Search Documents

By F. G. Prado

The technology for the extraction of zinc from zinc residues, such as zinc ashes, drosses and metallurgical flue dusts, by way of ammonium chloride solutions is well established, at least at the laboratory and bench scale levels. (3, 4) Zinc is soluble in ammonium chloride solutions in the form of zinc diammine chloride. Its solubility depends upon the concentrations and temperatures employed. The procedure and the equipment required are simple, and they can be applied either to small or large operations. As a by-product, zinc diammine chloride is produced with extremely low impurities in quantities which are stoichiometrically proportional to the zinc removed. The technology has been applied experimentally to galvanized steel residues. The dezincing results, including removal performance, energy and reagents required, and by-products are summarily presented in this paper.

Jan 1, 1992

By Harold L. Lovell

The areas of application, the limitations imposed by water chemistry as well as the advantages and disadvantages in the use of limestone for the treatment of coal mine drainage have recently been described by the authors (1),(2), (3). The process has been demonstrated in continuous, full-scale operation to yield a treated water meeting specifications established by the Pennsylvania Sanitary Water Board and containing excess alkalinity. Their final pH levels are usually less than seven, a condition which avoids consumption of excess neutralization reagents, but which occurs with lime-based processes and results from unwanted side reactions. Operating experience has been cited by Calhoun (4) using ferric waters while others (5), (6), (7), (8), (11), have reported on related research efforts. Despite the advantages including ?the relative simplicity, and minimal costs of the process, there have been very limited industrial applications of mine drainage neutralization with limestone. Although any treatment of these waters may be considered as a temporary control measure (9), the lack of feasible, immediate alternatives, the extensive magnitude. of the waters and the high cost of treatment requires that optimum processes should be utilized and that operating experience in their use be developed as is feasible. This paper will review treatment experience with a ferrous water of moderate pollution loading .

Jan 1, 1972

By J. E. Murphy

The high-purity thorium metal was prepared by the Bureau of Mines from electrolytically produced thorium alloys. The thorium-chromium and thorium-manganese alloys were separated into the component elements by vacuum distillation. Chromium and manganese impurities remaining in the thorium metal after distillation at 1,850° C were <0.005 weight-percent. Removal of volatile impurities such as aluminum, calcium, magnesium, and lead was also accomplished.

Jan 1, 1969

Laminated ceramics have received widely scientific and commercial attention because their properties, such as mechanical properties and electrical properties, can be tailored by adjusting the structure, thickness and composition of the different layers. For example, ferroelectric Bi4T13O12 (BIT) which has a positive temperature coefficient of dielectric constant (TE) can be used to modify the negative of typical microwave dielectric ceramic BaNd2Ti4O12(BMT). However, BaNd2Ti4O12/Bi4Ti3O12/BaNd1Ti4O12 (BNT/BIT/BNT) laminated ceramics could not be prepared by the general method because the optimal sintering temperature of BaNd2Ti4O12 ceramic (around 1350°C was much higher than that of Bi4Ti3O12 ceramic (around /1100°C). in this research, a new method of spark plasma sintering (SPS) combined with post-sintering was successfully proposed to prepare BNT/BIT/BNT laminated divided proposed to prepare ceramics. It was divided into three steps. In first step, the BaNd2Ti4O12 ceramics were prepared by conventional sintering method. In second mop, the calcined and pre-pressed Bi4Ti3O12 powders were sandwiched between BaNd2Ti1O12 ceramic pellets and spark plasma sintered at 900&apos;C for 10min to synthesize BNT/BIT/BNT composite ceramics. In the last step, a post-sintering was employed to reoxidize the partially reduced BNT/BIT/BNT composite ceramics. The results of scanning electron microscopy (SEM) and electron probe mircoanalysis (EPMA) showed that BNT layer and BIT layer were well bonded and no significant interfacial infiltration between them was observed. The sandwiched BNT/B1T/BNT ceramic with 10.7% BIT in volume has a dielectric constant of 92.8, a low dielectric loss of 0.0068 and a small temperature coefficient of dielectric constant v/35 ppm/C at 1 MHz.

