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By B. J. Moore

This publication contains analyses and related source data for 256 natural gas samples from wells and pipelines in 17 States. All of the samples were obtained and analyzed during calendar year 1977 as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and a special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576.3 The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the public in general. Nineteen previous publications have presented the results of 11,317 gas analyses prior to 1977. The first three, Bulletins 486,4 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960. The other 16

Jan 1, 1978

By J. M. Riley

The Bureau of Mines investigated a promising new technology for recovering A1203 from alunite to support the Bureau's alumina miniplant project. Results are presented for a study of the technical feasibility of treating alunite crushing and grinding reject fines for recovery of A1203. Alunite pellets having sufficient strength and resistance to degradation were produced by combining fines and coarse alunite with a KOH binder. The best pellets were prepared, in a laboratory pelletizer, by adding 1 pct KOH as a 5-pct solution to a mixture of 40 pct alunite dust (98 pct minus 65 mesh) and 60 pct coarse alunite (minus 20 plus 65 mesh). Calcines suitable for K2SO4 and A1203 recovery were produced by reducing dehydrated alunite pellets with sulfur in a laboratory shaft furnace for 4 h at 600° C, followed by air oxidation of the reduced calcine for 1 h at 600° C. This report presents design calculations, schematic diagrams, and discussions of the essential features of a proposed process research unit (PRU)--a continuous, 6-lb/h alunite shaft furnace--for studying the process.

Jan 1, 1983

By Thomas O. Llewellyn

This U.S. Bureau of Mines (US8M) report presents a concise review on sources, processes, supply, and historical use patterns of domestic cadmium. It also covers a preliminary estimated cadmium material balance for the year 1989.

Jan 1, 1992

The development of an onboard contaminant diagnostic monitor to continuously measure contaminant level in a mining machine was advanced to a prototype stage in this contract. Several concepts were investigated and it was found that a static spool type sensor was the most reliable and accurate. Laboratory and field tests showed that an instrument based on this concept is capable of measuring contaminant levels and/or size distribution, depending on the configuration of the sensor. Moreover, this instrument can function on emulsions or homogeneous fluids. Current laboratory equipment can operate on homogeneous fluids only.

Jan 1, 1983

By A. J. Farstad

The principle objective of the research effort described herein was to identify as rapidly as possible a practical trapped miner location system. Much effort has been expended in the past on the development of a highly sophisticated seismic location system [1] for trapped miners. Field tests of this system have shown that the location accuracy is limited by a combination of seismic velocity anomalies, timing errors, and in general by the relatively weak nature of the signals received at the surface. It was first felt that similar propagation anomalies would be experienced by electromagnetic systems, but to a greater extent than the seismic. However, preliminary tests performed by Westinghouse on the Operations and Maintenance Program, Contract No. H0210063 in 1971 and 1972, indicated that an electromagnetic solution to the location problem may be more feasible than a seismic solution. Thus a more concentrated effort was launched in 1972 and 1973 to more completely determine the feasibility of electromagnetic location systems for trapped miners. Two different approaches to the location problem were undertaken on this program: (1) A pulsed electromagnetic system was developed by the Special Systems Division of Westinghouse in Baltimore, and (2) a Continuous Wave (CW) System was developed by Westinghouse Georesearch Laboratory (WGL) in Boulder, Colorado. Part I of this report will deal only with the development and results of CW Location System developed by WGL. The CW Location System was field tested at three eastern coal mines and at one western hardrock mine. The maximum overburden depth penetrated during these tests was 990 feet at the Robena No. 4 mine near Waynesburg, Pennsylvania. The earth conductivity at this mine was measured to be 1. 1X102 mhos/m, which combined with the deep overburden make this mine representative of expected worst case conditions for a coal mine EM location exercise.

