has received some attention. Zelle (2007) reported thigh-calf contact forces up to 30% bodyweight (BW) [4]. Zelle (2009) reported decreased knee forces when accounting for thigh-calf contact [5]. Caruntu (2003) reported erroneous force and moment estimations when thigh-calf contact was neglected from models to determine muscle and ligament forces [6]. In this study thigh-calf and heel-gluteus contact forces were quantified to determine their effect on the externally applied flexion moment in high flexion.

Jan 1, 2009

By George Burke

"Many soil mixing methods have evolved over the years, but the Trench Cutting Re-mixing Deep method (TRD) was developed in Japan, circa 1993, to construct continuous uniform cutoff walls, without the need for an open trench. TRD mixing has been used on over 300 projects in Japan for excavation support, groundwater barriers, liquefaction mitigation, soil improvement and pollution containment. To date, TRD mixing has been used on only three projects in the United States: a test cell in Long Beach, Calif., for seawater intrusion barrier in 2004; a groundwater barrier at a wastewater treatment plant in Lincoln, Calif., in 2005; and presently at Herbert Hoover Dike surrounding Lake Okeechobee in southeastern Florida.The most notable benefits of TRD are its abilities to overcome difficult geology, such as layered rock and dense cobbles and gravels that hinder other soil mixing methods, and to create extremely high-quality walls. The method is ideal for situations in which access precludes the use of more traditional methods due to spoil control, such as waterways and congested urban environments or subsurface obstruction/difficult ground. Spoil disposal is minimized since TRD mixes the soil in place.TRD mixing has a horizontal continuity advantage over traditional multi-auger deep soil mixing (DSM) systems. Because DSM systems create walls by overlapping soil-cement columns, the auger may be deflected by difficult ground, and gaps are possible. Gaps may also occur when constructing an exceptionally deep wall due to the possibility of auger deviation from its required vertical alignment.The method also has a homogeneity advantage in layered soils. Because DSM constructs columns by rotating the defined length mixing tools up and down the soil profile while injecting binder, strength and permeability in each layer will vary. The TRD method vertically mixes the entire profile and core samples show highly uniform strength. It is most cost-effective in deep difficult ground such as layered rock or dense cobbles and gravels."

Jan 1, 2009

By Jeff Wachendorf

As the title "Cast Blasting Around Town" implies, this paper details the starting of a cast blasting program in and around the town of Colstrip, Montana. As strip ratios have increased, the need to adapt and find solutions to provide coal at a reasonable cost to the captive power plants has risen. Colstrip, Montana has a long history of coal mining which dates back to the early 1920's when Foley Brothers began supplying coal strictly for powering locomotive engines. Early mining days starting in the 1920's and the progression up through the 1970's when mine mouth power plants were built will be discussed. To accomplish the desired results, early mining techniques included steam and electric powered equipment as well as a lot of actual horse power.

Jan 1, 2009

By M. E. Coleman, G. Money

"Clyde Materials Handling is an established customer-driven solutions provider, which utilizes its knowledge, expertise and technologies to transform the production processes of its customers, who operate in the ferrous and non-ferrous metals industries.With over 30 years experience in the process improvement industry, Clyde Materials Handling has helped their global customer base transform the way in which they operate their processes, which has enabled them to generate sustainable economic benefit and maintain their positions as leaders in their respective markets.Clyde Materials Handling has supported operators within the metals market by developing and deploying pneumatic conveying and pneumatic injection technologies. These environmentally supportive and sustainable solutions have been used to transport raw materials within operating facilities, from storage to silo, as well as injecting these materials directly into the heart of production processes.Clyde Materials Handling has worked closely with their customers, such as Codelco in Chile, where their pneumatic solutions have been used to inject a consistent, pulseless and accurate flow of copper concentrate into a bath smelter, which has helped to fuel the operational capacity, availability and productivity.This paper will discuss and highlight the ways in which pneumatic injection technologies, created by Clyde Materials Handling, and applied in partnership with their customers, have helped to improve the operational performance of the production processes of operators across the non-ferrous metals markets with specific reference to applications in the Peirce Smith Converter.Clyde Materials Handling has applications injecting Electronic Scraps, Dusts, Reverts, and other additives to the Peirce Smith Converter. They also have experience of modified PS Units used for Slag Cleaning. There experience with the Codelco Teniente Converter is also directly related to this area of operation."

