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By Olga Frank-Kamenetskaya

The experimental results of study of atmospheric corrosion processes on Saint-Petersburg bronze monuments surface, received in situ and by means of simulating experiments, have been discussed. Influence of the time factor on corrosion film (patina) mineral composition has been analyzed. Direct dependence between patina mineral composition and environmental conditions has been proved. The sequence of patina phases crystallization has been established. Effect of the chemical composition and heterogeneity of artistic bronze and also monument surface structure on the rate of corrosion process has been regarded. The time variations of mass of the crystallized in the hydrochloric acid vapor phases have been investigated. The kinetic laws of their development at the initial stage of formation, indicating simple (non chain) reactions, have been revealed.

Jan 1, 2006

By Aly M. Abdel-Rehim

The present work deals with a study of the mechanical activation of processing of Egyptian monazite by its simultaneous ball-milling and pressure leaching in order to improve the recovery of thorium and lanthanides from monazite. Experiments of simultaneous ball-milling and alkaline leaching of monazite contrary to autoclave leaching were carried out in stainless steel ball-mills of cylindrical shape under different conditions of temperature, pressure, time and alkali amount and strength. The ball-mills were heated and mechanically rotated in an electric furnace by means of roll mechanism. The effective rotation speed was fixed at 130 rpm in all tests. The charge of steel balls of different diameters was equivalent to 45% of the total mill volume. Monazite was charged in ball-mill without preliminary grinding. It is found that high rate of monazite leaching by ball-milling leaching method is achieved at lower temperature, shorter time and lower expense of alkali than in autoclaves. The results obtained show that complete recovery of thorium and lanthanides from monazite (99.8%) by simultaneous ball milling and alkaline leaching is attained at 140°C within 2 h. It is concluded that processing of monazite by its simultaneous ball-milling and leaching is mechanically activated and accelerated as a result of grinding action of steel balls that caused the continuous removal of the hydroxide product from reacting particle surfaces. This leads to the exposing of fresh and activated monazite particles surfaces to alkali leach solution and consequently the acceleration of the reaction of monazite processing.

Jan 1, 2006

By Jim Mikelait

?? Why do we need security? ?? Needs assessment ?? Elements to any security system ?? Protect, Detect, Alert, Response ?? Electronic Security System Criteria ?? Advantages and Limitations of Various Security Options ?? Internal measures to protect against potentially harmful employees ?? How can technology improve my business?

Jan 1, 2006

By S. Triantafyllidis

The tailings produced from the Kirki (Agios Filippos) high sulfidation epithermal deposit processing plant are laminated, weakly cemented and their particle size ranges from fine sand to fine silt. They are mainly composed of milling residues of gangue (quartz, dickite/kaolinite, pyrophyllite, illite); sulfides and secondary minerals (jarosite group minerals, butlerite, anglesite, beudantite and gypsum) are present to a lesser extent. They have high Pb and Zn (average 0.75 % and 0.57 % respectively) and low S (1.04 to 2.92 %), Cu, As, Cd, Ni and Sb content (average 248, 163, 59, 27, 20 g/t respectively). Stagnant waters forming small ponds on the surface of the impoundments exhibit low pH and high heavy metal and sulfate concentrations. Negative Net Neutralization Potential (NNP) characterizes the tailings, indicating moderate to high potential for acid generation. Application of the TCLP test revealed that the tailings are characterized as toxic because of the increased solubility of Pb and Cd. On the other hand, As TCLP solubility is very low.

Jan 1, 2006

By M. Ataka

Magnesium alloys are not easy to plastically deform at room temperature and may suffer from edge cracking at high reductions, especially during sheet rolling. In this study, the authors attempted to improve the rollability by the low-temperature hot rolling method, in which the rolling temperature range is lower than that of hot rolling, and also by the edge-heating method, which locally heats sheet edges.

