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By Sadegh Safarzadeh, Anne-Marie Suriano, Stanley Howard

The electrodeposition of metal ions from aqueous electrolyte solutions has been a well-known process for the last half century. With numerous industrial applications such as electroplating, electrowinning and electrorefining, the kinetics of electrochemical reactions involved in the process has been extensively researched. Arrhenius-type rate equations, the Butler-Volmer equation, and the empirical Tafel equation are among the most important models to explain the rate of electrochemical reactions. The study of the kinetics of metal deposition is critical to understanding the underlying mechanisms through which a certain morphology of metal deposit is formed on the cathode. The purpose of this paper is to elucidate the influence of experimental parameters such as pH and additives on the rate and the reaction mechanism determining the rate limiting step of the electrodeposition reactions.

Jan 1, 2015

By R. Padilla, M. C. Ruiz

Arsenic, antimony and bismuth are commonly found in copper concentrates usually as the minerals enargite, stibnite and bismuthinite, respectively. Concentrates having high levels of arsenic and antimony must be pretreated before smelting. Roasting is the preferred method for removing these toxic impurities from concentrates; However, the removal of As, Sb and Bi in oxidizing roasting by volatilization may not be complete due to the slow reaction rates at 500- 700 °C. Oxidizing/volatilization data were obtained from pure mineral mixtures and from arsenic rich copper concentrate. The reaction mechanism for the volatilization of arsenic and antimony were discussed. Near 100% As and over 95% Sb volatilized in the oxidation of a mixture of pure minerals at 700 °C, 1% oxygen, while over 95% As, and 35% Sb volatilized at 600 °C in 1% oxygen atmosphere when using a copper concentrate containing 3.51% As, 0.14% Sb, and 0.01% Bi. Bismuth did not volatilize.

Jan 1, 2015

By Syd S. Peng

According to accident statistics (l, 2), roof fall accidents occur quite frequently at the intersections of underground? openings and account for up to 30% of the roof fall fatalities. But this figure will certainly go up considerably if roof falls not associated with any fatal accident are included in the analysis. Unfortunately, nonfatal roof falls are seldom documented. In the underground coal mines, there are two types of entry intersections. One is the three-way (V type) and the other is the four-way (T type) intersections. A three-way intersection occurs whenever the mainline track haulageway turns at an angle into a section haulageway. The four-way intersections by far the most common type in the U.S. under-ground coal mines are formed by the intersections of two entries which are oriented perpendicular to each other or by the intersections of entries and crosscuts. However, crosscuts are frequently driven at an angle to the entry to facilitate machine movements. The four-way intersections formed by this method of crosscut development are angled. At the intersection of two underground openings, the diagonal roof span is wider than the width of each individual opening. This is one of the major reasons why roof falls occur more likely at the intersections than in the entry between pillars. Consequently, special intersection support plans are usually employed (Figs. 1 and 2) for intersections. The most popular practices are to decrease roof bolt spacing 1 ft. less than or to increase roof bolt length 1 to 2 ft. longer than those employed in the entry between pillars (3). The increase in bolt length or decrease in bolt spacing can be applied to all of the bolts in the intersection or employed only for the strategically located bolts depending on the individual mine practices. These rather generalized practices seems to be adequate for some areas but in many cases inadequate for others. Occasionally, the neighboring two lines of chain pillars are staggered such that the crosscuts in one row of chain pillars face the centers of the chain pillars in the neigh-boring rows. This layout forms T-type three-way intersections which are also inadequate for most weak roofs (3, 4). A study was therefore initiated to develop special techniques for intersection supports. The first phase of the study was the analysis of the stress fields for the underground entry intersections. A three-dimensional stress analysis was necessary for this purpose. Unfortunately, the three-dimensional problems of complicated boundary conditions are beyond the existing analytical methods. The three-dimensional finite element method (FEM) was therefore employed in this study. In the analysis, square pillars of 40 feet wide and an entry height of 8 feet were assumed while entry widths varied at 14, 20 and 26 feet. This model was selected to simulate the mine where roof falls data were collected. The second phase of the study was the collection of field data. The sizes of the roof falls including heights, lengths and widths were collected and analyzed. In the third phase study, the results of the first and second phases were compared and discussed. The analysis of field data revealed an arching zone within which roof falls occurred. The arching zone above an entry obtained empirically was compared with the calculated stress contours. Assuming that the bolts must be anchored in the rock strata outside the arching zone, the preferable systems of bolting were proposed. Also the amount of pretension required to inhibit sliding between layers was discussed.

