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By Andreas Cestonaro

Roll grade evolution in plate mill applications is traditionally following the development in hot strip mills. New grades normally find their way into service only after being successfully implemented in hot strip production. The majority of the plate mills worldwide are using work roll grades that have been invented before the 1980’s. But today the demands in the mills are pushed by sophisticated product mixes and longer rolling campaigns. The result of this development is a higher wear rate on the work rolls and as a consequence roll hardness is increased and advanced roll materials are used. The backup rolls are also affected by this. The wear rate is higher and the mechanical impact in terms of contact pressure and work hardening is increasing. This paper outlines the results of the roll grade development at Gontermann-Peipers and introduces new materials for work and backup rolls for plate mills.

Jul 30, 2018

By Martina Cadorin

Activated nanoporous biocarbon (aNBC) was prepared using E. grandis wood as a precursor material. Oxidated activated nanoporous biocarbon (ox-aNBC) sample was obtained from the aNBC by oxidation with nitric acid. The samples were tested as Pt nanoparticles catalysts support for ethanol oxidation reaction and as electrode materials for supercapacitors. The porous structure, chemical properties, and the structural and morphological characteristic of the materials were correlated with their electrochemical behaviour. Biocarbon materials showed similar high specific surface area. The oxidation treatment increases the content of the oxygenated and nitrogenated surface functional groups but without appreciably change in the nanostructure characteristic. The aNBC supported Pt nanocatalyst has better electrocatalytic performance for EOR. Oxygenated functional groups have a marked effect on the supercapacitors electrode behaviour, increasing the total electrical capacitance by pseudocapacitive contribution, but with a negative effect on the cell electrical resistance and cell response time.

Oct 30, 2017

By Rogério Felício dos Santos

Nitriding of metallic materials using electric discharges generated during electric discharge machining (EDM) is a recently developed technique. The aim of this paper was to correlate mechanical properties of a nitrided layer produced in AISI 4140 steel by EDM nitriding with the type and amount of nitrides. A conventional die-sinking EDM equipment and electrolytic copper electrodes were used to generate the electric discharges. The electrolyte was a solution of urea in deionized water. Knoop microhardness profiles assessed the variation of hardness along the nitrided layer, whereas the elastic modulus of this layer was measured using nanoindentation tests. Optical microscopy and X-ray diffraction (XRD) were used to characterize the nitrided surface. The results showed the formation of a nitrided layer containing iron nitrides with average thickness of around 25 µm. The amount of nitrides reduced from the surface towards the centre and these results correlated well with microhardness profiles obtained.

Jul 31, 2018

By Antonio Adel dos Santos, Carmos Antonio Gandra, Fabricio Mazola da Silva Paiva, Vicente Tadeu Lopes Buono

Abstract Usiminas Steel Plant in Ipatinga installed an accelerated cooling device named CLC (Continuous On-Line Control) in 2010, enabling it to supply steels produced by TMCP (Thermo Mechanical Control Process) technology. This technology complements the TMCR (Thermo Mechanical Control Rolling), with the inclusion of the accelerated cooling process after controlled rolling. There are various gains in terms of quality and productivity associated to the application of such technology. However, the flatness control for API steel becomes crucial because large thermal stresses may be generated due to thermal heterogeneity during the fast cooling when the austenite phase decomposes mostly into ferrite and bainite. In literature, there is lack of knowledge regarding a full understanding of the relation among cooling conditions and plate flatness. Therefore, this work has focused on the effect of the cooling strategy for API steels, aiming at optimizing flatness and keeping the mechanical properties within the specified ranges. The starting point was dilatometer simulation, where cooling conditions such as start cooling temperature, SCT, finish rolling temperature, FRT, and cooling rate, CR, were changed in order to evaluate their effect on microstructure. Those laboratory conditions supposed to give the best results were transposed to industrial scale, so as to produce experimental lots of plates with five different cooling strategies. It was shown the possibility to find a cooling profile that guarantees the balance between mechanical properties and flatness requirements. The influence of cooling strategy on flatness was explained by the varied heat transfer regimes occurring from hot steel surface to the ambient

