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SLAG composition, slag constitution, reactions in slag, and reactions between slag and metal-in other words, the physical chemistry of slags-are matters of great importance to the open-hearth operator, whether or not he makes use of any detailed knowledge of them. Although this is a relatively young branch of the science of steel- making, much progress has been made; however, much remains to be learned, and many of the statements that can be made at present are probably--or even certainly-subject to future change. Nevertheless, the physical chemistry of slags is sufficiently developed to provide a reasonably secure basis for real understanding of steelmaking reactions. FUNDAMENTALS OF SLAG CONTROL By way of introduction, some time is spent in this chapter on effecting an easy transition from some of the more "practical" manifestations of slag to discussions couched in the more formal language of physical chemistry. This necessitates a certain amount of repetition, but it is felt that the purpose of the chapter is best served in this way. Reactions in the metal phase have products that find their way into the slag and are important components thereof; they are discussed in detail in the preceding chapter. Some substances distribute themselves Between slag and metal in definite fashion, and others are found only in the slag. Their reactions are a large reason for this chapter. Limitations of Slag Control. The open-hearth process is essentially oxidizing and cannot be otherwise operated. (Oxygen gradients in the furnace, the mechanism of oxygen inflow, and similar subjects are discussed in Chapter XIX.) As shown in the calculations of material and heat balances for the charge (see Chapter XV), from 25 to 50 lb. of oxygen will flow from air or combustion gases into the charge or molten bath during the heat for each ton of liquid steel

Jan 1, 1944

By N. Moelans

A method using an ex-situ electrochemical measurement device was developed to determine the oxygen potential of non-ferrous metallurgical slags. The electrochemical cell consists of the molten slag sample, an inert Ir electrode, a stabilized Zr02 solid electrolyte and a NiINiO reference electrode. Different slags from non-ferrous pyrometallurgical processes were analysed at 1100 and 1200°C and pO2 values between 10-3 and 10.12 bar were obtained. The measurements were evaluated with? thermodynamic calculations and using processing considerations. It was found that the reproducibility and stability of the measurement was significantly improved by shielding the molten slag from the atmosphere by a thin layer of carbon, especially for slags with a low oxygen potential.

Jan 1, 2003

By Philip Derbyshire, Dale J. Scheffler

"Continuous Flight Auger (CFA) piling is a variation of Augered Cast-In-Place (ACIP) or augercast piling. In both cases a continuous auger with a hollow stem is used to drill a hole and a pile is formed by injection of cementitious material through the hollow stem as the auger is withdrawn. CFA differs from conventional American ACIP by the use of concrete rather than grout to form the pile, and by the type of equipment used to advance the auger into the ground and withdraw it. CFA installation uses a European style rig (i.e. fixed mast and rotary system) which can produce greater crowd and usually has a larger rotator or drill motor than the standard augercast setup. A standard augercast setup will consist of a lattice-boom crane and a set of leads to house the drill motor and auger. The auger size will range up to 24 inches (610mm). With CFA rigs larger diameter piles can be constructed, 24 to 36 in dia. (610mm to 915mm) are common and the technique has been applied with diameters up to 48-inch (1220mm). CFA makes use of sophisticated computer controlled monitoring systems, which have more recently been introduced for conventional ACIP piling. Developments in CFA have taken place over the last 25 years in Europe and particularly in the UK, but are relatively new in the USA. One application is in the construction of secant (overlapping) piled retaining walls. D.J. Scheffler Inc. recognized the potential of the CFA system following visits to the UK and has introduced its use into California for both secant piling and other applications.BACKGROUNDThe high price of real estate in many of the favored areas of California has increasingly led owners to want to build basements under their houses to increase the floor space available on a lot. Many of these areas are by the coast where the ground conditions are predominately granular and the water table is high. Conventional shoring and dewatering systems have often caused problems with adjoining properties. Clearly tangent walls are not suitable in these conditions because of leakage and loss of ground. The secant pile system, using CFA techniques, has proved very effective at overcoming the problems experienced by other methods. Other applications for CFA secant walls have included use for an emergency job on a highway following erosion caused by unusually heavy rainfall.METHODThe concept of secanting piles, whereby primary(female) piles are installed first and then secondary (male) piles are cut into the primary piles is not new. The method has been known for more than 30 years. Originally ‘Benoto’ grabbing rigs, developed in Japan, were used together with sectionalized double skinned casing and oscillators.This early method was slow, although very effective. More recently high torque rotary machines have been used. Contractors in the UK have increasingly used CFA techniques to further improve productivity of this type of piled wall. The improved capabilities of piling rigs available, as well as developments in concrete technology and instrumentation, have made this possible."