Jan 1, 2006

By Gábor Csicsovszki

We have developed a novel method - at the laboratory scale - comprising an ion-exchange separation and a membrane-electrolysis step for the purpose of zero-waste regeneration of spent HCl pickling liquors originating from hot-dip galvanizing of common steels. It is aimed at the parallel regeneration of HCl and iron. Experiments revealed that iron can be electrodeposited at high current efficiencies by maintaining the following conditions: 0.04-0.08 M HCl, 500-1000 A/m2, 20°C and stationary electrolyte in a conventional cell. Zinc in the solution did not disturb the deposition of iron, however it contaminated the product and it poisons the anion-exchange membrane required to tackle acidity during electrolysis. For a preliminary separation, anion-exchange tests were carried out to produce pure iron solutions. Beyond the equilibrium studies, column experiments were carried out showing that low flow rates of the loading solution and the ~1.5 M HCl eluent are essential for separation.

Jan 1, 2006

Electrochemical measurements are presented on electro-deoxidation of silica in molten calcium chloride at 900°C, with porous silica pellets as starting material. Measurements during pre-electrolysis (to remove water from the melt) showed electrochemical noise, which is consistent with the evolution of hydrogen. Throughout, the dominant anodic reaction appears to be CO2formation, based on the observed potential at the anode, and measured anode wear. Because of the presence of dissolved CaO in the melt, some of the CO2 candissolve in the melt; the resulting calcium carbonate formation was confirmed by electrolyte analysis after reduction runs. Reduction of dissolved CO2 at the cathode is likely to contribute to the background current during the reduction process. For the electrode and cell configuration used here, most of the over potential arises from polarization of the anode, and ohmic potential drop in the electrolyte.

Jan 1, 2006

By N. E. Izatt

Molecular recognition technology (MRT) has a wide range of applications in the hydrometallurgical and chemical processing industries for the selective removal of iron as well as various other impurities from a variety of streams, including aqueous solutions through a wide pH range, as well as organic solutions. An example of a commercial application is provided for the removal of iron from an aluminum chlorohydrate stream. In this example, MRT has a selectivity for iron relative to aluminum which is significantly higher than that of ion exchange resins. A discussion of MRT capabilities for other impurities and streams is also provided.

Jan 1, 2006

The main asset of a mining company is the mineral resource; without resources there is no mining business and the infrastructure is useless. In this context the role of the mining geologist is to always keep the resource inventory to an optimum level for the mining business and to maximise the transformation of the resources into reserves in a multi- disciplinary work environment. In short, a ægood mining geologist has to always provide the best ore to the millÆ.To do his/her work properly, several technical skills are needed: to know how to observe and describe nature in order to optimise the data acquisition process, particularly when mapping; to have a good understanding of natural variability in order to develop proper sampling strategies and sample preparation protocols to minimise all the errors generated by the sampling process; to have a good understanding of assaying practices: their limitations as well as their assaying errors; to carefully and properly store the geological data and information and to preserve the geological patrimony; to fully understand ore forming processes to generate the best possible geoscientific models, which are fundamental for the mining business; to fully understand the consequences of the geoscientific models along the value chain from rock to cathodes; and to continuously validate and improve geological practices and models by continuous data collection and observation of geo- mining-metallurgy processes. Some very important behavioural competencies are also needed:long-term vision, passion for excellence and value generation, strategic influence, systemic and innovative thinking, and knowledge and experience transfer. Last but not least, it is important to point out that a deep knowledge of the mining business is essential to add value by using geology best practices.

Jan 1, 2006

By K. Th. Mavrommatis

Cleanness of steel is justified, measured and estimated in steelmaking process through different concepts which are mainly based on operational, empirical or semiempirical parameters and describe ?cleanness as a state?. In this work a theoretical concept is developed, considering ?cleanness as a process? and introducing a dynamic aspect into the quantification of cleanness of a steel melt, linking operational parameters with physicochemical variables, which are based on first principles. This concept and the here derived and developed variables and parameters are based on the earlier defined agglomeration index (AI) of a steel melt, the ratio of the mean inclusions diameter (MID) to the mean inter-particle distance (MIPD), which is shown to be a measure of the agglomeration tendency of the melt after deoxidation, and can serve both, to monitoring cleanness during steelmaking operation and to be useful as a basis for mathematical modelling of cleanness and of the metallurgical measures in plant, associated with production of clean steels.