Jan 1, 1978

Characterization of ore and waste-rock material using automated quantitative micro-mineralogical techniques (e.g., QEMSCAN® and MLA) has the potential to complement traditional acid-base accounting and humidity cell techniques when predicting acid generation and metal release. These characterization techniques, which most commonly are used for metallurgical, mineral-processing, and geometallurgical applications, can be broadly applied throughout the mine-life cycle to include numerous environmental applications. Critical insights into mineral liberation, mineral associations, particle size, particle texture, and mineralogical residence phase(s) of environmentally important elements can be used to anticipate potential environmental challenges. Resources spent on initial characterization result in lower uncertainties of potential environmental impacts and possible cost savings associated with remediation and closure. Examples illustrate mineralogical and textural characterization of fluvial tailings material from the upper Arkansas River in Colorado.

Feb 27, 2013

By L. K. Marshall

The importance of high quality underground mine ventilation is readily apparent. The principles of primary and auxiliary mine ventilation, however, are sometimes less readily apparent. The first article in this two-part series discusses some general aspects of primary and auxiliary ventilation. Next month's article will detail considerations involved with auxiliary mine ventilation.

Jan 1, 1982

By Wm. Moorhead

Safety Measures Employed at the Dawson Mines Preventive measures for eliminating and localizing explosions is a subject of special interest to Coal Mining operators at the present time. I shall endeavor in this paper to present the practical methods which have been developed at the mines of the Stag Canon Branch of the Phelps-Dodge Corporation, Dawson, New Mexico. Adobe Dusting Adobe is used for practically all dusting on the main haulage roads. It is obtainable in sufficient quantities adjacent to the mines. Loaded into railroad cars by a clam-shell loading crane, and transferred to the mine pit cars at the nearest available point, it is readily distributed along the motor roads by means of the mine locomotives. Of first consideration for adobe dusting is the preparation of the roadway. It is essential that all loose coal and dust be removed, at least to a depth of three or four inches below the top of the rails. The adobe, in a more or less moist condition is unloaded by hand from the pit cars and stored along the previously prepared roadway, to be later scattered to a depth of several inches over the floor, and over the ribs and roof such as is possible by the use of a shovel. The adobe soon loses its moisture and becomes pulverized. Due to the disturbance caused by passing motor trips, men and animals, the dust is effectively scattered along the ribs and roof of the roads. The velocity of the intake air aids materially in sustaining the suspension of this inert matter. Another scheme for distributing the fine dust in use is to chain the top of a pine tree to the rear of the trips, both empty and loaded. Dragging it along the motor roads stirs up the dust and aided by the intake air it is carried for long distances into the workings. The adobe is continually loosened and raked, all rock, coal, etc., being collected in piles and later loaded out in pit cars. One man is employed for each six thousand feet of entry. Dusting Main Return Air-Courses The air-courses are first thoroughly cleaned. All the loose coal and rock is loaded out, the ribs and roof washed down several times. Every five or six hundred feet, the stoppings between the main and return entries are broken through and small doors installed. Blowers are used to force the fine dust into the return air-courses through these openings. Thus suspended the dust travels a considerable distance before it is deposited on the floor, ribs and roof. The material used is chiefly adobe, sun dried, and screened on the outside. A two ton car load of this dust will cover several hundred feet of airway as very little loss occurs, often depositing from 2 to 6 pounds per running foot of entry. Methods of Insertion Blowers are used to force the dust into the main returns. One unit consists of a small Buffalo blower mounted on a truck with a two H. P. motor. A six-inch pipe is attached to the blower and runs the full length of the truck with a projection over the end. A hopper is built over the pipe and connected. Stove pipe or canvas tubing is led from the pipe through door in stopping. When the blower is started dust is fed into the

