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By L. Zhang, Y. Zhou, H. Wang, C. Mo

Fluorination of magnetite (Fe₃O₄) by NH₄HF₂ was investigated using simultaneous thermogravimetry and differential thermal analysis (TG-DTA), and observing the morphology and phase changes using scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS) and X-ray diffractometry (XRD). The results indicate that fluorination with the involvement of oxygen begins at room temperature, peaks at 178.40C, and is completed at 2000C with the formation of only (NH₄)₃FeF₆. On heating, (NH₄)₃FeF₆ gradually releases NH₄F by the formation of NH₄FeF₄ at 2590C, then (NH₄)0.18FeF₃ at 3270C, and finally FeF₃ with minor FeF₂ at 4000C due to the partial reduction of Fe (III) to Fe (II). At 5500C, FeF₃ is oxidized to FeOF/Fe₂O₃.

Dec 13, 2022

By S. Fazluddin, K. C. Sole, M. R. Serwale, T. Coetsee

The CSIR-Ti process employs lithiothermic reduction of titanium tetrachloride feedstock to produce titanium sponge. The product is therefore contaminated by a range of lithium and chloride species. In this study we examine the effects of particle size, temperature, and HCl concentration as input leaching variables on the removal of chlorides from the crude titanium sponge. A review of the aqueous chloride chemistry of Li and Ti provided initial conditions for leaching of impurity species from the sponge. Experimental results confirm that the effectiveness of leaching and removal of dissolved impurities from the sponge are dependent on leaching kinetics, which are influenced by temperature, particle size, and morphology. Of the variables tested, reaction temperature had the strongest influence on the oxygen content of the leached product. The HCl lixiviant concentration had a negligible effect under the conditions tested. Leaching of crude titanium sponge (−10 mm size fraction after crushing) at 14°C in either 1 M or 0.032 M HCl yielded a titanium sponge product that met the ASTM standard specification for commercially pure Grade 1 titanium, i.e., oxygen content < 0.18 mass% and chloride content < 0.15 mass%.

Dec 13, 2022

By M. Mathey

The application of the Monte Carlo technique to production planning and everyday economic decisionmaking in mine production management is demonstrated. The logic is detailed using an example of underground production with continuous miners (CMs) and truck haulage. It is argued that availability of equipment and personnel are the predominant variables influencing mine output and productivity and that those availabilities may be well represented by binomial probability distributions. The probabilistic model is implemented in a standard Excel® spreadsheet with Palisade’s @Risk add-on to facilitate simulations. Starting from model calibration against data obtained from a mine’s annual reports, some general interdependencies of availability, utilization, productivity, and costs of production processes are outlined. Finally, several possible options and their consequences as regards production improvements are explored.

Dec 13, 2022

By M. L. Pududu, B. Ceki, K. Mohajane

This study was aimed at determining the effects of industrial action on profitability in the South African platinum mining sector. We compared companies where employees engaged in industrial action (affected companies) to strike-free companies (competing companies). Industrial action refers to strikes by rockdrillers, as these strikes typically result in the shutdown of production at the mines affected. A t-statistics analysis of significant differences in revenue and earnings of affected and non-affected platinum companies was conducted using data from platinum mining companies listed on the Johannesburg Stock Exchange from 2011 to 2015. Contrary to international studies, which suggest that the spillover effects of industrial action positively affect competing companies, our findings show that profits in the platinum sector decrease significantly during strike periods for both affected and competing companies. The results indicate industrial action is a threat to the profitability of all companies, and that employee demands should be prioritized and negotiated before they result in industrial action. Improved dialogue between management, labour unions, and employees in the platinum mining industry is recommended. The study contributes to the scanty literature on the effect of industrial action on the profitability of mining companies in a developing economy.

Dec 13, 2022

By M. S. Shishvan, J. R. van Duijvenbode

The results of dig limit delineation in open pit mining are never truly optimized due to gaps in the underlying data, such as insufficient sampling. Aside from the data uncertainty, there is also an influence on the final dig limit by either humans or by the heuristic character of an optimization method like simulated annealing. Several dig limit optimizers have been published, which can replace the manual dig-limits designing process. However, these dig limit designs are generally not adapted to account for this heuristic character. In this paper we present a stochastic analysis tool that can be used with the results of heuristic dig-limit optimization to increase confidence in the obtained results. First, an enhanced simulated annealing algorithm for dig limit optimization is presented. Then, this algorithm is tested on ten different blasts at the Marigold mine, Nevada, USA, as a case study. Finally, the results are analysed with a destination-based ensemble probability map and an analysis conducted of the final solution data distribution. The generated dig-limit designs of the algorithm include high revenue areas that are excluded in comparable manual designs and show improved objective and revenue values. The analysis tool provides block destination probabilities and box plots with the distribution of opportunity value for the dig limit. Furthermore, with the analysis tool, it is possible to make well-informed design decisions in areas of uncertainty.