Jan 1, 2006

By Paul D. Tomlingson

World class performance is the ultimate objective of many maintenance organizations. It marks the organization as a leader in its industry and sets it apart as the ultimate achiever. But what is a “world class” standard and how can it be achieved? Is there a yardstick by which an industrial organization can measure the relative performance of its maintenance activity and compare it with performance levels that universally identify “world class” status? Are there financial formulas, achievements, evaluation techniques or indices that provide this yardstick?

Jan 1, 2006

By Ishwinder Grewal, Michael Fullam

Many factors affect the overall performance of a gravity circuit beyond that of the primary gravity recovery device. It is critical to examine the gravity circuit in its entirety in order to determine the dominant operating variables that affect overall performance. Knelson has developed a mathematical model which has been used to assist in the design of gravity circuits, and in particular, in making accurate predictions of plant scale gravity recovery. More recently, inclusion of recovery by particle size class and additional data from various mine sites and research studies has made the model more robust. The model is now able to predict GRG (gravity-recoverable-gold) recoveries using various devices such as centrifugal concentrators, shaking tables, jigs and flash-flotation within the grinding circuit. The benefits derived by these recent advancements in modeling capability are two-fold; the first is as a tool to assist in circuit design and correct equipment selection and the second is as an analytical tool to help to evaluate and enhance the performance of existing gravity circuits.

Jan 1, 2006

By Hanlong Liu

The construction process and load-bearing behaviors of Cast-in-place Concrete Thin-wall Pipe Piles are analyzed based on its application on Yan-Tong Expressway project. The low strain test, static load test and field excavation are also carried out. It can be concluded that the new type of pile is convenient to construction with high bearing capacity and reliable quality, which has great potential in practical engineering.

Jan 1, 2006

By Dan Payne

Roof falls and other ground control incidents make up a significant portion of fatal accidents in underground mines. BHP Billiton has undergone a review of all fatalities in their operations and divided these into 10 fundamental categories of which underground ground control is one. Each underground roof fall fatality was investigated and the root causes workshopped to develop a protocol for the control of fatalities due to falls of ground. This protocol sets out 22 requirements which each BHP Billiton underground mine site must comply with. This paper describes the development, requirements and application of the protocol within BHP Billiton.

Jan 1, 2006

By L. Gasser, N. Bellinger, H. Awatta, A. Merati

As aircraft age, the extent of interactions between fatigue and other damage mechanisms, such as corrosion and fretting, increases. At present, however, there is no generally accepted methodology within the Aircraft Structural Integrity Program (ASIP) framework to account for the effects of these interactions on life and the residual strength of aging aircraft components. A comprehensive program is being carried out by the National Research Council Canada in collaboration with Analytical Processes/Engineered Solutions, using the Holistic Structural Integrity Process (HOLSIP) to address time and cyclic load issues. This approach predicts the evolution of a discontinuity state in a material from production to retirement. This paper summarizes the results of a study on the 2024-T3 aluminium alloy in different forms (clad and unclad), thickness, and specimen geometry. This study consisted of identifying the microstructural features associated with crack nucleation sites and relating them to the testing parameters and fatigue life. Several coupons were fabricated and fatigue-tested. The fracture surfaces were carefully examined, and the physical characteristics of the microstructural features found near the crack nucleation sites were analyzed. Effect of stress level, loading direction, coupon geometry and surface condition on the number of crack nucleation sites, and fracture origin size has been discussed. Four distinctive mechanisms were found to be responsible for crack nucleation: for unclad materials constituent particles, oxide residue, surface irregularities and for clad samples the clad layer was the sole fracture origin.

