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By Kirlk Yeager

"Ammonium nitrate (AN) is commonly mixed with a wide variety of additives to produce specialty formulations. Two additives commonly utilized are sodium nitrate (SN) and sodium nitrite (SNi). Application of the nitrite is primarily limited to gassing of emulsions. The nitrate, however, is incorporated in a wide variety of formulations. The effect of both these materials on the thermal stability of AN was examined. Experiments initially utilized lab-scale testing methods (sub-milligram sample size), such as differential scanning calorimetry (DSC), with scale-up to cook-off analyses (16 g) eventually applied. Labscale testing indicated that the presence of SN and SNi (both at 5 wt%) produced no harmful effects on the thermal stability of AN. The cook-off results did not agree with those from the lab-scale analyses, with both SN and SNi creating tremendous thermal destabilization of AN. These effects were seen at additive levels as low as 0.1 wt%. When SNi was employed as the additive, cook-offs became violent enough to create explosions in the testing apparatus. Although SN did not create as spectacular a destabilization, it did lower cook-off temperatures to approximately the same level as SNi. The dangerous situation created by SN andSNi seemed to be limited to cook-offs conducted in sealed vessels. If the SN/AN or SNi/AN formulations were allowed to cook-off in vented vessels, the thermal destabilization of AN did not occur. These results seemed to indicate that even “trace” amounts of what might ordinarily be viewed as benign additives could create significant destabilization of AN-based explosives under proper circumstances. Conditions created by blocked pumps, or deep boreholes could well overlap those produced in sealed cook-off vessels. In addition to showing the hazards potentially created by “benign” additives, the study also stressed that experiments designed to evaluate thermal hazards must include duplication of field variables to the fullest extent possible. "

Jan 1, 1999

By Martin Langenderfer, Sergii Chertopalov, Catherine Johnson, Vadym Mochalin, William Fahrenholtz

The high temperature and high pressure of an explosive detonation can be used for the production of nanomaterials. The controlled detonation of explosive compositions along with the collection and characterization of reaction products encompasses a process known as detonation synthesis. The primary advantage of the method of detonation synthesis is the possibility for producing monocrystalline nanoparticles with diameters of less than 10 nm. In order to successfully synthesize nanomaterials via the detonation process, it is necessary that the explosive detonation is conducted in a sealed environment. This environment when pulled to a vacuum or purged with inert gas such as argon will reduce the oxidation of detonation reaction products. Detonation synthesis testing is currently being conducted in a 1.8 cubic meters (m3) (64.3 cubic feet (ft3)) ellipsoidal pressure vessel consisting of two interlocking half shells. The testing involves the controlled detonation of cast mixtures of Cyclotrimethylene-trinitramine (RDX) and 2,4,6-Trinitrotoluene (TNT) in conjunction with siliceous compounds to produce nanocrystalline diamond and silicon carbide. Alternative detonation environments including the presence of a cooling medium such as water or dry ice to absorb residual, post detonation, thermal energy and enhance the stability of the materials being produced have improved yield. Modifications to the explosive charge composition have an effect on the type and quantity of materials that can be produced. Doping of explosive charges with various organic and inorganic compounds has shown promise in the synthesis of materials that are difficult or uneconomical to produce through other methods. This paper outlines the process development of detonation synthesis facilities. Preparation of the pressure vessel to create a suitable detonation environment for the production of nanomaterials is examined. Formulation of explosive charge compositions and considerations involving test charge initiation are discussed in detail. Experimental results and analysis from initial testing as well as plans for future research are also evaluated.

Jan 1, 2018

By PHILIPP HARTLIEB, Peter Schimek, Thomas Seidl, Paulo Couceiro, Pablo Segarra, José A. Sanchidrián, Juan Navarro

This paper describes a new methodology to assess rock mass-quality to guide blasting in open pit operations. A developed Structural Block Model and Strength-Grade factor have been combined in a Rock Factor, that, exclusively obtained from drilling data, can provide an automatic assessment of rock structure, strength, and waste/ore identification.