Dec 13, 2022

By Serhat Özdemir, Derya Öz Aksoy, Pınar Aytar Çelik, Ahmet Çabuk, Sabiha Koca, Hüseyin Koca

In carbonate flotation, oleate has been used for many years as a collector in industrial scale. Compared to sulfide minerals, the flotation of carbonate minerals requires more collector consumption and has lower yield and selectivity. It has been previously shown that surfactin provides higher yields in smaller amounts than oleate in the bioflotation of calcite as one of the carbonate minerals. In this study, the usability of surfactin as a flotation collector for magnesite was investigated. For this purpose, the adsorption of surfactin on the magnesite surface was inspected with analyses such as FTIR, SEM–EDS, contact angle, and zeta potential measurements. In addition, the effect of surfactin on the surface tension of water was also revealed. The same analyses were also performed for oleate as a reference point. All flotation experiments were performed without optimizing with both collectors. FTIR results showed that the surfactin, like oleate, was chemically adsorbed on the magnesite surface. Surface tension analyses showed that the surface tension of water decreased to approximately 32 N m− 1 at 10− 4 M oleate concentration, and this value decreased to below 25 N m− 1 at the same surfactin concentration. According to contact angle measurement results, the contact angle of magnesite was 85° after the surfactin adsorption of 2 × 10− 4 M concentration, while this value remained at 46° for oleate. Finally, according to flotation experiments, high temperatures and high collector dosages are necessary for acceptable flotation recovery with oleate, yet surfactin can produce the desired result at ambient temperatures and lower collector amounts.

Dec 13, 2022

By Hai Lin, Renshu Yang, Yongliang Li, Shizheng Fang

With the aim of solving the large deformation problem of surrounding rock in coal mine roadways with a thin sand-mudstone interbed roof, transportation roadway 1603 in Haoyuan Mine was considered. The failure mechanism of surrounding rock was studied through comprehensive on-site investigations, borehole image analysis, mineral composition analysis, and other means. Numerical simulations were performed to determine the influence of roof layer thickness, lateral pressure coefficient, and coal rib strength on the stability of the interbedded roof. The main reasons for support failure and deformation of the roadway are softening and swelling of the sand-mudstone interbed roof upon exposure to water, insufficient support capacity of the roof due to the soft coal rib, an unreasonable support scheme, or poor construction quality, which can reduce the bearing capacity of surrounding rock. Based on our analysis, a control strategy was devised for a thin coal-mudstone interbed roof. The support scheme combines long and short cable support, strengthening of the coal rib to consolidate the roof, and partially shotcrete grout, and was found to improve the overall mechanical strength of surrounding rock and maintain the stability of the thin sand-mudstone interbed roof. The results of the numerical simulations and monitoring data indicated that the proposed support scheme effectively controls the deformation of the surrounding rock of thin sand-mudstone interbed roof of coal mine roadways while maintaining the safety and stability of the surrounding rock and supporting structure.

Dec 12, 2022

By Abdelaziz Baçaoui, Imane Aarab, Abdelrani Yaacoubi, Khalid El Amari, Abderahman Etahiri

Phosphate ores upgraded by flotation are widely used as vital raw materials for the sustainable production of phosphate fertilizers to maintain the food supply. High-grade phosphate reserves become more and more depleted. Low-grade phosphate mining and processing are in the spotlight of the fertilizer industries to cope with the exponential growth in the world’s population and meet the increased demand for fertilizers. As part of a series of research works conducted within a major project aiming at upgrading a low-grade phosphate ore never-exploited before, the present work endeavors to optimize the flotation of this ore using the response surface method (RSM) as a follow-up of a screening study. Unveiling new insights on such a strategy paved the way for improving flotation performances. This work demonstrated that an optimum 30.18% P2O5 with 88.07% recovery was achieved using 63.10 g/t of sodium alginate (NaAL) and 2484.72 g/t of sodium oleate (NaOL) at pH 11.40. This maximum was contrasted with a new formulation of fatty acids (FAM). The 30.76% P2O5 grade with a recovery of 89.72% was attained using 50.94 g/t of NaAL and 1455.40 g/t of FAM at pH 11.68. FAM collector markedly outperformed NaOL at low concentrations proving the efficiency of synergists.