Jan 1, 2009

By G. Chi, A. Solomon, J. Lai

"The Buffalo gold deposit is a small deposit consisting of auriferous quartz-tourmaline veins within a granodiorite stock in the Red Lake greenstone belt. This study aims to characterize the mineralizing fluids through fluid inclusion and stable isotope analyses and to compare them with those of the world-class Campbell- Red Lake deposit. Four types of fluid inclusions were recognized, including carbonic, aqueous-carbonic, aqueous, and halite-bearing aqueous, with the carbonic type being the most abundant. Raman analyses indicate that the carbonic phase mainly consists of CO2, with minor amounts of N2 and CH4, and rarely detectable H2S. The homogenization temperatures of the carbonic inclusions range from -41.7° to 30.9°C. The homogenization temperatures and salinities of the aqueous, halite-bearing aqueous, and aqueous-carbonic inclusions are 130° to 276°C and 9.7 to 23.6 wt.% NaCl equiv., 155° to 207°C and 32.9 to 42.3 wt.% NaCl equiv., and 215° to 357°C and 8.3 to 19.7 wt.% NaCl equiv., respectively. The d18OVSMOW values of tourmaline range from 8.2‰ to 9.0‰, and those of quartz from 11.4‰ to 11.9‰, with estimated fluid temperatures from 323° to 399°C based on the quartz-tourmaline isotopic geothermometer. It is postulated that separate CO2-dominated and aqueous fluids intermittently invaded the fracture/vein system in response to fluid pressure fluctuations, with limited mixing. The CO2-dominated fluid, previously recognized in Campbell-Red Lake as the main mineralizing fluid, is inferred to have been derived from deeper parts of the crust. This deep CO2-dominated fluid reservoir might have been a common source for gold mineralization in the Red Lake greenstone belt. Le gîte aurifère Buffalo est un petit dépôt composée de veines de quartz-tourmaline à l’intérieur d’un stock de granodiorite dans la ceinture de roches vertes de Red Lake. Cette étude vise à caractériser les fluides impliqués dans la minéralisation par les inclusions fluides et par les isotopes stables ainsi que de les comparer avec ceux du gîte de classe mondiale de Campbell-Red Lake. Quatre types d’inclusions ont été notes, incluant des inclusions carboniques, aqueuses-carboniques, aqueuses et aqueuses avec halite, les inclusions carboniques étant la variété la plus abondante. Les analyses par spectroscopie Raman indiquent que la phase carbonique consiste principalement en CO2, avec des quantités mineures de N2 et de CH4, et rarement avec des quantités mesurables de H2S. Les températures d’homogénéisation des inclusions carboniques vont de -41.7° to 30.9°C. Les températures d’homogénéisation et les salinités des inclusions aqueuses, aqueuses avec halite et aqueuses-carboniques sont varient de 130° à 276°C et de 9.7 à 23.6 poids.% NaCl équiv., 155° à 207°C et 32.9 à 42.3 poids.% NaCl équiv., et de 215° à 357°C et 8.3 à 19.7 poids.% NaCl équiv., respectivement. Les valeurs de d18OVSMOW pour la tourmaline vont de 8.2 à 9.0‰, et celles du quartz de 11.4 à 11.9‰, avec une température estimée du fluide entre 323° et 399°C sur la base du géothermomètre isotopique quartz-tourmaline. Il est postulé qu’un fluide riche en CO2 et un fluide aqueux distinct ont envahi le système de fractures/veines par intermittence en réponse à des variations dans la pression des fluides, et qu’il y a eu peu de mélange. Le fluide riche en CO2 est également observé à Campbell-Red Lake ou il est le fluide minéralisant principal, il est présumé être dérivé de portions plus profondes de la croûte. Ce réservoir profond de fluides riches en CO2 pourrait être la source commune des minéralisations aurifères de la ceinture de roches vertes de Red Lake."