Jan 1, 2005

By G. S. Scott, G. W. Jones

"INTRODUCTION An important phase of the accident-preventing program of the Bureau Mines is the determination of the explosion hazards of various combustible gases, vapors, and liquids encountered in mining and allied industries and the development of methods of eliminating or mitigating them.Recently, isobutane has become a commercially important raw material in the production of aviation gasoline by the alkylation process. 4/ in which isoparaffins are combined with olefins to give higher molecular weight compounds of branched-chain structure.Because of the anticipated commercial importance of isobutane in industry, it has been deemed necessary to study and determine its general explosion haz¬ards. This report gives its limits of inflammability, minimum ignition temper¬atures, and the amounts of nitrogen and carbon dioxide required to render isobutane-air mixtures noninflammable."

Jun 1, 1947

By M. C. Harris

"Excess Gibbs energy is a thermodynamic parameter which quantifies the difference between the value of the Gibbs energy for a real mixture and that for an ideal mixture. More specifically the partial molar excess Gibbs energy of a species (i) in a mixture is indicated by the change in the overall excess Gibbs energy of the solution as the number of moles of species (i) changes while keeping temperature, pressure and the number of moles of all other species in the solution constant. Generally it is obtained from the activity coefficient which in turn can be obtained for a species in a mixture using a variety of models. The most widely used method is to use UNIFAC. Flotation is probably the most important process in the concentration of minerals and requires the use of reagents such as collectors and frothers. There is abundant experimental data which illustrates that collectors of different alkyl chain lengths will change the contact angle and that frothers of different structures and molecular weights will result in changes in key flotation properties such as froth behavior, surface tension and critical coalescence concentration. In this paper it is shown that there is a strong linear relationship between measured parameters such as froth volume/height, surface tension, critical coalescence concentration and contact angle and the partial molar excess Gibbs energy of the molecules used. Proposals are made to explain these correlations.INTRODUCTIONAs is well known froth flotation is arguably the most widely used process in the separation of minerals. In broad terms the process relies on the use of reagents known as collectors to adsorb onto a mineral surface and thus render the mineral particle hydrophobic. Alkyl thiolates are very commonly used for this purpose. The hydrophobicity is induced as a result of the alkyl group’s molecular structural properties which results in it forming a non-ideal mixture with the process water. Surfactants (or frothers) are typically alcohols and are known to lower the surface tension of the system and also inhibit bubble coalescence and reduce bubble size. Since alcohols are polar they will also form a non-ideal mixture with water. The hydrophobic mineral attaches to the bubble and rises to the froth phase where the valuable mineral is recovered as a concentrate. Frothers have often been characterized using the so-called HLB (hydrophobic-lipophilic balance) number but recently it was shown that the use of activity coefficients (?) or excess Gibbs energy (G ex ), which is calculated using equation (1) is a much more appropriate way to describe the behavior of these reagents in non-ideal mixtures with water (Corin and O’Connor, 2014)."