Jan 1, 2003

By Z. D. Tan

The continuous digestion technological conditions of phosphate tailings with high magnesium content in sulfuric and phosphoric mixed acid is studied in this paper. The influences of excess coefficient of sulfuric acid, weight liquid to solid, reaction temperature and time on conversion of P2O5 and MgO are discussed. The influence of infiltration capacity of phosphogypsum by the concentration of liquid-phase SO3 is discussed too. Under the optimal technological conditions, the conversion of P2O5 is 95.56% and MgO 98.63%, the filtration rate of phosphogypsum increases with the increasing of liquid-phase concentration of SO3, the optimal apparent concentration of SO3 is 0.135~0.14g? mL-1 in liquid-phase. The filtration rate of phosphogypsum is 1473kg? m-2? h-1. N-P-Mg compound fertilizer was produced by adding magnesia powder and inflating ammonia in filtering medium.

Jan 1, 2014

By Dr. -Ing. Wolfgang Pietsch

Many primary metallurgical wastes are in the sh.-ape of turnings; borings, chips, dusts, and other particuletes. While such. materials can be easily segregated and/or upgraded to yield high quality ?secondary metals with often known composition for easy recirculation into the production? process; their particulate nature results in various problems. Roller presses are used in an ever increasing number for size enlargement and densification of primary particulate metallurgical wastes for secondary metal recycling. The paper will mention the areas of application from A(luminum) to Z(ink), also including Brass; Cast Iron, lead, and Stainless Steel, as well as dusts from all types of melting and ladle furnaces or converters. Typical systems using roller presses for size enlargement. will be discussed.

Jan 1, 1995

By Yong .. Jun Wu

Laminated ceramics have received widely scientific and commercial attention because their properties, such as mechanical properties and electrical properties, can be tailored by adjusting the structure, thickness and composition of the different layers. For example, ferroelectric Bi4Ti3O12 (BIT) which has a positive temperature coefficient of dielectric constant (,E) can be used to modify the negative tE of typical microwave dielectric ceramic BaNd2Ti4O12(BNT), However, BaNd2Ti4O12/Bi4TiO12/Bi4Ti3O12/BaNd2Ti4O12 (BNT/BIT/BNT) laminated ceramics could not be prepared by the general method because the optimal sintering temperature of BaNd2Ti4O12 ceramic (around 1350°C) was much higher than that of Bi4Ti3O12 ceramic (around 1100°C). In this research, a new method of spark plasma sintering (SPS) combined with post-sintering was successfully proposed to prepare BNT/BIT/BNT laminated ceramics. It was divided into three steps. In first step, the BaNd2Ti4O12 ceramics were prepared by conventional sintering method. In second step, the calcined and pre-pressed Bi4Ti3O12 powders were sandwiched between BaNd2Ti4O12 ceramic pellets and spark plasma sintered at 900°C for 10min to synthesize BNT/BIT/BNT composite ceramics. In the last step, a post-sintering was employed to reoxidize the partially reduced BNT/BIT/BNT composite ceramics. The results of scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) showed that BNT layer and BIT layer were well bonded and no significant interfacial infiltration between them was observed. The sandwiched BNT/BIT/BNT ceramic with 10.7% BIT in volume has a dielectric constant of 92.85, a low dielectric loss of 01068 and a small temperature coefficient of dielectric constant of 35 ppm/°C at MHz.

Jan 1, 2003

By B. R. Bowerman, W. J. Thoburn, M. J. Humphris

"Nickel granules are produced for carbonylation by pouring a molten stream into a path of high pressure water. Granules and water are separated in dewatering bins. The overflow, which contains up to 0.1 weight percent solids, was initially cooled and recycled to the granulating step. However, the rate of buildup of these solids in the handling system was intolerable. A lamella thickener was installed to solve the problem by removing solids from the dewatering bin overflow. Its description, application and performance to date are discussed.The lamella thickener treats a slurry containing about 0.1% solids of which about 30 weight percent is less than 325 mesh. It recovers 80 to 90 percent of the input solids in an underflow slurry containing 90 weight percent solids. Since its installation the frequency of cleanout of the recycle water handling system has dropped from about once per month to about once or twice per-year."