Jan 1, 1924

By Aimee Williamson

Bio-mining is a cost-effective, energy efficient and potentially environmentally protective method of exploiting a variety of ore deposits, from high-grade base metal deposits of nickel to lower-grade uranium deposits such as are found in the uraniferous quartz-pebble conglomerate beds of the Quirke Syncline, Elliot Lake, Ontario, using bacterial metabolic processes are used to enhance the solubilization of the metal(s) of interest. The cost effectiveness of bio-mining in Elliot Lake depends on the bacterially-influenced dissolution metals of economic importance, as well as on the ability to suppress microbiological activity following the release to solution of the economically important elements. This poster provides an overview of elemental recovery results and release kinetics for more than 50 elements. The data is obtained using a combination of advanced spectroscopic tools (ICPAES and ICP-MS) to analyze solutions obtained from a series of environmentally controlled biologically mediated uranium ore extraction experiments. The focus will be on rare earth elements, potential environmentally toxic elements, and metals of economic importance. Furthermore, the importance of these findings will be put into an economic and geologic context for the re-development of the mining industry of the Elliot Lake Camp.

Aug 1, 2010

By O. P. Hood

.NONE of the methods now in use for the transportation of materials underground is entirely free from more or less serious objection. The great flexibility, ease, of control and economy of operation of electric tramming are accompanied by the serious menace of a trolley-wire distributing system. As the gasoline locomotive has even greater flexibility of application and requires no similar dangerous distributing system, it might be considered a safety device which would make possible the elimination of the dangerous trolley system were it not possessed of other objectionable qualities peculiar to itself. It is found that the exhaust gases from the engine may be injurious to the health of those breathing the air in which the locomotive has been operating. While electric shock may kill the individual who makes contact with uninsulated parts, the gasoline engine may be detrimental to the health of all those who have to work within the atmosphere corrupted by exhaust gases. The degree of pollution meas-ures the magnitude of the menace. This may be negligible at times, but with careless operation it becomes serious. The exhaust gases from an engine are composed of, nitrogen, a little free oxygen, hydrocarbons, hydrogen, carbon monoxide, and carbon dioxide, the last two being considered dangerous. The presence of carbon dioxide as a product of combustion of the gasoline was recognized as an objection from the beginning of the use of these machines, but attention was called to the fact that the amount produced was relatively small as compared to that from other sources of this gas, and it was not likely to be made in dangerous quantities. The effect of carbon dioxide, except in relatively large percentages, is confined to the effect it may have in reducing the oxygen content of the air that is breathed.

Jan 10, 1914

By Enver Alan

This Research & Development (R&D) study was conducted in the field of applied blasting engineering in Ethiopia, within the AKH Railway Project, which was built in Girena, within the boundaries of the province of Mersa, in the Basalt Quarry at km 346, Ashangi Formation, occured in Eocene geological time in the aphanitic trachibasalt.

Feb 1, 2020

By F. Dingwu

The demand of manufacturing high-purity magnetite concentrate leads to the advent of various magnetic separators. A novel magnetic drum separator has been developed with an optimal permanent magnet system and a complex-forces field is adopted, involving magnetic force, gravitation, fluid resistance, friction, inertial centrifugal force, etc. Proper ultrasonic probes are inserted into the bottom tank to break up the magnetic floes. The performance of magnetite in the complex-forces field is described and the optimal operation conditions are suggested.

Jan 1, 1995

By Robert H. Ridgway

Scrap iron and steel attracted attention during 1937 because of the unprecedented exports and the concomitant agitation in some quarters to prohibit the exportation of this essential raw material except on license by the President. This report does not attempt to analyze the statistics given in the light of the controversy over the limitation of scrap exports, but it is believed that students of this problem will find many essential basic data in the various tables presented herein. This paper presents the results of the third in the series of annual canvasses on the consumption of ferrous scrap and pig iron in the United States. The study was inaugurated in 1935 by the Bureau of Mines in response to requests from trade organizations and others for detailed

