Search Documents

By Fathi Habashi

Laboratory autoclaves for hydrometallurgical investigations are available in a variety of sizes, models, and materials of constructions. They vary in sizes from 25 mL to 2 liters for laboratory studies and 5 to 50 gallons for pilot plant work. They are essential tools for studying aqueous oxidation of sulfide concentrates, dissolution of oxide minerals at high temperature and pressure and hydrothermal precipitation reactions. The maximum pressure and temperature at which any pressure vessel can be used will depend upon the design of the vessel and the materials used in its construction. Since all materials lose strength at elevated temperatures, any pressure rating must be stated in terms of the temperature at which it applies. A review of existing models and their accessories will be given.

Jan 1, 2000

By K Nesbitt

Draw control at Premier Mine is considered important to avoid conditions of isolated draw, which results in early waste ingress, compaction of the kimberlite ore and loss of ore reserves. The Premier Mine kimberlite pipe is unique in that the pipe is cut at a depth of 400 metres below surface by a 75 metre thick gabbro sill. All cave mining at Premier is below the sill and failure to exercise good draw control could cause early ingress of gabbro waste. Gabbro causes problems in the diamond recovery plant and the amount of gabbro sent to the plant needs to be closely monitored. Fortunately coarse gabbro fragments are easy to recognise in drawpoints. It was anticipated that only 85 per cent of available ore would be drawn from the blocks immediately overlain by the gabbro sill before excessive gabbro waste forced the closure of drawpoints. Data on tons drawn per drawpoint and loaded per LHD as well as the tons tipped per pass is gathered by the vehicle monitoring and control (VMAC) system and information recorded by the load-haul-dump (LHD) drivers. Draw control staff monitor drawpoints on a shift basis and record the occurrence, type and height of hang-ups. Information pertaining to the status of the drawpoint in terms of support, waste and availability is also recorded. A database has been compiled that has been used to analyse the overall pattern of draw control, the frequency of occurrence of different types of hang-ups, secondary blasting efficiencies and drawpoint and LHD productivity. The gabbro sill has provided a unique marker horizon that has allowed the arrival of rock from a level 100 metres above the production level to be recognised. Data shows that ore migrates extensively towards groups of drawpoints that are heavily drawn with many drawpoints more than 100 per cent drawn before gabbro waste was recognised. This indicates that an accurate mixing algorithm is essential for good draw control. Data on tons drawn, drawpoint availability, productivity and the occurrence of various types of hang-ups has allowed better control of the mining operation and provided data for planning future caves. In the BA5 mining block a drawpoint spacing of 22 metres, horizontally across the major apex, has still allowed drawpoints to be pulled to waste with no loss of ore. In the BB1E mining block the drawpoint spacing has been increased to 23 metres and no problems have been experienced to-date. Future initiatives centre on improving the data gathering integrity of the vehicle monitoring and control system and a linear programme that will optimise draw control and productivity.

Jan 1, 2000

By C. Mattich, A. L. Beyzavi

The Waelz Plant at Taiwan Steel Union Co. Ltd. (TSU) was erected within nine months from September 1, 1998 to May 15, 1999. The nominal capacity of the plant is 50,000 tonnes per year of electric are furnace dust (EAFD). The plant, consisting of material handling, a waelz kiln, a waste gas cleaning system, waelz oxide leaching and waste water treatment, was commissioned within three months from July 1, 1999 until October 12, 1999. The specific problem of the plant is the high chlorine content in the EAFD pellets which is up to 6 %. Lurgi Metallurgie GmbH, Frankfurt, Germany was responsible for the engineering erection and commissioning of the plant.

Jan 1, 2000

It is proposed to consider a new access, mining and hoisting system for underground deposits, as an alternative to the commonly used decline or vertical shaft access. The proposed system offers fundamental improvements in gathering of exploration data, reduction of capital expenditure and significant savings in mine operating costs. The cost reductions are achieved through:superior orebody definition by Supersucker winzing on ore prior to the commencement of capital development; considerable reduction of capital development in waste; full capitalisation on all benefits of a raisebored excavation; introduction of rubber tyred skip and rubber tyred Mine Rapid Response Vehicle; introduction of simplified ore handling system and reduction of underground mobile diesel fleet; and introduction of minimum maintenance shaft concept. The system is applicable to deposits ranging from shallow, low dip angle, narrow vein, high-grade to bigger, massive type vertical mineralisations accessed from the surface, preferably from the bottom of an open pit; it is also suitable as a down dip extension of an existing underground mine. The system is highly conducive to mine automation and emerging trend aimed to increase the ratio of mined metal/mineral to mined waste. It offers substantial reduction in diesel exhaust gas emissions to the mine atmosphere.