Jan 1, 2016

By Lawrence Tsang, Conrad Ng, Tim Leung, Peter Poon

"The Mined Tunnel is part of the Central-Wan Chai Bypass and Island Eastern Corridor Link (CWB), which is a strategic road along the northshore of Hong Kong Island targeted to alleviate the heavy traffic congestion. The objective of this paper is to review the performance of construction of a 160m long Mined Tunnel with a trinocular cross-section area of 460m3 and a combined span of about 50m underneath the southern approach ramp of the existing Cross Harbour Tunnel (CHT) by sequential excavation method (SEM) in hard rock. Mechanical excavation of tunnel by adopting the New Austrian Tunnelling Method (NATM), together with the application of NGI Q-system allows observational approach and optimization of temporary rock support design. Furthermore, the good performance of optimized rock support and the stability of CHT are confirmed through instrumentation monitoring review. This paper also discusses the selection of different tunnel plant and equipment to achieve the planned rates of tunnelling by mechanical excavation in competent granitic rock. INTRODUCTION The works of the CWB mainly comprise construction of 4.5km dual three-lane trunk road, of which a 3.7km section is a tunnel connecting Rumsey Street Flyover in Central to Island Eastern Corridor at North Point (see Figure 1). The Mined Tunnel runs from the ex-Public Cargo Working Area (ex-PCWA), underneath the existing CHT, and through the Causeway Bay Typhoon Shelter. The Mined Tunnel passes at an oblique angle beneath the southern portal of CHT over a length of some 50m. CHT is the primary sensitive receiver of this project and is utilized with a daily throughput of about 120,000 vehicles that far exceeds the design capacity of 78,000 vehicles per day. Hence it is necessary to choose the most appropriate tunnelling method to preserve the structural integrity of the CHT. Other sensitive receivers in the vicinity include structures to the north of the Mined Tunnel, the Royal Hong Kong Yacht Club (RHKYC); and to the south of the Mined Tunnel, the Police Officers’ Club (POC)."

Jan 1, 2016

By R. Schempp

DURING the past few years, general interest in the steel-producing and steel-consuming industries has been centered on the so-called "inherent characteristics" of steels. While often vaguely described, these char-acteristics are known to influence the response to heat-treatment and the hardening characteristics of the material. Although most of the recent papers and discussions have associated the "inherent characteristics" with the austenitic grain size and empha-sized the importance of it, comparatively little is known of the variables that may affect the size of the austenite grain. The work to be described in this paper was carried out during the course of a study on the inherent characteristics of tool steel containing one per cent cart on. The discrepancies encountered in the determination and classification of the austenitic grain size led to in investigation of some of the variants influencing the austenitic grain size as determined by standard methods.

Jan 1, 1937

Comparison of Grinding and Liberation Processes for Stalky Biomass Materials as a Prerequisite for Production of Energy Pellets with High Calorific Value Pelletising biomass, especially straw and stalky materials, requires a product specific size reduction and liberation. However, moisture content plays an important role in palletising and also affects the energetic properties of the biomass. The paper illustrates the characteristics of the mentioned type of biomass and specifies the necessities for production of energy pellets. Defined requirements for biomass energy pellets will be shown based on relevant standards. The work focuses on a comparative investigation of the straw fibres after grinding with hammer/impact mill and after the liberation of the straw fibres with twin-screw extruder (two different communition units). A traditional hammer mill as well as an hydrothermal process taking place in a twin-screw extruder were utilised. Results of the grinding and liberation of rye and wheat straw fibres are discussed based on a detailed particle characterisation (particle size and shape distribution). Besides high calorific value the main pellet quality parameters are mechanical stability, abrasion resistance and further combustion technical characteristics. The particle size distribution displayed optimum characteristics for the combustion processes to be carried out in a furnace. The durability of the pellets produced from straw fibres liberated with twin-screw extruder was comparatively better then that prepared with the straw fibres after grinding with impact mill. Particle size distribution, abrasion values and the strength characteristics showed a good correlation with each. The high presence of N and S would result in high NOx and SOx emissions, where as the high concentrations of Cl would corrode the furnace. These chemical properties of the straw would restrict its usage in small scale furnaces.