Jan 1, 1973

By J. L. Wiley

[NOTE. - P before the number indicates that the ab tract appears in patent section. Abstract numbers without. P appear in literature section. A Abietic acid, hydrogenolysis - 404 Acetone, recovery - P-4024 Acetylacetonate catalyst - P-3352, P-3664, P-6067 Acetylene, production - P-2556, P-3169, P-4064, P-4221, P-4222, P-5002 Acid catalyst - P-4584 Salts - P-4555 See also Specific acid. Acid treatment. See Procedure. Adsorption. See Hydrogen, adsorption. Agitation. See Equipment, agitators; Procedure. Alcohols: Decomposition -1128 Hydrogenation - P-3288, P-4743 In motor fuel - 1486]

Jan 1, 1952

By R. M. Santmyers

The pigments, whose colors are due primarily to iron exides and iron hydroxides, comprise a variety of yellow, brown, red, and sometimes black paint-coloring agents, both natural and artificially prepared. The natural pigments in this group include ocher, umber, sienna, mineral paints, paint rock, and mortar colors. When the natural color or tinting power--either in the raw state or after treatment--is too weak, these pigments may be "forti- fied" or strengthened. Ocher, umber, and sienna, rhile often described as "iron oxide pigments," are also known as "earthy" rigments. Inasmuch as the iron content of these pigments is, in general, somewhat lower than that of other iron oxide pigments, the ochers, umbers, siennes, and other brown earth pigments are not discussed in the present paper. In addition to a discussion of natural or artificial pigments whose color is due to the presence of iron oxide in some form, this paper contains data on mortar colors, which are medium or low grade pigments used for tinting mortar, cement, and concrete. A great variety of materials are used for theso purposes, including "blue billy" (residue left from roast- ing pyrite), ground slate and shale, and even culm from coal washeries. Dur- ing the past three years, there has been a definite trend among the producers of iron oxide pigments to push the sales of the better grades of colors for tinting mortars. Due to the amount of low-grade coloring matter that is re- quired to impart a strong color to concrete (in soro cases as high as 15 per cent of pigment is necessary) the strength of the cement may be materially impaired. The addition of some 2 per cent of the higher grades of iron oxide to the concrete mix imparts a brighter and stronger colcr, does not weaken the material, and in the end is not as expensive as the low-grade pigments formerly used. Iron oxide pigments occur in nature in various shades and colors, but the red pigments are the most important and account for the larger part of the total red pigments used.3/ The nomenclature of these red pigments is involved and the names given to them are descriptive of the shade rather than of origin, method of produc- tion or chemical composition. In most cases the red pigments under this class may occur naturally or may be produced by heating hydrous iron oxide pigments such as yellow ocher to a sufficiently high temperature to drive off the water of composition. They may also be prepared by fortifying naturally-occurring pigments with stronger natural or synthetic oxides or with coal-tar dyes (e.g. alizarine lake), Most of the mineral reds derive their color from the presence of ferric oxide (Fe2O3), the mineral hematite. This may be present in relatively small percentages, as in the red slates and shales, or it may constitute as much as 90 per cent or more of the material, as in Spanish red. The principal iron oxide pigments used in the manufacture of paint are discussed in the following pages.

May 1, 1932

By P. R. Jones

A computer program was written for design and cost of a shell and tube heat exchanger in which the total cost, which includes annual fixed charges and annual operating costs, was minimized. The program was written for the type of heat exchanger in which only the tube side pumping costs were significant and for triangular pitch, single or multiple pass, heating or cooling, and no change in phase. Tube diameter was not optimized since the tube dimensions do not affect the cost very much. However, the tube dimensions do affect the shell diameter, number of tubes, and length of tubes; and price optimum design was obtained for four standard tube diameters. Standard heat exchangers having at least the required area are also listed. The program was made adaptable to various fluids and to various tube dimensions by including many of the required data such as physical properties of the fluids, tube data, and standard shell data as input data.

Jan 1, 1969

By D. Randolph Berry

The U.S. Bureau of Mines awarded a contract to Foster-Miller Associates, Inc. (FMA) to provide recommendations on the safest, most practical methods for complying with new regulations requiring that all underground coal miners have a self-contained, self-rescuer (SCSR) -a device capable of supplying, in an emergency, 1 hr of self-contained oxygen (no breathing of mine air). This report develops information and recommendations which could be used during the early stages of nationwide compliance, especially in the areas of inspection, testing, and underground storage of SCSRs. Volume I contains an Executive Summary, Introduction, Definitions, Recommended Guidelines for District Managers and Mine Operators, and a Storage Plan Checklist and Sample Form.

