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By J. R. Donald

Surface and interfacial phenomena play a significant role in refractory performance. For example, the wettability of the refractory material with slag, matte, and metal influences infiltration and interfacial reactions. Yet, very little fundamental information regarding the surface properties of refractory materials and slag is available. Thus, in the present work, the sessile drop technique incorporating a high temperature furnace equipped with X-ray fluorescope was employed to investigate the surface and interfacial phenomena of fayalite-type slags on solid alumina at 1200?C. The iron to silica (Fe/SiO,) ratios employed were 1.4 and 2.0, and the oxygen potentials used were log p02 =-11 and log p02=-9 atmospheres. The contact angle between the fayalite-type slags and the alumina were determined to be relatively low, at about 16.9 to 19.6 degrees under the experimental conditions. The surface tension of fayalite slag (Fe/SiO2=1.4) at an oxygen potential of log -11 was 0.298, which agreed with the work of previous researchers. The surface tension of the fayalite was observed to increase with time. The spinel FeAl2O4. was determined to be the product of the interfacial reaction, and 8.8 to 15.8 mass percent alumina was dissolved into the slag after 40 minutes.

Jan 1, 1996

By V. D. Ayurov, N. O. Kaledina

The coal mines monitoring should be based on the usage of simple and evident models, letting in the total unity to reflect a structure of organization of mine, system ability of its construction and specific character of its functioning. Such models are offered to create on the basis of extracted hierarchies of objects of mine. All objects of mine are broken on levels of technological hierarchy. For objects of each level of hierarchy there are made balanced models of entering and leaving material flows. Then these balanced models are coordinated among themselves by the help of the inter hierarchical relations. So the structured-qualitative characteristic of the object of monitoring, reflecting in a kind of the table structure of formation of material flows on mine, their intensity and measure of transformation is formed under transition from one level of hierarchy of mine to another. An example of real us- age of hierarchical balanced models on mine is given. The mathematical models of coal mine monitoring should reflect objective laws of their structural organization and functioning. Therefore under the constructing of mathematical models it is important such a way to reflect a structure of the mine organization, that in totality the models has been reproduction of system ability of its construction. The knowledge of the separate parties of functioning of mine, reflected in particular mathematical models, should "to be packed" in combined unity. Or else, they should be connected in system, convenient for recognition by the person. Considering the mine, the expert allocates multi-dimensionality of the objects of making its elements. He always has the knowledge of laws of development of mining work that is connected with pithy stratification of researched object. In dependence of sparial-temporary level of abstracting there are allocated the horizon, wing of a mine field, layer, panel, extracting face, longwall in coal mine. The human thinking on each of these levels operates with a set of concepts peculiar to him, characteristics, definitions.

Jan 1, 1996

By V. I. Lakshmanan

"Historically flowsheets are developed for efficient separation of metals for economic recovery. With increasing emphasis on reduction, reuse and recycle (3Rs) efficient methods are sought to recover values from a variety of feeds where cost of collection, transportation, local consumer behaviour and regulatory guidelines dictate the development of economically viable flowsheets. Innovative understanding of potential market applications can provide means to develop value added end products. The paper with examples will discuss the use of innovative-separation technologies to obtain value added end use materials from secondary sources.IntroductionFlowsheets are developed for the efficient separation of materials of value for economic recovery. However with increasing societal pressures and regulatory initiatives for stricter environmental guidelines, there is strong need to provide focus to recover materials efficiently and economically in an environmentally accepted manner. North American industries are increasingly caught between demands for high technology value added products and responsibility for environment. An aspect that is receiving increasing attention is Design for Environment'. This incorporates a system wide approach for product design and incorporates environmentally preferable features such as recyclability, disassembly, maintainability, reusability and use of safe materials as part of a product's design objectives.The present paper with case histories will address innovative flowsheet development to convert wastes into recyclables value added products or for minimising generation of waste materials. Case HistoriesProcess for Separating Fibres from Composite Materials 1In the automotive industry, sheet molded compound (SMC) is used to produce panels, bumpers and the like. During the manufacture and at the end of life, considerable waste materials are generated which are potentially recyclable. Fibre reinforced plastics where fibre substrate impregnated with thermosetting resin, find applications in several manufacturing processes and are potentially recyclable at the end of life."