Sep 13, 2010

By John T. Awald

The efficiency of search for porphyry copper and molybdenum deposits can be greatly increased. A model exploration system is here presented to show how geologic literature data and field surveys can be aided by modern statistical and computer methods. Assuming that major ore deposits occur in clusters, it is possible to evaluate rapidly large areas at modest cost and with minimum investment risk. An example of the success of these methods is given. Clusters of mine density and metal production covering the State of Nevada were plotted and machine contoured. Selection of a 47,300 square-mile area on the Nevada-California border was made. Within this area, detailed analyses were performed, and a 3000 square-mile site was picked for subsequent field examination. To initiate efficiently the field work, 81 stream sediment geochemical samples were collected and analyzed for copper, zinc, and molybdenum. These data established local variance and necessary statistical controls. Following this, a total of 151 geochemical samples were used to survey the 3000 square-mile area. Computer contouring of results directed attention to specific target areas for detailed geologic analysis, property acquisition and drilling. A total of 22 copper-zinc and molybdenum anomalies were identified. Four of these were recommended for further exploration. To date, two have been acquired and drilled and preliminary ore reserve and financial analysis have been made on one. The estimated cost and time for the regional exploration phases leading to these targets were thirty man-weeks and $16,000.

Jan 1, 1973

By G. L. Fredrickson, T. A. Johnson, B. R. Westphal, J. C. Wass, S. X. Li, D. Vaden

"Recovery of uranium from the Mk-IV and Mk-V electrorefiner vessels containing a LiCl/KCl eutectic salt has been on-going during the pyrometallurgical processing of used nuclear fuel for 14 and 12 years, respectively. Although austenitic stainless steels are typically utilized for LiCl/KCl salt systems, the presence of cadmium in the Mk-IV electrorefiner dictates an alternate material. A 2.25Cr-1Mo alloy (ASME SA-387) was chosen due to the absence of nickel in the alloy which has a considerable solubility in cadmium. Using the transition metal impurities (iron, chromium, nickel, molybdenum, and manganese) in the electrorefined uranium products, an algorithm was developed to derive values for the contribution of the transition metals from the various input sources. Weight loss and corrosion rate data for the Mk-V electrorefiner vessel were then generated based on the transition metal impurities in the uranium products. To date, the corrosion rate of the 2.25Cr-1Mo alloy in LiCl/KCl eutectic is ""outstanding"" assuming uniform (i.e. non-localized) conditions.IntroductionLow-enriched uranium products are being recovered from the Experimental Breeder Reactor-II (EBR-II) and Fast Flux Test Facility (FFTF) used nuclear fuels by a pyrometallurgical treatment process at the Idaho National Laboratory (INL). The treatment process comprises a set of operations designed to neutralize bond sodium, recover uranium from radioactive fission products, and place the fission products into acceptable waste forms [1-2]. Reactive sodium metal, essential for heat transfer purposes during reactor operations, is readily converted to chloride during the process. Electrorefined uranium products are currently being stored pending a final disposition decision. Treatment of the EBR-II used driver fuel was initiated in June 1996 while blanket fuel processing started in September 1998. These treatment processes continue on the balance of the used fuels."

Jan 1, 2011

By T Purvis

Xstrata Copper is extending the Ernest Henry Mine with a 6 Mtpa sub-level cave (SLC) mine being constructed under the pit. The SLC mine will maintain the EHM operation until 2024 after the pit is completed in August 2011. In February 2008, the first cut of the new underground mine at EHM was fired with the start of an exploration decline. Since then Xstrata Copper has continued the development and construction of a SLC mine. During this process a number of challenges arose, some of which had not been anticipated in the planning stages, that in turn has been addressed to ensure the development continued. The challenges have been many and varied and range from setting up the portal area and commencing the exploration decline development in an active large open pit, to management of underground water. Further challenges were presented by the effects of the GFC on investment recommendations, with the scale of the mine varying from a shaft mine to a smaller scale trucking only mine in mid-2009 and back to the full shaft mine in late 2009. The effect was the parallel development of two separate mining scenarios, with the challenge of maintaining commonality for as long as possible to keep both options alive until the final board approval was obtained. In 2010 the RSPT caused further impacts. This paper will describe the current progress of mine development as well as how the various challenges have been met and some key lessons learnt from these experiences.