Feb 1, 2020

By P. Ross, O. Rielo, P. Katsabanis

Selection of delay times to optimize fragmentation has been a controversial topic among researchers and blasting practitioners. The paper reviews all available experimental information, ranging from small and medium scale tests in geologic materials to small scale tests at the laboratory and synthetic materials, simulating rock. Tests have been re-analyzed and discussed in terms of the information they present and the limitation of the testing environment in representing actual conditions. New results obtained from blasting experiments in specimens made of a grout have provided a clear picture of the effect of delay on fragmentation. The grout used has a strength of 60 MPa (8700 psi), density of 2.5 g/cm3 and P-wave velocity of 4000 m/s (13100 ft/s). Each block was placed in a yoke to eliminate unwanted reflections and the desired delay was obtained using the appropriate length of detonating cord between holes or sub-millisecond electronic detonators. Delays ranged from 0.1 ms/m (0.03 ms/ft) of burden to 16 ms/m (4.9 ms/ft) of burden. Fragmentation was obtained using screen analysis of the collected fragments. Delay time has been shown to be a significant parameter affecting fragmentation and back break. Generally larger fragments and less back break was observed at short values, while fragmentation somewhat deteriorated at significant delay times, compared to what was observed at intermediate delay times. The work is now extended to include the effect of energy partition on fragmentation as well as the effect of initiation point and coupling ratio.

Jan 1, 2014

Controlled Blasting, Inc. (CBI) located in Norcross, Georgia recently teamed with the Dekalb county fire marshals office to stage a mock disaster to test new trainees of Community Emergency Response Team (CERT). It as an interesting example in which industry can help out the community and government through the use of explosives.

Jan 1, 2010

By Mark S. Stagg, David E. Siskind, Stephen V. Crun, Willard E. Pierce

The USBM is studying the impacts of low-frequency blast vibrations on residences to assess both response and cracking potential. Complementing coal mining sites monitored in the midwest and east, vibrations were analyzed at a major construction site in southern Florida where potentially serious low-frequency blast vibrations were believed to exist.

Jan 1, 1996

By Fumihiko Sumiya, Koichi Kurokawa, Yukio Kato, Tetsuya Sawada

In some metal mines, it is a serious problem the decomposition of explosives which occurs suddenly by contact with ore containing pyrites under high temperature conditions. In the present paper, we investigated heat resistant properties of emulsion explosives and other industrial explosives by contact with ore containing pyrites under high temperature conditions.

Jan 1, 1992

By Unknown

ATF has provided a Guide to Recording Suspicious Persons Description in the Safety & Security Brochure. This guide may be useful for recording descriptive information on any suspicious individual. Suspicious activities can be reported to ATF’s 24-hour hotline listed in the front of the Guide or to your local law enforcement authority.

Jan 1, 2009

By John R. Schuring, Walter Konon

The 2.0 in./sec. peak particle velocity criterion traditionally used to protect structures from blast induced vibration damage is non-conservative for landmark structures. Various factors which must be considered in establishing vibration criteria for landmark structures are discussed. Existing criteria by past investigators for this class of structure are presented.

Jan 1, 1984

By Kevin Cole, Dennis A. Clark, F William Laslow

Since 1976, the Metropolitan Sanitary District of Greater Chicago, (MSDGC), has commissioned the excavation of a tunnel system in the Chicago area, hundreds of feet below the surface in solid limestone. This paper outlines the blasting patterns, explosive selections, and monitoring techniques used to assure a satisfactory job completion, following the specifications.

Jan 1, 1982

By Goran Lande, Bernt Larsson, Dennis Clark

The effects of vibrations on close surroundings has been studied in Europe and the United States extensively in the past three to four years due to the ever increasing demands of environmental control. Therefore, "routine measurements" or "standard vibration consulting services" are being carried out by numerous firms with widely different qualifications.