Jan 1, 2009

By Gordon Chen

The Block 37 Chicago Transit Authority (CTA) Tunnel Construction Project was originally designed by STV to connect Blue Line subway in North Dearborn Street and Red Line subway in State Street in the downtown Chicago Area. The project was proposed using tunnel mining techniques combined with steel pipe jacking and fiber glass rebar soil reinforcement. Weidlinger Associates, Inc. (WAI) and Kiewit Construction Company proposed an alternate design using open cut construction technology. WAI designed a complex temporary excavation support system using Soldier Pile Tremie Concrete (SPTC) walls and Soldier Pile Lagging walls supported by cross lot/corner bracing elements. Below the top of the existing tunnel, a top-down construction technique was utilized. A steel temporary traffic decking system at top of the excavation site served as the daily street traffic function as well as the first level of bracing for the support of excavation. The project encountered great challenges of soft clay conditions in downtown Chicago, numerous existing utilities in the excavation site and the requirements of protection for a number of historical buildings nearby as well as the protection of the city streets. The construction was successfully completed at both State Street/Washington Street and Dearborn Street/Randolph Street. The monitoring system showed that ground movement and adjacent building settlement was kept to a minimum during construction.

Jan 1, 2009

By Jan Mehren, Arild Neby

Underwater Tunnel Piercing or Lake Tap, often also called the Norwegian Method, will in many projects be an important part of the hydro electric development scheme. The very last blasting round in the Lake Dorothy Lake Tap Tunnel, which penetrated into the lake at a depth of 120 ft (36 m), was such a key step in constructing the Lake Dorothy Hydroelectric Project. A lake tap project is multidisciplinary. Besides the pure blasting and construction technique aspect, engineering geological and geometric considerations that aim to optimize the tunnel alignment making a lake tap possible at minimized risk are of significant importance. Output data from numerical model analysis of the hydrodynamics resulting from the blasting is vital for the final adjustments to the geometrical layout. The planning of monitoring systems for the surveillance of hydrodynamic impact on valves and pipes as well as control with water levels and air pressures prior to and during the blasting, are all additional crucial elements in the design. More than 600 lake taps have been successfully performed in Norway since the 1890`s. The technique, which deserves to be called well proven, has been applied mostly in the hydropower sector but over the last 20 years also for shore approaches in the oil and gas industry. The demand for this technique seems to be ever more growing.

Jan 1, 2009

By C. Lara-Valenzuela, R. Perez-Garibay, F. López-Saucedo, A. Uribe-Salas, L. Magallanes-Hernandez

A relationship between gas dispersion parameters, namely gas rate (Jg), gas holdup (Eg), average bubble size (db) and bubble surface area flux (Sb), with the metallurgical performance (e.g., grade and recovery) has been established.. Results of eleven columns operating at five concentrators of Grupo Pefioles (Mexico), ranging between 1.52 to 3.35 min diameter and performing in the cleaning stages of lead and zinc circuits, are presented and discussed. The results showed that the effect of gas dispersion parameters was consistent and that both, Sb and Eg, correlate well with recovery particularly when the influence of feed pulp density is also considered.