Jan 1, 1977

By James W. Neill

Discussion of the paper of H. 0. Hofman, presented at the Canal Zone meeting, November, 1910, and printed in Bulletin No. 42, June, 1910, pp. 473 to 497. JAMES W. NEILL, Pasadena, Cal. (communication to the Secretary *) :-Professor Hofman&apos;s paper brings the art up to . date. As I was one of the pioneers in this business, I beg to give the following incomplete data regarding my efforts in this line. In the year 1883, while I was in charge of the smelting-operations at Mine La Motte, Mo., there was at the concentrator an unusually large production of a middle product, locally called "iron," which carried considerable values in nickel and cobalt, and which it was desirable, for this reason, to treat by itself. The works could not spare a furnace for the purpose; and to handle this product I improvised a "roast-hearth " from an old " lead-hearth." This was a small cast-iron furnace of the usual construction, about 2 by 4 ft. in dimensions, with a hollow cast-iron back, through which the wind circulated before entering the tuyeres. I had a cast-iron grate made to fit this hearth, and placed it flush with the lip, or apron, and above the tuyeres. On this grate, which had round holes about 0.25 in. in diameter, and a total surface of about 20 by 40 in., I roasted the nickeliferous pyrite product; starting the fire with kindling, then adding charcoal, and then gradually feeding the sulphides with a shovel, so as to cover the fire, choke down blow-holes, and get an even bed. Blast at a pressure of 3 or 4 oz. was supplied by a fail-blower. When a cake of roasted material had formed, it was removed with a steel bar, or fork, to the lip of the furnace, and thence into a wheel-barrow.. The fine material which had remained unmelted, but very hot, on top of the cake would promptly ignite when the cake was broken up and removed. The fire would then be covered with fresh material and * Received Aug. 29, 1910.

Apr 1, 1911

By Johannes Münzer

Regeneradores são elementos importantes em uma usina siderúrgica. Eles são os responsáveis pelo aquecimento do ar de sopro aplicado no alto-forno a partir do aproveitamento da energia contida nos gases do processo de produção de ferro gusa. Dessa forma, os regeneradores estão diretamente associados ao processo siderúrgico. Durante do seu ciclo de trabalho, o qual se denomina campanha, problemas podem ocorrer devido a variações operacionais indesejadas, falhas de projeto, entre outros fatores. Num ambiente onde o tempo cessante de um equipamento gera enormes custos, a solução é desenvolver soluções customizadas que minimizem essa interrupção. Cada uma das partes do regenerador tem funções únicas e consequentemente soluções únicas, que visam o reparo no estado da arte com menor custo.

Aug 17, 2017

By Lucas Coelho da Silva

Também chamado de PRFV, esse tipo de material é usado em diversos segmentos da indústria e a escolha por esse material é devido ao aprimoramento de suas características ou propriedades se comparados com os metais, cerâmicos ou polímeros isoladamente. O tempo médio de um incêndio foi estimado fazendo-se um levantamento de incêndios de média a grandes proporções e esse tempo usado para calcular a temperatura média do incêndio para materiais hidrocarbonetos. O tubo tem sua temperatura limitada em 200ºC, temperatura de degradação do polímero. As amostras foram envelhecidas no forno a uma temperatura próxima da deterioração e depois resfriadas à água e ao ar. Foi comprovado através da análise da transferência de calor que quanto mais perto o material estiver da fonte de calor, maior vai ser a energia incidente sobre o material. O estudo foi feito considerando uma fonte pontual de calor. Além disso, é feita uma análise do tempo que uma estrutura feita do mesmo material levaria para atingir a temperatura de degradação, descartando seu uso posterior.

Aug 16, 2017

By Chonghe Li, Xionggang Lu, Wei Xiao, Xingli Zou, Weizhong Ding

The reduction degree and rate of the initial ilmenite concentrate and pre-oxidation samples by hydrogen were investigated by using thermogravimetric analysis system. H2-TPR was used to detected reduction properties of the pre-oxidation products which were oxidized at different temperatures. The phase transformations and micromorphology changes during pre-oxidation and hydrogen reduction were identified by XRD and SEM. The FeTiO3 was decomposed into TiO2 and Fe2O3 at the temperature below 900 oC. With the temperature rising, Fe2TiO5 was the only stable phase in high temperatures. The reduction of pre-oxidation ilmenite concentrate was faster than the natural sample, which was attributed to the micropores generated on the surface of ilmenite concentrate during oxidation. The main phases of the reduction product were metallic iron, ferrous pseuodbrookite.