Jan 1, 1996

By R. Mensah-Biney

The kinetics of gold-bromide loading onto activated carbon has been investigated in a batch stirred reactor. The amount of gold adsorbed by the carbon was correlated with time based on a second-order equation. The rate constant for gold-bromide species onto activated carbon ranged from 0.27 to 1.2 x 10-3 (kg/t)-l(min)-l from a solution containing 25 ppm of Au, with 0.8 g carbon per liter of solution at 30° C. The equilibrium saturation capacity (Q.) was 36±3.0 kg/t from the same system. The rate of loading increased with decreasing particle size, decreasing pH, increasing temperature, and decreasing concentration of gold in solution. The calculated activation energy E. was 8.8 kcal/mole, significantly higher than those reported for physical adsorption. The equilibrium saturation capacity (Q.) increased with increasing concentration of gold in solution, but was independent of other variables such as temperature, agitation speed, particle size and pH. These rate constants and equilibrium saturation capacity for the gold-bromide species are higher than those reported for the gold-cyanide systems.

Jan 1, 1996

By Y. Iguchi, T. Narushima, T. Shiozawa, M. Maruyama, R. Arashi

"In situ observation system for thermal oxidation using Raman spectroscopy' was constructed, and oxide films formed on liquid pure Al and Al-Mg alloys (Mg contents = 1 and 4 mass%) were analyzed at room temperature to 1273 K in dry oxygen. In situ Raman spectra of the surface of a liquid Al-:-4mass%Mg indicated the formation of MgO • AlP3 (spinel) as oxidation products, while a -AlP3 and MgO • Alz03 (spinel) were observed on a liquid Al-1mass%Mg alloy. It was suggested that the formation of MgO film affected oxidation behavior of these alloys.IntroductionLiquid aluminum alloys are cast to ingots mainly by the continuous casting process. It is well-.known that surface cracks could be caused by oxide films formed on the surface of melt during continuous casting and defects due to the film. With regard to oxidation behavior of liquid aluminum alloys, many investigations l -s have been carried out from the view point of formation of ceramic metal composites(CMC) which are expected as cutting tools and structural materials 1.2. It is very important for reasonable continuous casting and CMC formation processes to elucidate oxidation behavior of melts.Oxidation behavior of materials generally depends on compositions and properties of oxide films formed on the surface. If in situ observations of oxide films are available during oxidation, evaluation of oxide films and interpretation of oxidation mechanism could be expected. Laser Raman spectroscopy is one of the most appropriate techniques for in situ observation of oxide films under various atmosphere at high temperatures. The authors have discussed the effects of atmospheres and sample compositions on oxide film formation mechanism on Fe-Si alloy6 and SiC-B4C composite7 on basis of an in situ observation by Raman spectroscopy. In spite of many previous studies, systematic and clear explanations have never been gotten on oxidation behavior of liquid aluminum alloys. And no in situ observation has been made except for transmission electron microscopy(TEM) and X-ray diffraction(XRD)."