Jan 1, 1983

By Alastair Torrance, Italo Onederra, Do Sun Kim, Kush Patel, Gary Cavanough

Reactivity of ammonium nitrate-based explosives is associated with the presence of sulphide in the ground reacting with explosive products and in some instances causing spontaneous reactions which can lead to detonation. This paper explains the mechanism of these reactions, the potential cause of spontaneous detonation and how inhibited explosives prevent the reaction

Jan 1, 2019

By Paulo Couceiro

Highly non-ideal explosives usually tend to react expressively below their ideal detonation velocities. In these cases, dimensional effects and product heterogeneities become important to proper model the detonation state. Although Direct Numerical Simulation (DNS) techniques can provide a complete and exact solution for this problem, its actual computation cost is still not practical for industrial applications. In order to minimize these constrains, a simplified two-dimensional steady non-ideal detonation model for cylindrical stick explosives is developed. Based on an ellipsoidal shock shape approach, the proposed model uses the quasi-one dimensional theory for the axial flow solution and combine the post-shock sonic flow criteria with some limiting conditions for the explosives’ unconfined radius determination. Due to its attractive fitting capability for unconfined detonation experimental data, the model offers the possibility to predict the non-ideal detonation state for any diameter, resulting in a full mapping of the diameter-effect curve of the explosive. Thus, the proposed engineering approach is used to model the main properties of some of the most common ammonium nitrate-based explosives used in mining and quarrying industries, including the complete axial flow solution.

By Tacio Ferreira

A surface copper mine in the Western United States faced challenges in recovering rock and ore from final walls because of geotechnical constraints that require restrictions on methods for loading blastholes adjacent to the pit boundaries to preserve wall conditions. The operation had been using the same drill and blast designs for years. With changing geology, such as harder rock, as mining progressed, material was being left unmined in final walls because of poor breakage. The amount of unrecovered, unprocessed ore was estimated at approximately 380,000 tons a year generated from an average of 60 final wall blasts performed annually. The mine engineering team and Dyno Nobel engaged to minimize the amount of material left on the final pit walls. In this paper we present how we collected data, reviewed design standards, and found opportunities to improve ore recovery from pit final walls without increasing drilling and blasting costs. The results collected from implementing the new design on two benches showed the potential for extra revenue of approximately $3.6 million generated annually from reducing final wall unrecoverable underbreak by nearly 71% on the mine’s highwalls.

Jan 21, 2025

By Romel Villanueva L.

"Peru does not produce ammonium nitrate; nevertheless it is a large consumer of both, porous prill (PP) and high-density (HD) varieties. Explosives cost is an important preoccupation in Peru, due tofluctuations of the imported ANFO grade Ammonium Nitrate (AN). The use of Gasified Emulsion (GE)-manufactured with much cheaper HDAN- has become an alternative to reduce such costs. However, some problems were reported in the application of pure GE, including explosive percolation in highly fractured rock and lack of sensitivity by the effect of hydrostatic pressure in very deep holes. It was, hence, proposed to have an explosive based on GE too, but more robust and capable to keep the shape of the explosive column into the blast hole, by minimizing the leakage into the cracks. This could be achieved by adding limited amounts of lower priced HDAN, at the same time of providing gas pressure benefits. Other alternative is to add a low-density material, such as polystyrene prills, into the GE, although it reduces the explosive energy. The chemical gassing controls the density of GE, thus it can be obtained a wide range of densities."

Jan 1, 2016

By Zhao Jie, Christopher G. Smith

Commercial explosive use in China has been dominated by powdered AN-TNT mixes. Water gels and emulsions are now gaining market acceptance because they offer potential for better performance. Although raw material costs for emulsions initially may be more than AN-TNT mixes, the more expensive technology improves sensitization and leads to lower costs overall for mining operations. A recently completed study in northeast China compared microsphere-modified emulsions to AN-TNT and lower-cost emulsions. Testing of microsphere-modified emulsions at several pH levels indicated a high degree of stability and consistency of VOD. Using 42 mm blastholes in underground mines and 170 mm holes in sandstone open pit mining demonstrated the superior performance of glass microsphere sensitized emulsions. Comparisons of explosive cost, drilling cost, secondary blasting cost and muck pile profile were favorable to the microspheres-sensitized-emulsions. Noxious fumes with AN-TNT or with water-based systems that partially fail during detonation are also a concern. Efficient detonation of emulsion products sensitized with hollow spheres appears to reduce fume generation. Prolonged storage or exposure to water also is not a problem.