Jan 1, 2009

By Jeffrey Loeb

Recent trends in blasting engineering and its related fields, at the level of professional academia, have tended to exclude detailed discussion and examination of the formative experiences of the engineering student. In particular, the extra-curricular aspects of the undergraduate program in engineering—focused, in this case, on the summer job—will be shown to contain a wealth of heretofore underappreciated knowledge in the field. In Surveying the Damage: Post Traumatic Stress and Pre-Blast Surveys, I intend to outline and examine some of the more unusual experiences afforded me by my work as a preblast surveyor in the summer of 2007. In this capacity, I was required to make a visual note of existing conditions of surrounding residential and commercial structures within 100 m (328 ft) of two separate blasting sites in central-east Ontario. In the interest of both convenience and specificity, I have attempted to organize the paper as a crossdiscipline survey of the field according to the conference’s list of suggested topics. In the paper’s first section, I will discuss the topic of Environmental Improvement and Remediation by using a case study in which not one, but two dead cats were found during the course of a routine pre-blast survey. The second section will undertake a discussion of on-site blaster gossip as an entry point into a wider discussion of Workplace Communications Management. In the paper’s final section, I will detail an early morning encounter with a 300 lb, stark-naked trailer park inhabitant as a cross-sectional analysis of the topics of Drilling in Hostile Environments, Vibration and Seismology (Sizemology?), Ethics in Blasting, Crisis Management, Risk Assessment and Public Relations. It is my hope that this paper will begin to open up a critical space for discussion of the formative experiences of engineering students during the undergraduate university program in terms of their far-reaching effects on later performance within the industry.

Jan 1, 2009

By Dennis Dolinar

Improperly designed support systems have led to unplanned roof falls in longwall tailgates. To prevent such falls requires appropriate support and adequately designed support systems. The National Institute for Occupational Safety and Health (NIOSH) is currently developing a standing support design methodology based on the ground reaction curve. To design the support system with this methodology requires a quantitative assessment of the ground and support interaction, which is developed from instrumented test sites installed in longwall tailgates. To compliment and expand the field data results and to optimize the support design, numerical modeling is also conducted. The models are calibrated from the test site data. In the present study, data was obtained from a longwall tailgate in the Illinois basin. The test site was located in the Herrin No. 6 coal seam at a depth of 500 ft. At the site, the immediate roof was a weak shale overlain by a competent limestone. Above the limestone, sandstone formed the intermediate roof. The floor consisted of a weak underclay. In the study, the performance and interaction with the surrounding rock mass of two different standing supports, an engineered crib and a conventional 4-point wood crib were monitored. The two cribs have similar load-displacement characteristics at least through 6 in of displacement. Beyond 6 in, the engineered crib becomes unstable and begins to strain soften and shed load. The measurements and developed ground reaction curves indicated that the tailgate at the mine was a low convergence environment until well inby the face. Because the convergence was well below their capacity, both supports provide more than adequate levels of support to the tailgate. Significant convergence and support loading did not occur until 90 to 100 ft inby the face. The results of this study were also compared with results from similar studies conducted in the Pittsburgh seam to further advance the development of the ?ground reaction curve? based support system design.

Jan 1, 2009

The roasting of sulphide ores and concentrates is often the first step in the production of metals or chemicals. In many processes, the production of sulphuric acid is viewed as a by-product, while in some plants production is an important economic factor. Regardless of the purpose, a pyrite roasting plant consists of mainly three plant sections: roasting, gas cleaning and sulphuric acid. With the addition of air, the pyrite concentrates are transformed into solid oxides and gaseous sulphur dioxide at temperatures of 600 - 1000° C. After cleaning and cooling, the sulphur dioxide in the roasting gas is further processed to sulphuric acid. Two types of reactors are used depending on the application: stationary or circulating fluid bed . For over 60 years, Outotec has progressively been developing the principle of fluidised bed technology in several different reactor types for a multitude of process applications. The versatility of the fluidised bed reactor system has manifested itself in the treatment of minerals, including solid fuels, and for metallurgical processes both in the ferrous and non-ferrous fields. Process applications have included roasting, calcining, combustion and charring of coals, as well as off-gas treatment. This paper provides a summary of the pyrite roasting technology currently used along with a simple cost comparison of pyrite roasting and sulphur burning processes.

Jan 1, 2009

By Y. P. Chugh

A novel dry and wet air dust filter concept was conceived and demonstrated successfully at two mines. A steel-wool and a fiberglass filter, suitable for underground use were identified through laboratory testing and demonstrated in the mine. The steel wool filter was operated with and without water sprays while the fiberglass filter was only operated in the dry mode. The dry steel wool filter provided a dust capture of 37% at a negligible pressure drop. When fine misting water sprays were used on the steel wool filter, the dust capture increased to 51% again with a negligible pressure drop. The filter screen also remained clean and no change in air flow characteristics was observed as a function of time. The dry fiberglass filter however did not perform as well achieving only 11% dust capture while introducing a significant resistance to air flow. This technology is seen to have several applications in underground coal mines.