Oct 1, 2019

By Lucia Vieira

Kelvin probe force microscopy (KPFM) can be used to monitor electrostatic charges on the surfaces of materials. In this paper, we describe the use of KPFM to evaluate the electrostatic effect induced by silver nanoparticles incorporated as clusters in diamond-like carbon (DLC) films, before and after scratching. The results are compared to those obtained for DLC films without silver nanoparticles. Raman spectroscopy was used to identify the DLC signature, and energy dispersive X-ray spectroscopy (EDX) was used to confirm the presence of silver in the film. The morphology of the DLC film containing silver was investigated using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The findings suggest that the incorporation of silver nanoparticles in amorphous materials could offer new options for electrostatic energy storage on the surfaces of these materials.

Jul 31, 2018

By Wolfgang Kern

The implementation of the Gas Treatment Plant (GTP) for CSPECEM, Ceara-Brazil is a result of the closed partnership between Paul Wurth Italia S.p.A. and DMT, the German leading company in Coke Oven Gas Treatment Plants. In addition to technical issues reducing emissions, avoiding of waste and saving environment and energy were technical challenges during the engineering phase. Below mentioned three descriptions of technical solutions represents examples of a number other innovations based on DMT’s know-how and experience in the field of by-product plants. Generally the design of the complete GTP is based on the consideration of modern features and design upgrading, with the aim of a safe operation with stable conditions and a long-living cycle of the whole of the plant.

Aug 16, 2017

By Anna Carolina Cerqueira Neves

Synthetic fiber has been gradually replaced by natural fiber, such as lignocellulosic fiber. In comparison with synthetic fiber, natural fiber has shown economic and environmental advantages. The natural fiber presents interfacial characteristics with polymeric matrices that favor a high impact energy absorption by the composite structure. However, until now little has been evaluated about the hemp fiber incorporated in polymeric matrices. This study has the purpose of evaluate the impact resistance of this kind of epoxy matrix composite reinforced with different percentages of hemp fibers. The impact resistance has substantially increased the relative amount of hemp fiber incorporated as reinforcement in the composite. This performance was associated with the difficulty of rupture imposed by the fibers resulting from the interaction of hemp fiber / epoxy matrix that helps absorb the impact energy.

Aug 16, 2017

By Marco Túlio Santiago Ferreira, Nilton Carlos Torquato, Washington Pirete da Silva

In 2005, with the significant reduction of iron content in the “Quadrilátero Ferrífero” reserves, Vale began the study of alternatives for the tailings disposal in other structures, that are not tailings dams. In 2011, after bench-scale and pilot-scale tests, it was defined to implement the project "Alternative methods for tailings disposal", including the construction of experimental drainage piles to get mineral and geotechnical process parameters for future projects. The result of this study shows that it is technically possible to replace traditional tailings disposal (dams), to dry stacking, with the proportion up to 20% of ultrafine tailings in the total tailings composition, however, this study is in evolution and the scale of the project / pile is being gradually increased to guarantee a good performance for the mineral and geotechnical process.

Oct 3, 2019

By Marcelo Rebellato, Beatriz Pereda, Beatriz Lopez, Pello Uranga

The classical application of Nb microalloying in the development of thermomechanical processes for flat products has been related to its suitability to enhance strain-induced precipitation and get a pancaked austenite prior to transformation. As new steel grades or new lay-outs are being developed, more complex metallurgical conditions need to be evaluated. In this context, Nb microalloying, alone or combined with other microadditions, needs to intervene in a more controlled way in additional steps of the thermomechanical process, besides its conventional strain-induced precipitation role. For example, the hardenability enhancement associated with Nb to properly achieve lower temperature transformation products, demands a proper balance of the Nb amount precipitated during rolling and the one remaining in solid solution. Similar effects are also sought when the final available Nb is used to increase strength through precipitation hardening. This manuscript evaluates how changes in the rolling strategies affect the interaction between Nb(C,N) precipitation and austenite recrystallization at different steps of the rolling process. As the possible interactions between parameters intervening simultaneously are quite complex, the application of microstructural models helps to properly define the best austenite conditioning combined with the convenient amount of Nb in solution, as a function of the final property requirements. Along the manuscript, several strategies will be discussed for the case of hot rolling of flat products comparing both normal and coarse initial austenite grain sizes.