Mar 21, 2011

By D Mather, H R. Asche

"In the civil tunnelling field, the use of tunnel boring machines (TBM) has now overtaken the use of conventional excavation methods (drill and blast / roadheader). This is due to a number of reasons, including the increasing availability and reliability of TBMs, the ability to deal with a wider range of face conditions, and the reduced excavation cost that TBMs can bring.Mining companies have spearheaded the advances in shaft boring by mechanised means, both in blind and raise boring. However, mining companies have been slower to adopt mechanised tunnelling.When contrasted with a conventional mining contract, there are good reasons why TBMs in mining applications are relatively rare. A conventional decline contract may have very little geotechnical information. The decline alignment can be subject to change as the tunnelling progresses. The infrastructure requirements are less for a conventional decline, and the sunk cost prior to excavation commencing is lower. Contract documents can be very simple.The history of TBM use in mining is reviewed and lessons are described. From the case histories and lessons learnt, the paper identifies ways that mining companies can maximise the potential benefit of TBM technology.We believe that despite the additional requirements for TBM declines, the cost and time advantage to mining companies is very attractive. The challenge is to recognise and to meet the requirements for success in a TBM drive to achieve the advantages of: faster advance rates reduced rock damage/overbreak reduced support requirements uniform muck characteristics greater personnel safety.From the case histories and lessons learnt, the paper identifies ways that mining companies can maximise the potential benefit of TBM technology.CITATION:Asche, H R and Mather, D, 2014. Use of ?tunnel boring machines in the mine environment, in Proceedings 15th Australasian Tunnelling Conference 2014, pp 655–662 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 17, 2014

During the construction of storage caverns, and during their lifetime if the use to which they are put so requires, it is necessary to provide adequate ventilation to ensure the safety and comfort of the underground workforce. An analysis of likely contaminants during construction has indicated that where a large facility is situated in a rock mass of even moderate temperature climatic conditions are likely to be the limiting factor during most of the mining operation and atmospheric pollution when blasting is undertaken. Possible options for improvement are increased air flow, cooling of intake air and reduction of the heat source by altering the number and type of haulage units employed in the cavern. Local solutions are an alternative approach where heat problems are confined to a few specific locations

Aug 1, 1994

By D. M. Muir

The mineralogy of residues formed during the pressure acid leaching of arid region nickel laterite ore varies according to the salinity of the process water, alkali cation additives and the overall acid loading. In fresh water, hematite is the main iron-bearing leach residue component, together with amorphous silica and hydronium or sodium alunite/jarosite [(H3O,Na)(Fe,Al)3(SO4)2(OH)6]. As the process water salinity increases, or as NH4+ or K salts are added, alunite/jarosite is the kinetically favoured iron-bearing phase accompanied by an increase in acid consumption. The alunite/jarosite appears as two XRD distinct phases with different Fe:Al molar ratios. In weakly saline water, iron-rich alunite/jarosite slowly transforms to hematite and an aluminium-rich alunite/jarosite together with the release of acid. The addition of potassium salts forms a more stable alunite/jarosite whilst the addition of ammonium salts leads to greater transformation of alunite/jarosite at 250°C. Weakly saline process water gives enhanced nickel recoveries, whilst strongly saline process water gives lower nickel recoveries but higher soluble iron because of chloro-complexation. SEM and microprobe analysis shows very little nickel is associated with the alunite/jarosite and hematite phases. Nickel losses to the residues are attributed to adsorption on amorphous silica and to a lesser extent on alunite/jarosite.