Jan 1, 2000

By Hamid Maleki

Results of geologic investigations, in-mine instrumentation, and numerical modeling are presented for two longwall mines in which pillars with large width-to-height ratios (8 to 9) are used. These investigations revealed that wide pillars unload when subjected to sufficient stress and that pillar unloading is influenced by geologic conditions. Field measurements in mine 1 clearly indicated load transfer from the longwall area toward the gate roads, resulting in pillar failure near the margin of a fluvial channel. Loads were shown to transfer to a harrier pillar (width height ratio equal to 9), contributing to progressive failure of this pillar. Unloading of the barrier pillar was associated with significant load transfer to the two-seam submains to the north of the harrier, contributing to roof falls, floor heave, and rib spalling within the submains. Stress analysis results addressed pillar peak strength and unloading behavior that was in agreement with the measurements and underground observations. Underground observations and stress analyses were completed before and after longwall mining near a six-entry submain in mine 2. This submain was intended to he used as a temporary bleeder and tailgate for a small longwall block consisting of one to two panels, depending on the development schedule in other areas of the trine and observed ground conditions. Numerical modeling using both elastic and inelastic pillar behavior for submain pillars with a width-to-height ratio of 8 was completed before mining began. Results indicated that pillar unloading was likely. During retreat of the first longwall panel, pillars unloaded. as evidenced by progressive rib spalling along the cleats, This behavior was mostly confined to the immediate face area, an observation that was in agreement with the modeling results,

Jan 1, 2000

By Shigehisa Endoh, Hitoshi Ohya, Atsushi Inaba, Shigeki Koyanaka

"Recycling should be promoted to keep the global environment. However, it is difficult to detennine the quantitative impact. A life cycle assessment is one of the most reliable methods to estimate the global environment impact.Exergy is useful like entropy when considering the sustainable development. All of our activities have been obtained exergy resources and/or energy itself and throw away waste and/or waste heat. We are trying to use exergy to estimate the quantity of energy and matter for resource accounting. For recycling plastic, plastic has two aspects; material and energy source.The environmental assessment of plastic recycling suggests that the exergy reduction of the entire system is estimated by the yield of matter and the process efficiency. The material recycling is better than the thennal recycling when the process efficiency is high. However, the thennal recycling is much better for the low efficiency. The transition point is able to be decided by the efficiency of the manufacturing and the electric power generation.IntroductionRecently, many of the global environmental problems have become conspicuous like global wanning, ozone layer depletion and acid rain. Some of the methods like life cycle assessment for solving these problems have been presented. Anxiety concerning the proble1ns of energy and resources has led to a rapid increase in the interest in describing and understanding the conversion processes of energy and other resources in today's society. All human activity is supported by obtaining power and products of high exergy from the environment and throwing away the waste material and the waste heat of low exergy back the environment. However, the total exergy in the whole system becomes absolutely smaller than before.The rate of obtaining high exergy products and energy itself by human activity and the speed, by which waste and waste heat having low exergy are thrown away are too fast to attribute to environmental problems [1-3].A material's use by recycling was often common in a circulating society mainly. A significant amount of energy is consumed during circulation. An environmental impact assessment method for the process or the system has not been devised when both of them are taken into consideration. Even if the life cycle assessment evaluation, which has been correctly used up to now, is applied, it is not sufficient for an overall evaluation concerning matter and energy.The real sustainable development is that the exergy reduction value by all human activities on the earth is kept within the range of the exergy reduction in order to consider the earth as closed stationary system. It is important to evaluate the process or the system by using the exergy, and design them so that the exergy loss may decrease as much as possible. We have to consider what process improvement is the most effective."