Jan 1, 2014

By Hongshuang Di, Tianyu Zhang, Huiqiang Huang

A CMnSiAl transformation induced plasticity (TRIP) steel was used to study the effect of retained austenite on room-temperature mechanical properties. The steel plates with retained austenite were obtained by hot rolling, cold rolling and subsequent continuous annealing. The starting and finishing temperature of hot rolling are between Ac1 and Ac3. Reduction ratio of cold rolling is 75%. The continuous annealing is carried out at different intercritical temperatures. The relationship between work hardening exponent and retained austenite was discussed. The results show that, the Ac1 and Ac3 were much high because of the alloy elements, and the temperature range between them was wide. Due to the high hot rolling temperature, the grains was hereditarily refined as a result of dynamic recrystallization. Annealing at intercritical temperature of 930 ºC, retained austenite with relatively high stability reached a maximum volume fraction of 25%, a maximum total elongation of 30.2% and a best ultimate tensile strength × total elongation of 20.1 GPa·%. Instantaneous work hardening exponent reflects strengthening mechanisms at different strain stages. The TRIP effect of retained austenite is the main mechanism during deformation. With retained austenite of sufficient amount and high stability, continuous work hardening was observed in the tensile specimen of 930 ºC.

Oct 1, 2019

By Bingyi Bai, Wangjun Peng, Yanling Guo, Jieyu Zhang, Guoding Gao

The phase transformation of bayan obo ore with high concentration of iron and calcium was reduced at temperatures no more than 1000℃ were investigated in this study. The samples with insufficient carbon were treated at the temperature using a vertical furnace with a thermogravimetry (TG). The mineral phases and content were examined using Xray diffraction (XRD) and X-ray fluorescence spectroscopy (XRF) respectively. The complex phases of bayan obo ore transformed to some simple phases after treated with different content of carbon at the same temperature for 10 hours. The result of XRD、 XRF and TG showed that the reduction degree of Fe3O4 phase formation varied with the temperature and the carbon content of bayan obo ore.

Jan 1, 2015

By Walter Hartig

Rogesa is operating two medium sized Blast Furnaces, No. 4 and No. 5 at Dillinger integrated steel works plant. The history of the results of the cooling concepts of the intersection between tuyère belt and bosh shows failures at both furnaces. At the 3rd reline of No. 5 Blast Furnace in 2010 changes were made to improve the cooling efficiency of the mentioned area. Two rows of copper cooling plates were installed. After commissioning and a short operating time hot spots occurred in the area of the cooling plates. The decision was taken to develop a new cooling concept together with Paul Wurth Umwelttechnik GmbH, Essen-Germany by replacing the cooling plates by one row of a short copper stave. The duration of the shutdown to perform the work was only 17 days including salamander casting. The operational results after the commissioning are very satisfying with outstanding performance of the new bosh cooling system.

Aug 1, 2018

By Xiaolong Lin, Yuanbo Zhang, Jiann-Yang Hwang, Guanghui Li, Hongjin Zhang, Jiaxing Yan, Zhiwei Peng, Tao Jiang

The pollution caused by the spent printed circuit boards (PCBs) is currently a concern of researchers and environmental managers due to its large quantity and exceptionally complex properties. This study characterized printed circuit boards (PCBs) from discarded computers using a number of characterization techniques, including chemical analysis, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), granulometric analysis and scanning electron microscopy (SEM).The PCBs contain approximately 50 wt% metals, 25 wt% glass fibers and 25 wt% polymers. The principal metals include copper, calcium, tin, aluminum, zinc and lead. They are still wrapped by brominated epoxy resin after the PCBs are preliminarily crushed. As precious metals, such as gold and silver, are barely found in the PCBs, copper and tin are the main metallic elements of recycling value which warrants extra attention.

Mar 1, 2017

By Mariana M. Arantes, F. R. Valenzuela-Díaz, Olgun Guven, Vijay K. Rangari, Julyana Santana, Esperidiana Moura

Nowadays, the development of polymeric materials reinforced with residues of vegetal fibers is becoming popular for application in different segments, from the automotive to the civil construction and furniture industry. Vegetal fiber residues may be used as reinforcement of the recycled polymer materials, for instance, to produce foams to packaging or to thermal and acoustic isolation for green building application. This work is focused on the development and characterization of recycled-HDPE/EVA foam reinforced with fiber residues from babassu coconut epicarp. Firstly, composites based on recycled-HDPE/EVA blend reinforced with babassu coconut fiber were obtained by melting extrusion process. The composites were then extruded in a special single screw for foaming. The foam samples were submitted to mechanical tests, density measurement, DSC, TG, and FE-SEM analysis.