Jan 1, 2006

By Martin A. Elliott

Recommendations for safe practices in the operation of Diesel engines underground must take into consideration the hazards that might be created if the composition of the underground atmosphere differs from that of normal air. One aspect of this problem was discussed in the second report6/ of this series, which presented the results of tests in which a Diesel engine was operated with mixtures of normal air and exhaust gas supplied to the intake of the engine. Atmospheres .of this type were studied first because they will be present whenever the exhaust was is discharged into the atmosphere of underground workings in which an engine operates. Diesel engines in underground service may operate in another type of atmosphere, namely, one

Jan 1, 1941

By Yogesh Narula

Nevis Bluff Landslide - On September 17” 2000, a rockfall measuring lO,OOOm3 at Nevis Bluff, New Zealand, triggered a loday emergency. It ended when a hazardous column of rock that towered over State Highway 6 was finally shattered. The operation called for unusual and unique solutions using aerial bombing and inverted blasting techniques, not known to have been attempted before under these conditions, anywhere in the world.

Jan 1, 2002

By K. Kawagishi, K. Matsumoto, Y Koizumi, H. Harada

A new burner rig for cyclic and hot corrosion testing of Ni-base superalloys and high-temperature coatings has been developed at the National Institute for Materials Science (NIMS) in Japan. The concepts of the rig design include: use of kerosene as fuel, easy operation for materials research and multi-specimen testing capability per test run. The burner rig consists of six blocks including combustion block, corrosion-solution injection block, furnace block, specimen block, controller block and outdoor facility block. During verification testing, it was confirmed that the rig had accurate specimen temperature control within ±1? from 600 to 1100? and automated easy operation. Cyclic testing of several Ni-base superalloys was conducted. The results from 50 cycle testing indicated that a new NIMS alloy developed for 1700? class gas turbine had higher oxidation resistance than CMSX-4. This new burner rig testing capability at NIMS can be very useful for future oxidation, hot corrosion and coating durability studies.

Jan 1, 2010

By M. F. Dunn

The objective of this work was to define jet fan performance in d variety of large cross-section underground mine applications and to develop guidelines for thin performance in open airways, dead headings, and multiple face areas. Measurements include common ventilation instruments, continuous recording remote electronic anemometers to measure air velocity, and sulfur hexaflouride tracer gas with chromatograph analysis to determine dilution rates and air recirculation. For open airways the following were determined: Large jet fans are leas efficient in smaller airways, but quite effective in larger open airways for achieving both uniformity end greater air entrainment, when inclined about 10° or elevated. For dead headings the following were determined: The jet fan must be placed against the rib of the heeding closest to the incoming airstream from the crosscut or recirculation will increase. The fan should be placed at the pillar corner to increase airflow. As the fan is moved closer inby, recirculation increases. Larger fans promote recirculation. Inclining fans about 12° improves airflow in large headings. For face areas the following were found: For panels having uncontrolled airflow, the fan should be placed in the incoming airflow, about one pillar inby, and directed diagonally across the faces. For panels having narrower rooms and controlled airflow, the fan should be placed alongside the panel side in the first room so as to direct or intersect the incoming airflow at the next entry or crosscut.