Jan 1, 2000

By James E. Hoffmann

Oxidative pressure leaching is gradually supplanting other techniques for the decopperizing of slimes. The reasons for this include: much more rapid reactions, more compact equipment, a reduced environmental burden, and perhaps most important, a much lower final copper concentration in the decopperized slimes. This paper will discuss the reactions occurring during decopperization, the acidity and temperatures encountered and the techniques employed for discharging non condensable gasses. A spreadsheet is provided which allows adjusting the operating conditions depending upon raw (undecopperized) slimes composition, solids concentration and lixiviant composition. A typical process equipment flowsheet is provided along with a process narrative.

Jan 1, 2000

By Akira Kaneda, Nozomu Hasegawa

"In the Mitsubishi Continuous Copper Smelting and Converting Process, slag/matte mixture overflowed from the smelting furnace is separated continuously in an electric furnace (slag cleaning furnace, CL-furnace). In order to improve the separation efficiency of slag and matte and to minimize power consumption, the design and the operating conditions of the CL-fumace should be optimized. In the previous study, the authors developed a mathematical model for simulating phenomena in the CL-furnace. The model consisted of 3 modules, electric field analysis, heat and fluid flow analysis and the particle tracking method. In this study, the model was partially modified: k -E. model was adopted, and the effects of various conditions, such as furnace shape (including accretion) and scale, electrodes configuration, immersion depth of electrodes, and thickness of slag layer, were evaluated. And the optimum design and operating conditions were discussed.IntroductionUnder the recent environmental restriction, advantageous features of the Mitsubishi process have attracted much attention. The process uses 3 furnaces connected by launders. Mixture of matte and slag formed in a smelting furnace flows continuously to a slag cleaning furnace (CL-furnace), where the matte is separated from the slag. The matte is continuously siphoned out to a converting furnace and converted to blister copper. The slag overflowed from the CL-furnace is discarded. Because the slag contains about 0.6 % copper, improving slag/matte separation efficiency and decreasing copper loss make a great profit. Moreover the process requires a large amount of electric energy, so reduction of electric power consumption brings in enormous benefit.The objective of this study is to optimize the design and the operating conditions of the process, especially the CL-furnace. This will be achieved by developing the mathematical model and clarifying relations between the design or the operating conditions and various phenomena in the furnace. Fig. 1 shows an outline of the CL-furnace. The mixture entering through an inlet is separated to slag layer and matte layer . In order to maintain the temperature of the melt at a predetermined level, 6 electrodes are immersed into the lag and Joule's heat is generated by 3-phase alternating current flowing."

Jan 1, 2000

By J. Fraser Forbes

"The meaning of the term ""process control"" has evolved significantly since its widespread use began in the manufacturing industries in the 1940s. Further, the scope of process control applications has drastically increased both in terms of the breadth of industries using process automation technologies and the vertical integration of these technologies within a single industry. This evolution and integration of process control technologies within the manufacturing industries has proceeded to such an extent that process automation is an integral part of modern business practices.This paper will examine the current status of process control technology from simple process regulation through process performance optimization to business planning. Each layer of the operations automation hierarchy will be discussed both in. terms of the current state-of-the-art and the directions in which these technologies are evolving. The key tools and tasks necessary for success at every level of the automation hierarchy will be introduced. Finally, the critical challenges that must be faced in accomplishing the goal of complete Computer Integrated Manufacturing (CIM) will be described.Finally, although this paper addresses issues of practical importance to any manufacturing company, the discussions will be framed in terms of the particular challenges facing and the opportunities available within the materials manufacturing industries."

Jan 1, 2000

By J-P Franzidis, E V. Manl, K Runge

Over recent years a number of techniques have been developed as part of the Australian Minerals Industries Research Association (AMIRA) P9 project to represent mathematically or measure directly subprocesses occurring in flotation cells. These include the determination of a:machine parameter (bubble surface area flux, Sb); froth parameter (froth recovery, Rf); entrainment and drainage parameters; and ore floatability parameter (Pi). A cost-effective methodology was developed for using these techniques to derive models of flotation circuits. This methodology was applied to derive a model of the flotation circuit at the Western Mining Corporation (WMC) Ltd Mt Keith Nickel Concentrator. The model was used to simulate a number of minor circuit flowsheet changes, the results of which are discussed in this paper. One year later, a second study of this plant was conducted. In this second study, data were collected while operating the plant in the flowsheet configurations that were simulated from the model developed from the first study. The results obtained from the second study showed reasonable agreement with the trends predicted from the first study model; discrepancies can be explained in terms of the model assumptions. This suggests that this simple circuit modelling methodology can be useful in assisting plant engineers to optimise flotation circuits.