Jan 1, 1996

By Dennis R. Dolinar

Controlling coal mine roofs subjected to high-horizontal stress conditions has always been difficult and uncertain. Traditional supports such as wooden cribs and posts, concrete donut cribs, and standing supports collapse and fail when the roof and floor move horizontally as mining progresses. The former U.S. Bureau of Mines (USBM) (currently the U.S. Department of Energy (DOE)), in cooperation with Western Fuels-Utah, Incorporated, conducted research to provide an alternative for traditional secondary support systems in a 3-entry gate road system subjected to high horizontal movements. The support system used in several other coal mine operations, consisted of internal high-strength galvanized resin-grouted cable supports. The system virtually eliminates the necessity for external crib, timber, or concrete supports. The support system consisted of 2.4 m (8 ft) full-column resin grouted bolts and 4.8 m (16 ft) long cable supports installed in conjunction with wire mesh and "Monster-Mats." Cable loading and roof deformations were monitored to evaluate the behavior of the immediate and main roofs during first and second panel extractions. Additionally, cable trusses were installed on the longwall headgate to protect the coal conveyance system from roof and pillar falls created by the formation of cutters and gutters. The test results indicated that the designed support system successfully maintained the roof during the extraction of two longwall panels and dramatically reduced the cost of secondary support. This paper describes the theory of high-horizontal roof movements, the advantages of vertical cable supports and cable trusses, and presents the roof and cable measurements made to assess the support performance during longwall retreat mining.

Jan 1, 1996

By Riel RG

Nickel and cobalt mineralisation at the Murrin Murrin deposits, in the North Eastern Goldfields region of Western Australia, occurs within laterites developed on Archaean serpentinised peridotite units. Lateritic weathering of the peridotite has produced a resource of 116.8 Mt at 1.10 per cent Ni and 0.082 per cent Co (resource at May 1996 with a 0.8 per cent Ni cut-off; see Fazakerley and Monti, this volume). The mineralogy of the Murrin Murrin laterites was investigated to identify the minerals hosting significant Ni mineralisation. Laterite profiles were studied using X-ray Diffraction (XRD), impregnated polished thin sections, and Energy Dispersive Spectroscopy (EDS) Electron Microprobe analysis, of RC percussion drill chips. This paper summarises the results of these studies, and briefly discusses the nature of the minerals hosting Ni mineralisation.

Jan 1, 1996

By M. J. Hrebar

A study was conducted to evaluate the applicability of large wheel loaders (Cat 994 class) as primary loading equipment in open pit iron ore operations. Field visits were made to taconite and gold mines that used large wheel loaders. Data were gathered on loader selection rationale; operating and maintenance experience; and production, availability, and cost information. Brief time studies were conducted to indicate machine performance and utilization. The paper summarizes the field data and includes economic comparisons of wheel loaders versus cable shovels in an iron ore application.

Jan 1, 1996

By L. R. Stace

Arguably, one of the most significant technological breakthroughs that had been experienced during the period when British Coal was the major coalmine operating company in the UK, the use of rockbolts as principal support in underground roadways brought with it the need to re-assess the technical knowledge, management controls and legislative frameworks associated with the support of mine workings. Following a major roof fall in a roadway supported principally using rockbolts in which fatalities occurred, the process of the design of rockbolted support and the systems and procedures that had been put in place to control its use in the UK were further reviewed. The paper discusses the outcome of these reviews, and how the incident initiated a major new interest in strata control research in the UK against the background of the fragmentation of the ownership of the mines following the sale of the former British Coal assets at the end of 1994, together with the proposed introduction of new strata control legislation in 1996.

Jan 1, 1996

By C. L. Karr

Researchers at the University of Alabama have developed a method for producing fuzzy linguistic models of mineral processing equipment directly from engineering data. These fuzzy linguistic models rely exclusively on data collected from the processing systems being modeled and do not presuppose an understanding of the physics of the system. The fuzzy linguistic models use descriptive rules and explicit membership functions that provide a precise, nonmathematical description of the processing equipment. A genetic algorithm is employed to simultaneously select rules and tune membership functions used in the fuzzy models. The result is an extremely flexible approach to modelling that is applicable in a variety of linear and nonlinear systems. The effectiveness of this approach to modelling is demonstrated using a four-input, two-output model of a grinding circuit.