Oct 1, 2019

By Luis Armando Espitia

AISI 410 martensitic stainless steel specimens were low temperature plasma nitrided at 400°C in a mixture of 75%N2:25%H2, during 20 h. Active screen technic was used to avoid any edge effect The nitrided case is composed of expanded martensite (a’N) and e-Fe3N iron nitride, whilst chromium nitride precipitation was avoided. Surface hardness reached 1275 HV0.01. The transverse microhardness profile shows a gentle hardness gradient with a NHT nitrided case depth of 28 µm. Nanoindentation tests were carried out in order to assess the hardness (H), the Young modulus (E), the H/E and H3/E2 ratios and the elastic recovery (We) of both nitrided and non-nitrided specimens. The cavitation erosion mass losses were measured as a function of exposure time. The results showed a decrease of 27 times of the mass loss compared to the non-nitride specimens. Wear rate decreased from 2.56 mg/h for the non-nitrided condition to 0.085 mg/h after nitriding. The increment in the elastic recovery and the higher hardness values are responsible for the greater cavitation erosion resistance exhibited by the expanded martensite. Such results showed that low temperature plasma nitriding and the formation of expanded martensite are effective to increase cavitation erosion resistance of AISI 410 stainless steel.

Jul 31, 2018

By Douglas Glenn Stalheim

The demands for improved mechanical properties in hot rolled long products are increasing as the expectations of global Standards and construction designer’s increase. Cost constraints limit the excessive use of expensive alloys to meet these expectations. In addition, depending on the mill, equipment can limit what can be realized to meet the increasing expectations. The most effective way to meet the increasing expectations for improved mechanical properties of optimum strength and ductility is through producing steel with as fine as possible uniform cross sectional grain size in the “as-rolled” condition. The best solution to the development of this fine and uniform cross sectional grain size is to develop a cost effective alloy design coupled with proper metallurgical process control implemented into an existing mill’s equipment capability and layout. In other words, properly bringing together alloy, metallurgy, process control and existing equipment capabilities to develop an optimum product that can meet the increasing demands of the construction designer. This paper is designed to give a solid understanding of the production and metallurgical requirements to achieve a grain size in “as-rolled” long products that is as fine as possible within the limitations of the process and production parameters of the individual plant.

Jul 30, 2018

By Washington Martins da Silva Júnior

In stamping process, sliding between metal sheet and forming tool leads to wear of tool surface. Maintenance of stamping tools involves polishing the tool edge, or, in case of severe damage, replacement of the tool. Hard coatings have been applied on the stamping tool surfaces in order to reduce the maintenance cost causing a great economic impact in metal work industry. In this work, CrAlSiN coatings were applied by PVD onto SRV2W tool steel. The coating toughness was avaliated by the critical load in scratch tests. The following coating parameters were analyzed: 1- substrate surface finishing process; 2- coating architecture (multilayer or gradient); 3- chemical composition of the coating. AlSi concentration varied from the substrate/coating interface to the surface. Coatings were 3 µm thick. Scratch tests were carried out using a Vickers indenter. The applied normal load was varied from 0 to 13 N for a scratch length of 5 mm. In order to study the effect in the toughness, the substrate roughness was controlled by the finishing process before PVD coating. Samples subjected to polishing presented highest critical loads. Gradient coatings presented higher critical loads than those with a multilayer architecture. Coatings with higher concentration of AlSi near the surface supported higher loads before failure.