Mar 1, 2018

By Pan Gu, Zhen Zhang, Wen-Feng Tan, Jiang Diao, Bing Xie, Wang Zhou

In order to recover the chromium resource in chromium-containing vanadium extraction residue, a promising method is to prepare ferrochromium with the residue. The synthetic residue has been reduced under 1300, 1350 and 1400 °C at the reduction time of 1, 2 and 3 h respectively. The reduced samples have been smelted and separated by an induction furnace. The contents of chromium and iron in metallic phase have been determined by an inductively-coupled plasma spectrometer. The results indicate that chromium iron carbide (Cr, Fe)3C7 is the intermediate phase and titanium oxides have been reduced during the reduction process. While the sample has been reduced under 1400 °C for 3 h, metallic phase becomes the dominate phase and reduction reactions almost complete. Moreover, the chromium content in the metal phase reaches 10.19%.

Mar 1, 2017

By G. Coetzer

"Prior to operating a non-recovery coke pilot plant oven, it was essential to ascertain coal cake stability during the loading of a 1 m3 (1 m × 1 m × 1 m) coal cake into the cold pilot-plant oven by a pusher mechanism. Previously established laboratory-scale compaction parameters, to obtain coal cakes with sufficient stability, were employed during the loading tests of the coal cakes. Two different coals were evaluated, namely Waterberg semi-soft coking coal (sscc) and Oaky North hard coking coal.It was demonstrated that lower applied compaction forces (14%) can be utilized during 1 m3 compaction, in comparison to laboratory-scale tests, to obtain similar wet cake densities, owing to differences in the effect of frictional forces. Wet cake densities for Waterberg sscc improved slightly (3%) to 1.13 t/m3 when utilizing 79 t/m2 applied force for a 1 m3 coal cake, in comparison to laboratory-scale tests. Similar results were obtained for Oaky North hard coking coal, with a 6% density increase to 1.27 t/m3 at a similar applied force. Porosities decreased by 13% and 32% for Waterberg sscc and Oaky North coal, respectively, when 1 m3 compaction was compared to laboratory-scale tests. An opportunity exists to further decrease the porosities of Waterberg sscc during compaction, whereas acceptable compaction parameters were achieved for Oaky North hard coking coal. Most major vertical cracks and the partial collapse of coal cakes were mitigated, and high-stability coal cakes were obtained that could be successfully loaded into the pilot-plant coke oven by a pusher mechanism.Factors contributing to the instability of the coal cake during loading into the oven, such as vertical cracks, are (i) the cubic geometry (1 m3) of the coal cake, (ii) friction exerted by the oven floor, and (iii) mechanical problems, such as a misalignment between the pusher machine feeder plate and the oven floor. IntroductionOperation of the stamp-charging horizontal 1 t electrically heated coke pilot-plant oven at Exxaro Resources requires coal cake stability during the loading of a 1 m3 compacted coal cake into the oven. In this case, a pusher plate is utilized to push the coal cake into the oven over the oven floor. This is in contrast to a ‘spoon’ or bottom plate feeding mechanism as found in industrial horizontal coke ovens. The pusher plate loading mechanism dictates that the coal cake should possess high stability and inherent strength owing to frictional forces exerted by the oven floor. In order to obtain a coal cake of acceptable stability for the 1 t coke oven, various compaction parameters need to be verified and established."

Apr 1, 2019

By A. J. Kraemer

The twenty-fourth of a series of semiannual surveys pertaining to motor gasoline marketed in the United States was made by the Bureau of Mines in August, 1931. The first part of a report giving the results of that survey as they pertain to specification data is given in this paper. A companion report, Part II, is in preparation and will discuss the results of other determinations made on the samples, including octane number ratings on the individual samples (to be made by the Bureau of Standards) and results of the determination of gravity, color, doctor test, and "gum" content by the copper dish method and the Bureau of Mines steam-oven method. The retail price and the tax at the time each sample was taken will also be reported.

Jan 1, 1932