Jan 1, 1996

By A. K. Kyllo

A study has been carried out on the dusts from Hudson Bay Mining and Smelting's Flin Flon copper smelter. The aim of the work was to determine the mechanisms of dust formation and the deportment of the various constituents. The work concentrated on the copper converters, but the electrostatic precipitators and baghouse also clean the reverberatory furnace off gas, so some mixing will have occurred. The dust composition was found to vary with distance from the furnace, and to be made up of three major components: solidified droplets, unreacted flux, and condensed particles. The solidified droplets were formed from material ejected from the converter during blowing, while the flux was blown out of the converters immediately after charging. The condensed particles contained the majority of the lead and zinc, as well as the volatile impurities. There was also a significant soluble content of the dusts, increasing with distance from the furnace. The condensed material may be separated from the remainder by a simple washing and sizing technique.

Jan 1, 1996

By Rashmi Kumar, Amit Chatterjee, Sanjay Chandra

The practice of adding alloying materials to a molten bath is an integral feature of many pyrometallurgical operations. However, very little is known about the dissolution rate and solution mechanisms of solid additives in liquid melts. In foundries where large tonnages of liquid metals are handled, there is considerable interest in achieving optimum metal quality at minimum cost. This objective is influenced by several factors and the solution is often plant specific. Though the amount, sequence and mode of ferroalloy addition vary from plant to plant, various fundamental factors determine how quickly these additions dissolve in the bath. At the Ingot Mould Foundry (IMF) in TATA STEEL blast furnace hot metal is used to cast ingot moulds. The composition of hot metal desired for making ingot moulds demands addition of 20 kg each of Ferromanganese and Ferrosilicon in the 12 T transfer ladles into which the blast furnace metal is poured at the IMF. Owing to low temperature of hot metal at the IMF, casting commences immediately and complete dissolution of the ferroalloys is often not possible. To study this aspect in detail and to evolve suitable corrective measures, a mathematical model for the melting of a solid particle in a liquid metal bath was developed at TATA STEEL. The model was validated using the data available in literature. In keeping with published work, two separate dissolution periods were identified - a "shell period" and a "free dissolution period". The maximum thickness of the crust formed around a spherical particle shortly after immersion, can be obtained by using the mathematical model which has been developed. The model can also be used to investigate the effect of various parameters such as superheat of the bath, size of the particle, etc., on the maximum crust thickness and the particle melting time. On the basis of this study, the addition of ferromanganese and ferrosilicon was optimized at the IMF in Tata Steel.

Jan 1, 1996

By B. I. Hop

The f10wfield set up by the standard Hydro gas purging unit has been predicted by a numerical model. In addition turbulent trajectories of gas bubbles released from the rotor are predicted. Here the deposition rate of inclusions on the bubble surface is allowed to depend on local conditions. Bubbles passing regions with strong pressure gradients, such as close to the rotor, will experience large slip velocities and large deposition rates. This model can deal with any distribution of bubble sizes and inclusions. The results found from the multidimensional flow predictions are discussed in relation to what can be obtained from a much simpler metallurgical engineering approach. The differences between these two approaches to predict the same process will be discussed. The model predictions are compared to experimental results for removal of SiC-particles from aluminium.

Jan 1, 1996

Contribution by W.D. Ortlepp In the Journal of May 1994, the authors first presented the concept and analysis that formed the basis for a design approach for deep tunnels, now expressed more explicitly in the present paper (March/April 1996). In a contribution in the Journal of March/April 1995, I expressed a certain disquiet about the validity of their original approach. The authors responded to these criticisms in the same issue. It is apparent to me now that both the contribution and its rebuttals were written, probably for different reasons, in such an obscure and pedantic way as to further confuse the reader rather than provide enlightenment. My concern still persists. But in order to avoid further confusion I will attempt to pose my uncertainties and difficulties in a much more direct way. On page 98 (top of 2nd column) in the earlier paper, an important statement concluded as follows: '. . . the horizontal ellipse requires 140 per cent less force for equivalent stability'.