Dec 7, 2022

By Ma Lianren, Wang Duolun, Chenzhe Li, Hongyan Xie, Fenglan Luo, Huixin Jin

In this study, the oxidation of low-grade pyrolusite to potassium manganate in alkaline solutions under O2 pressure has been investigated. The effects of different conditions on the high-grade and low-grade pyrolusite leaching process were investigated based on thermodynamic calculation, as well as the reaction mechanisms and kinetics of the low-grade pyrolusite during the leaching process. The results showed that the manganese conversion rates of the two types of pyrolusite were almost the same, and reaching 99% for high-grade pyrolusite and 96% for low-grade pyrolusite under optimal conditions. The optimum condition for low-grade pyrolusite sample JM-2 was achieved as 0.5 MPa of the oxygen partial pressure, 55% of KOH, 14 of the initial alkali-manganese ratio, and ≤ 48 μm of the mineral granularity at 260 °C within 150 min of leaching time and 500 rpm. In alkaline leaching of low-grade pyrolusite, Mn(IV) was oxidized into Mn(VI). The particles changed from large particles to flakes and finally formed crystals. Finally, the shrinking core model was used to fully describe the leaching kinetics of the manganese. It was demonstrated that the leaching of manganese was controlled by the chemical surface reactions and the activation energy which equals 115.9121 kJ/mol.

Dec 3, 2022

By S. Klein, M. McLeod, K. Johnson

The East Bay Municipal Utility District (EBMUD) delivers water to the San Francisco Bay Area through an aqueduct system extending from the Sierra Nevada Mountains to the East Bay. This aqueduct system, the Mokelumne Aqueducts, are comprised of three 82-mile long steel pipelines. The portion of the aqueducts crossing the Sacramento-San Joaquin River Delta is recognized to be vulnerable to seismic and flooding hazards. Previous studies evaluated alternatives for mitigating these hazards and increasing the reliability of the aqueducts for the next 100 years. The preferred solution involves construction of a 16.5-mile tunnel across the Delta and re-routing the existing aqueducts through this tunnel

Dec 1, 2022

By Anuradha Khetwal, Tala Tahernia

The estimation of TBM utilization rate can be problematic due to the uncertainty involved in the tunneling system reaction to various geology along the tunnel. Moreover, the impact of operational and management issues on TBM performance is unsettled. This includes the occurrence and duration of downtimes and the uniqueness of projects relative to the geology, machine type, backup system, site setup, crew experience, and operational restrictions imposed on the project by localities. The CSM2020 is a model based on discrete event simulation that predicts machine utilization for single or double shield TBM. This model was developed by the Earth Mechanics Institute (EMI) team, using the database of tunneling activities which was compiled based on field observation and measurements in pertinent projects. In the current study, CSM2020 was modified to simulate the workflow of slurry TBMs. The operating principle of slurry shield TBMs is different than open-mode TBMs. The model was verified by comparing results with a recently completed project in the United States. As a result, the model offers reliable utilization rate estimation in different types of TBM by implementing appropriate workflow.

Dec 1, 2022

By Irwan Halim, Young Jin Park

A new tunnel lining was designed for rehabilitation of the existing unlined Weehawken Tunnel in New Jersey. Structural assessment using beam spring models was performed for the lining design as a drained structure at the invert with a waterproofing umbrella. Empirical Federal Highway Administration (FHWA) guideline was typically adopted for estimating hydrostatic pressure, which recommends full hydrostatic pressure at the crown and ten or twenty-five percent gradual reduction from the initial pressure toward the invert. Finite element seepage analyses were conducted for the actual conditions based on anticipated drainage behind the lining and impact on the structural design. Considerations will be provided on the existing guideline for estimating hydrostatic pressures.

Dec 1, 2022

By Adam Bedell, Brad Crenshaw

Tunnel project contract documents often present groundwater infiltration requirements for components of the underground portions of the project. All too often these documents require quantifiable target inflows for these components, but only refer to them in subjective terms such as “dry,” “manageable,” etc. The Contractor’s definition of these terms will inevitably differ from the Engineer’s definition of these terms. The purpose of this paper is to look at common subjective terms used in documents and provide suggestions for reasonable quantifiable language. Additionally, the paper will provide information and recommendations on relative levels of cost and effort increase needed to provide increasing levels of water cutoff (i.e., achieve “dryness”?).

Dec 1, 2022

By Cory Dippold, Michael Mett, Jérôme Steinkühler, Kristi Latimer

For decades, tunnels of all types have been a significant part of our infrastructure. In particular, water tunnels carry millions of gallons of fresh water every day to major metropolitan areas and surrounding communities. As a critical piece of public health infrastructure, it is important to inspect the condition of these tunnels regularly to ensure reliable and continuous operation. A specific challenge with water infrastructure is that it’s often difficult or impossible to shut down the system for long periods of time to perform the needed inspections. The latest method of tunnel condition assessment is the use of hybrid reality 3-D scan data. Photogrammetric and LiDAR based 3-D data ensure a reliable and objective view of tunnel conditions. The data can be used to support a detailed digital inspection including the compilation of databases that consist of a wide variety of deficiencies such as cracks and spalls within the structure. Mott MacDonald, a design engineer company worked closely with Dibit, used a 360-degree scanning system to collect high-resolution photogrammetric and LiDAR data on a recent project involving a water tunnel. The allows for full 360-degree coverage of the tunnel surface including a water covered invert. It operates at walking speed and ensures a fast and reliable data acquisition which can reduce the time of tunnel shutdowns. Several allocated inspection weeks can reduce to few days, with the final work product being a higher quality and more complete deliverable than traditional inspection methods would have provided. The true-color 3D-model has a photo resolution of 1 × 1 mm (0.039 × 0.039 inches) which makes cracks visible with a width of down to 0.3 mm (0.011 inches). The assessment of water tunnels, its technical challenges and the results of the 3D-tunnel inspection case study are illustrated and described in this publication.