Jan 1, 1981

By J. B. Zadra

After the discovery of the rare-earth mineral deposit in the Clark Mountain area near Mountain Pass, San Bernardino County, Calif., two samples wore obtained through the Mining Division of the Bureau of Mines for investigation of possible method of concentration. Three other samples were received later from different locations in the same area. The rare-earth mineral in this ore had been identified by E. T. Schonk as bastnaesite, a fluocarbonate of the rare-earth metals containing cerium, lanthanum, praseodymium, thorium, uranium, etc. Associated with the bastnaesite were barite, silica, and some calcite. The bastnaesite contained a small amount of iron as a coloration and some manganese. Twenty to fifty percent of the weight of the samples studied was bastnaesite, or ten to twenty-five percent total rare-earth oxides; about half was cerium oxide. Apparently, none of this mineral occurred in pure form. Even the highest-grade particles 'wore contaminated by fine, interlocked grains of barite, calcite, and silica; barite contamination predominated, and the barite was interlocked with varying amounts of bastnaesite. While the specific gravities of pure bastnaesite and barite (approximately 5.0 and 4.50 respectively) differ enough to allow separation by gravity, the interlocking of the minerals nullified this difference. Consequently, only a partial separation could be made by gravity concentration. The extremely fine grained texture of most of the ore prevented grinding to a size that would make concentration by flotation practicable; a partial separation of barite by this means was effected.

Jan 1, 1952

By Jerry A. Wichser

A series of linear programmed instruction modules was developed in the general subject areas of Blasting Technology & Explosives Safety & Electrical Training. The linear programs (modules) were developed in the form of tape-slide plus workbook materials, while the branching format evolved from the LTS teaching machine system from MIT, through several other teaching machines and micro-computers, finally settling on Radio Shack TRS-80 microcomputers, Models I & III. Initial validation figures indicate that essentially the same result, are attained from both methods (based on pre and post test scores), with the most noticeable difference being an approximately 25% savings in study time with the branching modules. In December 1980, the development of modules on High-Voltage Training, Trolley Wireman Training, and Compressed Gas Safety was added to the overall tasks of the contract.

Jan 1, 1984

By S. H. Ash

Unusual mining conditions prevail in the State of Washington because the majority of the coal seams lie on extra steep dips, and the roof and floor of the seams are of such a character as to require an excessive amount of timber- ing. The seams as a rule give off a considerable amount of methane, which makes good ventilation imperative. Due to physical conditions, supervision is costly and travel about the workings is difficult. Because of the facts stated, the accident rate has been above the average, and for some time considerable thought has been given the idea of making promotion of safety in and about the mines a responsibility to be shared equally by the employees and the management. With this idea in mind the legislature of the State of Washington, turing March, 1927, passed laws providing that safety committees be selected to function at the coal mines of the State and at the same time recognizing the fact that first-aid education is an integral part of any safety movement; legislation was passed making it mandatory to have all persons in and about the ines trained in first-aid administration. The provisions of the State mining law3 are as follows: "In every mine a general safety committee shall be selected, composed of the mine superintendent or manager of mines, one man selected by the employees or any association of employees in or around said mine, and a third member selected by these two. "The general safety committee shall elect one of the members to act as chairman and one to act as secretary. The duties of the chairman shall be to preside at all meetings of the general safety committee, enforce its rules and regulations and see that its business is conducted in a prompt and business-like manner. The secretary shall keep an accurate written record of the proceedings of all meetings, conduct its correspondence and post notices of regular and special meetings and other matters pertaining to safety. The duties of the general safety committee shall be to investigate all serious and fatal accidents; make bi-monthly.