Jul 31, 2018

By Foluke Salgado de Assis

Natural fibers are attracting the interest of engineering sectors owing to specific advantages such as lightweight and lower cost as well as for their inherent condition of being renewable, biodegradable, recyclable and environmental correct material with respect to CO2 emission. The banana fiber is nowadays recognized by its mechanical properties. It is known that with the increase of fibers volume fraction the composite significant increases its tensile strength. This was obtained with amounts up to 30% in volume of banana fiber. However no higher volume of fibers was able to be molded in a composite plate until now. Thus the present work aims to study higher volumes of fiber in terms of the influence on the tensile strength of specimens prepared under 5 tons of pressure. The fibers were previously washed and dried in an oven at 60ºC, after that poured together with the epoxy resin and catalyst mixture in the metal molds bone-shaped, and pressured to ensure specimens quality. The tensile strength increased significantly with higher amounts of banana fiber incorporated in the epoxy matrix. This better performance can be directly related to the fracture obstacle imposed by the fibers as well as the type of cracks resulting from the fiber/matrix interaction.

Aug 16, 2017

By Stefan Stein, Jorge Davo, Adrian Villanueva, Abhay Kulkarni, Shane Hoff

Pellet sizing plays a key role in the productivity of the entire pelletization and subsequent induration processes, whereas uneven pellet sizing can increase the circulating load of the balling circuit inducing operational instability leading to production loses. The present work focuses in comparing the agglomeration kinetics, expressed as the number of pellets produced in a determined target size range, of different organic binder-bentonite binder systems. The batch experimental results show that the binder system has a great influence in the resulting pellet sizing, which could lead to advantages in terms of balling circuit efficiency and eventually operational de-bottlenecking.

Oct 1, 2019

By Bernhard Hiebl

Global trends that are constantly challenging the iron and steel producers are related to worsening of the iron ore grades, higher substitution rates of main iron ores to cheaper raw materials due to economic pressure and increased environmental standards. Changing the raw materials in an operating plant can significantly influence the sintering or pelletizing process. Adjusting all process parameters to regain stable and high productive operation takes considerable time and causes production losses. Furthermore changes in raw materials lead to variations in the process gas flows and emission concentrations.Therefore SVAI developed two models for numerical simulation of sintering process and pelletizing process. Amongst others the models are based on Ergun equation and include chemical reactions of the related process. For already operating plants the simulations shall predict changes of the process parameters when raw materials are exchanged or when operational parameters are varied. Furthermore the simulations give advantageous information for the design of green field plants and allow the simulation of different plant configurations.The objective of this paper is to demonstrate what the latest developments are in these numerical simulations and what Siemens VAI is doing to overcome the remaining challenges in this field.

Aug 2, 2018

By Walter Valery, Kristy Duffy, Alex Jankovic, Peter Holtham

Hatch’s Mine to Process Optimization projects integrate mining and processing strategies, minimizing operating costs and maximizing overall profit. The methodology involves ore characterization, blast audits, plant surveys, analysis of historical data, and integrated modelling and simulation of mining and processing. Blast designs are tailored according to ore type and the downstream process is optimized for the changed feed. This approach has increased throughput and minimized costs for many operations worldwide. The implementation of this methodology at an iron ore operation that faced challenges with increasing mining strip ratio and ore body mineralogy changes is presented in this paper. The larger stripping ratio increased mining costs and constrained the run-of-mine (ROM) delivery to the process plant. Process performance was affected as the ore mineralogy shifted from predominantly hematite to include greater proportions of magnetite. The project objective was to minimize overall cost per ton mined and processed and maximize profit. Tailoring the blast designs according to ore type and process optimization increased the throughput of all process lines. This provided the potential to shut down one of the five processing line, aligning the mine and plant capacity and significantly reducing the processing costs.