Jan 1, 1938

By I M. Platten, Y Xie

Sampling protocols that are designed to suit the mineralisation style will result in a reduction of the nugget effect and hence resource risk. The a priori need for all sampling programs is the effective characterisation of the mineralisation type(s) to support optimisation. This requires a program of sampling for sampling followed by holistic characterisation. At each end of the coarse-gold to fine-gold spectrum, the samplability of a deposit ranges from relatively simple for fine-grained disseminated gold particles, through to extremely difficult for coarse nuggety mineralisation. Many deposits contain a proportion of both particle size types. The proportion and size of coarse gold particles has a direct impact on the effectiveness of sampling, where coarser particles will require larger samples and more specialised protocols. The nature of mineralisation geology/mineralogy and associated gold particle sizing can only be determined by sampling to facilitate optimised protocols. Mineralogical studies, focusing on particle size, particle clustering and distribution in host minerals, are required as part of wider paragenetic and metallurgical investigations. This paper discusses the role of mineralogical studies in the characterisation of gold ores for sampling optimisation through a series of case studies.

Jan 1, 2008

By P. D. R. Maltby

This paper describes the background and markets for calcium carbonate and silica sand in Canada, as well as the results of recent test work carried out at the Ontario Research Foundation. Tests on sericite, tremolite, vermiculite, barite and graphite are also mentioned.

Jan 1, 1979

By Geovane Viturino da Silva, Jeziel de Melo Canedo, André Wulff Hirano, Maxwell Pereira Cangani, Luiz Henrique Curado Ribeiro

With the deterioration of the quality of the iron ore, the new conditions of quality of the raw materials (mainly sinter feed) were adapted to their processes, resulting in the need for changes in the chemical quality of the sinter for blast furnaces in the Ternium Brazil, without changing the parameters of chemical, physical and metallurgical quality. Due to the change in this scenario, there was a great impact on the quality of the fine iron ore this year in 2019, due to which the work ranges of sinter MgO and B2 were currently modified to minimize these impacts in the blast furnaces of Ternium Brazil. This work aims to minimize the effects of the sinter worsening, with the reduction of the sinter MgO and B2 bands, with an increase of 2% in the mixture yield and FeT elevation in the range of 1.6% in the sinter product.

Oct 1, 2019

By A. J. Strazisar

The Bureau of Mines conducted a laboratory investigation to study the effectiveness of low-pressure steam and water spray in suppressing respirable dust at the tips of a saw-type cutting wheel. Suppression efficiencies were found to be proportional to the amount of the water or steam applied at the cutter tips. For equivalent water output rates, a maximum efficiency of approximately 80 percent was reached for both steam and water spray. Results from the steam and water spray tests showed an increase in suppression efficiency with an increase in particle size of 1 to 8 micrometers. The data indicate no advantages for using steam as a dust suppressant.

Jan 1, 1972

By Licheng Zhou

The use of aquatic plants for the removal of heavy metals from wastewater has gained high interest. In this study, batch experiments were conducted to evaluate the adsorption of copper ions in aqueous solution by P. pectinatus L. under various conditions of contact time, initial pH of the solution, metal concentration and adsorbent dosage. The results showed that the maximum adsorption amount of copper ions by P. pectinatus L. was 22.60 mg/g when the initial copper ions concentration was 98.41 mg/L at pH 4.5. The Langmuir and Freundlich models were used to describe the adsorption equilibrium of copper ions on P. pectinatus L. and the adsorption followed the Langmuir isotherm. The adsorption kinetic was well-fitted with pseudo-second-order sorption equations.

Jan 1, 2009

By Z. G. Li

The large-scale vibrating screen has been applied widely in coal industry and other industrial areas as a kind of important device. As vibration mechanical device, it works very hardly and works in very bad environment so that the structure of screen is damaged easily. Therefore, it is very important that how to detect the fault of structure as early as possible to make the repair schedule reasonably and economically and to avoid the body hurt and device damage. As a kind of important structure of vibrating screen, the lower crossbeam is the main carrying structure and it is easily damaged, so it is regarded as a researched object in this thesis and it is tested under the load in the laboratory. Based on the test, acoustic emission wave signals can be got-ten by modern acoustic emission testing technique. Then, the ?wavelet packet - energy? from the characteristics of acquiring signals is used as neural network input vector. In the BP network structure design, the design of a hidden layer with variable number of BP network is established. Based on the error by contrast, the best nerve number can be identified in the hidden layer. Through integrated analysis, using Levenberg-Marquard BP study algorithm, network-training errors are relatively small, the acoustic emission signal is used in BP neural network as a pattern of recognition. In Matlab6.5, neural network model identification is created and taking advantage of nonlinearity and the ability of learning and memory of Neural Network, this model is fixed by training structure of network with training samples. The work presented shows that acoustical emission signal processing and research on early fatigue fault diagnosis based on the wavelet and the neural network is viable.