Dec 1, 2022

By Milton Gomez, Nico Sutmoller

Low-density cellular concrete (LDCC) was first introduced to the market in the early 1900s and since then has made continuous technological advances. There are two primary types of LDCC: permeable and non-permeable. Both types of cellular concrete offer advantages in different types of geotechnical engineering applications. Because of its unique characteristics of low density, high compressive strength, and high fluidity during placement, LDCC offers an effective solution for a wide variety of engineering applications, and in many cases provides a more cost-effective, labor saving alternative to traditional fill materials. This paper will review the history, characteristics, and technological advances of LDCC, highlighting multiple real-world case studies that showcase the high-performance capabilities of both permeable and non-permeable LDCC.

Dec 1, 2022

By Wern-ping N. Chen

Pressure tunnel includes water-supply tunnels and tunnels for hydroelectrical power plants. Their design principles are different from those of water/wastewater/conveyance and transportation tunnels. Though theoretical pressure tunnel design guidelines exist, a comprehensive guide to summarize these guidelines to facilitate the planning and design of a pressure tunnel program is lacking. The purpose of this paper is to fulfill this need. It first provides key pressure tunnel design concepts in hard rock environment; then, it illustrates associated final lining design principles, including the design of un-reinforced concrete lining, steel lining, and reinforced concrete lining. Design diagrams and a flowchart for the reinforced concrete lining design are provided.

Dec 1, 2022

By Charles Stone, Eric Wang

A method for estimating geotechnical rock loads for shallow cut and cover subway stations is presented. Localized geotechnical conditions lead to extreme variations in rock loading on the walls of subway structures. Actual lateral rock stress on these structures can range from near zero to over four times the vertical in-situ rock stress. The primary factors affecting the actual lateral stress are intact and rock mass mechanical properties, excavation sequence, localized tectonic conditions, and potential future adjacent structures. The authors recommend using the AASHTO code value of 65 pounds per cubic foot (10 kN/m3) during concept design, followed by numerical analysis of rock wedges and stress measurement for final design.

Dec 1, 2022

By Christopher Nelsen, Daniel Dobbels, R. Zachary Hollenbeck

Recent major floods have inundated Historic Ellicott City, Maryland, resulting in loss of life and property damage. Howard County, Maryland, has developed the Ellicott City Safe and Sound Plan to mitigate the risk of flash flooding in the Historic District, including a proposed stormwater conveyance tunnel. Challenges to overcome include thick zones of saprolite along the alignment, multiple near-surface structures, and minimal rock cover under an active railroad, while minimizing impacts to the public and historic structures. The project will also pursue recognition through the ISI Envision verification process.

Dec 1, 2022

By Silas Li, Michael Harris-Gifford, Jason Choi, William H. Hansmire

Twin-bore tunnels with a single track in each tunnel are currently the most common subway tunnel configuration. However, a large diameter single-bore tunnel with two tracks separated by a center wall could replace twin-bore tunnels and introduce potential benefits but require necessary modifications to the subway system. In particular, a nominal 40-foot-diameter single-bore tunnel can be considered in lieu of nominal 20-foot-diameter twin-bore tunnels. This paper discusses the benefits and modifications introduced by replacing twin-bore tunnels with a single-bore tunnel, with respect to various elements of the subway related to the tunnel, stations, track, and tunnel systems.

Dec 1, 2022

By Kexin Cai, Isidro Rivera, Shawna Von Stockhausen, Maria Chastka, Kevin Huynh

The Newell Creek Dam Inlet/Outlet Replacement Project is located approximately 11 miles north of Santa Cruz, California along Highway 9 in the San Lorenzo Valley. This project will replace the existing inlet/outlet works at the Loch Lomond Reservoir by constructing a tunnel using conventional excavation methods while simultaneously drilling three intake shafts to intercept the tunnel from within the city’s water supply. This project will improve the system’s overall operational efficiency and performance, and provide a safe and reliable facility for the City of Santa Cruz’s drinking water supply. This paper discusses the overall project configuration, construction observations, and challenges during construction, including tunnel excavating through the marine sedimentary siltstone of the Monterey Formation, probing and pre-excavation grouting, and the tools utilized to manage the project.

Dec 1, 2022