Jan 1, 2009

By E. Amini

"While methods exist to allow the simulation and optimization of existing flotation operations, there is a deficit in the ability to predict the performance of a new ore type pre-processing. A laboratory scale batch flotation testing methodology has been developed to assess the flotation potential of ores (known as the JK Floatability Index or JKFI). Previous work conducted by Alexander and Collins (2008) showed that the test could be used to predict full scale results in base metal ores. In this work, JKFI tests were applied to three different types of ore and one blend from a greenfields gold deposit to show the test applicability to flotation of precious metals. The results from the JKFI test on one ore type were then used to predict the response of all ore types (including the blend). To validate the predicted kinetic parameters, a comprehensive survey was performed on a pilot plant where each of ore types was processed in the circuit. An acceptable agreement was found between the experimental recoveries and predicted recoveries which indicate the potential of this method for use in predicting the flotation response of an ore.INTRODUCTIONOver 100 years, flotation has been considered an efficient method to concentrate different types of sulphide and oxide minerals and coal. Thus, numerous research studies have been undertaken to find an appropriate model to predict the behaviour of particles in flotation circuits (Barnwal et. al., 2006; Bascur and Herbst, 1983; Cecile and Villeneuve, 1991; Deng et. al., 1996; Zheng et. al., 2006). Most methods are based on the ore flotation response in an industrial plant which is expensive and time consuming to characterise. It is difficult to reliably predict flotation response for new types of ores in industrial scale plants.The floatability component modelling (FCM) approach, developed within the Australian Minerals Industry Research Association (AMIRA) P9 project, has been used to derive models of operating flotation plants for the purpose of simulation and optimisation (Alexander and Morrison, 1998; Alexander et. al., 2000; Varadi, 2006). This approach has been applied at a large number of operating sites treating a wide variety of ores. The approach requires metallurgical surveys to be undertaken in conjunction with batch flotation tests and cell characterisation. This allows ore and machine parameters to be derived, which are then used in the P9 Flotation Model. The development of a FCM generally requires a large commitment of resources and time. While there has been significant support of this approach in industry, the FCM approach is limited to ores already being processed (Runge, 2004; Wightman, 2006)."

Jan 1, 2009

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

By J. M. Musadaidzwa

Skorpion Zinc is located 25 km north-west of the small settlement of Rosh Pinah in southern Namibia. Commissioned in early 2003, Skorpion Zinc became the first mine-to-metal operation to commercially apply a purely hydrometallurgical process route to exploit a zinc oxide orebody. The novel technology, known as The Modified ZincexTM Process patented by Tecnicas Reunidas, comprises sulphuric acid atmospheric leaching, zinc solvent extraction (SX) and electrowinning (EW) to produce London metal exchange (LME) Special high grade (SHG) zinc. Forming the core of the process, the SX step has thrived in its role as a barrier to impurities and also in the upgrading of the pregnant liquor solution (PLS), converting it into a loaded electrolyte (LE) sufficiently rich and pure for EW. Against this successful run, a number of challenges have, however, been encountered in SX due the emergence of upset conditions largely emanating from upstream processes. This paper outlines some of the major deviations that have beset the SX process in its first five years of continuous operation. Impurity excursions, temperature depressions, changes in phase continuity, excess aqueous entrainment, the effect of colloidal silica and the accumulation of rare earth elements on the organic phase will be discussed in detail. Keywords: skorpion zinc, solvent extraction, the Modified ZincexTM Process (MZP) DE2HPA, aqueous entrainment (AE), loaded electrolyte (LE), standard liquid validation (SLV) test, organic continuity, aqueous continuity (AC), electrowinning, colloidal silica, phase disengagement time (PDT), rare earth elements (REE).

Jan 1, 2009