Jan 1, 2000

By Song Yongxue

During the design and operation stages of a block caving project, a large amount of research and development work has been undertaken in the Tongkuangyu Copper Mine. This paper presents the research achievements from these studies, including a rock mass quality evaluation method, cavability prediction, fragmentation evaluation, caving mechanisms, a computerised production scheduling model and the optimised draw control system. The main features of the block caving system in the Tongkuangyu Copper Mine are also discussed.

Jan 1, 2000

By N. Ohmura, H. Saiki, T. Nagaoka

A microbiological flotation system that facilitates the removal of pyritic sulfurfrom coal is reported. The chemoautotrophic bacterium Thiobacillus ferrooxidans is utilized as a pyrite-selective biological surfactant that augments the flotation-mediated rejection of pyritic sulfur. The bacteria were produced by continuous cultivation in 50-L tanks, where it was possible to produce 3.8 x 1012 cells/day when the dilution rate was optimal and the pH was 1.6, a condition that prevented ferric precipitation. Prior to flotation, the bacteria were mixed with coal, which allowed cells to selectively adhere to the pyrite. The adherence of bacteria made the pyrite surfaces more hydrophilic, which facilitated separation by increasing the tendency of pyrite to sink, while the hydrophobic coal floated. When a synthetic coal/pyrite mixture (10.1 % sulfur) was subjected to microbial flotation, the level of sulfur rejection was stable during the entire period of operation (i.e., one hour). In the absence of bacteria, flotation reduced the sulfur content of a coal/pyrite mixture to within the range of 6.7% to 7.4%, with the combustible recoveries ranging from 93.9% to 99.0%. In the presence of bacteria, the sulfur content of cleaned coal was in the range of 1.3% to 1.4%, with the combustible recoveries ranging from 80.8% to 86.3%. Bacterial activity accounted for 57% of the total sulfur rejected through flotation. The desulfurization capacity of the system was further confirmed by testing it with run-of-mine coal. The pyritic sulfur content was reduced from 2.9% in the feed coal to around 1.2% in the froth product, while 80% of the combustible recovery was retained. Microbial flotation removed 60% of the pyritic sulfur from the feed. These findings demonstrated that micro¬bial flotation could be utilized for the removal of pyritic sulfur from coal in a semicontinuous system.

Jan 1, 2000

By M. Olper, M. Maccagni

"The crude zinc oxides (CZO) produced in any thennal process dealing with EAF dust also contain lead, cadmium, and a considerable amount of halides (chlorides and fluorides). The high halide contents make these crude zinc oxides less and less attractive, both technically and economically, and a further refining procedure is nece'ssary to meet the zinc and zinc oxide market requirements.Hydrometallurgical techniques commercially used to dehalogenate the crude zinc oxides are not effective enough to upgrade the crude zinc oxides to the required specification for their direct use in the traditional sulphuric electrolysis by primary zinc producers.The EZINEX® PROCESS has solved the problem of the halides contained in the crude zinc oxides. This process is the only proven technology electrowinning zinc from a chloridebased electrolyte in a conventional cell house. This paper discusses the process economics taking the data from feasibility studies of different size commercial plants."

Jan 1, 2000

By Ali S. Al-Watban

"In this paper, the room temperature friction and deformation properties of various polycrystalline diamonds; i.e. aggregates of diamond crystals with a ""binder"" phase of cobalt and a polycrystalline coating produced by a chemical vapour deposition processes (CVD) were studied when softer metallic and ceramic sliders were used. The experiments were conducted· at relatively low sliding speeds (10 mm/min), in a vacuum of 10-5 mbr after having cleaned the specimen surfaces by out-gassing them for about 30 min at 800 °C. As a result of increasing the number of traversals significant wear of the coated diamond by softer metallic sliders (aluminium and mild steel) was observed. With ceramic sliders, it is shown that the multiple traversals result in the formation of wear groove. With diamond silicon carbide, high friction and adhesion lead to significant metal transfer which then pre-empts cumulative deformation of the harder materials. With the diamond-cobalt composite, the friction is surprisingly low, there accumulation of wear debris on the tip of the slider but no permanent transfer of metal and the harder specimen is not damaged even after 5000 traversal.IntroductionPolycrystalline diamond is mainly produced as tool materials for the machining of hard metals and composites. Thus, the sliding friction and wear resistance are amongst the most important properties relevant to those applications.During cutting by PCD the wear mechanism is mostly influenced by the chemical affinity between the tool material and the workpiece. For example, diamond based materials are not recommended for machining ferrous materials because carbon is highly solubie in iron: This leads to the graphitisation of diamond particles and hence a high rate of diffusion wear is observed (Brookes and Lambert, 1982)."