Jan 1, 1997

By K. G. Holley

Blasting is usually required to produce easily-excavated broken rock, while leaving surrounding rock masses as undamaged and stable as possible. In mining applications, it is common to utilise production blasting in the centre of an open pit, and specially developed limits blast designs when blasting adjacent to the excavation perimeter. In open pit blasting, limits blast designs generally include pre-splitting, trim blasts, or buffer blasts, all of which are designed to limit, or eliminate, damage beyond the designed pit wall. This paper reports on the findings of a study of the profile of damage in rock masses surrounding blasts, determined by a combination of vibration monitoring, displacement monitoring using extensometers, and video inspection of open holes drilled at various distances behind blasts. The results obtained suggest that the profile of damage may extend for the full depth of the bench, for distances of up to 12 to 15 metres behind blasts. This suggests that entire berms may be affected by blasting, displaying loss of friction and cohesion along joint and fracture planes. The study has considered production blasts and trim blasts with small diameter blastholes and pre-splits.

Jan 1, 2004

By Andrew P. Ritter, James W. Reil, Douglas A. Anderson, Stephen R. Winzer

We have developed a method for predicting and controlling ground vibration from blasting using a rigorous scientific approach. The method is based upon the superposition of seismic waveforms generated by a single-hole free-face shot, recorded at seismographs deployed in an array that includes environmentally sensitlve locations. Waveforms generated by single-hole shots are shown to be reproducible. The waveforms for each of the sites are used to construct synthetic seismograms for delayed shots based upon linear superposition. A computer code systematically constructs the seismograms for the delayed shots, with incremental delays between holes of 1, 2, or 3 milliseconds (ms). A Fourier amplitude specs-rum is calculated for each synthetic seismogram and the spectra are plotted on a map in delay-frequency space, i.e., each row of the map represents the Fourier spectrum for a blast with a particular delay interval. For single-row shots, the delay between holes in a row is used; for multiple-row shots, the delay between holes In a row is kept constant and the delay between rows is incremented. Predicted vibration varies strongly as a function of delay and h

Jan 1, 1985

BLASPA is the name for a computer code which can assist in the rapid optimisation of blasting procedures in an open-pit mine. BLASPA is based on a mathematical model of the blasting process, a model which has been developing since 1963 as a result of blasting research carried out at the College Militaire Royal de Saint-Jean under sponsorship of the Defence Research Board, and in co-operation with the mining and explosives industry. The model presently includes the following aspects: (1) Geometry, i.e. spacing, burden, bench height, collar, sub-grade drilling; (2) Explosives, i.e. types and grades of explosives, distribution into bottom and top load or decking, size of hole and coupling; (3) Hookup, i.e. parallel or angled firing, delays, location of primers. Computer costs are very small, by comparison with purely spherical AEC codes, so that any number of simulations can be carried out very efficiently. The system has already been used to carry out thousands of simulations for over 40 mines in Canada and abroad. It will be explained how such simulations become a useful guide for a mine's blasting engineer who wishes to optimize his blasting and drilling costs.

Jan 1, 1980

By E Novikov, D Johansson, U Nyberg, A Beyglou, N Petropoulos

Fragmentation is an important factor for improving downstream processes in mine operations. Six trials have been conducted at the Aitik copper mine to investigate the effect of ultra-short inter-hole delay times, i.e. smaller than 1 ms/m of burden, on fragmentation. Swelling, MWD data, and crusher efficiency were also evaluated for trials. According to the results, the effect of examined short inter-hole delay times, i.e. 0.14 to 0.86 ms/m of burden, on fragmentation was found to be marginal. Delay time of 0.43 ms/m of burden resulted in slightly finer fragmentation and larger swell; however, the effect of short delays was overshadowed by the effect of small variations in specific charge.

Jan 1, 2014