Oct 3, 2019

By Jan Bak

Rourkela Steel Plant (RSP), which is operated by the Steel Authority of India Limited (SAIL), was inaugurated in 1959 and was the first Integrated Steel Plant in the public sector in India. In 2013, RSP commissioned their No. 5, 4060 m³ Blast Furnace, India's largest. It was built as a turn-key project by a consortium consisting of Danieli Corus and Tata Projects Ltd. and is entirely based on the technology and know-how of Danieli Corus. The new Blast Furnace is the key element of an expansion program that doubles the plant's production capacity and with much of the existing ironmaking capacity reaching the end of its technical and economic life span, it enables RSP to meet existing as well as growing demand for its products. This article discusses how this greenfield Blast Furnace was built in an existing and operating Integrated Steel Plant. It covers the accommodation of land, planning of the new installation to fit the available plot as well as the updated logistical lay-out of the plant. Technical details of the installation are presented, including their consequences for RSP's environmental performance and new perspectives for campaign planning.

Aug 2, 2018

By Carolina Gomes Dias Ribeiro

The modern composite materials, especially those reinforced with synthetic fibers such as glass and carbon, have been used since last century to attend the demands required by most technological fields, from home appliances to aerospace. Natural fibers composites with biodegradable polymer matrices are considered environmentally friendly materials and currently accepted as possible substitutes for synthetic composites. These green composites can be safely discarded or composted at the end of their life without harm to the environment. Another alternative for synthetic composites is to apply natural lignocellulosic fibers as reinforcement of conventional polymer matrices and already used in the automobile industry. In addition to the environmental and societal advantages of the green composites, the lignocellulosic fiber reinforced conventional polymer composite also has economical and technical advantages. In the case of a fiber collected as a waste, the price of the composite can be considerably lower than “fiberglass”. Furthermore, with high strength lignocellulosic fibers such as sisal, ramie and malva the specific strength of a composite may approach that of “fiberglass”. Therefore the objective of the present work is to investigate the mechanical behavior of polymer matrix composites reinforced with high volumes of natural malva fibers subjected to tensile stresses.

Aug 16, 2017

By Thamiris Auxiliadora Gonçalves Martins, Karen Espina Gomes, Amilton Barbosa Botelho Junior

The present work aims at the synthesis of nanoparticles of copper by chemical reduction in microwave oven. The solution used comes from the selective copper precipitation of the lateritic nickel leachate. The copper solution (20mL) was placed in a beaker, and 2mL of 100g/L ascorbic acid and 20mL of 20g/L sodium citrate were added in that order and at room temperature. The pH of the mixture was corrected with 1M sulfuric acid or 2M sodium hydroxide. Then the mixture was placed in a microwave oven. The effect of pH, time and microwave power were evaluated. The morphology, composition and size of the particles were verified in Scanning Electron Microscopy with Energy Dispersion Spectroscopy (SEM/EDS). Results showed that the particles formed had no nanometric size. This may have occurred because the reducing action of ascorbic acid together with sodium citrate generates a very rapid reduction rate, which makes it impossible to form particles on a gauge scale. Particles synthesized at pH 4, after 4 minutes of reaction with 1000W of power presented particles with spherical morphology and only copper in the composition.

Oct 3, 2019

By Rudi César Comiotto Modena, Gabriel de Castro Moreira, Diego Machado Marques

The definition of geological/geostatistical domains is the first step in building a mineral resource model. A suitable division for these domains requires some prior knowledge about the deposit geology and can be supported by a careful statistical analysis. It is crucial that data with similar characteristics are grouped together, to avoid the mixing of statistical populations, defining the so-called stationary domains. In order to assist in this definition, two unsupervised clustering algorithms were applied: Otsu and K-means. The first one is widely used in image segmentation and it is based on the exhaustive search of the data to determine the best threshold for separating them. K-means is one of the most used techniques in machine learning, and it is based on the iterative analysis of the statistical distribution. Clustering algorithms may present some shortcomings when applied to geological data, since they are based on pure statistical analysis, not considering spatial distribution or data location. Choosing the most appropriate number of domains can also be challenging. Some methods for defining the best number of groups are presented, based on the analysis of variances between/inside groups, supported by indicators variography in order to verify this definition.

Oct 3, 2019