Jan 1, 2006

By William R. Yernberg

The 2006 North American Tunneling (NAT) Conference was held June 10-15, 2006, in Chicago, IL. The biennial conference was the first NAT conference by the newly formed Underground Construction Association of SME (UCA of SME). The UCA of SME was formed earlier this year at the request of members of the American Underground Association (AUA) (ME, April 2006, page 75). The conference included a keynote session, technical programs, workshops, a trade show and social activities. The conference exceeded expectations with 570 attendees. They included engineers, equipment manufacturers, representatives from government agencies and other interested individuals in the underground construction industry. The trade show was also a success with more than 86 booth spaces sold. Vendors included the biggest names in the underground construction and tunneling industry and included equipment manufactures, construction contractors and engineering companies. The trade exhibition provided a forum for interested parties in the tunneling industry to meet and discuss services, equipment and techniques.

Jan 1, 2006

By M. Imamura

Sumitomo Metal Mining Co., Ltd. has developed a novel hydrometallurgical process for producing not only copper metal but also iron metal from copper concentrates. Because copper concentrates generally contains the same amount of iron as copper, cost-effective rejection of the iron is a key issue for the development of the process. Conventional hydrometallurgical processes produce a large volume of goethite or hematite for disposal and the residues are not environmentally friendly. In the novel Sumitomo hydrometallurgical process, copper is leached effectively from chalcopyrite concentrates using chlorine gas, followed by purification through solvent extraction and electrowinning for copper and iron recovery. This process has many advantages such as the minimization of the volume of solid waste by the recovery of metallic iron and the production of high purity copper. Iron metal with a purity of more than 98% can be recovered from the purified raffinate. This paper presents the results of the batch and continuous tests of the process flowsheet.

Jan 1, 2006

By M. Hagfors

Underwater explosions have been used several decades for the determination energy content of explosives. It’s the only test method by which shock and gas heave energy values can be determined separately. The total energy is a sum of these two partial energies. This test method enables us to develop explosives for different purposes; the military high explosives should contain more shock energy whereas the gas heave energy is a very important feature for the blasting explosives. The method also enables us to observe the changes and to adjust the energy content of an explosive as a function of increments of one or more energetic component.

Jan 1, 2006

By Moo Eob Choi

A new process for converting sulfur dioxide to elemental sulfur by a cyclic process involving calcium sulfide and calcium sulfate without generating secondary pollutants was developed at the University of Utah. In this process, sulfur dioxide is reacted with calcium sulfide to produce elemental sulfur and calcium sulfate. The latter is reduced by hydrogen to regenerate calcium sulfide. In the present work, the effects of different pelletization conditions for the initial reactant calcium sulfate on the strength and reactivity of the pellets were determined. These conditions include the type, amount, and impregnation method of catalyst, binder amount, and sintering. Experiments were also performed to determine the effects of temperature in the range of 973-1173 K, pellet size, cycle repetition, and water vapor or carbon dioxide content in sulfur dioxide stream on the reaction rates of the cyclic process. Nickel-catalyzed fired pellets produced by the use of molasses or cement as a binder showed good reactivity as well as high compressive strength during the cyclic tests. The binder amount did not significantly affect the reaction rate.

Jan 1, 2006

By S. Foged

Umicore and MWH jointly demonstrated that mechanical dewatering of goethite and neutralised tailings significantly increased the life of a 30 ha tailings pond and improved the operation of the pond. Umicore operates one of its zinc production plants in Balen, Belgium. As part of its production process, an excess of neutralised and goethite¬containing tailings is generated. These have historically been stored inside large lined ponds. As the storage area of the current goethite pond was nearing its capacity, Umicore studied the potential for an extension to the existing embankment. However, this extension would face intense regulatory scrutiny, because the environmental and safety impacts were considered important. Together with Umicore, MWH suggested and investigated an alternative treatment approach consisting of mechanical dewatering prior to storage. A feasibility study was prepared where wet storage was compared to dry storage. Differences in safety risks, environmental impacts and economic costs were outlined. The study demonstrated that the life of the tailings pond could be increased from 6 to 22 years, seriously reducing the environmental impacts and safety risks at no significantly higher cost than would have been incurred with the continued operation of the existing pond. The results of the study are presented in this paper.

Jan 1, 2006