Jan 1, 1996

By H. J. Zhang, W. Wui

With the adoption of market-oriented economic policies, Chinese non-ferrous metals industry has gained remarkable progress. The continuously increasing domestic demand for non-ferrous metals, however, calls for more import of raw materials in short supply, such as copper concentrate and bauxite. As an alternative for balancing the shortage and assurance of more stable mineral supply, direct investment in oversea mining project has come to the agenda. This paper discusses the computer-assisted method used for evaluation and comparison of potential mining projects.

Jan 1, 1996

By L. H. Michaud

A mining company plans to extend its surface coal-mining operations in central Pennsylvania. Although the proposed site contains pyritic material, the results of the acid-base accountings for the site shows an overall Neutralization Potential to Maximum Potential Acidity Ratio (NP:MPA) of 4.26:1 for the entire site. The pyritic material is, however, associated with the lower of the three seams to be mined. If traditional dragline-mining methods are used, this would result in the acidic material being placed at the top of the spoil piles, exposing it to air and water, and therefore to the formation of acid mine drainage (AMD). Further concerns are associated with the fact that the alkaline material is not distributed evenly over the mine site. To prevent the formation of AMD, the company has proposed to mine the area using truck-shovel mining methods. This technique offers a more flexible alternative for cut sequencing and for the selective placement of waste material. Working with the Department of Mineral Engineering at The Pennsylvania State University, amine plan was developed for this site. This plan results in the layering of the alkaline and acidic spoil to achieve an overall net alkalinity in all spoil areas. Therefore, mining this site should not result in the formation of AMD.

Jan 1, 1996

By G. A. Doyle

The quality of water in mine pit lakes depends in part on the physical limnology (Le. stratification, turnover, and development of anoxic conditions with depth) of the lake. Limnologic data collected from four existing pit lakes indicate that pit lakes develop a thermocline, or temperature stratification, in the upper 10m to 30 m of the water column. Two of the pit lakes (26 m and 55 m deep) undergo seasonal turnover of the entire water column, whereas two deeper pit lakes (110 m and 240 m) undergo seasonal turnover of only the upper portion of the water column. In the deeper lakes, seasonal mixing does not extend through the entire water column and a distinct chemocline develops with depth.

Jan 1, 1996

By Patrick R. Taylor

This investigation studied the inflight calcination kinetics of nuclear waste simulant using a thermal plasma reactor. A series of experiments were performed to determine the conversion of insoluble aluminum compounds to the soluble compounds and the decomposition of complex organic and nitrite compounds present in the simulant waste. Thermodynamic calculations based on free energy minimization were performed to establish a theoretical basis for this investigation. A kinetic model to describe the conversion of gibsite to sodium aluminate has been proposed. The products of the calcination were characterized using XRD, Gas Chromatography, and chemical analysis by ICP. The results of this investigation indicated 85% gibsite conversion to sodium aluminate, 90% of nitrate decomposition, 52% TOC decomposition and 90% conversion of chromium to soluble compounds. A process is identified for inflight calcination of wastes. Key words: Plasma, waste, simulant, calcination

Jan 1, 1996

By Bensley C. N

In June 1995, BHP announced that it would build a Hot Briquetted Iron (HBI) plant and associated beneficiation, materials handling and infrastructure facilities at Port Hedland, Western Australia. This plant, the first direct reduction plant in Australia, will convert beneficiated iron ore fines into metallic iron for briquetting into HBI. The reduction plant will be based on the FINMET fluid bed technology jointly developed by Fior de Venezuela and Voest-Alpine Industrienlagenbau. Electric Arc Furnace steelmakers in the Asia Pacific region will be the principal customers for the product. This paper presents an overview of the facilities to be constructed by the project as well as discussing some particular technology and design engineering issues associated with the project.

Jan 1, 1996

By Virgil L. Lewis

On September 7, 1994, a Burlington Northern coal train crashed into a parked train in the downtown Gillette, Wyoming rail yard. I would like to address two issues in regards to this accident. One, a slide presentation of the damage created by the accident and the resulting required clean-up and two, a simulation of "what if" had there been an explosion during the course of the crash.

Jan 1, 1996