Jun 1, 1930

By Arno C. Fieldner

The determination and publication of data o the chemical and physical properties of American coals have been primary functions of the Bureau of Mines since its creation in 1910. In recent years this program has been expanded to meet increasing needs for information on the suitability of coals for the production of coke, gas, and byproducts, and within the last year an experimental coal-hydrogenation plant has been completed. With this addition, the Bureau is able to cover every phase of coal utilization, including combustion, carbonization, liquefaction, and complete gasification. The need for this information is increasing not only to meet the requirements of consumers but also to give the data required to establish the classification and minimum selling price of coal by the National Bituminous Coal Commission.

Jan 1, 1938

By McHenry Mosier

This is the fourth progress report in the series on the use of detachable rock-drill bits in the metal mines of the United States. It contains comparative statistics and costs or drilling at eight mines not reviewed in previous reports, comparison of the use of detachable bits at small mines and large mines, a discussion on the life of drill rods, and general conclusions derived from an analysis of the rock-drilling practice at all the mines investigated on this survey. This paper completes the descriptions of operating practice in rock drilling at individual mines. Data on drilling practices at 28 mines are given in appendices I and II and drilling costs are shown in appendix III. Research in the fundamentals of rock drilling, including the use of detachable bits, has been undertaken by the Bureau of Mines in its testing adit at Mount Weather, Va. Reports on the progress off this investigation will be issued when results warrant their publication.

Jan 1, 1937

By Horace C. Porter, F. K. OVITZ

Much has been written of the changes undergone by coal in storage and the deterioration of coal through exposure to the weather. In order to obtain definite information for the benefit of the Government departments and of all who store coal in large quantitieS', a series . of tests was begun in the fall of 1909 under the supervision of tT. A. Holmes, then chief technologist of the United States Geological Survey, and was continued by the Bureau of Mines after its establishment in 1910. The tests were confined to determinations of the loss in heating value of the coals and did not include a study of other deterioration; for exaIp.ple, in coking quality or the yield of by-products in coking. The Bureau of Yards and Docks of the Navy Department cooperated in tests of New R~ver (W. Va.) coal, a variety largely used by the Navy. A preliminary report presenting a brief account of the early results of these tests has been published by the Bureau of Mines as Technical Paper 16.a The detailed report is presented in this bulletin, which gives a fu11 account of the tests and the analytical data covering a period of five years' storage. Data of somewhat similar experiments for shorter periods with gas coal from the Pittsburgh bed, with Pocahontas coal on the Isthmus of Panama, and with Sheridan, Wyo., subbituminous coal, which is used for railroad and other purposes in the West, are included. The tests of New River coal, in cooperation with the Navy Department, were undertaken to determine the advantage to be gained by storing coal under water, and particularly under salt water. Small lots were used in order to make the tests of maximum severity, and parallel experiments were made with run-of-mine and crushed coal under one-fourth inch size. All of the small lots tested under the different conditions (except those tested near Key West, Fla.) were taken as representative portions from one large original lot. The tests of Pocahontas coal, which, like the New River, is semibituminous, were undertaken chiefly to determine th.e effect of the tropical conditions in Panama. They were made on an outdoor pile of 100 tons of run-of-mine coal. Pittsburgh gas coal, a high-volatile, bituminous type used at gas and by-product coke works, was exposed for test at Ann Arbor, Mich., in cooperation with the University of Michigan. The university agreed to make tests at successive intervals of storage to determine, in its illuminating-gas experiment station, the yields of gas and byproducts from the coal. The coal, screened lump, was stored in about 4-ton lots out of doors in open bins. Subbituminous coal, which is mined in Colorado, Wyoming, and other States, and is known also as "black lignite," is commonly supposed to deteriorate rapidly in storage, especially by "slacking" or crumbling of the lumps. The tests herein described were undertaken at Sheridan, Wyo., in cooperation with the Chicago, Burlington & Quincy Railroad Co., in order to determine the extent of this slacking and the accompanying loss of heat value. The tests were in open bins holding 4 to 12 tons.