Jan 1, 2000

By Serdar Aksu, Fiona M. Doyle

"CMP will be an essential process in the production of integrated circuits containing copper interconnects. This study aims to improve our mechanistic understanding of the role that organic chelating agents might play in the reactive slurries used in copper CMP. Copper dissolution behavior in EDTA arid glycine was first examined by producing potential-pH diagrams for the copper-water-EDTA and copper-water-glycine 'systems. The results of potentiodynamic polarization experiments were then considered in light of these diagrams. . In-situ polarization experiments were conducted to gain insight into the electrochemistry of copper during dynamic polishing in slurries prepared from EDT A and glycine.IntroductionCopper has recently started to replace aluminum as the interconnect metal in integrated circuits. Copper interconnection offers faster and more reliable integrated circuits due to its higher electrical conductivity and superior electromigration resistance (1). The damascene method is used to form multilevel interconnects in the manufacture of integrated circuit devices with copper metallization (2, 3). Copper is deposited by CVD or electroplating into vias and trenches etched in the interlayer dielectric (IDL), over a diffusion barrier usually made from titanium, tantalum or their nitrides. Chemical mechanical planarization (CMP) then prepares the wafer for the next deposition step, by removing excess copper and planarizing the surface. During CMP, the wafer is rotated and pressed against a rotating platen covered with a polishing pad. Chemically active slurries containing submicron size abrasive particles (Si02, Al20 3, ceria, diamond, etc.) are applied. Both the mechanical action of the abrasive particles and the chemical action of slurry constituents remove material from the wafer surface. Planarization results because material is removed faster from protruding regions on the surface than from recessed regions. Since CMP can globally planarize .the entire wafer, it has become one of the key technologies for producing integrated circuits with copper metallization."

Jan 1, 2000

By A. N. Aposhian

The electronics industry generates tin/lead bearing by-products that can be recycled for their metal value. This paper will cover the processes used to recycle these tin/lead bearing byproducts from the plating, circuit-board fabrication and assembly industries. Though these processes are well known to the companies who do the recycling, few outside the industry including the generators of the by-products, understand the processes or needs of the industry. This paper will give a broad overview of these processes, and describe the services provided by this industry. The paper will also touch upon the future of the recycling industry, including the legislative and environmental push for the elimination of lead from electronics.

Jan 1, 2000

By A Grice

AMC has completed a number of backfill options studies, including several in recent years for large, three-dimensional orebodies involving total extraction by longhole open stoping with backfill. This has led to the development of a thorough review methodology that assists in the selection of the most appropriate backfill system and the most economic mixes to achieve the required performance. A recently developed design tool has simplified the calculation of backfill strengths for various exposure dimensions and automatically determines strengths incrementally over the height of a stope. Using a generic orebody with a plan dimension of 120 m wide by 360 m long, several different stoping layouts have been analysed to determine the effect of stope dimensions and sequencing on backfill strength requirements. This has been done for stope heights from 50 m to 300 m, in 50 m increments. The required strengths have been calculated in slices and summarised for each stope in four equal layers. The average strength requirement for each layout at each stope height has been compared graphically. For all stope heights, a panel stope layout that minimises the proportion of primary stopes results in a lower average strength requirement than grid layouts on a checkerboard pattern. However, for very high stopes, smaller plan dimensions become more economic. The increase in required strength with stope height is non-linear, making taller stopes potentially more attractive. The main cost factor in most backfills is the rate of binder addition, which is closely related to the strength required. By choosing a layout that minimises the backfill strength requirement, significant savings in binder addition rates and overall costs can be achieved. These must, of course, be weighed against other factors to determine the optimum stoping layout and backfill system.