Jan 1, 2014

By Gaifeng Xue, Xiaohong Xu, Meng Liu, Yijie Song, Guotao Xu, Jixiong Liu

BN (Boron Nitride) based composites were prepared with hot-pressing by using h-BN as main material in ceramic preparation process. The relative density, bending strength, vickers’ hardness, thermal shock resistance, thermal expansion coefficient, thermal conductivity, phase composition and microstructure were tested and analyzed by using modern testing technology. The results indicate that the best formula is B, the relative density is 97%, the bending strength is 260 MPa, the hardness is HV5 343kg/mm2, the thermal expansion coefficient is 2.8×10-6℃-1, the thermal conductivity is 22 W/(m.K) and have no crack after thermal shock for 20 times by water cool. XRD analysis indicates that the main phase compositions are h-BN, β-Si3N4 and sialon. SEM studies show that the grains wrapped up by solid solution.

Jan 1, 2015

By S Raval

The estimation of greenhouse gas emissions from coalmines is increasingly becoming a priority for both operators and regulators. At the same time, involved scientific challenges in the methane measurements is generating significant interest from global research community. Various technology providers are also actively engaged in improving their sensors and platforms to address the measurement challenges and capitalise the market opportunities. This presentation highlights rapidly evolving multifaceted landscape of coalmine greenhouse gas emissions. It covers the advances in sensors for the detections, including ground-based, airborne, and satellite-based systems as well as models for the emission estimations, including attempts to reduce the involved uncertainties.

Sep 1, 2024

By Martin B. Hudson, Andrew K. Cho, Rolff B. Knobel, Les R. Chernauskas, Jonathan L. Ernst

ABSTRACT The Bruce Museum, located in Greenwich, Connecticut, is home to an extensive display of art and natural history exhibitions. A large addition was designed to be constructed adjacent to the museum requiring new spread footings to be installed up to 16.5 feet below the existing foundations. The soil conditions at the site consist of highly variable sand and gravel overlying weathered rock and sound bedrock. The Contract Documents called for traditional foundation underpinning. Traditional underpinning techniques, however, presented two major challenges on this Project; (1) deep underpinning pits would be required involving multiple levels and staging with tieback support and (2) the highly variable soil and bedrock composition and elevations presented uncertainty in the design and construction of the pits. In lieu of traditional underpinning, Geosciences Testing and Research, Inc. (GTR) proposed an “active” soil nail underpinning system. A major reason that the soil nail underpinning option was feasible, related to the fact that the soil nails and facing could be installed slightly in front of the existing footings rather than directly underneath the existing footings. The soil nail wall design involved one to four rows of soil nails with nail positions and wall depth able to be adjusted “on the fly” as excavation progressed depending on the field conditions encountered. To create the “active system,” the soil nails were pre-loaded to mitigate wall deformations that would be associated with a standard passive soil nail wall design. To evaluate the performance of the active soil nail wall and confirm design assumptions, an extensive automated monitoring, on-site testing and inspection program was proposed and executed by GTR to monitor deformations of the wall and the museum in real-time, evaluate and confirm bedrock and soil bond stresses and ensure that each soil nail was pre-loaded and locked off. Careful analysis, planning, and use of the observational method illustrates the importance of collaboration between design and construction personnel and applying engineering judgement throughout construction. The use of the observational method includes the potential for modifying design based on conditions observed. This paper presents a unique case study of the “active” soil nail underpinning system to support and protect sensitive structures, close collaboration between design and construction facilitated by real-time deformation monitoring, and its successful application as a safe and cost-effective alternative to traditional underpinning.

Oct 1, 2022