Jan 1, 1983

By A. E. Powers

YEARS of experience and research have shown that molybdenum, tungsten, and vanadium are among the most useful and effective elements in augmenting the high-temperature strength of heat-treatable, ferritic steels. Grün, for example, in conducting an early survey of the strengthening effects of various elements in annealed, low-carbon steel at 750° and 930°F (400° and 500°C), found molybdenum and vanadium to be the most effective.' Holtmann comprehensively studied the strengthening effects of molybdenum and vanadium in quenched and tempered steels at 930°F as a function of microstructure and carbon content.' He found creep strength to be related to the saturation of the austenite at the austenitizing temperature, such that strength is increased by alloying until the y loop is reached—the terminus of complete austenitization. Beyond this degree of alloying, the inability to heat treat will result in lower strength, at least for low and moderate creep temperatures. Tungsten, owing to higher cost than molybdenum, has been little used in ferritic high-temperature steels. As a result, very few investigations have been made of its high-temperature strengthening ability, and reliable data on its effectiveness are not available. Grün rated tungsten far less effective than molybdenum at 930°F (500°C) on a weight-percentage basis.' However, Tammann has found that tungsten is as effective as molybdenum in raising the recrystallization temperature of iron. For this reason Smith, in a review of the subject, has advocated a re-examination of the influence of tungsten on the high-temperature strength of steel.' In any study of the effects of alloying additions on high-temperature properties, recognition must be made of the many variables involved, some of which can be controlled but have been ignored in innumerable investigations of the past, and some of which are difficult or even impossible to control. One cannot, for example, assign a definite strengthening index to any one alloying element, for this will be dependent upon the microstructure (heat treatment and mechanical treatment), testing con- ditions (temperature, time, and stress), and the complete composition of the steel (accompanying alloying elements, impurities, etc.). One ever-appear ing variable, hardness or tensile strength at room temperature, may be eliminated by heat treating all of the alloys to a single hardness level. An attempt may be made to control the variable of primary quenched structure by oil or water quenching the test specimen. The control of such variables may not be possible in cases of widely varying compositions, but at least such deviations should be recognized. Material and Procedure The alloys, made as 30-lb ingots in an induction furnace, all had the same base composition of about 0.18 pct C, 0.85 pct Mn, and 0.48 pct Si. They were grouped as follows: Mo Group—Containing up to 5.2 pct Mo. W Group-Containing up to 6.0 pct W. V Group—Containing up to 3.3 pct V. Mo-V Group—Containing up to 2.7 pct Mo and up to 1.4 pct V. Mo-W Group—Containing up to 2.5 pct Mo and up to 2.5 pct W. The steels, listed in Table I, were forged to ¾ in. sq bars and the material for the high-temperature, rupture-test specimens was further swaged to %-in. round bars.

Jan 1, 1957

By Chas. B. Dudley

A Discussion of the papers of Mr. James Gayley, on "The Application of the Dry-Air Blast to the Manufacture of Iron," and of Mr. J. E. Johnson, Jr., on "The Physical Action of the Blast-Furnace," by Messrs. Charles B. Dudley, R. W. Raymond, J. E. Johnson, Jr., William F. Mattes, James Gayley, David Baker, John Birkinbine and F. E. Bachman. (Washington Meeting, May, 1905.) CHAS. B. DUDLEY, Altoona, Pa.:-Pam not a blast-furnace man, and this always puts me it a disadvantage because I cannot go into the details of the making of iron and steel. I have not the experience, and have to take the statements of other people, so what I say regarding the subject of this paper is not in the sense of an expert. When I first heard of Mr. Gayley's experiments, I said to myself, " I fear they will result in failure, since, apparently, Mr. Gayley has forgotten one chemical fact, namely, that carbon does not combine with oxygen in the absence of water-vapor." This fact which was so astonishing when it was first brought out some years ago, and which those who are interested may find in the Journal of the Chemical Society of London, for 18S5, page 349, and 1894, page 611, led me to think that the drying of the air would be a mistake. The general subject of the influence of water-vapor on chemical action is a large one; but the special point in which we are for the moment interested, namely, the influence of water-vapor on the combustion of carbon, was especially treated by Mr. H. B. Baker, in the papers referred to. Apparently, however, as the result of Mr. Gayley's experiments, we are to learn that the amount of moisture still left in the desiccated air is sufficient to secure perfectly satis¬factory combustion. In thinking over Mr. Gayley's paper, it occurred to me that there were two alternatives, either of which might be chosen, namely, we might dry the air as Mr. Gayley does, or possibly we might, in a very much simpler way, simply saturate the air at a constant temperature, and thus get uniform working and

Sep 1, 1905