Jan 1, 2000

By Wantae Kim, Furnia Saito, Qiwu Zhang

"A novel mechanochemical processing technique for the preparation of zeolites from kaolinite in NaOH solution was investigated. Dry and wet mechanochemical treatments combined by subsequent moderate heat treatment could accelerate the synthetic reaction for zeolites from kaolinite. This stimulating process produced zeolite-A and zeolite-X from activated kaolinite at extremely lower reaction temperature than conventionally applied for zeolites production. Conversion to zeolite-A and zeolite-X was strongly dependent on the activated state of kaolinite. Wet mechanochemical treatment modified the chemical composition of activated solids. Rapid dissolution of AIO species rather than SiO ones in the reactant solution was accelerated by wet milling together with NaOH that promoted the formation of zeolite-X of high specific surface area.IntroductionZeolites are a family of hydrated alumina-silicate minerals contains alkali and alkaline earth metals. They have a framework structure that encloses inter-connected cavities occupied by large metal cations and water molecules. Zeolites are characterized for their ability toward ion exchange and reversible dehydration. Properties of them are exploited through commercial productions of particular structural and chemical features. Zeolites are used as commercial uses for catalysis for FCC (fluidized catalytic cracking) of petroleum refining, drying reagents of gases and liquids, and selective adsorbent for pollution control [1-3]. In such purposes, artificially synthesized zeolites are employed, although natural ones are associated with hydrothermal and hot spring alteration of volcanic materials. Commercially, a hydrothermal process has been used for the preparation of zeolite synthesis. This preparation method gives zeolites of high chemical homogeneity and purity, however, this wet-chemistry-based processing is significantly influenced by reaction temperature, pH, concentration, and composition of starting substances [4]."

Jan 1, 2000

By W. Jiao, Y. Yongqi, R. Shan

Soft rock mines are distributed through out P.R.C. And drilling and blasting is still the main method of driving a tunnel in these mines. Traditional smooth blasting has been widely and deeply studied and put into practice in P.C.R since 1970s. But the cartridge and blast hole are both columns, the stress field in the rock around blast hole at the beginning is symmetry around hole axis, and the original cracks in the rock can be activated randomly. So serious overbreak and underbreak at the boundary of an excavation occur often, especially when the excavation is in soft rockmass, and the rates of half-hole marks are generally about 50% in medium rock, and 20-30% in soft rock in Chinese coal mines. For the sake of overcoming the situation, we have been studying directed crack blasting since ten years, and have got some obvious achievements in this respect. Slotted cartridge control blasting in soft rock is studied in this paper. Through model experiments, reasonable decouple coefficient range and slot width are gotten, and unsymmetrical dynamic strain field is analyzed. Through underground test in soft rock with a strength lower than 1OMpa in Dayan Mining Bureau, The results of which the rates of half-hole marks and the nonsmooth grades of the cut contours are 83.3% and 1OOmm respectively have been achieved.

Jan 1, 2000

By M. Canty

This paper presents results from pilot-scale and field testing of an innovative technology that uses sulfate-reducing bacteria (SRB) to treat and control acid mine drainage (AMD). Sulfate-reducing bacteria, a common group of anaerobic bacteria, produce hydrogen sulfide and bicarbonate when supplied with sources of carbon and sulfate. Hydrogen sulfide reacts with metal ions in AMD, precipitating them as metal sulfides. The bicarbonate produced serves to help neutralize the drainage. Pilot-scale metal-removal efficiencies reached 99% for zinc, 99% for aluminum, 96% for manganese, 98% for cadmium and 96% for copper. However, the iron and arsenic removals were not as effective as the aforementioned metals. This was largely attributed to high levels of iron and arsenic that contaminating the organic substrate. There was evidence that both adsorption and sulfate reduction were occurring within the reactors. The SRB field demonstration involved using the flooded subsurface mine workings of the Lilly/Orphan Boy Mine near Elliston, MT, as an "in situ biological reactor." In the mine, high removal efficiencies were observed for aluminum, cadmium, copper and zinc (70% to near 100%) during the four years of monitoring. However, for reasons similar to the pilot scale testing, low removal efficiencies were observed for arsenic and iron. Sulfate reduction was evident by measured decreases in sulfate and the detection of soluble sulfide within the mine water.

Jan 1, 2000