Jan 1, 1917

By M. J. Ferrante

Relative enthalpies of V20S from 298.15 to 1,101.0 K were measured at the Bureau of Mines to provide data needed for the advancement of min-eral technology. Enthalpies were measured with a copper-block calorimeter. A sharp melting point was found at 951 K, with [~~ = 15.690 kcal/ mol ] for the standard enthalpy of melting. Tabulated values are given at selected temperature increments between 298.15 and 1,500 K for the standard relative enthalpy [(HO -H~98),] heat capacity (CpO), entropy (SO), and Gibbs energy function [-(Go -H298)/T]. Standard relative enthal-pies are also given in equation form and combined with data from the literature to derive values of standard enthalpies of formation and Gibbs energies of formation.

Jan 1, 1986

By Cleo G. Rall

The method for determining the effective porosity of oil- and gas-bearing sands described in this report is a development of earlier methods (28)3/ devised by the Bureau of Mines. The apparatus bas been improved and made more convenient to use, but the procedure is essentially the same as that which has been in use for maw years. A tabulation at the end of the report gives the results of more than 4,800 porosity determinations for oil sands4/ in the fields of 13 States, A selected bibliography of references to articles containing descriptions and evaluations of various methods of' determining porosity is included in this report. The method was devised and developed at the Petroleum Experiment Station at Bartlesville, Okla., as part of the Bureau's research on fluid-energy relationships and on methods of improving the recovery of crude oil from underground reservoirs.

Jan 1, 1954

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

Safe operation and system integrity are two important properties of a mine hoist electrical system. Previous methods used to assess these systems, though rare, have involved extensive downtime and required skilled personnel. The recommended design considerations presented in this report are for a proposed automated system that will perform real time measurements, calculations, and recordings of pertinent performance data. Included are equipment installation and test procedures to be used with the system. The report also contains descriptions of the hoist performance criteria, and how they are to be collected.

Jan 1, 1985

By Bertha R. Klahold

"In response to numerous inquiries regarding tests and analyses of minerals and related inorganic materials; Bureau of Mines Information Circular 6999, ""Laboratories That Make Fire Assays, Analyses, and Tests on Ores, Minerals, Metals and Other Inorganic Substances,"" by C. W. Davis and M. W. von Bernewitz, was published .in 1938 and revised in 1939 (I. C. 6999R). In this paper on analytical and testing laboratories, the original text has been rewritten and expanded, and a table has been added, in which are listed laboratories prepared to offer a number of special testing services in addition to ordinary assays and chemical analyses. The arrangement of laboratories on, a geographical basis has been maintained.This circular is compiled as a public service, and none of the laboratories listed herein is recommended over any other,These lists were compiled from questionnaires sent to organizations whose work is connected with mineral and metallurgical testing. The response in general was very satisfactory, and the author takes this opportunity to express her appreciation to the officers of the listed laboratories for their cooperation.Acknowledgment is also made of the valuable assistance of the members of the technical staff particularly Morris Slaving/ of the Eastern Experiment Station of the Bureau of Mines at College Park, Md., in the preparation of the questionnaire and technical descriptions.Many mineral samples are sent to government agencies in the National Capital with the request that they be assayed or chemically analyzed. It should be emphasized that there is no place in Washington D. C. where assays and quantitative analyses are made for the public b the Federal Government.Virtually all of the States maintain a bureau of mines, a geological survey, or some similar organization, frequently at the State University, where minerals found by residents of the State will be identified free of charge. Usually, a charge is made for assays. Specific tests, as on clays, are made by some of these offices.The Federal Bureau of Mines, although it attempts to avoid duplication of services rendered by State Bureaus, is always glad to give advice as to prospective markets. It does not compete with private assayers and chemists, but with respect to samples sent to its field laboratories, it does offer to identify them as far as this can be done by inspection and simple optical and chemical tests. This examination is usually sufficient to indicate whether the material has commercial value, or at least if the expense of an assay would be warranted. Except in connection with its own technical investigations, no assays or other special tests are made by the Bureau of Mines.The Federal Geological Survey and the National Museum also make simple tests of specimens as a public service. Neither of these bureaus nor the Bureau of Mines, however, can afford to render such services on long suites of specimens submitted by mineral dealers, well drillers, or others, when such work can be done regularly by commercial concerns."

Oct 1, 1949